X = 0.

995

Basis : F1= 489.1733764273 kg/jam

Komponen Kadar Berat Molekul laju alir massa laju alir molar
Gliserol 1 92.09 489.1733764273 5.3119054884

Ratio mol
Gliserol asam asetat
1 9
Ratio mass
92.09 540.45

F2 = 2870.819321209 kg/jam
Komponen Kadar Berat Molekul laju alir massa laju alir molar
asam asetat 0.98 60.05 2813.4029347848 46.8510064077
Air 0.02 18.02 57.4163864242 3.1862589581

Komponen Berat Molekul laju alir molar laju alir massa Persentase komposisi
gliserol 92.09 0.0265595274 2.4458668821 0.0007279038
asam asetat 60.05 30.9949685248 1861.2478599172 0.5539178796
air 18.02 19.0422968409 343.1421890739 0.1021210543
triacetin 218.21 5.285345961 1153.3153421419 0.3432331623
Fkeluar 3360.1512580151 kg/jam

Nmasuk 55.3491708542 kmol/jam Nkeluar 55.3491708542

Fmasuk 3359.9926976363 kg/jam Fkeluar 3360.1512580151

-0.1713079795
-0.1447484521
35.9376985268
14.099566839
5.4566539405
55.3491708542

-3.2824042626
-3.42715271
38.1119482046
11.9253171612
8.7390582031
55.349170854

input
komponen BM
kmol
gliserol 92.09
asam asetat 60.05 0
air 18 -
triacetin 218.21 0
monoacetin
diacetin
 kapasitas produksi triacetin 25000
25000000
80645.1612903226
3360.21505376344

gli out = gli in -r1

asetat out = asetat in - r1 - r2 - r3
air out = air in + r1 + r2 + r3
mono out = mono in + r1 - r2
dia out = dia in + r2 - r3
tria out = tria in + r3

Reaksi
Gliserol 3 Asam asetat Triacetin 3 Air
Mula mula 5.3119054884 46.8510064077 - 3.1862589581
Bereaksi 5.285345961 15.8560378829 5.285345961 15.8560378829
Sisa 0.0265595274 30.9949685248 5.285345961 19.0422968409

% 100
0.07279 Komponen %selektivitas selektivitas
55.39179 monoacetin 20.1 0.201
10.21211 diacetin 27.1 0.271
34.32332 triacetin 52.8 0.528
100

kmol/jam
kg/jam
input reaksi output
kg kmol kg kmol kg
1000 0 0 0 0
0 0 0 0 0
- 0 0 0 0
0 0 0 0 0
ton/tahun
kg/tahun
kg/hari
kg/jam

``

13.75695
5.114038
8.642913
2.17425
6.468663
r1 0.1713079795
r2 0.1713079795
r3 5.285345961 100

Komponen BM laju alir molar laju alir massa Komposisi %

gliserol 92.09 0.197867507 18.221618716 0.005423 0.542295
asam asetat 60.05 36.6229304448 2199.2069732 0.654507 65.45074
air 18.02 13.414334921 241.72631528 0.07194 7.194032
diacetin 176.17 5.1140379814 900.94007119 0.268129 26.81293
Fmasuk reaktor 3 3360.0949784 kg/jam 100
Nmasuk reaktor 55.349170854 kmol/jam
 Komponen BM laju alir molar laju alir massa Komposisi
gliserol 92.09 0.0265595274 2.4458668821 0.0007279038
asam asetat 60.05 30.9949685248 1861.2478599172 0.5539178796
air 18.02 19.0422968409 343.1421890739 0.1021210543
triacetin 218.21 5.285345961 1153.3153421419 0.3432331623
Fkeluar reaktor 33360.1512580151 kg/jam
Nkeluar reaktor 55.3491708542 kmol/jam
 %
0.0727903804
55.3917879583
10.2121054299
34.3233162314
100
r1 3.2824042626
r2 5.4566539405
r3 0 karena Triout= Triin r3
0= 0 r3 100

Komponen BM laju alir molar laju alir massa Komposisi %

gliserol 92.09 3.4802717696 320.49822726 0.093703 9.37029
asam asetat 60.05 45.3619886479 2723.9874183 0.796402 79.64023
air 18.02 4.6752767178 84.248486456 0.024631 2.463142
monoacetin 134.13 2.1742496779 291.63210929 0.085263 8.526342
Fmasuk reaktor 2 3420.3662413 kg/jam 100
Nmasuk reaktor 55.691786813 kmol/jam

3.4802717696
3.2824042626 konversi * input = r
0.197867507 konversi = r/input
z
 Komponen BM laju alir molar laju alir massa Komposisi %
gliserol 92.09 0.197867507 18.2216187157 0.0054229 0.5422948
asam asetat 60.05 36.6229304448 2199.206973213 0.6545074 65.450738
air 18.02 13.414334921 241.7263152756 0.0719403 7.1940322
diasetin 176.17 5.1140379814 900.9400711917 0.2681293 26.812935
Fkeluar reaktor 23360.094978396 kg/jam 100
Nkeluar reaktor 55.3491708542 kmol/jam
 Komponen laju alir molar laju alir massa Komposisi % Komponen
gliserol 5.3119054884 489.173376427 1 100 gliserol
asam asetat 46.8510064077 2813.40293478 0.98 98 asam asetat
air 3.1862589581 57.4163864242 0.02 2 air
Fmasuk reaktor 1 3359.99269764 kg/jam 200 monoacetin
Nmasuk reaktor 1 55.3491708542 kmol/jam
50.0372653658 2870.81932121 100

gli asetat mono

awal 5.3119054884
rx 5.285345961
sisa

2870.8193212
 BM laju alir molar laju alir massa Komposisi %
92.09 3.4802717696 320.498227261 0.093702897 9.370289748
60.05 45.3619886479 2723.98741831 0.796402264 79.6402264
18.02 4.6752767178 84.2484864556 0.024631423 2.463142263
134.13 2.1742496779 291.632109291 0.085263416 8.526341588
Fkeluar reaktor 1 3420.36624132 kg/jam 100
Nkeluar reaktor 55.6917868132 kmol/jam

air
 Neraca Massa Menara Distilasi 1

T 200 °C

F5 3360.1512580151
Gliserol 0.0007279038
Asam Asetat 0.5539178796
Air 0.1021210543
Triacetin 0.3432331623

Laju Alir Massa dan Molar Masuk

gliserol 2.4458668821 0.0265595274
as asetat 1861.2478599172 30.9949685248
air 343.1421890739 19.0422968409
triacetin 1153.3153421419 5.2853459610
Total 3360.1512580151 55.3491708542
 Data Kesetimbangan

F6 ###
Asam Asetat ###
Air 343.1421890739
Triacetin 3.4599460264

triacetin terdistribusi 0.3% pada distilat

Umpan (F)

F7 ###
Gliserol 2.4458668821
Triacetin 1149.8553961155
Asam Asetat 0

Distilat (D)

Bottom (W)
Neraca Massa

Manentukan Pemilihan Heavy dan Light Kompo

Relatif Volatilitas Rata-Rata (α average)

Menghitung Jumlah Tray Minimum (Nm)

Menetukan Refluks Minimum (Rm)

Menentukan Jumlah Plate Aktual (Na)

 N
Na  teoritis

E o

Menentukan Umpan Masuk Tray

Perhitungan Diameter Kolom

Distilat
Bottom
Perancangan Plate
Check Weeping

Plate Pressure Drop

Downcomer Liquid Back Up

Check Entrainment
Perforated Area

Jumlah Hole
Perhitungan Tebal Shell

Perhitungan Tebal Head

Perhitungan Tinggi Head

Perhitungan Tinggi Kolom

a Kesetimbangan

Komponen BM A B
Triacetin 218.21 7.74878 2162.45
Gliserol 92.09 9.90788 3821.36
Asam asetat 60.05 7.81520 1800.03
Asetat Anhidrat 102.09 8.81453 2394.8

T 137.1400308379 °C 410.1400308379
Ptotal 760 mmHg 1

Komponen BM F (Kg/jam) N (Kmol/jam)

