N17/4/CHEMUSPM/ENG/TZO/XX eared Enea ) ere} Chemistry Standard level Paper 1 Wednesday 8 November 2017 (afternoon) 45 minutes Instructions to candidates + Do not open this examination paper until instructed to do so. + Answer all the questions. + For each question, choose the answer you consider to be the best and indicate your choice on the answer sheet provided. + The periodic table is provided for reference on page 2 of this examination paper. + The maximum mark for this examination paper is [30 marks]. 8817-6104 13 pages © International Baccalaureate Organization 2017N17/4/CHEMISPM/ENG/TZO/XX (egz) | (6sz) | (esz) | (sz) | (esz) | (esz) | (ave) | (zp2) | (eve) | (vez) | (ez) | cove | vo vez |po'zez a ON PW wd a cd 4a wo uy d aN n ed 4 sor | zor | tor | oo | 65 | a6 | we | 96 | so | v5 | ce | we | ie | 0 |g LGVL| |SOELL | C689 |9z'291 |€6'¥9L | 0S'Z9L | £6'BSI | Sz'zSt | 96'LSL |9EOSI | (SPI) | PZ HPL | LEO | ZL OPE _ aA wh a oH fa aL Po 2 ws Wd PN ad 8 2 | oc | 9 | e9 | uo | 9 | so | | co | zo | wo | of | os | os |y [ (vez) | (vez) | (esz) | (ez) | (az) | (e8z) | (Gaz) | (ae) | (ee) | (ezz) | (ez) | (oxz) | Coz) | (eae) | oe) | ze | Ceze) | ze) Fenn | son | unn | ann | 8nn | aun | uo | by | sa | w | cH | ua | Bs | aa | mw | ov | ew | ag elt Lue ou Sut vu ete | Zu Abb Ou 60+ | gor | 2OF 904 SOL vol | +68 88 2 (zzz) | (o12) | (602) | e6'802 | z:zoz |se'v0z |6s'00z | 26'961 | go's61 | zz ze1 |ez'o6! |rzoet | ve'eet | seost |srezt|teeer ee zes |rezer wa] ow fod | ia | ad | uu | fH] ny | ag | at | so | ou | m | oe | a |e | eg | 29 98 s8 8 £8 we 1 08 6L eh ab gL SL ve eh a dis 9s 3S G2LEL | OG'9ZL | O9AzL | 94 LZt | Let | ZevLE | Ly ZHL| L8'L0L | Zp'901 | L6zOL |zo'L01 | (g6) | 96's6 | teze | zzt6 | 1688 | zoze | zwSe ex I 1 as us ur PO by Pd a mn L ow aN 4Z A 4s ae vs es ws is os 6y ay ly oy sy vy ey oy Ww Or ee ee le oses | osez | a6'ez | zovz | eaves | zze0 | e's0 | soo | eos | eeas | sass | vers | ooze | veos | zezr | evr | eoor | ove mt | ag | es | sv | 99 | © | uz | no | Ww | ep | ed | UW | up A u | og | eo x x | se | ve | ec | ze | se | of | oz | a | wz | oz | sz | we | ce | | iz] o | o seee | svse | zoze | z60¢ | eorez | sez leve aw s d is Ww 5w ab a | st fom | ss zt eb0z | 006+ | oot | tov | oz | eon Scuicnions en 6 | 69 oN a ° N 2 a eee Eg 1 OL 6 8 Z 9 gs | v € quowio 00% 7 hor oH 4 if sequinu o1WO}y ¥ ab a ob sb oh ci a Wb oF 6 8 a 9 gs v t z b SIGE Dpoed eyN17/4CHEMI/SPM/ENG/TZ0/XX How many atoms of nitrogen are there in 0.50 mol of (NH,),CO,? A 4 Bo 2 C. 3.01 x 10" D. 6.01x 10" What is the value of x when 32.29 of Na,SO,-xH,0 are heated leaving 14.2g of anhydrous Na,SO,? M,(H,O) = 18; M,(Na,SO,) = 142 Na,SO,-+xH,0(s) > Na,SO, (s) + xH,0(g) A 04 Bt a 5 D. 10 How many grams of sodium azide, NaN, are needed to produce 68.1.cm’ of N, (g) at STP? Molar volume at STP = 22.7dm' mol"; M,(NaN,) = 65.0 2NaN, (s) > 3N, (g) + 2Na(s) 32.5 65.0 130.0 990 Dp > 195.0 What is the sum of the coefficients when the following equation is balanced using the smallest whole numbers? —C1H1,0,(aq) -» _C;H,OH (aq) + _CO,(g) A 4 BOS mn) D. 10 Turn over7 =4- N17/4/CHEMISPM/ENG/TZO/XX What is the number of protons and the number of neutrons in "1? Protons Neutrons A 53 78 B. 53 131 c. 78 53 D. 131 53 Which is the electron configuration of a chromium atom in the ground state? A. [Ne]3s*3p"4s'3d* B. [Arsa® C. _ 18'2s?2p"3s’3p"4s'3d* D. [Arl4s'3d° Which trends are correct across period 3 (from Na to Cl)? |. Atomic radius decreases |. Melting point increases Ill. First ionization energy increases A. Land tl only B. Landiii only C. Mand Ill only D. i landiltN17/4/CHEMISPM/ENG/TZO/XX 8 — Which oxide dissolves in water to give a solution with a pH below 7? MgO Lio CaO so D> PQ0 9. The electronegativity values of four elements are given. c N ° FE 26 3.0 34 4.0 What is the order of increasing polarity of the bonds in the following compounds? A. CO 2Fe(s)+3CO,(g) AH = -26.6kJ 13.3kJ are released for every mole of Fe produced. 