Page # 52 ALKYL HALIDE

Exercise - IV (One or more than one option correct)

1. Which of the following compound will not 4. Which are possible products in following
undergo Nucleophillic substitution reaction.
CH3 moist Ag2O
Cl CH2Cl SN 1

CH3 OH
(A) (B)
Cl
CH3
(A) (B)
CH 2OH

Cl
Br
CH2OH CH3
| |

(C) (D) (C) (D)

OH

2. Consider the given reaction

5. SN1 & SN2 product are same in (excluding
CH3 steroisomer)
| NaCN
H — C — OTs CH3CH2 CH—CN Cl
| |
(S) H
C2H5 CH3
(A) (B)
Which of following statement are correct for
Cl
above reaction.
(A) Product formation takes place due to the
breaking of O— Ts
(B) The reaction SN2
(C) The reaction is SN1
(D) Configuration of product is (R) (C) (D) Ph — CH — CH — CH 3
| |
CH3 Cl
3. Rate of SN2 will be negligible in
Cl
Br Br 6. Statement 1 : On moving 1° to 3° alkyl halide
rate of E2 increases while rate of SN2 decreases
Statement 2 : E2 reaction give element effect
(A) (B)
respect to halogen.
(A) Statement-1 is true,statement-2 is true and
statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true
Br Br
and statement-2 NOT the correct explanation
for statment-1
(C) (D) (C) Statement :1 is true, statement-2 is false.
(D) Statement : 1 is false, statement -2 is
true

394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
IVRS No. 0744-2439051, 0744-2439052, 0744-2439053, www.motioniitjee.com, email-info@motioniitjee.com
 HALOGEN DERIVATIVES Page # 53

Paragraph for Question Nos. 11 to 13 (3 questions)

PCl5
7. CH3 — CH2 — O — CH3 :
Products are : Dehydration require an acid catalyst to
(A) CH3 — Cl (B) Et — Cl protonate the hydroxy group of the alcohol
and convert it into good leaving group. Loss of
(C) Cl (D) Cl water followed by a loss of a proton, given the
alkene an equilibrium is stablished between
reactants and products.
O
OH
8. PCl5
Ph — C — CH3   product are

+
H
Cl CH 3—CH=CH 2
|
(A) Ph — C — CH3 (B) Ph — CH — CH2 Mechanism
| | | H
+ +
Cl Cl Cl OH + H2SO4 O CH3—CH—CH2
(r.d.s) |
HSO4
Cl H H

(C) Ph — CH2 — CH H2O:

Cl
(D) Ph — CH2 — CH2 +
CH3—CH=CH2 + H3O
11. To improve the yield of above reaction which
of following is correct.
Zn—dust (A) High temperature
9. (p)
(B) Distillation
compound (p) is (C) Addition of H2O
(D) Both (A) and (B)
CH3 CH3
H Br +
H Br H
(A) (B)
H Br Br H 12. (i) (A) Major
OH
CH3 CH3

OH
Br H
+

Br (ii) (B) Major

(C)

Br
(D) Br OH

+
H
(C) Major
CH3

H Br Zn—dust
10. (p). The product (p) Total number of -hydrogen in A + B + C is
Br H
(A) 23 (B) 25
CH3 (C) 37 (D) 29

is 13. Which alcohol is most reactive towards

dehydration of alcohols in acids catayzed
(A) (B) reaction.

(C) (D)

394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
IVRS No. 0744-2439051, 0744-2439052, 0744-2439053, www.motioniitjee.com, email-info@motioniitjee.com
Page # 54 ALKYL HALIDE

OH OH

(A) (B)

OH
OH

(C) (D)

394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
IVRS No. 0744-2439051, 0744-2439052, 0744-2439053, www.motioniitjee.com, email-info@motioniitjee.com