Triacetin 218.21 1458.33000 6.68315
Gliserol 92.09 0.00000 0.00000
Asam asetat 60.05 550.76000 9.17169
Asetat Anhidrat 102.09 934.00000 9.14879
Total 2943.09000 25.00363

T dew point 130.7282706195 °C 403.7282706195

Ptotal 760 mmHg 1

Komponen BM F (Kg/jam) N (Kmol/jam)

Triacetin 218.21 0.31000 0.00142
Gliserol 92.09 0.00000 0.00000
Asam asetat 60.05 531.97000 8.85878
Asetat Anhidrat 102.09 923.03000 9.04134
Total 1455.31000 17.90154

T bubble point 220.0918181437 °C 493.0918181437

Ptotal 760 mmHg 1

Komponen BM F (Kg/jam) N (Kmol/jam)

Triacetin 218.21 1458.02000 6.68173
Gliserol 92.09 0.00000 0.00000
Asam Asetat 60.05 18.79000 0.31291
Asetat Anhidrat 102.09 10.97000 0.10745
Total 1487.78000 7.10209
aca Massa

Input
Komponen BM
F (kg/jam) N (Kmol/jam)
Triacetin 218.21 1458.33000 6.68315
Gliserol 92.09 0.00000 0.00000
Asam asetat 60.05 550.76000 9.17169
Asetat Anhidrat 102.09 934.00000 9.14879
Total 2943.09000 25.00363

entukan Pemilihan Heavy dan Light Komponen Pada Distilat

Komponen XiF YiD

Triacetin 0.267 0.000 0.000

Gliserol 0.000 0.000 #DIV/0!
Asam Asetat 0.367 0.495 0.966
A. Anhidrat (LK, D) 0.366 0.505 0.988
Total 1.000 1.000 1.954

tif Volatilitas Rata-Rata (α average)

Persamaan 11.7-13
Geankoplis

Komponen α (Distilat) α (Bottom) α (Average)

Triacetin 0.007 0.028 0.014
Gliserol 0.001 0.008 0.003
Asam Asetat 1.933 1.000 1.390
Asetat Anhidrat 1.000 0.825 0.909
Total 2.941 1.862 2.316

ghitung Jumlah Tray Minimum (Nm)

Persamaan 11.7-12
Geankoplis
 XLD 0.495 αLK (Bottom)
XHD 0.000 αLK (Distilat)
XHW 0.941 αLK (Average)
XLW 0.044
D 17.902
W 7.102

Nm 8.3258117982 Theoretical stages

Nm 8 Theoretical trays

etukan Refluks Minimum (Rm)

Persamaan 11.60
Coulson

Persamaan 11.61
Coulson

Trial : θ 1.3549792919
q 1

Komponen αi XiD XiF

Triacetin (HK) 1.0000000 0.0000794 0.2672872
Gliserol 0.0025275 0.0000000 0.0000000
Asam Asetat (LK) 63.1410363 0.4948615 0.3668144
Asetat Anhidrat 42.0632923 0.5050591 0.3658985
Total 106.2068560 1.0000000 1.0000000

Rm + 1 1.02736
Rm 0.02736
Roperasi 0.03283

entukan Jumlah Plate Aktual (Na)

0.0266317579

0.0317887912

N  Nm   R  R m  0,566 
 0,75 1     Persamaan 15-4
Peters
N 1   R  1  
 N  Nm   R  R m  0,566 
 0,75 1     Persamaan 15-4
Peters
N 1   R  1  

Nm 8
N-Nm/N+1 0.7113708860 N-Nm
Nteoritis 29.0000000000
Nteoritis 29 Plate

N
Na  teoritis

E o

Eo = eff plate untuk sieve tray (menurut peter 60 - 80%)

Maka, E0 80%
Na 36.2500000000 Plate
Na 37 Plate

entukan Umpan Masuk Tray

Persamaan 11.7-21
Geankoplis

0.8284308262

Ne/Ns 6.7364459
Nteoritis = Ne + Ns
Ns 4.7825578422
Ne 32 Dari atas

hitungan Diameter Kolom

T dew point 130.7282706195 °C 403.7282706195

Ptotal 760 mmHg 1

Komponen BM F (Kg/jam) N (Kmol/jam)

Triacetin (HK) 218.21 0.3100000000 0.0014206498
Gliserol 92.09 0 0
Asam asetat (LK) 60.05 531.9700000000 8.8587843464
Asetat Anhidrat 102.09 923.0300000000 9.0413360760
Total 1455.3100000000 17.9015410722

Laju Alir Massa Cairan 47.7814605640

 Laju Alir Massa Cairan 47.7814605640

Laju Alir Massa Uap 1503.0914605640

BM  P
Densitas Uap  v 2.2889731073
RT

Densitas Cairan 927.1878801728

P 1
Kondisi Operasi R 0.08205
T 403.7282706195

V 656.6662822661
Laju Alir Volumetrik Maksimum Qv 
v 0.1824073006

Tegangan Permukaan 0.0009085551

Liquis-Vapor Flow Factor 0.0015794667

Plate Spacing 0.3 m

Nilai K1 0.05

Kecepatan Flooding 1.0050711161

Source:
Asumsi Kecepatan Flooding Maksimum 80%
Coulson, 1983

Kecepatan Flooding Sesungguhnya 0.8040568929 m/s

Q
Luas Area Netto A n  v
0.2268586990
U f

Downcomer Area (Ad) 0.0453717398

An
Cross-Sectional Area (Ac) Ac  0.2835733737
1  0,12
 An
Ac 
1  0,12

0.6010324172
4  Ac 
Diameter Kolom Dc 
 23.6627063691

0.3005162086 m
Jari-Jari Kolom
11.8313531845 in

T bubble point 220.0918181437 °C 493.0918181437

Ptotal 760 mmHg 1

Komponen BM F (Kg/jam) N (Kmol/jam)

Triacetin (HK) 218.21 1458.0200000000 6.6817286101
Gliserol 92.09 0.0000000000 0.0000000000
Asam asetat (LK) 60.05 18.79000 0.31291
Asetat Anhidrat 102.09 10.97000 0.10745
Total 1487.7800000000 7.1020887289

Laju Alir Massa Cairan 2990.8714605640

Laju Alir Massa Uap 1503.0914605640

1487.7800000000 Kg/jam

1.9898133540 Kg/jam

BM  P
Densitas Uap  v 4.7592933101
RT

Densitas Cairan 932.7102110331

P 1
Kondisi Operasi R 0.08205
T 493.0918181437

V 315.8224052655
Laju Alir Volumetrik Maksimum Qv 
v
 V
Laju Alir Volumetrik Maksimum Qv 
v 0.0877284459

Tegangan Permukaan 0.0008762835

Liquis-Vapor Flow Factor 0.1421380035

Plate Spacing 0.30 m

Nilai K1 0.057

Kecepatan Flooding 0.7959139618

Source:
Asumsi Kecepatan Flooding Maksimum 65%
Coulson, 1983

Kecepatan Flooding Sesungguhnya 0.5173440752 m/s

Q
Luas Area Netto A n  v
0.1695746605
U f

Downcomer Area (Ad) 0.0423936651

An
Cross-Sectional Area (Ac) Ac  0.2119683256
1  0,12

0.5196377053
4  Ac 
Diameter Kolom Dc 
 20.4581884199

0.2598188526 m
Jari-Jari Kolom
10.2290942099 in

ncangan Plate

Diameter Kolom (Dc) 0.6010324172 m

Luas Kolom (Ac) 0.2835733737 m2
Luas Downcomer (Ad) 0.0453717398 m2
Luas Netto (An) 0.2382016339 m2
Luas Aktif (Aa) 0.1928298941 m2
Luas Hole (Ah)
0.0192829894 m2
(10% Aa)
 Luas Hole (Ah)
0.0192829894 m2
(10% Aa)
Weir Length (lw)
0.4627949613 m
(76% Dc)
lw / Dc 0.77
(Ad / Ac) x 100% 16%

