Acetona-Metanol

1800

1700

1600

1500

x2
P mmHg

1400
y2

1300

1200

1100

1000
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x2, y2
 Acetona-Metanol
1800

1700

1600

1500
P mmHg

1400 x1
y1

1300

1200

1100

1000
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x1, y1
 K °C
T 333.15 60
V cm3/mol
1 Pv acetona mmHg 866.62707 74.05
2 Pv metanol mmHg 633.740984 40.73
R 1.9872 cal/mol*K �_1=1/(𝑋_1+𝐴_12∙𝑋_
Ecuacion de Wilson (�_1+�_12∙�_2 )−�_2
�_2=1/(𝑋_2+𝐴_21∙𝑋_1
(�_1+�_12∙�_2 )−�_21
cal/mol
T °C X1 X2 P1 P2 Λ12 Λ21
60 0 1 866.62707 633.740984 -161.88 583.11
60 0.002 0.998 866.62707 633.740984 -161.88 583.11
60 0.008 0.992 866.62707 633.740984 -161.88 583.11
60 0.01 0.99 866.62707 633.740984 -161.88 583.11
60 0.012 0.988 866.62707 633.740984 -161.88 583.11
60 0.014 0.986 866.62707 633.740984 -161.88 583.11
60 0.016 0.984 866.62707 633.740984 -161.88 583.11
60 0.02 0.98 866.62707 633.740984 -161.88 583.11
60 0.04 0.96 866.62707 633.740984 -161.88 583.11
60 0.08 0.92 866.62707 633.740984 -161.88 583.11
60 0.1 0.9 866.62707 633.740984 -161.88 583.11
60 0.15 0.85 866.62707 633.740984 -161.88 583.11
60 0.2 0.8 866.62707 633.740984 -161.88 583.11
60 0.25 0.75 866.62707 633.740984 -161.88 583.11
60 0.3 0.7 866.62707 633.740984 -161.88 583.11
60 0.4 0.6 866.62707 633.740984 -161.88 583.11
60 0.45 0.55 866.62707 633.740984 -161.88 583.11
60 0.5 0.5 866.62707 633.740984 -161.88 583.11
60 0.6 0.4 866.62707 633.740984 -161.88 583.11
60 0.65 0.35 866.62707 633.740984 -161.88 583.11
60 0.7 0.3 866.62707 633.740984 -161.88 583.11
60 0.75 0.25 866.62707 633.740984 -161.88 583.11
60 0.8 0.2 866.62707 633.740984 -161.88 583.11
60 0.82 0.18 866.62707 633.740984 -161.88 583.11
60 0.86 0.14 866.62707 633.740984 -161.88 583.11
60 0.88 0.12 866.62707 633.740984 -161.88 583.11
60 0.9 0.1 866.62707 633.740984 -161.88 583.11
60 0.92 0.08 866.62707 633.740984 -161.88 583.11
60 0.94 0.06 866.62707 633.740984 -161.88 583.11
60 0.98 0.02 866.62707 633.740984 -161.88 583.11
60 1 0 866.62707 633.740984 -161.88 583.11
 Acetona Metanol
A 7.11714 A 8.08097
B 1210.595 B 1582.271
C 229.664 C 239.726
�_1=1/(𝑋_1+𝐴_12∙𝑋_2 )+ 〖𝑒𝑥𝑝〗 ^(𝑋_2 [�_12/
(�_1+�_12∙�_2 )−�_21/(�_2+�_21∙�_1 )] )
�_2=1/(𝑋_2+𝐴_21∙𝑋_1 )+ 〖𝑒𝑥𝑝〗 ^( 〖−𝑋〗 _1 [�_12/
(�_1+�_12∙�_2 )−�_21/(�_2+�_21∙�_1 )] )
1/(𝑋_1+𝐴_12∙𝑋_2 �_12/(�_1
1/(𝑋_2+𝐴_21∙𝑋_1
) ) +�_12∙�_2 ) �_21/(�_2+�_21∙�_1 )
A12 A21 �_1 �_2
0.7023966 0.75351397 1.42369709 1 1 0.75351397 2.70321841 2
0.7023966 0.75351397 1.42249168 1.00049322 0.99915332 0.75388561 2.69982834 2.0000028
