(H 1 Batch) IRP Test 1 (JEE Advance) (Paper 1) Code A

DATE : 15-05-14 CODE - A
VIBRANT ACADEMY
(India) Private Limited
A-14(A), Road No.1, Indraprastha Industrial Area, Kota-324005 (Raj.)
Tel.:(0744) 2428664, 2428666, 2423406, 3205261, 3205262 Fax: 2423405
Email: admin@vibrantacademy.com Website : www.vibrantacademy.com
IRP H-1 BATCH TEST–1 (COURSE-2014)

JEE Advance (Paper-1)
Time : 3 Hours Maximum Marks : 252
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
INSTRUCTIONS
A. General :
1. This booklet is your Question Paper containing 84 questions. The booklet has
40 pages.
2. The question paper CODE is printed on the right hand top corner of this sheet and
on the back page (page no. 40) of this booklet.
3. The question paper contains 2 blank pages for your rough work. No additional sheets
will be provided for rough work.
4. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and
electronic gadgets in any form are not allowed to be carried inside the examination hall.
5. Fill in the boxes provided below on this page and also write your Name and VA
Roll No. in the space provided on the back page (page no. 40) of this booklet.
6. The answer sheet, a machine-readable Objective Response Sheet (ORS), is provided

separately.
7. DO NOT TAMPER WITH / MUTILATE THE ORS OR THE BOOKLET.
8. Do not open the question-paper booklet before being instructed to do so by the invigilators.
B. Question paper format  Read the instructions printed on the back page

C. Marking scheme  (page no. 40) of this booklet.
Name of the candidate VA Roll Number
I have read all the instructions and I have verified all the information filled
shall abide by them. in by the candidate.
.......................................................... ............................................................
Signature of the Candidate Signature of the invigilator
USEFUL DATA
Atomic weights: H = 1, He = 4, Li = 7, g = 10 m/s2 , B = 11, C = 12, N = 14, O = 16, F = 19, Ne = 20, Na = 23,
Mg = 24, Al = 27, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Ar = 40 , Ti = 48, Cr = 52, Mn = 55, Fe = 56,
Co = 59, Cu = 63.5, Zn = 65.5, Br = 80, Mo = 96, Ag = 108, I = 127, Ba = 137, U = 238
PART I : MATHEMATICS
SECTION - I
Single Correct Choice Type
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
1 1
1. Let f ( x )  lim n2  x n – x n 1  ; x  0 , then
n     xf(x) dx equals to
x2 x2 x2 x2 x2 x2 x2
(A) ln x  c (B) – ln x  c (C) ln x  c (D) ln x – c
2 4 2 2 4 2 4
 x 2 1  
2.    e  ln x  x – 2  dx  dx =
 x  
1
(A) ex.lnx + C1x + C2 (B) ex.lnx +  C1x  C 2
x
ln x
(C)  C1x  C 2 (D) None of these
x
– 1tan x   
 tan x – 2 cot x  0  x  
3. Let  tan 
 2 
 dx   then the value of
 tan –1
 3
 dx equals to :
  2 
x x 2 x x 2 x x 2 x x 2
(A) 2    c (B)  –  c (C) –  –  c (D) –   – c
2 2 2 2 2 2 2 2
Space For Rough Work
Vibrant Academy (I) Pvt. Ltd. "A-14(A)" Road No.1, Indraprastha Industrial Area, Kota (Raj.) Ph. 0744-2423406 [IRP [H1] T-1,P-1-A-2]
MATHEMATICS
4. If the functions f : {1, 2, ......., n}  {2011, 2012} satisfying f(1) + f(2) + ....... + f(n) = odd integer, are formed;
then the number of such functions are
(A) 2n (B) 2n/2 (C) n2 (D) 2n – 1