Weir Height (hw) 0.05 m 50

Hole Diameter (Dh) 5 mm 0.005
Hole Radius (Rh) 2.5 mm 0.0025
Tebal Plate 5 mm 0.005

ck Weeping

Laju Cairan Maksimum

0.0132726279 Kg/s
(Lw)
Turn Down 80%
Laju Cairan Minimum
0.0106181023 Kg/s
(Lw)

Weir Crest Minimum

(how) 0.6368761070
Weir Crest (how)
Weir Crest Maksimum
(how) 0.7390292566

Pada Laju Minimum 0.0506368761 m

Nilai K2 30.2

Laju Uap Minimum 7.8258470780

Laju Uap Minimum

7.5675942858
Aktual
0.1459258405
e Pressure Drop

Laju Uap Maksimum

9.4594928572 m/s
Melewati Lubang

Ah Ah
 10%
Ap Aa
Co 0.84
Tebal Plate / Diameter
1
Hole
 Dry Plate Drop 15.9668871340 mm liquid

Residual Plate 13.4816257495 mm liquid

Total Plate Pressure

80.1875421402
Drop

ncomer Liquid Back Up

Downcomer Pressure
40 mm
Loss

Area Under Apron 0.0185117985 m2

Head Downcomer 0.0000980915 mm

Back Up In Downcomer 130.926669488308 mm

0.381 m

hb

Sehingga plate spacing dapat diterima

Residence Time 417.4489416733

ck Entrainment

Actual Velocity 0.3682948956 m/s

37%

Nilai 38% dibulatkan menjadi 40%

FLV 0.1421380035
 ѱ 0.0042
Entrainment dapat diterima karena nilai yang direkomendasikan
adalah kecil dari 0,1

orated Area

lw/Dc 0.77
θ 99
Angle subtended by the
81
edge of the plate
Mean length,
0.7786088055 m
unperforated edge strips
Area of unperforated
Ae = hw * ml 0.0389304403 m2
edge strips
mean length of calming
mlcz = lw + hw 0.5127949613 m
zone, Approx

Area of calming zones Acz = 2(mlcz * hw) 0.0512794961 m2

Total area for

Ap = Aa - Ae -Acz 0.1026199577 m2
perforations

Ah/Ap 0.1879068150

lp/dh 2.3

Area of one hole 0.0000196250 m2

Number of holes 983 Buah

hitungan Tebal Shell

Bahan konstruksi Carbon steel SA-283 grade C

Tegangan yang
12650 lbf/in2 12650
diizinkan (f)

Sambungan Double welded butt joint

Effisiensi sambungan
80%
(E)

Faktor korosi (C) 0.125 in

23.6627063691 in
Diameter dalam (ID)
0.6010327418 m 60.1032741775

11.8313531845 in
Jari-jari (r)
0.3005163709 m 30.0516370887

Poperasi 1 atm 14.6959502530

Pdesign (10%) 1.2 atm 17.6351403036

0.1456389284 in
Tebal Shell (ts)
0.0036992288 m

0.1875 in 3/ 16
Tebal shell (ts) standar
0.0047625 m 0.47625

24.0377063691 in
Diameter luar (OD)
0.6105577418 m 61.0557741775

hitungan Tebal Head

0.1458529760 in
Tebal head (th)
0.0037046656 m
 0.1875 in 3/16
Tebal head (th) standar
0.0047625 m 0.47625

hitungan Tinggi Head

Berdasarkan tabel 5.7 pada buku Brownell and Young

th standar 3/16 in
OD 24.0377063691 in
OD standar 24 in
icr 1.5 in
sf 2 in
r 24 in

a 10.2290942099 in

b 3.26228280947886 in

AB 8.7290942099 in

BC 22.5 in

AC 20.7377171905 in

5.4497828095 in
Tinggi Head (OA)
0.1384244834 m

hitungan Tinggi Kolom

N 37 Plate
Plate spacing 0.3 m
Tebal plate 0.005 m
OA 0.1384244834 m
Tinggi Kolom 11.2618489667 m 443.3801200047
Tinggi Total Kolom 12.3880338634 m
 C
185.221
253.806
246.894
264.961

K
Geankoplis
atm

Xi Log Pi Pi (atm) Pi (mmhg)

0.26729 1.04062 0.01445 10.98040
0.00000 0.13323 0.00179 1.35904
0.36681 3.12804 1.76695 1342.88017
0.36590 2.85881 0.95060 722.45843
1.00000 7.16070 2.73379 2077.67804

K
atm

Yi Log Pi Pi (atm) Pi (mmhg)

0.00008 0.90449 0.01056 8.02574
0.00000 -0.02975 0.00123 0.93379
0.49486 3.04845 1.47109 1118.02763
0.50506 2.76231 0.76119 578.50385
1.00000

K
atm

Xi Log Pi Pi (atm) Pi (mmhg)

0.94081 2.41352 0.34096 259.13029
0.00000 1.84420 0.09192 69.85552
0.04406 3.96063 12.01753 9133.32649
0.01513 3.87734 9.92024 7539.38148
1.00000
 Distilat
Fraksi F (kg/jam) N (Kmol/jam) Fraksi (Yi)
0.26729 0.31000 0.00142 0.00008
0.00000 0.00000 0.00000 0.00000
0.36681 531.97000 8.85878 0.49486
0.36590 923.03000 9.04134 0.50506
1.00000 1455.31000 17.90154 1.00000

Keterangan

Terdistribusi
Tidak Terdistribusi
Terdistribusi
Terdistribusi
 35.246
139.305
13.212

Tav 448.4100443816 175.4100443816

p 10.2000000000 7752.0000000000
Log P P Ki
Triacetin 1.7524853557 56.5568685912277 0.0072957777
Asam Asetat 3.5527970608 3571.0592900967300 0.4606629631
Asetat Anhidrat 3.3763886177 2378.9680955964300 0.3068844293

αiXiF / αi-θ αiXiD / αi-θ

-0.7529655 -0.0002236
0.0000000 0.0000000
0.3748587 0.5057140
0.3780774 0.5218700
-0.0000294 1.0273604
K
atm

Yi Lo ρ liquid (kg/m3) Yi / ρ liquid

0.0000793591 0.0101780739 1049 0.0000000757
0 0 0 0
0.4948615491 17.4659031933 923 0.0005360801
0.5050590918 30.3053792967 931 0.0005423743
1 47.7814605640 2903 0.0010785301

47.7814605640
Kg/jam
Kg/jam

1503.0914605640
Kg/jam

Kg/m3

Kg/m3

atm
m3.atm/kmol.K
K

m3/jam

m3/s

N/m

m/s

m2

m2

m2
m

in

K
atm

Xi Lo ρ liquid (kg/m3) Xi / ρ liquid

0.9408117619 47.8704366296 944 0.0009968568
0.0000000000 0.0000000000 0 0.0000000000
0.04406 0.61692 793 0.00006
0.01513 0.36017 768 0.00002
1 48.8475317271 2504 0.0010721444

Kg/jam

Kg/jam

Kg/m3

Kg/m3

atm
m3.atm/kmol.K
K

m3/jam
m3/s

N/m

m/s

m2

m2

m2

in
mm
m
Coulson, 1983
m
m

mm liquid 0.0006368761 m liquid

mm liquid 0.0007390293 m liquid

50.6368761070 mm

m/s

m/s
 mm liquid

0.04 m

0.1309266695 m

40%

% dibulatkan menjadi 40%

 Psi

cm

cm

Psia

Psia

0.3699228782 cm

in

cm

cm

0.3704665590 cm
in

cm

0.0013842448 cm
Ki (Pi/Ptot) Yi (Ki.Xi) Komponen BM
0.01445 0.00386 Triacetin 218.21000
0.00179 0.00000 Asam asetat 60.05000
1.76695 0.64814 Asetat Anhidrat 102.09000
0.95060 0.34782 Total
2.73379 0.99983

Ki (Pi/Ptot) Xi (Yi/Ki) α (Ki/Kc) Komponen

0.01056 0.00751 0.00718 Triacetin
0.00123 0.00000 0.00084 Asam asetat
1.47109 0.33639 1.93262 Asetat Anhidrat
0.76119 0.66351 1.00000 Total
1.00742 2.94063