26.6kJ are absorbed for every mole of Fe produced. Oo Dp > 53.2kJ are released for every mole of Fe produced, D. 26.6kJ are released for every mole of Fe produced.14. 15. N17/4/CHEMUSPM/ENG/TZO/XX The enthalpy changes for two reactions are given. Br,(l) +F,(g) > 2BF(g) AH =xkd Br,(l) + 3F,(g) > 2BrF,(g) AH=ykd What is the enthalpy change for the following reaction? BrF (g) + F,(9) > BrF, (9) A x-y B. x+y c. pet) d te-y 30) What is the enthalpy change, in kd, of the following reaction? 3H, (g) + N,(g) = 2NH, (g) Bond Bond enthalpy / kJ mol 945, 436 391 A. (6 x 391) ~[(3 x 436) + 945] B. (3x 391) - (436 + 945) C. -[(B x 436) + 945] + (3 x 391) D. -(6 x 391) + [(3 x 436) + 945] Turn over16. N17/4/CHEMISPM/ENG/TZO/XX The diagram shows the energy profile for a catalysed and uncatalysed reaction, Which represents the enthalpy change, AH, and the activation energy, E, _ for the catalysed reaction? 3 2 5 5 3 é Reaction coordinate aH E, (catalysed reaction) | A z | x+2 8 z zty c, ~z x D, zee x7. 18. N17/4\CHEMISPM/ENGITZO/XX Excess magnesium powder was added to a beaker containing hydrochloric acid, HCL(aq) ‘The mass of the beaker and its contents was recorded and plotted against time (line 1) Mass 1 Time Which change could give line II? A. Doubling the mass of powdered Mg B. Using the same mass of Mg ribbon C. Increasing the temperature D. Using the same volume of more concentrated HCl ‘What will happen if the pressure is increased in the following reaction mixture at equilibrium? CO, (g) + H,0(l) = H (aq) + HCO, (aq) A. The equilibrium will shift to the right and pH will decrease. B. The equilibrium will shift to the right and pH will increase. C. The equilibrium will shift to the left and pH will increase. D. The equilibrium will shift to the left and pH will decrease. Turn over19. 20. 24. 22. =10- N17/4/CHEMUSPM/ENG/TZOXX 10.0.cm® of an aqueous solution of sodium hydroxide of pH = 10 is mixed with 990.0cm’ of distilled water. What is the pH of the resulting solution? A 8 Bg aon Dd 12 ‘Which statement is incorrect for a 0.10moldm* HCOOH solution? pH=1 [H"] << 0.10moldm® Oo Dp > [HCOO" | is approximately equal to [H"] D. HCOOH is partially ionized What are the oxidation states of chromium in (NH,),Cr,O, (s) and Cr,O,(s)? (NH,),Cr,0, (8) Cr,0,(s) A 47 +3 B +6 i 3 c +6 +6 D. 47 a +6 Which of the following is a redox reaction? A. 3Mg(s) + 2AICL, (aq) > 2Al(s) + 3MgCl, (aq) B. Si0,(s) + 2NaOH (aq) > Na,SiO, (aq) + H,0(l) ©. KCl (aq) + AgNO, (aq) -» AgCl(s) + KNO, (aq) D. 2NaHCO, (aq) -» Na,CO, (aq) + CO, (g) + H,O(l)23. 25. -- N17/4ICHEMUSPM/ENG/TZ0/XX ‘What is the reaction type and major product at the anode (positive electrode) when molten sodium chlorid electrolysed using platinum electrodes? Reaction type Product i reduction ct, oxidation ct, reduction Na oxidation Na What is the major product of the reaction between HCI and but-2-ene? A B c. D. 1,2-dichlorobutane 2,3-dichlorobutane 1-chlorobutane 2-chlorobutane Which compound can be oxidized when heated with an acidified solution of potassium dichromate(V1)? A B. CH,C(O)CH,CH, CH,CH,CH(OH)CH, (CH,),COH CH,(CH,), COOH Turn over26. 27. -12- N17/4/C HEMUSPM/ENG/TZO/XX What is the name of this compound, using IUPAC rules? A. 3-methylbutan-3-ol B. 2ethylpropan-2-01 C. 2-methylbutan-2-o1 D. 3-methylbutan-2-o1 ‘Which type of reaction occurs between an alcohol and a carboxylic acid? A. Addition B. Oxidation Cc. Esterification D. Polymerization How many structural isomers of C,H, exist? A 4 5 B c 6 D.29. 30. -13- N17/4iC HEMVSPM/ENG/TZO/XX What information is provided by 'HNMR, MS and IR for an organic compound? A. B. c. D. |. 'HNMR: chemical environment(s) of protons Il, MS: fragmentation pattern lil. IR: types of functional group and Il only | and Ill only Wand Ill only 1, Wand Il student performs an acid-base titration using a pH meter, but forgets to calibrate it. Which type of error will occur and how will it affect the quality of the measurements? A B c. D. Random error and lower precision ‘Systematic error and lower accuracy ‘Systematic error and lower precision Random error and lower accuracy