5. The area between the curve y = 2x4 – x2, the x-axis and the ordinates of two minima of the curve is , then
120
the value of '' is
(A) 7 (B) 11 (C) 13 (D) 17
6. A polynomial f(x) of degree 6 satisfies f(x) = f(2 – x)  x  R. If f(x) = 0 has 4 distinct and two equal roots; then
the sum of the roots of f(x) = 0 is
(A) 0 (B) 4 (C) 6 (D) 8
MATHEMATICS
7. Let m be the slope of tangent to the curve ey = 1+ x2, then |m| takes its largest value at x =
(A) 0 (B) ±1 (C) ± 2 (D) ± e
8. Lef f: [1, 2]  [1, 4] and g : [1, 2] [2, 7] are two continuous and bijective function such that f(1) = 4 and
g(2) = 7. The number of solutions of the equation f(x) = g(x)  x [1, 2] is :
(A) 0 (B) 1 (C) 2 (D) more than 2
MATHEMATICS
SECTION - II
Comprehension Type
This section contains 2 paragraphs. Based upon the first paragraph, 2 multiple choice questions and based
upon the second paragraph 3 multiple choice questions have to be answered. Each of these questions has
four choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
Paragraph for Question Nos. 9 to 10
1
ex
Let P  dx then answer the following.

0
x 1
1
x 2e x
9.  1  x dx
0
equals to
(A) P – e (B) e – 2 + P (C) 2 + P (D) 2 – e + P

1 2
 x  x
10. 
0
  e dx equals to
 x  1
e e e e
(A) P – (B)  1– P (C) –P (D) P – 1 
2 2 2 2
MATHEMATICS
Functions f, g, h are differentiable on some open interval around 0 and satisfy the equations and initial
conditions
1
f  = 2 f 2 gh + gh , f(0) = 1
4
g = fg2h + , g(0) = 1
fh
1
h = 3fgh2 + fg , h(0) = 1
11. The explicit formula for f(x), valid in some open interval around 0 is :
1 1 1 1
 2   6     6     6     6
1  sin  6 x    1  sin 6 x    1  sin 6x    1  sin 6 x   
 4   4     4 
     4   
(A) 2 12
 (B) 2 6
(C) 2 4 (D) 2 12  
3  3     
 cos  6 x  4    cos  6 x  4    cos 4  6 x     cos 2  6 x   
       4    4

12. The explicit formula for g(x), valid in some open interval around 0 is :
1 1 1 1
 4   6  4   6  2   6  3   6
1  sin  6 x    1  sin  6x    1  sin  6 x    1  sin  6x   
4 4 4 4
(A) 2 4   
(B) 2 12   
(C) 
2 12 
  (D) 2 6  
          
 cos  6 x     cos 3  6 x     cos 6x     cos 6 x   
  4    4   4    4 
13. The explicit formula for h(x), valid in some open interval around 0 is :
1 1 1 1
    6  2   6  3   6     6
1  sin 6x    1  sin  6 x    1  sin  6x    1  sin 6 x   
  4   4  4 – 4 
      
(A) 4
2  (B) 2 12 (C) 6
2  (D) 2 6
4    3     3 
 cos  6 x  4    cos  6 x  4    cos 6 x  4    cos  6 x   
           4
MATHEMATICS
SECTION - III
Multiple Correct Choice Type
answer, out of which ONE OR MORE is/are correct.
14. The triangle formed by the normal to the curve f(x) = x2 – ax + 2a at the point (2, 4) and the coordinate axes
lie in second quadrant. If its area is 2 sq. units, then a can be
17 19
(A) 2 (B) (C) (D) 5
4 4
2
15. The values of  in the interval [–, 0] satisfying sin+  cos 2x dx  0 is :

 
(A) –  (B)  (C)  (D) 0
2 3
16. Let f(x) = min ((t) , –3  t  x) x [–3, )

where (x) = ||x – 1| – |x + 1||, then
(A) f(x) is non differentiable at x = –1, 0 (B) f(x) is non differentiable at x = –1, 1
10
(C) f(100) = 0 (D)
 f (x) dx  5
3
MATHEMATICS
17. If sin(x + 20º) = 2sinx cos40º where x  (0, 90º), then which of the following hold good
x x
(A) sec = 6 2 (B) cot  2 3
2 2
(C) tan4x = 3 (D) cosec 4x = 2
1 1 2 1
2 3 2 4
x x x x
18. 
0