Ki (Pi/Ptot) Yi (Ki.Xi) α (Ki/Kc) Komponen

0.34096 0.32078 0.02837 Triacetin
0.09192 0.00000 0.00765 Asam Asetat
12.01753 0.52947 1.00000 Asetat Anhidrat
9.92024 0.15009 0.82548 Total
1.00034 1.86150
 Bottom
F (kg/jam) N (Kmol/jam) Fraksi (Xi)
1458.02000 6.68173 0.94081
0.00000 0.00000 0.00000
18.79000 0.31291 0.04406
10.97000 0.10745 0.01513
1487.78000 7.10209 1.00000
 ρ uap (kg/m3) Yi / ρ uap Pch σ (dyne/cm) Yi * σ
6.5872918070 0.0000120473 402.6 13.6684551159 0.001084716
0.0000000000 0 0.0 0.0000000000 0.000000000
1.8127806838 0.2729847871 118.0 10.7418044624 5.315705996
3.0818781017 0.1638802948 181.8 7.4620181573 3.768760114
11.4819505925 0.4368771292 702 31.8722777357 9.085550826
0.0009085551
 Atom Kontribusi
C 4.8
H 17.1
H dalam OH 11.3
O 20.0
O2 dalam ester 60.0
N 12.5
S 48.2
P 37.7
F 25.7
Cl 54.3
Br 68.0
I 91.0
Se 62.5
Si 25.0
Al 38.6
Sn 57.9
As 50.1
posisi 2,3- 23.2
posisi 3,4-
Rangkap tiga 46.6
Cincin
3- ikatan 16.7
4-ikatan 11.6
5-ikatan 8.5
6-ikatan 6.1
 ρ uap (kg/m3) Xi / ρ uap Pch σ (dyne/cm) Xi * σ
5.3934700018 0.1744353378 402.6 8.9850470304 8.453237927
0.0000000000 0.0000000000 0.0 0.0000000000 0.000000000
1.4842485386 0.02968 118.0 5.8426321627 0.257416404
2.5233461000 0.00600 181.8 3.4488480833 0.052180879
9.4010646405 0.2101152282 702 18.2765272764 8.762835211
0.0008762835
 F (Kg/jam) N (Kmol/jam) Xi Log Pi Pi (atm)
1458.33000 6.68315 0.26729 2.13525 0.03440
550.76000 9.17169 0.36681 3.78733 1.54386
934.00000 9.14879 0.36590 3.66399 1.16216
2943.09000 25.00363 1.00000 11.07376 2.74815

BM F (Kg/jam) N (Kmol/jam) Yi Log Pi

218.21000 0.31000 0.00142 0.00008 0.90449
60.05000 531.97000 8.85878 0.49486 3.04845
102.09000 923.03000 9.04134 0.50506 2.76231
1455.31000 17.90154 1.00000

BM F (Kg/jam) N (Kmol/jam) Xi Log Pi

218.21000 1458.02000 6.68173 0.94081 2.41352
60.05000 18.79000 0.31291 0.04406 3.96063
102.09000 10.97000 0.10745 0.01513 3.87734
1487.78000 7.10209 1.00000
 Density

Asetat Anhidrat
Triacetin
Asam Asetat
dyne/cm
N/m
Komponen BM F (Kg/jam)
 Triacetin (HK) 218.21000 0.31000
Asam asetat (LK) 60.05000 531.97000
Asetat Anhidrat 102.09000 923.03000
Total 1455.31000

Komponen BM F (Kg/jam)
Triacetin (HK) 218.21000 0.31000
Asam asetat (LK) 60.05000 531.97000
Asetat Anhidrat 102.09000 923.03000
Total 1455.31000

Komponen BM Yi
Triacetin (HK) 218.21000 0.00008
Asam asetat (LK) 60.05000 0.49486
Asetat Anhidrat 102.09000 0.50506
Total 1.00000

Komponen BM Yi
Triacetin (HK) 218.21000 0.00008
Asam asetat (LK) 60.05000 0.49486
Asetat Anhidrat 102.09000 0.50506
Total 1.00000
 Density

Asetat Anhidrat
Triacetin
Asam Asetat
dyne/cm
N/m

Komponen BM F (Kg/jam) N (Kmol/jam)

Triacetin (HK) 218.21000 1458.02000 6.68173
Gliserol 92.09000 0.00000 0.00000
Asam asetat (LK) 60.05000 18.79000 0.31291
Asetat Anhidrat 102.09000 10.97000 0.10745
Total 1487.78000 7.10209

Komponen BM F (Kg/jam) N (Kmol/jam)

Triacetin (HK) 218.21000 1458.02000 6.68173
Gliserol 92.09000 0.00000 0.00000
Asam asetat (LK) 60.05000 18.79000 0.31291
Asetat Anhidrat 102.09000 10.97000 0.10745
Total 1487.78000 7.10209
 Pi (mmhg) Ki (Pi/Ptot) Yi (Ki.Xi)
136.53659 0.03440 0.00919
6128.18820 1.54386 0.56631
4613.07475 1.16216 0.42523
10908.50314 2.74815 1.00074

Pi (atm) Pi (mmhg) Ki (Pi/Ptot) Xi (Yi/Ki) α (Ki/Kc)

0.01056 8.02574 0.01056 0.00751 0.00718
1.47109 1118.02763 1.47109 0.33639 1.93262
0.76119 578.50385 0.76119 0.66351 1.00000
1.00742 2.94063

Pi (atm) Pi (mmhg) Ki (Pi/Ptot) Yi (Ki.Xi) α (Ki/Kc)

0.34096 259.13029 0.34096 0.32078 0.02837
12.01753 9133.32649 12.01753 0.52947 1.00000
9.92024 7539.38148 9.92024 0.15009 0.82548
1.00034 1.86150
 A B n Tc densitas
0.3357800000 0.2408000000 0.2699000000 569.1500000000 0.9312003158
0.3496400000 0.2463000000 0.2857000000 704.0000000000 1.0487385003
0.3518200000 0.2695400000 0.2684300000 592.7100000000 0.9231111767

N (Kmol/jam) Yi ρ liquid (kg/m3) Yi / ρ liquid

 0.00142 0.00008 1048.73850 0.00000
8.85878 0.49486 923.11118 0.00054
9.04134 0.50506 931.20032 0.00054
17.90154 1.00000 2903.04999 0.00108

N (Kmol/jam) Yi ρ uap (kg/m3) Yi / ρ uap

0.00142 0.00008 6.58729 0.00001
8.85878 0.49486 1.81278 0.27298
9.04134 0.50506 3.08188 0.16388
17.90154 1.00000 11.48195 0.43688

Pch σ (dyne/cm) Yi * σ
402.60000 13.66846 0.00108
118.00000 10.74180 5.31571
181.80000 7.46202 3.76876
702.40000 31.87228 9.08555 dyne/cm
0.00091 N/m

Pch σ (dyne/cm) Yi * σ
402.60000 13.66846 0.00108
118.00000 10.74180 5.31571
181.80000 7.46202 3.76876
702.40000 31.87228 9.08555 dyne/cm
0.00091 N/m
 A B n Tc
0.3357800000 0.2408000000 0.2699000000 569.1500000000
0.3496400000 0.2463000000 0.2857000000 704.0000000000
0.3518200000 0.2695400000 0.2684300000 592.7100000000

Xi ρ liquid (kg/m3) Xi / ρ liquid

0.94081 943.77828 0.00100
0.00000 0.00000 0.00000
0.04406 792.67853 0.00006
0.01513 767.78128 0.00002
1.00000 2504.23809 0.00107

Xi ρ uap (kg/m3) Xi / ρ uap

0.94081 5.39347 0.17444
0.00000 0.00000 0.00000
0.04406 1.48425 0.02968
0.01513 2.52335 0.00600
1.00000 9.40106 0.21012
g/ml 931.2003157747 kg/m3
1048.7385003426
923.1111766882
 densitas
0.7677812804 g/ml 767.7812804015 kg/m3
0.9437782764 943.7782764319
0.7926785319 792.6785319461
 Neraca Massa Menara Distilasi 1

