PH8

ASAP 2020 V1.
05 H Unit 1 Serial #: 182 Page 1

Sample: ZNIM2
Operator:
Submitter:
File: H:\...\FARID\PH8.SMP
Started: 2010-06-19 12:48:48 Analysis Adsorptive: N2
Completed: 2010-06-19 19:03:55 Analysis Bath Temp.: 77.
298 K
Report Time: 2010-07-13 12:14:05 Thermal Correction: No
Sample Mass: 0.1921 g Smoothed Pressures: No
Warm Free Space: 27.7346 cm³ Measured Cold Free Space: 84.40
75 cm³
Equilibration Interval: 10 s Low Pressure Dose: Non
e
Automatic Degas: Yes
Isotherm Tabular Report

Relative Absolute Quantity Elapsed Saturation
Pressure Pressure Adsorbed Time Pressure
(p/p°) (kPa) (mmol/g) (h:min) (kPa)
-----
01:34 100.736783
0.010948592 1.102822 0.35763 01:49
0.022316096 2.247798 0.36175 01:52
0.037499821 3.777114 0.36429 01:55
0.065598928 6.607230 0.36655 01:58
0.081622810 8.221079 0.36805 02:00
0.106026993 10.678876 0.36994 02:03
0.130565092 13.150068 0.37263 02:06
0.154891388 15.599836 0.37577 02:09
0.179260732 18.053960 0.37818 02:11
0.203700907 20.515027 0.38053 02:14
0.228217186 22.983666 0.38319 02:17
0.252631769 25.441971 0.38533 02:20
0.276997295 27.895243 0.38672 02:23
0.301403885 30.352748 0.38776 02:25
0.325810287 32.809761 0.38883 02:29
0.350213519 35.266773 0.38945 02:31
0.374573855 37.719168 0.39004 02:34
0.398997858 40.177882 0.39021 02:37
0.442977291 44.605359 0.38939 02:41
0.467227497 47.046630 0.38902 02:43
0.491566655 49.496486 0.38893 02:46
0.515995789 51.955310 0.38857 02:49
0.540436955 54.415252 0.38791 02:52
0.564826831 56.869938 0.38741 02:55
0.589134442 59.316620 0.38654 02:57
0.613551500 61.773873 0.38583 03:00
0.637965071 64.230682 0.38569 03:03
0.662494138 66.699446 0.38470 03:05
0.686910057 69.156755 0.38426 03:07
0.711250226 71.605928 0.38371 03:10
0.735689195 74.064955 0.38399 03:13
0.741063613 74.604616 0.38490 03:16
0.765429098 77.056580 0.38555 03:18
0.808778839 81.419112 0.38637 03:21
0.833286427 83.885219 0.38790 03:23
0.838733185 84.431943 0.38881 03:26
0.863239898 86.897301 0.39127 03:29
0.887512707 89.339581 0.39560 03:31
0.912059522 91.809382 0.40142 03:33
03:35 100.660349
0.936399236 94.258042 0.41269 03:38
0.960253435 96.659049 0.43108 03:40
0.989378495 99.590531 0.48272 03:43
0.947395233 95.364274 0.44733 03:46
0.922164239 92.824232 0.41343 03:50
0.896260312 90.216544 0.40154 03:53
0.871019398 87.675606 0.39662 03:56
0.845776338 85.134465 0.39385 03:59
0.820622377 82.602373 0.39184 04:01
0.795353059 80.058612 0.39058 04:04
0.770161386 77.522679 0.39035 04:07
0.744990527 74.988854 0.38995 04:10
0.739101266 74.395934 0.38967 04:12
0.715203495 71.990271 0.38950 04:15
0.671745602 67.615817 0.38974 04:17
0.647462756 65.171421 0.39056 04:20
0.623101075 62.719051 0.39165 04:24
0.598894529 60.282361 0.39176 04:27
0.574458106 57.822545 0.39257 04:30
0.550105600 55.371188 0.39345 04:33
0.525759280 52.920465 0.39384 04:36
0.501423957 50.470861 0.39449 04:39
0.477254433 48.037918 0.39453 04:43
0.452809549 45.577313 0.39416 04:46
0.447841222 45.077155 0.39416 04:48
0.404107699 40.675086 0.39360 04:51
0.399237300 40.184762 0.39333 04:54
0.374836847 37.728701 0.39330 04:56
0.331181734 33.334600 0.39212 04:58
0.326291118 32.842261 0.39184 05:01
0.311771146 31.380727 0.39162 05:03
0.282644263 28.448947 0.39088 05:06
0.261619536 26.332683 0.39003 05:09
0.253428242 25.508146 0.38978 05:12
0.236545138 23.808763 0.38895 05:15
0.229012419 23.050523 0.38868 05:18
0.211368675 21.274612 0.38777 05:20
0.204970752 20.630600 0.38742 05:23
0.186183012 18.739556 0.38636 05:25
0.161138987 16.218803 0.38437 05:28
0.156135064 15.715128 0.38390 05:30
0.132063337 13.292255 0.38148 05:33
0.110850520 11.157145 0.37905 05:36
05:39 100.650112
0.107556048 10.825528 0.37668 05:41
0.085671109 8.622807 0.37367 05:44
0.057798925 5.817468 0.36753 05:46
0.035453052 3.568354 0.36061 05:50
0.010012646 1.007774 0.34404 06:00
ASAP 2020 V1.05 H Unit 1 Serial #: 182 Page 1