0
1

Let 1  (2010 ) dx,  2  (2010 ) dx,  3  (2010 ) dx,  4  (2010 ) dx then
0
(A) I1 > I2 (B) I2 > I1 (C) I3 > I4 (D) I2 > I4
MATHEMATICS
SECTION - IV
Integer Answer Type
This section contains 10 questions. The answer to each of the questions is a single-digit integer, ranging
from 0 to 9. The appropriate bubbles below the respective question numbers in the ORS have to be darkened.
For example, if the correct answers to question numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively,
then the correct darkening of bubbles will look like the following :
In all cases round answer to nearest integer value (if required)
X Y Z W
0 0 0 0
1 1 1 1
2 2 2 2
3 3 3 3
4 4 4 4
5 5 5 5
6 6 6 6
7 7 7 7
8 8 8 8
9 9 9 9
19. If 1, 2, 3, ......., n are the roots of the equation xn – 6x + 7 = 0 and (1 – 2) (1 – 3) ........ (1 – n) = ,
then the value of n1n – 1 –  is equal to.
20. The smallest value attained by function f(x) = (x – 2) (x – 4) (x – 6) (x – 8) + 17 is :
MATHEMATICS
21. If log2 (a + b) + log2(c + d)  4, then minimum value of the expression a + b + c + d is.
22. Let f(x) = ax2 + bx + c, (a 0) & f(x) = 0 has two distinct real roots. If range of values of 'k', (k  0) for which
f(x + k) +  f(x) = 0 has exactly one root between the roots of f(x) = 0, for any real value of  is (k1, k2) – {0}
k1
then find k
2
MATHEMATICS
23. Find the sum of all real values of x satisfying the equation
17  8 x – 2x 2  4  12x – 3 x 2  x 2 – 4 x  13.
  1  
24. Let f(x) be a continuous function defined for x  R and lim  ef ( x )  ln 1 – ef ( x )  – ln f ( x )   1 . Then f(0) is
x 0  e  
MATHEMATICS
f ' (x) x
25. Let f(x) be a differentiable function satisfying the equation  f(x)  x  R .
2 e
If f'(1) = 1; find the number of solution of the equation f(x) = f '(x).
26. Find the sum of all values of 'x' which satisfy x2 + 2x sin(xy) + 1 = 0.
MATHEMATICS
27. If f : R  R is a monotonic, differentiable real valued function, a, b are two real numbers and
b f (b )
 f ( x)  f (a) f (x)  f (a) dx  k  xb – f 

–1
( x ) dx then find the value k
a f (a )
28. In an acute angled triangle ABC, A = 20º, let DEF be the feet of altitudes through A, B, C respectively and
AH BH CH
H is the orthocentre of ABC. Find   .
AD BE CF
PART II : PHYSICS
SECTION - I
29. The moment of inertia of hollow sphere of mass M inner radius R/2 and outer radius R, having material of
uniform density, about a diametrical axis is
31MR2 43 MR 2 19 MR 2
(A) (B) (C) (D) None of these
70 90 80
30. Characteristic X-rays are produced due to

(A) transfer of momentum in collision of electrons with target atom
(B) transition of electrons from higher to lower electronic orbit in an atom
(C) heating of the target
(D) transfer of energy in collision of electrons with atoms in the target
31. An organ pipe vibrates in fundamental mode with the medium first as air, then hydrogen and then methane.
The velocity of sound in the three media are different owing to which in the three cases :
(A) the frequency changes
(B) the wavelength changes
(C) the wavelength & frequency both changes
(D) the wavelength & frequency both remain unchanged
PHYSICS
32. The longest wavelength of the radiation which leads to ionization of hydrogen atom in the ground state, is m.
What is the wavelength of the radiation (in terms of m) emitted by hydrogen atom when it undergoes
transition from N = 2 to N = 1 state, N being the principal quantum number?
4 3 1 2
(A) m (B) m (C) m (D) m
3 4 4 3
33. In a photoelectric experiment, the potential difference across the electrodes is equal to the stopping potential
and the emitter plate is held at negative potential with respect to the collector plate. Mark the correct
statement, if light of sufficient energy falls on emitter
(A) No electron is emitted from the emitter plate.
(B) Electron is emitted from the emitter plate but it stops at half the length of the tube.
(C) Electron is emitted from the emitter plate but it stops just before reaching the collector plate.
(D) Emitted electrons will reach the collector plate.
34. The space between the plates of a parallel plate capacitor is filled completely with a dielectric substance
having dielectric constant 4 and thickness 3 mm. The distance between the plates is now increased by
inserting a second sheet of thickness 5 mm and dielectric constant K. If the capacitance of the capacitor so
formed is one-half of the original capacitance, the value of K is
10 20 5 15
(A) (B) (C) (D)
3 3 3 3
PHYSICS
35. The type of metal usually preferred in cooking utensils is one having
(A) Low thermal conductivity but high specific heat capacity
(B) High thermal conductivity but low specific heat capacity
(C) High thermal conductivity and high specific heat capacity
(D) Low thermal conductivity and low specific heat capacity
36. Two vessels of volume V1 and V2 contain same gas at pressure P1 and P2 respectively at the same
temperature. Pressure of the gas when the vessels A and B are connected by a tube of negligible volume is:
P1V1  P2 V2 P1V1  P2 V2 P1V2  P2 V1 (P1  P2 )( V1  V2 )

