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On Rayleigh and Fanno Flows of Homogeneous Equilibrium Two-Phase Fluids
On Rayleigh and Fanno Flows of Homogeneous Equilibrium Two-Phase Fluids
homogeneous equilibrium
two-phase fluids
S. K. Chan
School of Mechanical and Production Engineering, Nanyang Technological University, Singapore
W. A. W o o d s
Department of Mechanical Engineering, Queen Mary and Westfield College, University of London, London, U K
This article introduces a model fluid that has ideal liquid and perfect gas phases and a
homogeneous two-phase mixture region. The thermodynamic-state properties of the model
compare favorably with those of three common fluids.
A gas dynamic study of Rayleigh and Fanno flows is discussed using one approach
similar to the classical work of Shercliff and another based on the proposed model.
The role of the isentropic and Newtonian and other new "sound speeds" are discussed.
The relevance of these sound speeds in relation to critical speeds of the fluid is examined.
It is concluded that in the two-phase region, a Rayleigh flow exhibits a maximum enthalpy
at a point where the flow velocity reaches the isenthalpic speed of sound. This third speed
of sound a. is defined by the relation a~ = (c~p/c~p)..
© 1992 Butterworth-Heinemann
Int. J. Heat and Fluid Flow, Vol. 13, No. 3, September 1992 273
Rayleigh and Fanno flows of two-phase fluids: S. K. Chan and W. A. Woods
in which the fluid remains in the two-phase state. A simple 1 as a straight line at Vf = 0.4. This assumption is not very
model of a two-phase fluid is used in which the fluid is assumed accurate for liquids at high temperatures near the critical point.
to be a homogeneous mixture of an ideal liquid and an ideal However, in most parts of the region of interest, the assumption
vapor, the proportion of which is given by the dryness fraction. of incompressibility can be shown to be reasonable. Data taken
An ideal liquid is, in this case, conveniently defined as one from Reynolds (1979) and given nondimensionally in Figure
whose density and specific heat capacity do not change for the 1 show the saturated-liquid specific volume Vf against the
processes under consideration. An ideal vapor is defined as one saturated temperature 0,at for water, refrigerant-22, and
obeying the perfect gas law. The model is then used to predict ammonia; it also shows that Vf does not change extensively
the behavior of Rayleigh and Fanno flows in a homogeneous over the range of interest. Both Vf and 0s,t are normalized using
two-phase region. In this work, considerations of slip between the thermodynamic critical-point values. Also, in the liquid
the phases and phase-change relaxation times are excluded. region, it is assumed that the specific heat capacity c does not
change with pressure and temperature. The values for c were
taken from Rosenhow et al. (1985) corresponding to a
M o d e l f o r an ideal fluid temperature of 300 K.
As such, the equilibrium condition reduces to Tds = cdT,
which, after integration, yields
The l i q u i d region
In the liquid region, an ideal liquid can be defined as one whose - In (1)
C
density po (or specific volume Vo) is a constant. F o r the model
liquid, the value of Vois selected as 0.4v* ; this appears in Figure where the superscript (*) is used to denote properties at an
274 Int. J. Heat and Fluid Flow, Vol. 13, No. 3, September 1992
Rayleigh and Fanno flows of two-phase fluids: S. K. Chan and W. A. Woods
0.6
0.5
0.4
NH3
MODEL
R-22
.0
/
AO°@
~ ./.
¢0
T p v'p* 0.3
¢o °
0- P = -- c< - (3)
T* p* cT* 0.2
~.~o~°~°
s - s* h - h*
S- H - (4) 0.1
c cT*
0.0 .... i
o~al
S =In(0) (5)
H=(0-1)+~(P--1) (6) Figure 2 The variation of the normalized saturated pressure with
the normalized saturated temperature
We note that (OH/OS)v = 0 = es and (OH/OP), = ~, i.e., the
distance between any two isobars in the enthalpy-entropy
(H, S) thermodynamic plane along a line of fixed entropy is
proportional to the pressure difference. Furthermore, this and they indicate that the model equations give reasonable
separation does not change with a change in the line of fixed representation of the real fluids.
entropy. The parameter ~ is expected to be small, of the order
of 0.025, so the dependence of H on pressure P is small.