Sample: ZNIM2
Operator:
Submitter:
298 K
75 cm³
e
Isotherm Linear Plot
ZNIM2 - Adsorption
Relative Pressure (p/p°) Quantity Adsorbed (mmol/g)
0.0109486 0.357626
0.0223161 0.361748
0.0374998 0.364291
0.0655989 0.366546
0.0816228 0.368048
0.106027 0.369939
0.130565 0.372632
0.154891 0.375773
0.179261 0.378177
0.203701 0.380529
0.228217 0.383195
0.252632 0.38533
0.276997 0.386722
0.301404 0.387759
0.32581 0.388835
0.350214 0.389446
0.374574 0.390042
0.398998 0.390213
0.442977 0.389385
0.467227 0.38902
0.491567 0.388927
0.515996 0.388567
0.540437 0.387911
0.564827 0.387406
0.589134 0.386539
0.613551 0.385834
0.637965 0.385693
0.662494 0.384699
0.68691 0.384257
0.71125 0.383715
0.735689 0.38399
0.741064 0.3849
0.765429 0.385554
0.808779 0.386371
0.833286 0.387897
0.838733 0.388805
0.86324 0.39127
0.887513 0.395604
0.91206 0.401419
0.936399 0.41269
0.960253 0.431075
0.989378 0.482722
ZNIM2 - Desorption
0.989378 0.482722
0.947395 0.447332
0.922164 0.413426
0.89626 0.401541
0.871019 0.396616
0.845776 0.393854
0.820622 0.391837
0.795353 0.390584
0.770161 0.390353
0.744991 0.389948
0.739101 0.389666
0.715203 0.389501
0.671746 0.389739
0.647463 0.390562
0.623101 0.391654
0.598895 0.391762
0.574458 0.392568
0.550106 0.393449
0.525759 0.393845
0.501424 0.39449
0.477254 0.394533
0.45281 0.394163
0.447841 0.394165
0.404108 0.393602
0.399237 0.393326
0.374837 0.393295
0.331182 0.392121
0.326291 0.39184
0.311771 0.391621
0.282644 0.390878
0.26162 0.390028
0.253428 0.389784
0.236545 0.388948
0.229012 0.388675
0.211369 0.387775
0.204971 0.387424
0.186183 0.386365
0.161139 0.384372
0.156135 0.383898
0.132063 0.38148
0.110851 0.379053
0.107556 0.376684
0.0856711 0.373669
0.0577989 0.36753
0.0354531 0.360612
0.0100126 0.344036