(A) (B) (C) (D)
2( V1  V2 ) V1  V2 V1  V2 V1  2V2
PHYSICS
SECTION - II
Comprehension Type
Three identical smooth cylinders each of mass m are kept on a smooth horizontal surface as shown in figure. A
horizontal force F is applied on the cylinder A. Line of action of force F passes through mid point (centre) of
cylinder A.
A B
F
37. What is minimum value of F such that all three cylinders move together ?
mg mg
(A) (B) (C) 3mg (D) 3 3mg
3 2
38. What is maximum value of F such that all three cylinders move together ?
mg
(A) (B) 3mg (C) 3 3mg (D) 3 mg
2
PHYSICS
There is a rigid cover on top of the cylinder, fully filled with water. The cylinder is rotated with angular speed
0 about its geometrical axis. Now the cover is removed and centre of bottom is just exposed after spill of
liquid (Case-1). Then angular speed is increased from 0 to 20 (Case-2).
0 20
R R
H H
Case-1 Case-2
39. Force on top cover when the fully filled cylinder is rotating with 0, is
 2R 4 32R 4
(A) (B) (C) 2R4 (D) None of these
4 4
40. Which of the following is true of case-1?
2gH 2gH 2gH 2gH
(A) 0  (B) 0  (C) 0  (D) 0 
3R 2R R 4R
41. In case-2, how much area of bottom will get uncovered?
R 2 3R 2 R 2
(A) (B) (C) (D) None of these
4 4 8
PHYSICS
SECTION - III
c
42. Refer to the circuit given below. If switch s is closed then
(Choose the correct option(s)) s
(A) Charge on capacitor a will increase
(B) Capacitance of the circuit will increase a b
+
d
(C) Potential difference across capacitor e will increase – f e
(D) Energy stored in the system will increase
43. In the circuit shown, the coil resistance of the Ammeter is 1 while that of the Voltmeter is 200. The main
branch current is 1A. Choose the correct option(s).
1
(A) Reading of ammeter is A
3
100V
400 A
(B) Reading of voltmeter is V 1A 100 99
3
200
(C) Reading of ammeter is V V
3
420
(D) Reading of voltmeter is V
3
PHYSICS
44. Which of the following transitions of He+ ion will give rise to spectral line which has same wavelength as
some spectral line in hydrogen atom?
(A) n = 4 to n = 2 (B) n = 6 to n = 5 (C) n = 6 to n = 3 (D) n = 8 to n = 4
45. Two pulses on the same string are described by the following wave equations :
5 5
y1 = 2 and y2 = .
(3 x  4 t )  2 (3 x  4t  6 )2  2
Choose the correct statement(s).
(A) Pulse y1 and pulse y2 travel along +ve and –ve x axis respectively.
(B) At t = 0.75 s, displacement at all points on the string is zero.
(C) At x = 1m displacement is zero for all times.
(D) Energy of string is zero at t = 0.75 s.
46. Which of the following statement(s) are not true?