0.7023966 0.75351397 1.41888767 1.00197578 0.99662187 0.75500275 2.68973793 2.0000447
0.7023966 0.75351397 1.41769038 1.00247095 0.99578091 0.75537586 2.68640083 2.00006979
0.7023966 0.75351397 1.41649512 1.00296661 0.99494135 0.75574935 2.68307682 2.00010042
0.7023966 0.75351397 1.41530186 1.00346275 0.99410322 0.7561232 2.67976584 2.00013658
0.7023966 0.75351397 1.41411062 1.00395939 0.99326649 0.75649742 2.67646782 2.00017825
0.7023966 0.75351397 1.41173414 1.00495414 0.99159726 0.75724698 2.66991042 2.0002781
0.7023966 0.75351397 1.39997056 1.00995762 0.98333456 0.76101717 2.63788083 2.00110435
0.7023966 0.75351397 1.37702188 1.02011554 0.96721549 0.76867131 2.57742886 2.00435748
0.7023966 0.75351397 1.36582739 1.02527151 0.95935251 0.7725564 2.54890181 2.00676528
0.7023966 0.75351397 1.33862158 1.03839238 0.94024325 0.78244316 2.48216314 2.01500031
0.7023966 0.75351397 1.31247843 1.05185344 0.92188039 0.79258626 2.42145248 2.02632609
0.7023966 0.75351397 1.28733687 1.06566807 0.90422104 0.80299578 2.366212 2.04067928
0.7023966 0.75351397 1.26314042 1.07985041 0.88722554 0.81368237 2.31596877 2.05802907
0.7023966 0.75351397 1.21737739 1.10937852 0.85508174 0.83593221 2.22893337 2.10174798
0.7023966 0.75351397 1.19571723 1.12475655 0.83986772 0.84751977 2.19151745 2.12820591
0.7023966 0.75351397 1.17481438 1.14056691 0.82518562 0.85943309 2.15783642 2.15783809
0.7023966 0.75351397 1.13512707 1.17355964 0.7973094 0.88429358 2.10093174 2.22713607
0.7023966 0.75351397 1.11627225 1.19078228 0.78406583 0.89727108 2.07742509 2.26714059
0.7023966 0.75351397 1.09803356 1.20851796 0.77125504 0.91063516 2.05708167 2.31100226
0.7023966 0.75351397 1.08038129 1.22678994 0.75885614 0.92440335 2.03983922 2.35898741
0.7023966 0.75351397 1.0632876 1.24562292 0.7468496 0.93859427 2.02566468 2.41140916
0.7023966 0.75351397 1.05660063 1.25331902 0.74215269 0.94439339 2.02085194 2.43370014
0.7023966 0.75351397 1.04347588 1.26900009 0.73293391 0.95620929 2.01270082 2.48069099
0.7023966 0.75351397 1.03703502 1.27698869 0.72840987 0.96222881 2.00936672 2.50544785
0.7023966 0.75351397 1.03067318 1.28507851 0.72394134 0.96832461 2.00653106 2.53108664
0.7023966 0.75351397 1.02438893 1.29327149 0.7195273 0.97449813 2.00419789 2.55764046
0.7023966 0.75351397 1.01818084 1.3015696 0.71516676 0.98075088 2.00237209 2.58514449
0.7023966 0.75351397 1.00598771 1.31848945 0.70660235 0.99350022 2.00026618 2.64315487
0.7023966 0.75351397 1 1.32711541 0.7023966 1 2 2.67374302
Pt Y1 Y2
1267.48197 0 1