Equations 5 and 6 are also assumed to apply at the The vapor region
saturated-liquid state, so the changes of specific entropy Sf and In the vapor region, a perfect gas model is used. This is defined
of enthalpy He are given by by the equation of state, p = pRT, together with the condition
Sf = In 0,,t (7) that the specific heat capacities do not change with temperature
and pressure. As an approximation, the saturated-vapor state
and is also assumed to follow this law, so the specific volume, vv
H f = (0,, t - 1 ) + ct(P,=t - 1) (8) is given by vg = RT, at/P,= or, in the normalized form,
In the two-phase region, pressure and temperature are v, ( R T * ~ 0,~,
v, = = (lO)
dependent on each other, and an empirical relation between
the saturated pressure P,a, and saturated temperature 0,,t is
required. Figure 2 shows the variation of e s a t against 0~t for where the term within the parentheses does not change for a
water, refrigerant-22, and ammonia, and a suitable equation given fluid, i.e.,
to represent the real fluid data adequately is given by RT*
C-
P,., = (0..,) k, (9) v'p*
where k is a constant used for curve fitting. The magnitudes of The values of R were taken from Reynolds (1979).
this and of the other parameters used for calculating the curves Equation 10 implies that Vs is a function of 0,=t (or P,,t) only.
for the model and the points for the actual fluids are given in Figure 5 shows that the variation of Vs with saturated
Tables 1 and 2. temperature, 0,=, in the region of interest, except in the vicinity
Figures 3 and 4 show the graphical representations of of the thermodynamic critical point, can be represented
Equations 7 and 8 for the variations of Sf and Hr with saturated adequately by the equation
temperature 0,=r Comparisons are made between the fluid
properties for water, refrigerant-22, ammonia, and the model,
Vg-~- C(0sat) 1-k (11)
The values of the dimensional empirical quantities and
parameters for the selected fluids are summarized in Table 1,
and the values of the nondimensional curve-fitting constant k
10
and parameter C are given in Table 2. These values of C are
~)" 0.9 approximately four, rather than the value of unity, which would
0.8 - - MODEL satisfy Equation 11 at the thermodynamic critical point.
R-22
0.7 NH5 However, to provide a reasonable fit for Figure 5, a compromise
H2O %
value of C = 2 has been used. This gives rise to discrepancies
0.6
in x, which are most pronounced in the vicinity of the
05
thermodynamic critical point, apparent later in Figures 8 and
0.4
0.3
ouooooooo~h"h~dbeo°°°° 11.
0.2
The two-phase homogeneous mixture region
0.1
Int. J. Heat and Fluid Flow, Vol. 13, No. 3, September 1992 275
Rayleigh and Fanno flows of two-phase fluids: S. K. Chan and W. A. Woods
Dimensional quantities
Nondirnensional quantities
v'p*
= = 0.025
cT*
RT*
C- - 2.0
v'p*
G2v*2
2= = 0.0005
2cT .2
G2v .2
p*
"Used in conjunction with the Reynolds Thermodynamic Properties (Reynolds 1979) in calculating the points shown on the figures. Note
that the asterisk (*) refers to the thermodynamic critical point.