(A) The doppler shift for sound waves observed only when there is relative motion of the source and the
receiver.
(B) Only transverse waves can diffract.
(C) Two wave sources that are out of phase by 180° are incoherent.
(D) Interference patterns are only observed for coherent sources.
PHYSICS
SECTION - IV
Integer Answer Type
X Y Z W
0 0 0 0
1 1 1 1
2 2 2 2
3 3 3 3
4 4 4 4
5 5 5 5
6 6 6 6
7 7 7 7
8 8 8 8
9 9 9 9
47. A hollow cylinder of mass M = 4 kg and radius R = 1 m is pivoted in a vertical plane at its centre and has three
particles of mass m = 2 kg, mounted at its perimeter as shown in the figure. The system is originally at rest.
Find the angular speed (in rad/sec) of the cylinder, when it has swung through 90º in anticlockwise direction.
m
m R
M
PHYSICS
48. Interference pattern is formed on a screen by Young’s double slits S1 & S2 illuminated by mono-chromatic
light of wavelength . Points P and P are on the screen closest to and on either side of central maximum
where intensity is one fourth of that at the central maximum. If PP is written in terms of , d and D, correct
2D
expression is PP  . Find the value of x.
xd
P
S2
d
S1
P
D
49. In the figure three process on a gas are shown. Determine the value of Cv/R = x for the gas, if AC represents
adiabatic process and BA represents isothermal process.
P
16P0 = P1 A
2P0 = P2 B
P0 = P3 C
V
O
PHYSICS
50. The depth of water in a swimming pool is 2 m. An incandescent lamp is operated 3 m above the surface of the
water. Exactly below the lamp a 1 diopter lens, which has small diameter, is moved up and down. The lens
is at a distance x meter from the surface of the water, when a sharp enlarged image of the filament of the
lamp appears at the bottom of the pool. Find the value of 6x. (Refractive index of water = 4/3)
51. A solid sphere of copper of density , specific heat c and radius r is at temperature T1 K. It is suspended
inside a chamber whose walls are at temperature 0 K. Emissivity of the sphere is e. The time 't' required for
the temperature of the sphere to drop to T2K is given by following equation :
rc  1 1 
 
t = xe   T 3 T 3  . What is the value of x?
 2 1 
PHYSICS
52. Two concentric coplanar circular loops made of wire, with resistance per unit length 10–4 m–1, have diameters
0.2 m & 2m. A time varying potential difference (4 + 2.5 t) volts (t is time) is applied across the larger loop. If
5
the current in the smaller loop is Ampere, find the value of n.
n
53. Imagine a very thin uniform wire of length meter and total mass 1 gram. Fix one end of the wire in the

ceiling, hang a large mass of 1 kg from the other end, then pluck the wire meter from the top. Assume that
4
as the wire vibrates the large mass is not moving. The lowest frequency heard by us is 100 Hz. What is the
length of the wire (in meter).
54. A certain crude oil has an idex of refraction of 1.25. A ship dumps 1 m3 of this oil into the ocean and it spreads
 4
into a thin uniform film on water surface     . When light of wavelength 500 nm is incident on it, the
 3 
reflected light shows maximum. What is the area (in km2) covered by the spilled oil? Assume that the
thickness of film is minium required to satisfy this criterion.
PHYSICS
55. The diagram shows a circuit having a coil of resistance R = 10  and inductance L connected to a conducting
rod PQ which can slide on a perfectly conducting circular ring of radius 10 cm with its centre at 'P'. Assume
that friction & gravity are absent and a constant uniform magnetic field of 5 T exists as shown in figure. At
t = 0, the circuit is switched on and simultaneously a time varying external torque is applied on the rod so
that it rotates about P with a constant angular velocity 40 rad/s. If the magnitude of this torque (in milli Nm)
10
when current reaches half of its maximum value is equal to then n is. (Neglect the self inductance of the
n
loop formed by the circuit.)
56. At a certain place, the angle of dip is tan–1(4/5). The earth’s magnetic field has a vertical component of
2/25 T at that place. A square coil ABCD of side 2 m is hinged on a vertical fixed axis through its COM (as
shown in figure) such that initially its normal makes an angle of 37º from the horizontal component of the
earth’s magnetic field. The plane of the coil is always vertical and it is free to rotate around the shown axis.
If the coil is made of 4 rods each of mass 300 gm, find the angular acceleration (in rad/s2) of the coil when a
current of 10 A passes through it.
A B
COM
D C
Vertical
Axis
PART III : CHEMISTRY
SECTION - I
57. AgBr has the highest solubility in
(A) 0.01 M KBr (aq) solution (B) 0.1 M HBr (aq) solution
(C) 0.1 M NH3(aq) solution (D) pure water
58. Compound N2+[PtF6]¯ is not formed in analogy to compound O2+ [PtF6]¯ as formed in Bartlett’s experiment,
because
(A) The I.E. of N2 is higher than that of N atom (B) The I.E. of N2 is lower than that of O2
(C) The I.E. of N2 is higher than that of O2 (D) The I.E. of N atom is higher than O atom
59. Myrcene , C10H16 , a terpene isolated from oil of bay, absorbs three moles of hydrogen to form C10H22. Upon
ozonolysis myrcene yields :
CH3 – C – CH3 H–C–H H – C – CH2 – CH2 – C – C – H