Sample: ZNIM2
Operator:
Submitter:
298 K
75 cm³
e
Isotherm Log Plot
ZNIM2 - Adsorption
0.0109486 0.357626
0.0223161 0.361748
0.0374998 0.364291
0.0655989 0.366546
0.0816228 0.368048
0.106027 0.369939
0.130565 0.372632
0.154891 0.375773
0.179261 0.378177
0.203701 0.380529
0.228217 0.383195
0.252632 0.38533
0.276997 0.386722
0.301404 0.387759
0.32581 0.388835
0.350214 0.389446
0.374574 0.390042
0.398998 0.390213
0.442977 0.389385
0.467227 0.38902
0.491567 0.388927
0.515996 0.388567
0.540437 0.387911
0.564827 0.387406
0.589134 0.386539
0.613551 0.385834
0.637965 0.385693
0.662494 0.384699
0.68691 0.384257
0.71125 0.383715
0.735689 0.38399
0.741064 0.3849
0.765429 0.385554
0.808779 0.386371
0.833286 0.387897
0.838733 0.388805
0.86324 0.39127
0.887513 0.395604
0.91206 0.401419
0.936399 0.41269
0.960253 0.431075
0.989378 0.482722
ZNIM2 - Desorption
0.989378 0.482722
0.947395 0.447332
0.922164 0.413426
0.89626 0.401541
0.871019 0.396616
0.845776 0.393854
0.820622 0.391837
0.795353 0.390584
0.770161 0.390353
0.744991 0.389948
0.739101 0.389666
0.715203 0.389501
0.671746 0.389739
0.647463 0.390562
0.623101 0.391654
0.598895 0.391762
0.574458 0.392568
0.550106 0.393449
0.525759 0.393845
0.501424 0.39449
0.477254 0.394533
0.45281 0.394163
0.447841 0.394165
0.404108 0.393602
0.399237 0.393326
0.374837 0.393295
0.331182 0.392121
0.326291 0.39184
0.311771 0.391621
0.282644 0.390878
0.26162 0.390028
0.253428 0.389784
0.236545 0.388948
0.229012 0.388675
0.211369 0.387775
0.204971 0.387424
0.186183 0.386365
0.161139 0.384372
0.156135 0.383898
0.132063 0.38148
0.110851 0.379053
0.107556 0.376684
0.0856711 0.373669
0.0577989 0.36753
0.0354531 0.360612
0.0100126 0.344036

Sample: ZNIM2
Operator:
Submitter:
298 K
75 cm³
e
BET Surface Area Report

BET Surface Area: 29.6683 ± 0.3393 m²/g
Slope: 3.317342 ± 0.037377 g/mmol
Y-Intercept: -0.028543 ± 0.004204 g/mmol
C: -115.222864
Qm: 0.30406 mmol/g
Correlation Coefficient: 0.9998096
Molecular Cross-Sectional Area: 0.1620 nm²
Relative Quantity
Pressure Adsorbed 1/[Q(p°/p
(p/p°) (mmol/g) - 1)]
---
0.065598928 0.36655 0.19153
0.081622810 0.36805 0.24148
0.106026993 0.36994 0.32060
0.130565092 0.37263 0.40300
0.154891388 0.37577 0.48774

Sample: ZNIM2
Operator:
Submitter:
298 K
75 cm³
e
BET Surface Area Plot
ZNIM2
Relative Pressure (p/p°) 1/[Q(p°/p - 1)]
0.0655989 0.191529
0.0816228 0.241482
0.106027 0.320599
0.130565 0.403004
0.154891 0.48774
Sample: ZNIM2
Operator:
Submitter:
298 K
75 cm³
e
Langmuir Surface Area Report

Langmuir Surface Area: 36.0178 ± 0.0376 m²/g
Slope: 2.709019 ± 0.002825 g/mmol
Y-Intercept: 0.129007 ± 0.012945 kPa·g/mmol
b: 20.998988 1/kPa
Qm: 0.36914 mmol/g
Molecular Cross-Sectional Area: 0.1620 nm²
Quantity
Pressure Adsorbed p/Q
(kPa) (mmol/g) (kPa·g/mmol)
---
2.247798 0.36175 6.214
3.777114 0.36429 10.368
6.607230 0.36655 18.026

Sample: ZNIM2
Operator:
Submitter:
298 K
75 cm³
e
Langmuir Surface Area Plot
ZNIM2
Pressure (kPa) p/Q (kPa·g/mmol)
2.2478 6.21372
3.77711 10.3684
6.60723 18.0256