Table 2 Nondimensional parameters' The link between the entropy value of the saturated vapor
Sg and that of the saturated liquid Sr is provided by the
Magnitudes used Magnitudes corresponding to Clausius-Clapeyron equation as
in calculating the actual property values
curves for the model
shown in the figures Water Refrigerant-22 Ammonia s, = s, + ~ ( v , - v,) ~ - . , (13)
v'p* The saturated-vapor specific enthalpy H~ is given by
a= 0.025 0.0258 0.0205 0.0250
cT*
Hg = Hf + O,at(Sg - Sf) (14)
RT*
C= 2.0 4.2865 3.7413 4.0592 The specific entropy S and enthalpy H for the two-phase
v'p* mixture region can be written in terms of their respective values
k=9 at the saturated states and the dryness fraction as follows:
G2v .2
2= 0.0005 S = Sr + x ( S g - Sf) (15)
2cT*
H=Hf+x(H,-Hf) (16)
G2V.2
fl= p* 0.3 As mentioned above in connection with Equation 12, the
dryness fraction is indeterminate at the thermodynamic critical
Vo = v° 0.4
V* 8t~?f
' Used in conjunction with the model fluid in calculating the curves 0.5 0.5 0.7 0.8 0.9
shown on the figures. Note that the asterisk ( * ) refers to the
thermodynamic critical point.
276 Int. J. Heat and Fluid Flow, Vol. 13, No. 3, September 1992
Rayleigh and Fanno flows of two-phase fluids: S K Chan and W A Woods
800
-1 .O
.,v = \OpJs
Figure 4 The variation of the normalized saturated-liquid specific where M is the Mach number. By writing Equation 20 as
enthalpy with the normalized saturated temperature
t~SJRAY\t~P/s \t~SJRAYkt~PJs
l~ 700
v a
we obtain
600 MODEL
* o ~ R-22
500 • NH3
v = H20
Therefore,
400
300 ~ ~
2OO
i-~ (~las)~)
_ (ddp/c3s)p ~1 -- M 2 (ctP/dP)s~
O0
iZ~ ( (¢3P/~P)sJ
O t i i "~ i
04 0.5 0.6 0.7 0.8 0.9 1,0 i.e.,
esat
Int J Heat and Fluid Flow, Vol 13, N o 3, September 1992 277
Rayleigh and Fanno flows of two-phase fluids." S. K. Chan and W. A. Woods
Hence, a h < a,, since (dp/dT)p is always positive. In the the dryness fraction until the point where u = a, is reached.
subsonic region of the flow, heating will cause the enthalpy h The implication here is that the heat transfer in this case is
to rise until the sound speed a h is reached; thereafter, the being utilized for the conversion of the state of a fluid fraction
enthalpy decreases until Mach unity. Between the sound speed from liquid to vapor.
a h and the adiabatic sound speed, heating results in the decrease Consider a Rayleigh curve that passes through the
of the enthalpy, h, and an increase in the flow kinetic energy. thermodynamic critical-state point. From Equation 19, we may
In the supersonic region, as the entropy decreases, the enthalpy write
decreases and the rate of decrease also decreases from an infinite P + G2v = p* + GZv *
value at the sonic point.
When q5 = e, Equation 21 becomes or
ae -- 1
2
_e(0q and is a parameter that depends upon the value of G.
Equation 28 is an alternative, normalized version of Equation
as r \Op/s 19 and represents families of the Rayleigh line (depending on
Hence a, < a,, since (OT/dp), is always positive. the chosen values of fl) on the pressure-volume (P, V)
When 4~ = T, Equation 21 becomes thermodynamic plane.
In the case of flow in a two-phase fluid, the specific volume
V is given by Equation 12, so Equation 28 can be written as
cp \ 1 - M 2,] (Ps,, - 1) + fl(V, - 1)x = 0 (30)
where M r is the "isothermal" Mach number, i.e., the ratio u/a+, The value of G selected to compute the curves shown in Figures
and where aT = (dp/Op)~/2 is the isothermal or Newtonian 6, 7, and 8 is given in Table I, and the corresponding values
sound speed. The ratio M ~ / M 2 is equal to the specific heat of the nondimensional parameter fl are given in Table 2.