|| || || || ||
O O O O O
On the basis of isoprene rule, what is the most likely structure for myrcene?
(A) (B) (C) (D)
CHEMISTRY
60. What is the value of compressibility factor for 1 mole of a vander waals gas at 24.5 atm pressure present in
2.0 L vessel ? Assuming that the volume of gas molecules is negligible & vander Waal constant
a = 2 L2 atm mol–1
(A) 0.5 (B) 0.75 (C) 0.98 (D) 0.99
cat. AlCl3  or
61. (A) + 2 Br2 (B)
h
Major compounds (A) and (B) are respectively :
Br Br
Br
(A) ; (B) ; Both
Br
Br Br
Br
Br Br
(C) ; (D) ; Both
Br Br
Br

62. Fe  Cl2 ( dry gas )  P
Excess
compound P doesnot undergo redox reaction with

(A) I– (aq) (B) SCN– (aq) (C) S2O32– (aq) (D) (NH4)2S
CHEMISTRY
63. Final product of the below reaction sequence is :
O O 1) 1 equivalent of
NaOEt in EtOH 2) dilute NaOH; 
OEt ?
acidic workup
Br
(0.5 equivalent)
Br
O
O O
(A) (B) (C) (D)
64. Predict the major product of the following
HNO3
?
75% H2SO4/25% H2O
NO2
(A) (B) (C)

NO2 NO2
(D) All the three products are in same ratio
CHEMISTRY
SECTION - II
Comprehension Type
In close packing arrangement some space isocupied by spheres. The remaining space is vacant and constitates
interstitial voids or holes like tetrahedral voids, octahedral voids, cubic voids.
65. Metal X crystallizes in primitive (simple) cubice lattice. The radius of largest atom that can fit into the voids
of metal X lattice without disturbing it is 146.4 pm. The edge length of unit cell is :
(A) 200 pm (B) 400 pm (C) 707.2 pm (D) None of these
66. Select incorrect statement

(A) A NaCl type AB crystal lattice can be interpreted to be made up of two individual FCC type lattice of A+
and B– fused together in such a manner that the corner of one unit lattice become edge centre of the
other.
(B) In a face centred cubic unit cell, the body centre is octahedral void.
(C) In a simple cubic unit cell, there is no octahedral void
(D) In a body centred cubic unit cell, the body centre is cubic void
CHEMISTRY
The splitting of five degenerate d-orbitals of the metal ion in to sets of orbitals having different energies is
called crystal field splitting. The concept froms the basis of crystal field theory.
67. The expected spin-only magnetic moments of K3[Co(CN)6] and K4[MnF6] respectively are
(A) 1.73 and 1.73 BM (B) 1.73 and 5.92 BM (C) 0.0 and 1.73 BM (D) 0.0 and 5.92 BM
68. Which of the following complex has its CFSE = – 4 Dq

(A) Cr(CO)6 (B) [Cr(NH3)6]3+ (C) [FeF6]4– (D) [Ni(Py)6]2+
69. The complex exhibits lowest energy absorption band is

(A) [NiCl4]2– (B) Ni(CO)4 (C) [Ni(CN)4]2– (D) [Ni(H2O)6]2+
CHEMISTRY
SECTION - III
70. Consider the following reactions :
(i) K2[PtCl4] + 2NH3  ‘A’ + 2KCl
(ii) [Pt(NH3)4] (NO3)2 + 2KCl  ‘B’ + 2NH3 + 2KNO3
If empirical formulae of A and B are same and A is more soluble in polar solvents, such as ethanol, while B is
more soluble in carbon-tetra chloride, then according to the given information the correct statement(s) is/are
(A) ‘A’ and ‘B’ are geometrical isomers. (B) B is non reactive towards H2C2O4
(C) A is reactive towards H2C2O4 (D) ‘A’ is paramagnetic, while ‘B’ is diamaganatic.
71. Which of the following compound is/are aromatic?
H3C CH3
2+ 2– +
(A) (B) (C) – (D)
H3C CH3
 H2O
72. P4  Cl2 (dry gas)  X  Y
(Limited)
then correct statement(s) about Y is/are