1269.62826 0.00368572 0.99631428
1276.01821 0.01461421 0.98538579
1278.13201 0.01821492 0.98178508
1280.23778 0.02179495 0.97820505
1282.33557 0.02535452 0.97464548
1284.42541 0.02889385 0.97110615
1288.58138 0.03591262 0.96408738
1308.89692 0.06986215 0.93013785
1347.31757 0.13262914 0.86737086
1365.48719 0.1617699 0.8382301
1408.1065 0.22914919 0.77085081
1447.03196 0.29004145 0.70995855
1482.60241 0.34578107 0.65421893
1515.10453 0.39741441 0.60258559
1571.83989 0.49156508 0.50843492
1596.45497 0.5353441 0.4646559
1618.77494 0.57760946 0.42239054
1657.00555 0.6592824 0.3407176
1673.1023 0.69943681 0.30056319
1687.27891 0.73959667 0.26040333
1699.58167 0.78009486 0.21990514
1710.03844 0.82126614 0.17873386
1713.70689 0.83800007 0.16199993
1720.16065 0.87204906 0.12795094
1722.9436 0.88941217 0.11058783
1725.42805 0.90703447 0.09296553
1727.6113 0.9249423 0.0750577
1729.48999 0.94316317 0.05683683
1732.31663 0.98066086 0.01933914
1733.25414 1 0
 Pt 78.926 Acetona
V cm3/mol A 7.11714
Tb acetona °C 2.2543094 74.05 B 1210.595
Tb metanol °C 16.1496457 40.73 C 229.664
R 1.9872 cal/mol*K
0.76683146
TK T °C X1 X2 P1 P2 Λ12 Λ21
289.299646 16.1496457 0 1 155.700983 78.926 -161.88 583.11
288.532814 15.3828142 0 1 150.272633 75.6192494 -161.88 583.11
287.765983 14.6159827 0 1 145.001227 72.4323455 -161.88 583.11
286.999151 13.8491513 0.2 0.8 139.883275 69.3616852 -161.88 583.11
286.23232 13.0823198 0.25 0.75 134.915331 66.4037483 -161.88 583.11
285.465488 12.3154884 0.3 0.7 130.094005 63.5550965 -161.88 583.11
284.698657 11.5486569 0.35 0.65 125.415952 60.8123723 -161.88 583.11
283.931825 10.7818254 0.4 0.6 120.877878 58.1722976 -161.88 583.11
283.164994 10.014994 0.45 0.55 116.476539 55.6316724 -161.88 583.11
282.398163 9.24816251 0.5 0.5 112.20874 53.187374 -161.88 583.11
281.631331 8.48133105 0.55 0.45 108.071332 50.8363554 -161.88 583.11
280.8645 7.71449959 0.6 0.4 104.061219 48.5756446 -161.88 583.11
280.097668 6.94766813 0.65 0.35 100.175351 46.4023427 -161.88 583.11
279.330837 6.18083667 0.7 0.3 96.4107269 44.3136235 -161.88 583.11
278.564005 5.41400521 0.75 0.25 92.7643937 42.3067319 -161.88 583.11
277.797174 4.64717375 0.8 0.2 89.2334465 40.3789826 -161.88 583.11
277.030342 3.88034229 0.01155181 0.98844819 85.8150278 38.5277594 -161.88 583.11
276.263511 3.11351083 0.035335 0.964665 82.5063278 36.7505137 -161.88 583.11
275.496679 2.34667936 0.0607669 0.9392331 79.3045837 35.0447632 -161.88 583.11
275.404309 2.2543094 1 0 78.926 34.844003 -161.88 583.11
 Metanol
A 8.08097
B 1582.271
C 239.726