capacity ratio ?, since Since Vs = V~(P, at), Equation 30 represents the Rayleigh line
a s2 (Op/(?p) s _ (Os/c~T)p Cp in the (P, x) plane for various values of ft. The Rayleigh line
in the (0, S) plane will be of interest. This can be obtained by
a~ (Op/gp)T (gs/gT)p Cv
Equation 25 is applicable to all flows in single-phase fluids in
equilibrium and indicates that the stationary values of the flow 0.2
i 0.0 t
02 -01 o S
02
which indicates that only one stationary value exists for the
Rayleigh line in the (T, s) plane when the flow occurs in the
- - MODEL
two-phase region. The stationary value occurs at maximum R-22
NH3
entropy. o H20
When flow occurs in the two-phase region, heating results
in a decrease of temperature in the flow direction when flow is
initially subsonic and an increase in temperature when flow is
initially supersonic. This is to be expected, since pressure Figure 6 The Rayleigh process in the (H, S) thermodynamic plane
for a homogeneous two-phase fluid
decreases with accelerating flow and increases in decelerating
flow.
The density p in terms of the dryness fraction x and the 10
278 Int. J. Heat and Fluid Flow, Vol. 13, No. 3, September 1992
Rayleigh and Fanno flows of two-phase fluids: S. K. Chan and W. A. Woods
0.9 o v In the (T, s) plane, howe~er, the gradient of the Fanno line
can be obtained by writing
O.7 o A~
0.6 °D Z/
0.5 where
04 (t~h) 1/c~p\
o~ / : ~ MODE~ ~SS T: T "l'-;t~S) T
~- R-22
02 NH3
and
O1
0.0
0.0 02
a~:b
0.4
I
0.6
I
H20
0.8
P
1.0
(o,,)
77, = t,77 :,
I
Therefore,
Figure 8 The Rayleigh process in the (P,= ~ x) thermodynamic
plane for a homogeneous two-phase fluid (~sT)vAN= _{OT'~ ( M 2 1
(36)
Plt~p)slM~ 1 p-T (~--PS)T- 1 }
combining Equations 15, 13, and 30, resulting in (after some For flow in the two-phase region, Equation 36 reduces to
rearrangement)
Therefore, -0.06
~o
(t3h) ( M 2 ~ ( d h ~ _ TM 2 (35)
~S FAN = ~',M2 -- 1,]\dS,/p M 2 -- 1
D A
Int. J. Heat and Fluid Flow, Vol. 13, No. 3, September 1992 279
Rayleigh and Fanno flows of two-phase fluids: S. K. Chan and W. A. Woods
10
The correlation and representation aspects of the
results
e~,,i
The first five diagrams give the static fluid properties. Figure
MODEL
R -22 J
NH3 09 1 shows a very good correlation for R-22 and ammonia and
H20
quite a good correlation for water. The model is not good in
the vicinity of the thermodynamic critical point and is fair
elsewhere. Figure 2 shows a good correlation and a fair
0.8 5\:," representation by the model. Figure 3 shows a very good
correlation for R-22 and ammonia, with a fair one for water.
There is a fair representation by the model, and this could be
improved by the selection of a different value of c. Figure 4
shows a very good correlation for water and R-22, with quite
-0.04 -0.02 0.00 002 004
5 a good one for ammonia. The model gives a fair representation
and could be improved similarly to Figure 3, by the selection
Figure 10 The Fanno process in the (O.,S) thermodynamic plane of a different c. Figure 5 shows a fair correlation for R-22 and
for a homogeneous two-phase fluid ammonia, but not a very good one for water. The representation
by the model is rather poor, and this could be improved by
using a higher value, perhaps C = 4.
The next three figures are concerned with Rayleigh flows.
0.9
o
Figure 6 shows a good correlation and quite a good
0.8
representation by the model except in the vicinity of the sonic
0.7
ov
\
r ----- MODEL
point. Figure 7 shows a fair correlation and the model gives a
R-22 reasonable representation. Figure 8 shows a good correlation
NH3
0.6 H20 for R-22 and ammonia. The model gives a good representation
I
05
for the lower half of the pressure range, but then deviates
o~ ,-
markedly. This point will be discussed again later.