(A) PH3 can be obtained on heating Y (B) Y has reducing character
(C) Y exhibits tautomerism (D) Y has oxidizing character
CHEMISTRY
Et
, cat. AlCl3
Cl (P)
73.
(Q)
CO2Me
, cat. AlCl3
OMs
Major products (P) and (Q) are :
Et CO2Me
(A) Product (P) = ; Product (Q) =
Et Et CO2Me
(B) Product (P) = + ; Product (Q) =
(50 : 50)
Et CO2Me CO2Me
(C) Product (P) = ; Product (Q) = +
(50 : 50)
Et Et CO2Me CO2Me
(D) Product (P) = + ; Product (Q) = +
(50 : 50) (50 : 50)
74. Consider the following reaction

XeF6 + water  Xe-compound + HF
then molecular shape of all Xe-compound(s) formed during stepwise hydrolysis is/are
(A) Square pyramid (B) Bent-T-shape
(C) Triangular pyramid (D) See-Saw
CHEMISTRY
SECTION - IV
Integer Answer Type
X Y Z W
0 0 0 0
1 1 1 1
2 2 2 2
3 3 3 3
4 4 4 4
5 5 5 5
6 6 6 6
7 7 7 7
8 8 8 8
9 9 9 9
75. How many moles of permangnate are required to oxidise one mole of toluene to benzoic acid (use H2O &
protons to balance the equation).
Ph – CH 3 + MnO 4 PhCO 2H + MnO2
Toluene Permanganate Manganese
dioxide
76. Consider the following sequence of reactions and predict number of atom(s) in compound (Y) which is/are
sp2 hybridized.
conc H SO CH OH
Na 2B 4O 7 ·10H2 O   
2

4
( X)  
3
( Y )  (Volatile compound)
CHEMISTRY
77. 40 ml of 0.5 M oxalic acid (molar mass = 126) is shaken with 25.2 g of wood charcoal. The final concentration
of the solution after adsorption is 0.25 M. If the weight of oxalic acid adsorbed per g of carbon is represented
as y × 10–2 then find the value of y. (Assume volume of oxalic acid remains constant)
78. How many sulphur atom(s) have zero oxidation state present in product (X) formed in following reaction.
S2O32– (aq) + I3– (aq)  I¯ (aq) + (X)
CHEMISTRY
79. X = total number of -elimination products. Find the value of X ?
80. 12 ml aqueous solution of a diprotic acid (d = 1.25 g/ml) containing 17 weight percent of acid is completely
neutralised with x g of NaOH. If x g NaOH dissolved in water and formed 15 litre NaOH(aq) solution.
Calculate pOH of solution at 25ºC (Given : Molar mass of acid = 34 g)
CHEMISTRY
81. How many moles of hypophosphorous acid are involved in its thermal decomposition reaction when one mole
of each product is formed.
O
||
82. X = number of reaction in which will form as final product.
CH3
H3C CH3
H3C CH3
C—C
 solvolysis
(1) H3C O CH3 H 2O (2) H3C — C — C — CH3 H2O
+
H HO Cl
H3C CH3 H3C CH3

Ag+ HNO 2
(3) H3C — C — C — CH3 (4) H3C — C — C — CH3 H 2O
H2O
HO Cl HO NH2
H3C CH3

(5) H3C — C — C — CH3 H 2O
HO +OH2
Find value of 'X' ?
CHEMISTRY
83. A mixture of ethyl alcohol and propyl alcohol has a vapour pressure of 320 torr at 300 K. Calculate moles of
ethyl alcohol in vapour phase if total moles of mixture in vapour phase are 10.29.
Given : Vapour pressure of pure ethyl alcohol = 350 torr ; Vapour pressure of pure propyl alcohol = 200 torr.
84. How many of the structures with the molecular formula C6H12Cl2 can exist as meso compound ?
DATE : 15-05-14 CODE - A
Name of the candidate VA Roll Number
B. Question paper format :

