NAMA : ASLAMI KHAIRULLAH

NIM :D1121141008

KELOMPOK :3

1. Pembuatan NaOH

m 1000 m 1000
M NaOH = × 0.1 M = × m NaOH = 2 gr
Mr NaOH v(ml) 40 50 ml

2. Pembuatan H2C2O4

m 1000 m 1000
MH2C2O4 = × 0.5 M = × m NaOH
Mr H2C2O4 v(ml) 126.072 50 ml
= 3.1518 gr

3. Pembuatan CH3COOH
Konsentrasi 0.5 M
𝑀1 × 𝑉1 = 𝑀2 × 𝑉2
17.49𝑀 × 𝑉1 = 0.5𝑀 × 50𝑚𝑙
𝑉1 = 1.4𝑚𝑙
Konsentrasi 0.25 M
𝑀1 × 𝑉1 = 𝑀2 × 𝑉2
17.49𝑀 × 𝑉1 = 0.25𝑀 × 50𝑚𝑙
𝑉1 = 0.71𝑚𝑙
Konsentrasi 0.125 M
𝑀1 × 𝑉1 = 𝑀2 × 𝑉2
17.49𝑀 × 𝑉1 = 0.125𝑀 × 50𝑚𝑙
𝑉1 = 0.35𝑚𝑙
Konsentrasi 0.0625 M
𝑀1 × 𝑉1 = 𝑀2 × 𝑉2
17.49𝑀 × 𝑉1 = 0.0625𝑀 × 50𝑚𝑙
𝑉1 = 0.17𝑚𝑙
4. Standarisasi NaOH
Vol titrasi rata rata = 32 ml
n H2C2O4 = M x V = 0.5 x 0.032 L = 0.0032 mol
5. Perhitungan konstanta distribusi CH3COOH
Reaksi CH3COOH+ NaOH CH3COONa+H2O
 Konsentrasi 0.5 M
n NaOH = M x V = 0.1 x 0.0172.5 = 0.001725 mol
n CH3COOH = n NaOH
𝑛 0.001725
M CH3COOH = = = 0.345 M
𝑉 0.005
Cair = (Mteori CH3COOH – Mpercobaan) x M NaOH
= 0.5 – 0.345 x 0.1 = 0.0155 M
Ceter = (Mteori eter – Cair
= 0.5 – 0.0155 = 0.4845 M
K1 = Cair⁄Ceter
= 0.0155 ⁄0.4845 = 0.03199

 Konsentrasi 0.25 M
n NaOH = M x V = 0.1 x 0.01015 = 0.001015 mol
𝑛 0.001015
M CH3COOH = = = 0.203 M
𝑉 0.005
Cair = 0.25 – 0.203 x 0.1 = 0.0047 M
Ceter = 0.25 – 0.0047 = 0.2453 M
K2 = 0.0047 ⁄0.2453 = 0.01916

 Konsentrasi 0.125
n NaOH = M x V = 0.1 x 0.0045 = 0.00045 mol
𝑛 0.00045
M CH3COOH = = = 0.09 M
𝑉 0.005
Cair = 0.125 – 0.09 x 0.1 = 0.0035 M
Ceter = 0.125 – 0.0035 = 0.1215 M
K3 = 0.0035 ⁄0.1215 = 0.02880

 Konsentrasi 0.0625
n NaOH = M x V = 0.1 x 0.0031 = 0.00031 mol
𝑛 0.00031
M CH3COOH = = = 0.062 M
𝑉 0.005
Cair = 0.0625 – 0.062 x 0.1 = 0.00025 M
Ceter = 0.0625 – 0.00025 = 0.06225 M
K4 = 0.00025 ⁄0.06225 = 0.00401
 𝐾1+𝐾2+𝐾3+𝐾4
6. Konstanta distribusi = 4
𝟎.𝟎𝟑𝟏𝟗𝟗+𝟎.𝟎𝟏𝟗𝟏𝟔+𝟎.𝟎𝟐𝟖𝟖𝟎+𝟎.𝟎𝟎𝟒𝟎𝟏
= 4
= 0.02099