04
The next three curves discuss the Fanno flows. At the critical
03 point, Figure 9 shows a good correlation that deteriorates to
0.2
fair as the enthalpy decreases. The model representation is
similar, varying from good to poor as the enthalpy is decreased.
01
Figure 10 shows a good correlation. The model gives a good
0.0 i I I I representation except near the sonic point, where it is fair. In
O.O 02 04 06 08 10
Figure 11, the parameters correlate the data points quite well
for water and ammonia, but R-22 deviates quite markedly in
Figure 11 The Fanno process in the (P,=e~) thermodynamic plane the vicinity of maximum x. The model represents the trends
for a homogeneous two-phase fluid quite well at low pressures, but then shows quite a different
trend over most of the pressure range. The value of x is
indeterminate at the critical point, and this will be discussed
Substitution of H (from Equation 32) and V (from Equation again later.
40) into Equation 38 results in the equation of the Fanno line
in the (0, S) plane, i.e., The nature and meaning of the Rayleigh and Fanno
flows
(0,,,, - 1) + ~(P,,,, - 1) + O,,,(S - In O,,,t) Figures 6 and 7, respectively, show the variation of enthalpy
H and saturated temperature 0s,t with entropy S for the
(41) Rayleigh process. The model fluid equations are used, and
comparisons are made graphically using the properties of water,
ammonia, and refrigerant-22. The general features of the graphs
The corresponding equation of the Fanno line in the (H, S) are similar and indicate the fact that the critical velocities of
plane can be obtained by eliminating 0sat from Equations 32 the fluids of the process occur, as predicted, when the enthalpy
and 41. The comparisons shown in Figures 9, 10, and 11 are and entropy are at their maximum. It has been shown (Shercliff
on the basis of the same values of ct, C, and 2.
1958) that for Rayleigh processes involving the perfect
gas, the critical velocities of the fluids are associated with the
points of maximum temperature and entropy. However, with
flow occurring in a homogeneous two-phase fluid, where
Discussion pressure and temperature are uniquely related properties, the
isothermal speed of sound is always zero, since
This section of this article is in two parts. The first discusses
two aspects of the nondimensional parameters used for
presenting the information on the figures. The first aspect
considers how well the nondimensional parameters correlate
the points for the three different fluids, and the second reviews Here, the point of maximum enthalpy occurs when the fluid
how well the curves of the model represent the data points of velocity is equal to the speed
the three actual fluids.
The second part of the discussion deals with the Rayleigh
and Fanno flows and considers the nature of the flows and a. = \~pA
what they mean physically. This is the speed at which infinitesimally small pressure
280 Int. J. Heat and Fluid Flow, Vol. 13, No. 3, September 1992
Rayleigh and Fanno flows of two-phase fluids: S. K. Chan and W. A. Woods
disturbances would travel if the state changes within the slight deviation near the sonic point for Rayleigh and Fanno
disturbances occurred at constant enthalpy. Because of this, ah flows.
has been termed the isenthalpic speed of sound. On account The results of the thermodynamic analyses have shown that
of the analogy with the general behavior of the Rayleigh and Fanno processes,
(Op~ 1/2 whatever the fluid, is qualitatively similar to that involving the
perfect gas only, as demonstrated by Shercliff (1958). For
flows involving saturated two-phase fluid only, the character-
which is widely called the Newtonian speed of sound, it is istics of the flows are governed by the pressure/temperature
reasonable to refer to ah as the third speed of sound, thus dependence, so in the case of an accelerating flow with pressure
implying that Newton's aT is the second speed of sound. It is reducing, the temperature has to reduce but enthalpy and
interesting to note that if the two-phase fluid is simplified to a internal energy may increase or decrease. The latent heat of
single-phase gas, then the isenthalpic sound speed reduces to vaporization, needed to increase the dryness fraction of the
the Newtonian sound speed. Figure 7 shows that for a Rayleigb fluid for an accelerating flow, is derived from the heat transfer
process, heat transfer in a subsonic accelerating flow leads to to the fluid in the case of the Rayleigh process, and is generated
a decrease in temperature, which is the opposite effect to that as a result of frictional dissipation in the case of the Fanno
for a gaseous flow accelerating below the Newtonian Mach process.