9. The question paper consists of 3 parts (Chemistry, Mathematics and Physics).
Each part has 3 sections.
10. Section I contains 8 multiple choice questions. Each question has 4 choices (A),
(B), (C) and (D) for its answer, out of which only one is correct.
11. Section II contains 2 paragraphs. Based upon the first paragraph, 2 multiple choice
questions and based upon the second paragraph 3 multiple choice questions have to
be answered. Each of these questions has four choices (A), (B), (C) and (D), out of
which only one of correct.
12. Section III contains 5 multiple choice questions. Each question has 4 choices (A),
(B), (C) and (D) for its answer, out of which one or more is/are correct.
13. Section IV contains 10 questions. The answer to each of the questions is an

integer, ranging from 0 to 9. The answer will have to be appropriately bubbled in the
ORS as per the instructions given at the beginning of the section.
C. Marking Scheme :
14. For each question in Section I, you will be awarded 3 marks if you darken the
bubble corresponding to the correct answer and zero mark if no bubble is darkened.
In case of bubbling of incorrect answer, minus one (–1) mark will be awarded.
15. For each question in Section II, you will be awarded 3 marks if you darken the
bubble corresponding to the correct answer and zero mark if no bubble is darkened.
In case of bubbling of incorrect answer, minus one (–1) mark will be awarded.
16. For each question in Section-III, you will be awarded 3 marks if you darken the
bubble corresponding to the correct answer and zero mark if no bubbles is darkened.
No negative marks will be awarded for in this Section.
17. For each question in Section-IV, you will be awarded 3 marks if you darken the
bubble corresponding to the correct answer and zero mark if no bubbles is darkened.
No negative marks will be awarded for in this Section.

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DATE : 15-05-14 CODE - A

IRP H-1 BATCH TEST–1 (COURSE-2014)

6. The answer sheet, a machine-readable Objective Response Sheet (ORS), is provided

7. DO NOT TAMPER WITH / MUTILATE THE ORS OR THE BOOKLET.

Space For Rough Work

Space For Rough Work

Space For Rough Work

(A) P – e (B) e – 2 + P (C) 2 + P (D) 2 – e + P

Space For Rough Work

16. Let f(x) = min ((t) , –3  t  x) x [–3, )

Space For Rough Work

(C) tan4x = 3 (D) cosec 4x = 2

(A) I1 > I2 (B) I2 > I1 (C) I3 > I4 (D) I2 > I4

Space For Rough Work

20. The smallest value attained by function f(x) = (x – 2) (x – 4) (x – 6) (x – 8) + 17 is :

Space For Rough Work

Space For Rough Work

Space For Rough Work

Space For Rough Work

 f ( x)  f (a) f (x)  f (a) dx  k  xb – f 

Space For Rough Work

30. Characteristic X-rays are produced due to

Space For Rough Work

P1V1  P2 V2 P1V1  P2 V2 P1V2  P2 V1 (P1  P2 )( V1  V2 )

Space For Rough Work

Space For Rough Work

Space For Rough Work

Space For Rough Work

46. Which of the following statement(s) are not true?

Space For Rough Work

Space For Rough Work

Space For Rough Work

Space For Rough Work

Space For Rough Work

Space For Rough Work

CH3 – C – CH3 H–C–H H – C – CH2 – CH2 – C – C – H

(A) (B) (C) (D)

Space For Rough Work

compound P doesnot undergo redox reaction with

Space For Rough Work

(A) (B) (C) (D)

64. Predict the major product of the following

(A) (B) (C)

(D) All the three products are in same ratio

Space For Rough Work

66. Select incorrect statement

Space For Rough Work

68. Which of the following complex has its CFSE = – 4 Dq

69. The complex exhibits lowest energy absorption band is

Space For Rough Work

71. Which of the following compound is/are aromatic?

then correct statement(s) about Y is/are

Space For Rough Work

(A) Product (P) = ; Product (Q) =

(B) Product (P) = + ; Product (Q) =

(C) Product (P) = ; Product (Q) = +

(D) Product (P) = + ; Product (Q) = +

(50 : 50) (50 : 50)

74. Consider the following reaction

Space For Rough Work

Space For Rough Work

Space For Rough Work