T 200 °C

F5 3360.1512580151
Gliserol 0.0007279038
Asam Asetat 0.5539178796
Air 0.1021210543
Triacetin 0.3432331623

Laju Alir Massa dan Molar Masuk

gliserol 2.4458668821 0.0265595274
as asetat 1861.2478599172 30.9949685248
air 343.1421890739 19.0422968409
triacetin 1153.3153421419 5.2853459610
Total 3360.1512580151 55.3491708542
 Data Kesetimbangan

F6 ###
Asam Asetat ###
Air 343.1421890739
Triacetin 3.4599460264

triacetin terdistribusi 0.3% pada distilat

Umpan (F)

F7 ###
Gliserol 2.4458668821
Triacetin 1149.8553961155
Asam Asetat 0

Distilat (D)

Bottom (W)
Neraca Massa

Manentukan Pemilihan Heavy dan Light Kompo

Relatif Volatilitas Rata-Rata (α average)

Menghitung Jumlah Tray Minimum (Nm)

Menetukan Refluks Minimum (Rm)

Menentukan Jumlah Plate Aktual (Na)

 N
Na  teoritis

E o

Menentukan Umpan Masuk Tray

Perhitungan Diameter Kolom

Distilat
Bottom
Perancangan Plate
Check Weeping

Plate Pressure Drop

Downcomer Liquid Back Up

Check Entrainment
Perforated Area

Jumlah Hole
Perhitungan Tebal Shell

Perhitungan Tebal Head

Perhitungan Tinggi Head

Perhitungan Tinggi Kolom

a Kesetimbangan

Komponen BM A B
Triacetin 218.21 7.74878 2162.45
Gliserol 92.09 9.90788 3821.36
Asam asetat 60.05 7.81520 1800.03
Asetat Anhidrat 102.09 8.81453 2394.8

T 127.3398239806 °C 400.3398239806
Ptotal 760 mmHg 1

Komponen BM F (Kg/jam) N (Kmol/jam)

Triacetin 218.21 0.00000 0.00000
Gliserol 92.09 0.00000 0.00000
Asam asetat 60.05 531.97000 8.85878
Asetat Anhidrat 102.09 923.03000 9.04134
Total 1455.00000 17.90012

T dew point 118.0656346334 °C 391.0656346334

Ptotal 760 mmHg 1

Komponen BM F (Kg/jam) N (Kmol/jam)

Triacetin 218.21 0.00000 0.00000
Gliserol 92.09 0.00000 0.00000
Asam asetat 60.05 527.98000 8.79234
Asetat Anhidrat 102.09 3.99000 0.03908
Total 531.97000 8.83142

T bubble point 138.4519212838 °C 411.4519212838

Ptotal 760 mmHg 1

Komponen BM F (Kg/jam) N (Kmol/jam)

Triacetin 218.21 0.00000 0.00000
Gliserol 92.09 0.00000 0.00000
Asam Asetat 60.05 3.99000 0.06644
Asetat Anhidrat 102.09 927.02000 9.08042
Total 931.01000 9.14686
aca Massa

Input
Komponen BM
F (kg/jam) N (Kmol/jam)
Triacetin 218.21 0.00000 0.00000
Gliserol 92.09 0.00000 0.00000
Asam asetat 60.05 531.97000 8.85878
Asetat Anhidrat 102.09 923.03000 9.04134
Total 1455.00000 17.90012

entukan Pemilihan Heavy dan Light Komponen Pada Distilat

Komponen XiF YiD

Triacetin 0.000 0.000 #DIV/0!

Gliserol 0.000 0.000 #DIV/0!
Asam Asetat 0.495 0.996 0.992
A. Anhidrat (LK, D) 0.505 0.004 0.004
Total 1.000 1.000 #DIV/0!

tif Volatilitas Rata-Rata (α average)

Persamaan 11.7-13
Geankoplis

Komponen α (Distilat) α (Bottom) α (Average)

Triacetin 0.005 0.008 0.007
Gliserol 0.001 0.001 0.001
Asam Asetat 2.093 1.000 1.447
Asetat Anhidrat 1.000 0.542 0.736
Total 3.099 1.552 2.191

ghitung Jumlah Tray Minimum (Nm)

Persamaan 11.7-12
Geankoplis
 XLD 0.996 αLK (Bottom)
XHD 0.000 αLK (Distilat)
XHW 0.000 αLK (Average)
XLW 0.007
D 8.831
W 9.147

Nm 21.0000000000 Theoretical stages

Nm 21 Theoretical trays

etukan Refluks Minimum (Rm)

Persamaan 11.60
Coulson

Persamaan 11.61
Coulson

Trial : θ 1.3549792919
q 1

Komponen αi XiD XiF

Triacetin (HK) 1.0000000 0.0000000 0.0000000
Gliserol 0.0007680 0.0000000 0.0000000
Asam Asetat (LK) 146.7259406 0.9955745 0.4949008
Asetat Anhidrat 74.7703272 0.0044255 0.5050992
Total 222.4970358 1.0000000 1.0000000

Rm + 1 1.00936
Rm 4.00000
Roperasi 5.00000

entukan Jumlah Plate Aktual (Na)

3.9629022117

0.8333333333

N  Nm   R  R m  0 , 566 
 0,75 1    
N 1   R  1   Persamaan 15-4
Peters
 Persamaan 15-4
Peters

Nm 21
N-Nm/N+1 0.4779632012 N-Nm
Nteoritis 21.0000000000
Nteoritis 21 Plate
N
Na  teoritis

E o

Eo = eff plate untuk sieve tray (menurut peter 60 - 80%)

Maka, E0 80%
Na 26.2500000000 Plate
Na 27 Plate

entukan Umpan Masuk Tray

Persamaan 11.7-21
Geankoplis

#DIV/0!

Ne/Ns #DIV/0!
Nteoritis = Ne + Ns
Ns #DIV/0!
Ne #DIV/0! Dari atas

hitungan Diameter Kolom

T dew point 118.0656346334 °C 391.0656346334

Ptotal 760 mmHg 1

Komponen BM F (Kg/jam) N (Kmol/jam)

Triacetin (HK) 218.21 0.0000000000 0.0000000000
Gliserol 92.09 0 0
Asam asetat (LK) 60.05 527.9800000000 8.7923397169
Asetat Anhidrat 102.09 3.9900000000 0.0390831619
Total 531.9700000000 8.8314228788

Laju Alir Massa Cairan 2659.8500000000

 Laju Alir Massa Cairan 2659.8500000000

Laju Alir Massa Uap 3191.8200000000

BM  P
 v
RT
Densitas Uap 1.8748949690

Densitas Cairan 938.9329922381

P 1
Kondisi Operasi R 0.08205
T 391.0656346334
V
Qv 
v 1702.3993625009
Laju Alir Volumetrik Maksimum
0.4728887118

Tegangan Permukaan 0.0011478528

Liquis-Vapor Flow Factor 0.0372383068

Plate Spacing 0.3 m

Nilai K1 0.05

Kecepatan Flooding 1.1401578013

Source:
Asumsi Kecepatan Flooding Maksimum 80%
Coulson, 1983

Kecepatan Flooding Sesungguhnya 0.9121262410 m/s

Q
A n  v

U f

Luas Area Netto 0.5184465599

Downcomer Area (Ad) 0.1296116400

An
Ac 
1  0,12
Cross-Sectional Area (Ac) 0.6480581998

4  Ac 
Dc 

 4  Ac 
Dc  0.9085988372
Diameter Kolom

35.7716270793

0.4542994186 m
Jari-Jari Kolom
17.8858135397 in

T bubble point 138.4519212838 °C 411.4519212838

Ptotal 760 mmHg 1

Komponen BM F (Kg/jam) N (Kmol/jam)

Triacetin (HK) 218.21 0.0000000000 0.0000000000
Gliserol 92.09 0.0000000000 0.0000000000
Asam asetat (LK) 60.05 3.99000 0.06644
Asetat Anhidrat 102.09 927.02000 9.08042
Total 931.0100000000 9.1468638674

