Lectore3 : oa Show that PV¥= constant holdy For an acliahale proacea PV RT, for Isothermal proces) a hal. tie we fdw> -fray> -¢ [4 a <= juz L\(eu, - Fu) al a ¥, - : See = sen a Stabe k ln: ke inf A! ; . ~ At) = kf bn! - deal = tain)! Wis bg nese bell = Mla N-M Skelnge Under what Cenditiena to Hic lings pprevimectcen rue © » N21D SG)= [(len)- N)- (nino -n)- ((N-n) tnW-2) wit” : kel NinN~nban ~Al-n\lntn-n)| dimension leaw On (Wet a2 Nw p+ eT 7 uae | nsx Erle N leper z = kT* Gv @ T= 0K lurile as a power of i 10 2 p77 - e = fog x Ine tO= fax _ fax oe Dye ~ “agoa & Mullen atoms bn the Surfer, of & mele of Crystal dele 6" =T= 1000K er =_l piood). )V #2 feV 2 Ir 76 (S307 72 ar Jae tay e Ayo nz W103 =(O atoms on a N ote crystal @ feook ee ory A tem at equilibricm aheat b ic heat Capacity > © of hoot & Compexce| Lo syste The system ist infar oy Sekt earn awd ts Lekt bath, probability of Finding the Systern un a ae eantum Skete. p= PorheulanState a ha,g,,,. ondey of ener y Ge heat recharge, Treat bath What a the Probability 2 Fundamental Postulates Ail microslates of Same Ex are egal Probable, > Total encg q the system Eo= Er + Eneas bath < Sulte- Ee 2 Ke ISG) TALS ees Ap X € lan GAT Pre pr * (constaat e ORT Bolte mann Can dettimune the conotant normolegectton aR=t pce 26@2i 1h s Eeeer -GSRT Z = Canenical Equiparbien Funchor = Le the tude b & fund a 2 thot Ha fo fegure dou git 2 demple eile oes ~BE, < B= to et=%e? Kei rieee ere ee Denvetion We tadk getthe crac enmgy of 2 System, thuncfore. une wa alti an untentaiz by he mary miceestates) OAR »* SU(E-E= “The number microstates oF the heat bash But he Oyatem jo in an cxact stake (2 #0, 2, +10, (&-&) PrX La(E-Er) Uoefial fendamiuntal postulate aSa (Ee~E,) = kU 23 (6-G) heat back ale-ED- eG EV. de Tefen Sees expansion Sy(Eo- Er) = Sp lE&)- & aS - eS as, | a a Ble E> & 1A | ne Ee Second Ter, er a \ rT se. era ee 2 (4 ee . ; ~ (aT 5 Hw third te of} (Me cco He tention fis tim &>Ey Chiminecticl | SoG) = Sate) Ea = Salle)~ Er db. |t-e, iAUseful Result? pe Le® bet é Wdhet lo the megy gf thesysten? Statiotcal anrage eur all microstatta) XE>=FEp = SE Leet. Set he r a Zz ¢ z 2-3 su Can Caletate th Aho functed ging cer setae te eat feat Cowl woe S= Rex( ) 40 get ectropy, but we Can aleo oe the enh o py. (ao"> Slee SE = ain? , 0 Ind -QSEY «E>-ZG p, B 7 dpe * ap = gt EP —— = re, 2 7 Beate “Ln een = aT se Stee. -pe[Lé*Le) (4) eae P ee © ~dDLEpere ~ a = y PN = Lee (28g: (Zep) <> - cay =( OE) itn Obat- - ey = -a = -d BT OF 27> oe 83 OS or eee = kT?3<> at ed, Reareapetly