Sample: ZNIM2
Operator:
Submitter:
298 K
75 cm³
e
t-Plot Report
Micropore Volume: 0.000488 mmol/g
Micropore Area: 24.5259 m²/g
External Surface Area: 5.1424 m²/g
Slope: 0.014832 ± 0.000364 mmol/g·Å
Y-Intercept: 0.315229 ± 0.001543 mmol/g
Surface Area Correction Factor: 1.000
Density Conversion Factor: 0.0015468
Total Surface Area (BET): 29.6683 m²/g
Thickness Range: 3.5000 Å to 5.0000 Å
Thickness Equation: Harkins and Jura
t = [ 13.99 / ( 0.034 - log(p/p°) ) ] ^ 0.5
Relative Statistical Quantity

Pressure Thickness Adsorbed
(p/p°) (Å) (mmol/g)
---
0.022316096 2.8811 0.36175
0.037499821 3.0955 0.36429
0.065598928 3.3904 0.36655
0.081622810 3.5308 0.36805
0.106026993 3.7244 0.36994
0.130565092 3.9034 0.37263
0.154891388 4.0714 0.37577
0.179260732 4.2337 0.37818
0.203700907 4.3928 0.38053
0.228217186 4.5504 0.38319
0.252631769 4.7067 0.38533
0.276997295 4.8632 0.38672
0.301403885 5.0214 0.38776
0.325810287 5.1817 0.38883
0.350213519 5.3451 0.38945
0.374573855 5.5120 0.39004
0.398997858 5.6839 0.39021
0.442977291 6.0077 0.38939
0.467227497 6.1955 0.38902
0.491566655 6.3919 0.38893
0.515995789 6.5981 0.38857
0.540436955 6.8146 0.38791
0.564826831 7.0424 0.38741
0.589134442 7.2825 0.38654
0.613551500 7.5389 0.38583
0.637965071 7.8127 0.38569
0.662494138 8.1078 0.38470
0.686910057 8.4249 0.38426
0.711250226 8.7680 0.38371
0.735689195 9.1444 0.38399
0.741063613 9.2320 0.38490
0.765429098 9.6544 0.38555
0.808778839 10.5300 0.38637
0.833286427 11.1167 0.38790
0.838733185 11.2583 0.38881
0.863239898 11.9560 0.39127
0.887512707 12.7674 0.39560
0.912059522 13.7518 0.40142
0.936399236 14.9566 0.41269
0.960253435 16.4636 0.43108
0.989378495 19.0285 0.48272

Sample: ZNIM2
Operator:
Submitter:
298 K
75 cm³
e
t-Plot
Harkins and Jura
ZNIM2
Thickness (Å) Quantity Adsorbed (mmol/g)
2.88111 0.361748
3.09554 0.364291
3.39035 0.366546
5.02135 0.387759
5.18174 0.388835
5.34513 0.389446
5.51203 0.390042
5.68395 0.390213
6.00768 0.389385
6.19551 0.38902
6.39191 0.388927
6.59807 0.388567
6.81462 0.387911
7.04237 0.387406
7.28255 0.386539
7.53893 0.385834
7.81265 0.385693
8.10783 0.384699
8.42491 0.384257
8.76799 0.383715
9.14437 0.38399
9.232 0.3849
9.65441 0.385554
10.53 0.386371
11.1167 0.387897
11.2583 0.388805
11.956 0.39127
12.7674 0.395604
13.7518 0.401419
14.9566 0.41269
16.4636 0.431075
19.0285 0.482722
Fitted Points
Thickness (Å) Quantity Adsorbed (mmol/g)
3.53082 0.368048
3.72437 0.369939
3.90343 0.372632
4.07141 0.375773
4.23368 0.378177
4.39276 0.380529
4.55038 0.383195
4.70672 0.38533
4.8632 0.386722