Laju Alir Massa Cairan 4114.8500000000

Laju Alir Massa Uap 3183.8400000000

931.0100000000 Kg/jam

1.2924173325 Kg/jam
BM  P
 v
RT
Densitas Uap 3.0087250192

Densitas Cairan 919.0574076026

P 1
Kondisi Operasi R 0.08205
T 411.4519212838
V
Qv  1058.2023879603
Laju Alir Volumetrik Maksimum v
 Laju Alir Volumetrik Maksimum
0.2939451078

Tegangan Permukaan 0.0007105520

Liquis-Vapor Flow Factor 0.0739473649

Plate Spacing 0.30 m

Nilai K1 0.050

Kecepatan Flooding 0.8724449494

Source:
Asumsi Kecepatan Flooding Maksimum 65%
Coulson, 1983

Kecepatan Flooding Sesungguhnya 0.5670892171 m/s

Q
A n  v
U f
Luas Area Netto 0.5183401463

Downcomer Area (Ad) 0.1295850366

An
Ac 
1  0,12
Cross-Sectional Area (Ac) 0.6479251829

4  Ac 
Dc  0.9085055853
Diameter Kolom 
35.7679557451

0.4542527927 m
Jari-Jari Kolom
17.8839778725 in

ncangan Plate

Diameter Kolom (Dc) 0.9085988372 m

Luas Kolom (Ac) 0.6480581998 m2
Luas Downcomer (Ad) 0.1296116400 m2
Luas Netto (An) 0.5184465599 m2
Luas Aktif (Aa) 0.3888349199 m2
Luas Hole (Ah)
0.0388834920 m2
(10% Aa)
 Luas Hole (Ah)
0.0388834920 m2
(10% Aa)
Weir Length (lw)
0.6996211046 m
(76% Dc)
lw / Dc 0.77
(Ad / Ac) x 100% 20%

Weir Height (hw) 0.05 m 50

Hole Diameter (Dh) 5 mm 0.005
Hole Radius (Rh) 2.5 mm 0.0025
Tebal Plate 5 mm 0.005

ck Weeping

Laju Cairan Maksimum

0.7388472222 Kg/s
(Lw)
Turn Down 80%
Laju Cairan Minimum
0.5910777778 Kg/s
(Lw)

Weir Crest Minimum

(how) 6.9902496061
Weir Crest (how)
Weir Crest Maksimum
(how) 8.1114661289

Pada Laju Minimum 0.0569902496 m

Nilai K2 30.3

Laju Uap Minimum 8.7199873506

Laju Uap Minimum

9.7293465707
Aktual
0.3783109694
e Pressure Drop

Laju Uap Maksimum

12.1616832134 m/s
Melewati Lubang
Ah Ah

Ap Aa
10%

Co 0.84
Tebal Plate / Diameter
1
Hole
 Dry Plate Drop 21.3472197919 mm liquid

Residual Plate 13.3129841036 mm liquid

Total Plate Pressure

92.7716700244
Drop

ncomer Liquid Back Up

Downcomer Pressure
40 mm
Loss

Area Under Apron 0.0279848442 m2

Head Downcomer 0.1369891944 mm

Back Up In Downcomer 151.020125347753 mm

0.500 m

hb

Sehingga plate spacing dapat diterima

Residence Time 24.3481981283

ck Entrainment

Actual Velocity 0.5669728194 m/s

50%

Nilai 38% dibulatkan menjadi 40%

FLV 0.0739473649
 ѱ 0.0042
Entrainment dapat diterima karena nilai yang direkomendasikan
adalah kecil dari 0,1

orated Area

lw/Dc 0.77
θ 99
Angle subtended by the
81
edge of the plate
Mean length,
1.2132001569 m
unperforated edge strips
Area of unperforated
Ae = hw * ml 0.0606600078 m2
edge strips
mean length of calming
mlcz = lw + hw 0.7496211046 m
zone, Approx

Area of calming zones Acz = 2(mlcz * hw) 0.0749621105 m2

Total area for

Ap = Aa - Ae -Acz 0.2532128016 m2
perforations

Ah/Ap 0.1535605299

lp/dh 2.3

Area of one hole 0.0000196250 m2

Number of holes 1981 Buah

hitungan Tebal Shell

Bahan konstruksi Carbon steel SA-283 grade C

Tegangan yang
12650 lbf/in2 12650
diizinkan (f)

Sambungan Double welded butt joint

Effisiensi sambungan
80%
(E)

Faktor korosi (C) 0.125 in

35.7716270793 in
Diameter dalam (ID)
0.9085993278 m 90.8599327814

17.8858135397 in
Jari-jari (r)
0.4542996639 m 45.4299663907

Poperasi 1 atm 14.6959502530

Pdesign (10%) 1.2 atm 17.6351403036

0.1562004907 in
Tebal Shell (ts)
0.0039674925 m

0.1875 in 3/ 16
Tebal shell (ts) standar
0.0047625 m 0.47625

36.1466270793 in
Diameter luar (OD)
0.9181243278 m 91.8124327814

hitungan Tebal Head

0.1565240729 in
Tebal head (th)
0.0039757115 m
 0.1875 in 3/16
Tebal head (th) standar
0.0047625 m 0.47625

hitungan Tinggi Head

Berdasarkan tabel 5.7 pada buku Brownell and Young

th standar 3/16 in
OD 36.1466270793 in
OD standar 24 in
icr 2.375 in
sf 2 in
r 36 in

a 17.8839778725 in

b 6.16525129401117 in

AB 15.5089778725 in

BC 33.6 in

AC 29.8347487060 in

8.3527512940 in
Tinggi Head (OA)
0.2121598829 m

hitungan Tinggi Kolom

N 27 Plate
Plate spacing 0.3 m
Tebal plate 0.005 m
OA 0.2121598829 m
Tinggi Kolom 8.3593197657 m 277.9292839400
Tinggi Total Kolom 9.1952517423 m
 C
185.221
253.806
246.894
264.961

K
Geankoplis
atm

Xi Log Pi Pi (atm) Pi (mmhg)

0.00000 0.83029 0.00890 6.76529
0.00000 -0.11810 0.00100 0.76191
0.49490 3.00529 1.33192 1012.26147
0.50510 2.71003 0.67487 512.89796
1.00000 6.42751 2.01669 1532.68662

K
atm

Yi Log Pi Pi (atm) Pi (mmhg)

0.00000 0.61873 0.00547 4.15649
0.00000 -0.36814 0.00056 0.42841
0.99557 2.88307 1.00520 763.95102
0.00443 2.56222 0.48019 364.94153
1.00000

K
atm

Xi Log Pi Pi (atm) Pi (mmhg)

0.00000 1.06781 0.01538 11.68980
0.00000 0.16592 0.00193 1.46529
0.00726 3.14399 1.83308 1393.13905
0.99274 2.87818 0.99396 755.40653
1.00000
 Distilat
Fraksi F (kg/jam) N (Kmol/jam) Fraksi (Yi)
0.00000 0.00000 0.00000 0.00000
0.00000 0.00000 0.00000 0.00000
0.49490 527.98000 8.79234 0.99557
0.50510 3.99000 0.03908 0.00443
1.00000 531.97000 8.83142 1.00000
1.03572

Keterangan

Terdistribusi
Tidak Terdistribusi
Terdistribusi
Terdistribusi

1.9648435786
 119.176
183.797
17.406

Tav 401.2587779586 128.2587779586

p 10.2000000000 7752.0000000000
Log P P Ki
Triacetin 0.8505678918 7.0887211333848 0.0009144377
Asam Asetat 3.0170747941 1040.0992759887100 0.1341717332
Asetat Anhidrat 2.7242971729 530.0259985116470 0.0683728068

αiXiF / αi-θ αiXiD / αi-θ

0.0000000 0.0000000
0.0000000 0.0000000
0.4995137 1.0048541
0.5144215 0.0045071
1.0139352 1.0093613
K
atm