1/(𝑋_1+𝐴_12∙𝑋_2
1/(𝑋_2+𝐴_21∙𝑋_1
) 𝐴_12/(𝑋_1+𝐴_12∙𝑋_2
) ) 𝐴_21/(𝑋_2+𝐴_21∙𝑋_1 )
A12 A21 �_1 �_2
0.72891775 0.65934278 1.3718969 1 1 0.65934278 2.77776816 2
0.72946344 0.6575678 1.37087062 1 1 0.6575678 2.77923947 2
0.73001246 0.65578819 1.36983964 1 1 0.65578819 2.78071708 2
0.73056482 0.65400392 1.27477549 1.07434375 0.93130613 0.70262502 2.47552372 2.02963766
0.73112057 0.65221498 1.25259847 1.09522578 0.91580051 0.71432266 2.41572119 2.04610383
0.73167973 0.65042136 1.23126051 1.11716065 0.90088835 0.72662515 2.36099681 2.06622473
0.73224233 0.64862306 1.21071603 1.14022736 0.88653752 0.73957776 2.31095109 2.09009188
0.7328084 0.64682005 1.19092273 1.16451307 0.87271818 0.7532304 2.26524785 2.11784216
0.73337799 0.64501233 1.17184127 1.19011413 0.85940259 0.76763829 2.22360697 2.14966117
0.73395111 0.64319989 1.15343506 1.21713738 0.84656494 0.78286262 2.18579889 2.18578812
0.7345278 0.64138271 1.13566996 1.24570157 0.83418116 0.79897144 2.15164052 2.22652253
0.73510811 0.63956078 1.11851413 1.27593909 0.8222288 0.8160406 2.12099248 2.27223306
0.73569205 0.6377341 1.10193783 1.307998 0.81068689 0.83415492 2.09375766 2.32336916
0.73627966 0.63590265 1.08591322 1.34204436 0.79953582 0.85340956 2.069881 2.38047609
0.73687098 0.63406641 1.07041426 1.37826513 0.78875721 0.87391162 2.04935066 2.44421448
0.73746605 0.63222539 1.05541653 1.41687149 0.77833386 0.89578213 2.03220062 2.51538577
0.7380649 0.63037956 1.34936246 1.00428809 0.99591707 0.63308269 2.78074814 2.00010547
0.73866756 0.62852892 1.33707404 1.01330051 0.98765321 0.63688868 2.73973381 2.00098274
0.73927407 0.62667346 1.32429708 1.02321249 0.97901849 0.64122011 2.69767235 2.00289478
0.73934739 0.62644963 1 1.59629753 0.73934739 1 2 2.89407429
Pt Error
157.852 78.926
151.238499 72.31249883
144.864691 65.938691043
181.880143 102.95414347
183.381179 104.4551788
184.068837 105.14283748
184.057785 105.13178532
183.447188 104.52118801
182.323206 103.39720555
180.761035 101.83503466
178.826592 99.900592197
176.577912 97.651911838
174.066311 95.140310528
171.337369 92.411368923
168.43176 89.505760432
165.385956 86.45995555
78.9260132 1.32267E-05
78.9260221 2.211237E-05
78.926022 2.195363E-05
157.852 78.926
 Pt 78.926 Acetona
V cm3/mol A 7.11714
Tb acetona °C 2.2543094 74.05 B 1210.595
Tb metanol °C 16.1496457 40.73 C 229.664
R 1.9872 cal/mol*K
0.76683146
TK T °C X1 X2 P1 P2 Λ12 Λ21
289.299646 16.1496457 0 1 155.700983 78.926 -161.88 583.11
288.532814 15.3828142 0 1 150.272633 75.6192494 -161.88 583.11
287.765983 14.6159827 0.15 0.85 145.001227 72.4323455 -161.88 583.11
286.999151 13.8491513 0.2 0.8 139.883275 69.3616852 -161.88 583.11
286.23232 13.0823198 0.25 0.75 134.915331 66.4037483 -161.88 583.11
285.465488 12.3154884 0.3 0.7 130.094005 63.5550965 -161.88 583.11
284.698657 11.5486569 0.35 0.65 125.415952 60.8123723 -161.88 583.11
283.931825 10.7818254 0.4 0.6 120.877878 58.1722976 -161.88 583.11
283.164994 10.014994 0.45 0.55 116.476539 55.6316724 -161.88 583.11
282.398163 9.24816251 0.5 0.5 112.20874 53.187374 -161.88 583.11
281.631331 8.48133105 0.55 0.45 108.071332 50.8363554 -161.88 583.11
280.8645 7.71449959 0.6 0.4 104.061219 48.5756446 -161.88 583.11
280.097668 6.94766813 0.65 0.35 100.175351 46.4023427 -161.88 583.11
279.330837 6.18083667 0.7 0.3 96.4107269 44.3136235 -161.88 583.11
278.564005 5.41400521 0.75 0.25 92.7643937 42.3067319 -161.88 583.11
277.797174 4.64717375 0.8 0.2 89.2334465 40.3789826 -161.88 583.11
277.030342 3.88034229 0.01155181 0.98844819 85.8150278 38.5277594 -161.88 583.11
276.263511 3.11351083 0.035335 0.964665 82.5063278 36.7505137 -161.88 583.11
275.496679 2.34667936 0.0607669 0.9392331 79.3045837 35.0447632 -161.88 583.11
275.404309 2.2543094 1 0 78.926 34.844003 -161.88 583.11
 Metanol
A 8.08097
B 1582.271
C 239.726