number Mr. This is because the heat transfer is being used to The significance of adiabatic and Newtonian sound speeds
increase the kinetic energy and to increase the vapor portion in single-phase gaseous flows have been demonstrated by
of the fluid stream. Figure 8 shows that the dryness fraction of Shercliff ( 1958 ).
the fluid increases as the pressure decreases in a subsonic In Rayleigh flows in two-phase fluids, a point of maximum
accelerating flow. The differences apparent at high pressures enthalpy occurs where the flow velocity reaches the isenthalpic
are thought to be due to the indeterminacy of the dryness "speed of sound." This has become the significant parameter
fraction at the thermodynamic critical point. for two-phase fluids. For the perfect gas flow, the isenthalpic
Figures 9, 10, and 11 show the behavior of the Fanno process sound speed degenerates to that of the isothermal sound speed,
in a two-phase flow. The process, as plotted in the (H, S) plane i.e., Newtonian sound speed. Hence the isenthalpic speed of
(Figure 9), is similar to that in the (0, S) plane for a single-phase sound could be considered to be more general than the
gaseous flow. The change of enthalpy in the subsonic branch Newtonian speed of sound.
A simple model of a homogeneous two-phase fluid has been
of the flow is considered to be small, and it would be reasonable
presented. It has been shown to be capable of predicting
to assume that enthalpy remains essentially constant in many
satisfactorily the general features of the Rayleigh and Fanno
practical cases, such as flow in the expansion tube of a
flows in a two-phase fluid environment.
refrigeration system. However, temperature and pressure
changes are significant in the subsonic branch of the process,
as shown in Figure 10. The calculated results shown in Figure
11 indicate that the change in the dryness fraction in the
subsonic branch of the process is quite small. The redistribution
of energy required for the change of phase of the fluid from the
liquid to the vapor state is the result of a friction-generated, References
combined temperature reduction and drying process. The
change of the dryness fraction predicted by the model fluid is ASHRAE Equipment Handbook. (1988) Chapter 19, p. 22
not particularly accurate at high pressures because of Liepmann, H. W. and Roshko, A. (1957) Elements of Gas Dynamics.
limitations imposed by the indeterminacy of the dryness fraction John Wiley and Sons, New York
at the thermodynamic critical point already mentioned. Reynolds, W. C. (1979) Thermodynamic Properties in S.L Department
of Mechanical Engineering, Stanford University, Stanford, CA
Rosenhow, W. M., Hartnett, J. P., and Ganic, E. N. (1985) Handbook
of Heat Transfer Fundamentals. McGraw-Hill, New York, Chapter 3
Conclusions Shapiro, A. H. (1953) The Dynamics and Thermodynamics of
Compressible Fluid Flow, Vol. 1. The Ronald Press Company, New
The parameters selected to present the results correlate the data York
Shapiro, A. H. and Hawthorne, W. R. (1947) The mechanics and
for the three fluids quite well. The exceptions are the cases thermodynamics of steady one-dimensional gas flow. J. Appl. Mech.,
involving the dryness fraction in the vicinity of the 14, 317
thermodynamic critical point. Shercliff, J. A. (1958) Some generalizations in steady one-dimensional
The model fluid represents the trends quite well in most cases. gas dynamics. J. Fluid Mech., 3, 645-657
The exceptions are those involving the dryness fraction in the Stocker, W. F. and Jones, J. W. (1982) Refrigeration and
vicinity of the thermodynamic critical point. There is also a Air-Conditioning. second ed. McGraw Hill, New York
Int. J. Heat and Fluid Flow, Vol. 13, No. 3, September 1992 281