Yi Lo ρ liquid (kg/m3) Yi / ρ liquid

0.0000000000 0.0000000000 0 0.0000000000
0 0 0 0
0.9955745340 2639.9000000000 939 0.0010603828
0.0044254660 19.9500000000 950 0.0000046560
1 2659.8500000000 1889 0.0010650387

2659.8500000000
Kg/jam
Kg/jam

3191.8200000000
Kg/jam

Kg/m3

Kg/m3

atm
m3.atm/kmol.K
K

m3/jam

m3/s

N/m

m/s

m2

m2

m2
m

in

K
atm

Xi Lo ρ liquid (kg/m3) Xi / ρ liquid

0.0000000000 0.0000000000 0 0.0000000000
0.0000000000 0.0000000000 0 0.0000000000
0.00726 19.95000 913 0.00001
0.99274 4635.10000 919 0.00108
1 4655.0500000000 1832 0.0010880713

Kg/jam

Kg/jam

Kg/m3

Kg/m3

atm
m3.atm/kmol.K
K

m3/jam
m3/s

N/m

m/s

m2

m2

m2

in
mm
m
Coulson, 1983
m
m

mm liquid 0.0069902496 m liquid

mm liquid 0.0081114661 m liquid

56.9902496061 mm

m/s

m/s
 mm liquid

0.04 m

0.1510201253 m

40%

% dibulatkan menjadi 40%

 Psi

cm

cm

Psia

Psia

0.3967492465 cm

in

cm

cm

0.3975711452 cm
in

cm

0.0021215988 cm
Ki (Pi/Ptot) Yi (Ki.Xi) Komponen BM
0.00890 0.00000 Triacetin 218.21000
0.00100 0.00000 Asam asetat 60.05000
1.33192 0.65917 Asetat Anhidrat 102.09000
0.67487 0.34087 Total
2.01669 1.00004

Ki (Pi/Ptot) Xi (Yi/Ki) α (Ki/Kc) Komponen

0.00547 0.00000 0.00544 Triacetin
0.00056 0.00000 0.00056 Asam asetat
1.00520 0.99043 2.09335 Asetat Anhidrat
0.48019 0.00922 1.00000 Total
0.99964 3.09935

Ki (Pi/Ptot) Yi (Ki.Xi) α (Ki/Kc) Komponen

0.01538 0.00000 0.00839 Triacetin
0.00193 0.00000 0.00105 Asam Asetat
1.83308 0.01332 1.00000 Asetat Anhidrat
0.99396 0.98674 0.54223 Total
1.00005 1.55168
 Bottom
F (kg/jam) N (Kmol/jam) Fraksi (Xi)
0.00000 0.00000 0.00000
0.00000 0.00000 0.00000
3.99000 0.06644 0.00726
927.02000 9.08042 0.99274
931.01000 9.14686 1.00000
 ρ uap (kg/m3) Yi / ρ uap Pch σ (dyne/cm) Yi * σ
0.0000000000 0.0000000000 0.0 0.0000000000 0.000000000
0.0000000000 0 0.0 0.0000000000 0.000000000
1.8714782013 0.5319722844 118.0 11.4935519269 11.442687603
3.1816687688 0.0013909261 181.8 8.0987735295 0.035840847
5.0531469701 0.5333632105 300 19.5923254563 11.478528450
0.0011478528
 Atom Kontribusi
C 4.8
H 17.1
H dalam OH 11.3
O 20.0
O2 dalam ester 60.0
N 12.5
S 48.2
P 37.7
F 25.7
Cl 54.3
Br 68.0
I 91.0
Se 62.5
Si 25.0
Al 38.6
Sn 57.9
As 50.1
posisi 2,3- 23.2
posisi 3,4-
Rangkap tiga 46.6
Cincin
3- ikatan 16.7
4-ikatan 11.6
5-ikatan 8.5
6-ikatan 6.1
 ρ uap (kg/m3) Xi / ρ uap Pch σ (dyne/cm) Xi * σ
0.0000000000 0.0000000000 0.0 0.0000000000 0.000000000
0.0000000000 0.0000000000 0.0 0.0000000000 0.000000000
1.7787517147 0.00408 118.0 10.2905768149 0.074752787
3.0240260208 0.32828 181.8 7.0822142966 7.030767690
4.8027777355 0.3323666981 300 17.3727911115 7.105520477
0.0007105520
 F (Kg/jam) N (Kmol/jam) Xi Log Pi Pi (atm)
1458.33000 6.68315 0.26729 2.13525 0.03440
550.76000 9.17169 0.36681 3.78733 1.54386
934.00000 9.14879 0.36590 3.66399 1.16216
2943.09000 25.00363 1.00000 11.07376 2.74815

BM F (Kg/jam) N (Kmol/jam) Yi Log Pi

218.21000 0.31000 0.00142 0.00008 0.90449
60.05000 531.97000 8.85878 0.49486 3.04845
102.09000 923.03000 9.04134 0.50506 2.76231
1455.31000 17.90154 1.00000

BM F (Kg/jam) N (Kmol/jam) Xi Log Pi

218.21000 1458.02000 6.68173 0.94081 2.41352
60.05000 18.79000 0.31291 0.04406 3.96063
102.09000 10.97000 0.10745 0.01513 3.87734
1487.78000 7.10209 1.00000
 Density

Asetat Anhidrat
Triacetin
Asam Asetat
dyne/cm
N/m
Komponen BM F (Kg/jam)
 Triacetin (HK) 218.21000 0.31000
Asam asetat (LK) 60.05000 531.97000
Asetat Anhidrat 102.09000 923.03000
Total 1455.31000

Komponen BM F (Kg/jam)
Triacetin (HK) 218.21000 0.31000
Asam asetat (LK) 60.05000 531.97000
Asetat Anhidrat 102.09000 923.03000
Total 1455.31000

Komponen BM Yi
Triacetin (HK) 218.21000 0.00008
Asam asetat (LK) 60.05000 0.49486
Asetat Anhidrat 102.09000 0.50506
Total 1.00000

Komponen BM Yi
Triacetin (HK) 218.21000 0.00008
Asam asetat (LK) 60.05000 0.49486
Asetat Anhidrat 102.09000 0.50506
Total 1.00000
 Density

Asetat Anhidrat
Triacetin
Asam Asetat
dyne/cm
N/m

Komponen BM F (Kg/jam) N (Kmol/jam)

Triacetin (HK) 218.21000 1458.02000 6.68173
Gliserol 92.09000 0.00000 0.00000
Asam asetat (LK) 60.05000 18.79000 0.31291
Asetat Anhidrat 102.09000 10.97000 0.10745
Total 1487.78000 7.10209

Komponen BM F (Kg/jam) N (Kmol/jam)

Triacetin (HK) 218.21000 1458.02000 6.68173
Gliserol 92.09000 0.00000 0.00000
Asam asetat (LK) 60.05000 18.79000 0.31291
Asetat Anhidrat 102.09000 10.97000 0.10745
Total 1487.78000 7.10209
 Pi (mmhg) Ki (Pi/Ptot) Yi (Ki.Xi)
136.53659 0.03440 0.00919
6128.18820 1.54386 0.56631
4613.07475 1.16216 0.42523
10908.50314 2.74815 1.00074

Pi (atm) Pi (mmhg) Ki (Pi/Ptot) Xi (Yi/Ki) α (Ki/Kc)

0.01056 8.02574 0.01056 0.00751 0.00718
1.47109 1118.02763 1.47109 0.33639 1.93262
0.76119 578.50385 0.76119 0.66351 1.00000
1.00742 2.94063

Pi (atm) Pi (mmhg) Ki (Pi/Ptot) Yi (Ki.Xi) α (Ki/Kc)

0.34096 259.13029 0.34096 0.32078 0.02837
12.01753 9133.32649 12.01753 0.52947 1.00000
9.92024 7539.38148 9.92024 0.15009 0.82548
1.00034 1.86150
 A B n Tc densitas
0.3357800000 0.2408000000 0.2699000000 569.1500000000 0.9504960679
0.3496400000 0.2463000000 0.2857000000 704.0000000000 1.0625030667
0.3518200000 0.2695400000 0.2684300000 592.7100000000 0.9388822208