Sample: ZNIM2
Operator:
Submitter:
298 K
75 cm³
e
Summary Report
Surface Area
Single point surface area at p/p° = 0.154891388: 30.9862 m²/g
BET Surface Area: 29.6683 m²/g
Langmuir Surface Area: 36.0178 m²/g
t-Plot Micropore Area: 24.5259 m²/g
t-Plot External Surface Area: 5.1424 m²/g
BJH Adsorption cumulative surface area of pores
between 17.000 Å and 3000.000 Å width: 4.1336 m²/g
BJH Desorption cumulative surface area of pores
between 17.000 Å and 3000.000 Å width: 3.0895 m²/g
Pore Volume
Single point adsorption total pore volume of pores
less than 1839.7910 Å at p/p° = 0.989378495: 0.016736 cm³/g
t-Plot micropore volume: 0.010929 cm³/g
BJH Adsorption cumulative volume of pores
between 17.000 Å and 3000.000 Å width: 0.003673 cm³/g
BJH Desorption cumulative volume of pores
between 17.000 Å and 3000.000 Å width: 0.001546 cm³/g
Pore Size
Adsorption average pore width (4V/A by BET): 22.5642 Å
BJH Adsorption average pore width (4V/A): 35.541 Å
BJH Desorption average pore width (4V/A): 20.018 Å
Horvath-Kawazoe
Maximum pore volume at p/p° = 0.960253435: 0.014945 cm³/g
Median pore width: 11.8546 Å
Dubinin-Radushkevich
Micropore surface area: 0.0000 m²/g
Monolayer capacity: 0.000000 cm³/g
Dubinin-Astakhov
Micropore surface area: 40.5700 m²/g
Limiting micropore volume: 0.012887 cm³/g

Sample: ZNIM2
Operator:
Submitter:
298 K
75 cm³
e
Sample Log Report

Date Time Message
2009-10-17 13:35:18 Degas operation started on Unit 1 - S/N: 182, port 1

.
2009-10-17 13:35:18 Started evacuation at 5.0 mmHg/s to 10 µmHg,
hold for 20 minutes.
2009-10-17 13:35:31 Operation canceled.
2009-10-17 13:35:31 Started backfilling.
2009-10-17 13:35:34 Degas operation done.
.
2010-01-21 20:01:57 Started temperature ramp at 10.0 °C/min to 300 °C.
2010-01-21 20:01:58 Started temperature hold at 300 °C for 600 minutes.
.
2010-06-18 18:09:29 Started temperature ramp at 10.0 °C/min to 300 °C.
2010-06-18 18:09:29 Started temperature hold at 300 °C for 600 minutes.
2010-06-19 4:09:30 Started cool-down wait.
2010-06-19 4:57:50 Started backfilling.
2010-06-19 12:48:48 Analysis Started.
2010-06-19 19:03:55 Analysis Done.

PH8

Uploaded by

Document Information

Original Description:

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

PH8

Uploaded by

Copyright:

Available Formats

ASAP 2020 V1.

05 H Unit 1 Serial #: 182 Page 1

Isotherm Tabular Report

ASAP 2020 V1.05 H Unit 1 Serial #: 182 Page 1

Isotherm Linear Plot

ASAP 2020 V1.05 H Unit 1 Serial #: 182 Page 1

Isotherm Log Plot

ASAP 2020 V1.05 H Unit 1 Serial #: 182 Page 1

BET Surface Area Report

ASAP 2020 V1.05 H Unit 1 Serial #: 182 Page 1

BET Surface Area Plot

Langmuir Surface Area Report

ASAP 2020 V1.05 H Unit 1 Serial #: 182 Page 1

Langmuir Surface Area Plot

ASAP 2020 V1.05 H Unit 1 Serial #: 182 Page 1

t = [ 13.99 / ( 0.034 - log(p/p°) ) ] ^ 0.5

Relative Statistical Quantity

ASAP 2020 V1.05 H Unit 1 Serial #: 182 Page 1

ASAP 2020 V1.05 H Unit 1 Serial #: 182 Page 1

ASAP 2020 V1.05 H Unit 1 Serial #: 182 Page 1

Sample Log Report

2009-10-17 13:35:18 Degas operation started on Unit 1 - S/N: 182, port 1

2010-06-19 19:03:55 Analysis Done.

You might also like