1/(𝑋_1+𝐴_12∙𝑋_2
1/(𝑋_2+𝐴_21∙𝑋_1
) 𝐴_12/(𝑋_1+𝐴_12∙𝑋_2
) ) 𝐴_21/(𝑋_2+𝐴_21∙𝑋_1 )
A12 A21 �_1 �_2
0.72891775 0.65934278 1.3718969 1 1 0.65934278 2.77776816 2
0.72946344 0.6575678 1.37087062 1 1 0.6575678 2.77923947 2
0.73001246 0.65578819 1.2978407 1.05444275 0.94743988 0.6914911 2.54087631 2.01677807
0.73056482 0.65400392 1.27477549 1.07434375 0.93130613 0.70262502 2.47552372 2.02963766
0.73112057 0.65221498 1.25259847 1.09522578 0.91580051 0.71432266 2.41572119 2.04610383
0.73167973 0.65042136 1.23126051 1.11716065 0.90088835 0.72662515 2.36099681 2.06622473
0.73224233 0.64862306 1.21071603 1.14022736 0.88653752 0.73957776 2.31095109 2.09009188
0.7328084 0.64682005 1.19092273 1.16451307 0.87271818 0.7532304 2.26524785 2.11784216
0.73337799 0.64501233 1.17184127 1.19011413 0.85940259 0.76763829 2.22360697 2.14966117
0.73395111 0.64319989 1.15343506 1.21713738 0.84656494 0.78286262 2.18579889 2.18578812
0.7345278 0.64138271 1.13566996 1.24570157 0.83418116 0.79897144 2.15164052 2.22652253
0.73510811 0.63956078 1.11851413 1.27593909 0.8222288 0.8160406 2.12099248 2.27223306
0.73569205 0.6377341 1.10193783 1.307998 0.81068689 0.83415492 2.09375766 2.32336916
0.73627966 0.63590265 1.08591322 1.34204436 0.79953582 0.85340956 2.069881 2.38047609
0.73687098 0.63406641 1.07041426 1.37826513 0.78875721 0.87391162 2.04935066 2.44421448
0.73746605 0.63222539 1.05541653 1.41687149 0.77833386 0.89578213 2.03220062 2.51538577
0.7380649 0.63037956 1.34936246 1.00428809 0.99591707 0.63308269 2.78074814 2.00010547
0.73866756 0.62852892 1.33707404 1.01330051 0.98765321 0.63688868 2.73973381 2.00098274
0.73927407 0.62667346 1.32429708 1.02321249 0.97901849 0.64122011 2.69767235 2.00289478
0.73934739 0.62644963 1 1.59629753 0.73934739 1 2 2.89407429
Pt Error
157.852 78.926
151.238499 72.31249883
179.432499 100.50649884
181.880143 102.95414347
183.381179 104.4551788
184.068837 105.14283748
184.057785 105.13178532
183.447188 104.52118801
182.323206 103.39720555
180.761035 101.83503466
178.826592 99.900592197
176.577912 97.651911838
174.066311 95.140310528
171.337369 92.411368923
168.43176 89.505760432
165.385956 86.45995555
78.9260132 1.32267E-05
78.9260221 2.211237E-05
78.926022 2.195363E-05
157.852 78.926