N (Kmol/jam) Yi ρ liquid (kg/m3) Yi / ρ liquid

 0.00142 0.00008 1048.73850 0.00000
8.85878 0.49486 923.11118 0.00054
9.04134 0.50506 931.20032 0.00054
17.90154 1.00000 2903.04999 0.00108

N (Kmol/jam) Yi ρ uap (kg/m3) Yi / ρ uap

0.00142 0.00008 6.58729 0.00001
8.85878 0.49486 1.81278 0.27298
9.04134 0.50506 3.08188 0.16388
17.90154 1.00000 11.48195 0.43688

Pch σ (dyne/cm) Yi * σ
402.60000 13.66846 0.00108
118.00000 10.74180 5.31571
181.80000 7.46202 3.76876
702.40000 31.87228 9.08555 dyne/cm
0.00091 N/m

Pch σ (dyne/cm) Yi * σ
402.60000 13.66846 0.00108
118.00000 10.74180 5.31571
181.80000 7.46202 3.76876
702.40000 31.87228 9.08555 dyne/cm
0.00091 N/m
 A B n Tc
0.3357800000 0.2408000000 0.2699000000 569.1500000000
0.3496400000 0.2463000000 0.2857000000 704.0000000000
0.3518200000 0.2695400000 0.2684300000 592.7100000000

Xi ρ liquid (kg/m3) Xi / ρ liquid

0.94081 943.77828 0.00100
0.00000 0.00000 0.00000
0.04406 792.67853 0.00006
0.01513 767.78128 0.00002
1.00000 2504.23809 0.00107

Xi ρ uap (kg/m3) Xi / ρ uap

0.94081 5.39347 0.17444
0.00000 0.00000 0.00000
0.04406 1.48425 0.02968
0.01513 2.52335 0.00600
1.00000 9.40106 0.21012
g/ml 950.4960678978 kg/m3
1062.5030667127
938.8822208088
 densitas
0.9191002064 g/ml 919.1002063934 kg/m3
1.0402286032 1040.2286032093
0.9132457195 913.2457195166
 C1, C2, etc constants from table 2-6 in Perry. These are used to calculate VP below
b.p. degC c1 c2 c3 c4
Acetic Acid 118 53.27 -6304.5 -4.2985 8.89E-18
Acetic Anydride 140 100.95 -8873.2 -11.451 6.13E-06
Temp K VP A Acid VP A Anhydride Rel Vol
391 100833.21657 51335.03451598 1.9642183457
413 190456.02075 102397.4133169 1.8599690615
1.9120937036 average relative volatility (I check for

Option 1 - Use Vapour Pressures

x, y data from Dalton's + Raoult's laws at a pressure of 101325
b (LVC) a (MVC)
Temp K VP A Anhydride VP A Acid Xa Ya
391 51335 100833 1.01 1.01
393 54875 107188 0.89 0.94
395 58610 113863 0.77 0.87
397 62549 120872 0.66 0.79
399 66700 128227 0.56 0.71
401 71071 135939 0.47 0.63
403 75670 144022 0.38 0.53
405 80506 152488 0.29 0.44
407 85588 161351 0.21 0.33
409 90924 170624 0.13 0.22
411 96524 180321 0.06 0.10
413 102397 190456 -0.01 -0.02

Extra data for IA1 problem question

x=y data Rectifying line equation Stripping line equation
0 0 y=0.75x + 0.225 y=1.42x - 0.042
1 1 x y x
0 0.225 0.1
0.9 0.9 0.6
d to calculate VP below
c5 Temp (K) VP (Pa)
6 391 100833.216575 1.2
2 391 51335.034516
1

0.8

elative volatility (I check for variation in RV with temp and then use average)
0.6

Option 2 - RV 0.4
Pa
0.2
x,y data using rel vol
0
Xa Ya X Y 0 0.2
1.00 1.00 0 0
0.90 0.95 0.1 0.18
0.80 0.88 0.2 0.33
0.70 0.82 0.3 0.46
0.60 0.74 0.4 0.57
0.50 0.66 0.5 0.66
0.40 0.56 0.6 0.75
0.30 0.45 0.7 0.82
0.20 0.32 0.8 0.89
0.10 0.18 0.9 0.95
0.00 0.00 1 1

x y
0.00 0
1.00 1 Heat Capacity Coefficient of Liquids
line equation Cp liq =A+B*T+C*(T^2)+D*(T^3) Cp (J/(mol K))
No Name Formula
y 7 acetic acid C2H4O2
0.1 8 acetic anhydride C4H6O3
0.81

∆Hvap = A(1-T/Tc)^n ∆Hvap (kJ/mol)

No Name Formula
7 acetic acid C2H4O2
8 acetic anhydride C4H6O3
 Chart Title

0.2 0.4 0.6 0.8 1 1.2

Heat Capacity Coefficient of Gases

mol K)) (T=K) Cp gas =A+B*T+C*(T^2)+D*(T^3)+E*(T^4
A B C D NAME
-18.944 1.0971 -2.8921E-03 2.9275E-06 acetic acid
71.831 0.8888 -2.6534E-03 3.3501E-06 acetic anhydride

T(K) CP LIQUID
MW A Tc n Acetic Acid
60.053 11.575 592.71 -0.65 Acetic Anhydride
102.09 58.52 569.15 0.28
 ∆Hvap
Acetic Acid
Acetic Anhydride

∆Hvap
Acetic Acid
Acetic Anhydride

XD
XF
XW

Volatility

Rmin

q
Slope

a1
a2
b1
b2

1.2

1
y, fraksi mol vapor asam asetat

0.8

0.6

0.4

0.2

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x, Fraksi mol liquid asam asetat
y, frak
0.2

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x, Fraksi mol liquid asam asetat
 1 1.2
Rectifying Section y=0.5088x+0.489
x y x y
0 0.5087728323 0 0.15
0.99 0.99 0.99 0.9927383625

x y x y
0.4949 0.4949 0.0072641979 0.0072641979
0.4949 1

Coefficient of Gases
T+C*(T^2)+D*(T^3)+E*(T^4 Cp (J/(mol K)) T (K)
Formula MW A B C D
C2 H 4 O 2 60.053 34.85 0.03763 2.8311E-04 -3.077E-07
C4 H 6 O 3 102.090 9.50 0.34425 -8.6736E-05 -7.677E-08

144.584169416
217.336692229
 Dew Point Latent heat of feed 32936.5280514443
23.3285371251
42.2684237069 Specific heat of feed 181.331408742

Bubble Point (feed) heat to vaporise 1 mol of feed 33550.9598539144

24.0535361981 24053.5361981 q 1.0186550265
41.6401652703 41640.1652703 slope q 54.6048556065
R 1.0357180256
y 0.5087728323
0.4890532586
45 line
0.995574534 x y
0.494900824 0 0 Top
0.0072641979 1 1
Stage 1-a
1.9648435786 Top Section x
x y 0.995574534
4 0.995574534 0.995574534 0.9913416218
0 0.165929089
5 Stage 2-a
q-line x
1.0186550265 x y 0.9913416218
54.6048556065 0.494900824 0.494900824 0.9844928009
0.504150902 1
0.8333333333 Stage 3-a
54.6048556065 bottom section x
0.165929089 x y 0.9844928009
-26.529087209 0.0072641979 0.0072641979 0.9735089105
0.4903663244 0.5745676926
Stage 4-a
bottom section slope x
1.1742931021 0.9735089105
0.9561404808
bottom section intercept
-0.0012660996 Stage 5-a
x
0.9561404808
0.9292807463

Stage 6-a
x
0.9292807463
0.8891397187
0.7 0.8 0.9 1
t
0.7 0.8 0.9 1
t Stage 7-a
x
0.8891397187
0.8321154918

Stage 8-a
x
0.8321154918
0.7566795984

Stage 9-a
x
0.7566795984
0.6657711903

Stage 10-a
x
0.6657711903
0.5677592375

Stage 11-a
x
0.5677592375
0.4739939182

Stage 2-a
x
0.4739939182
0.3940070264

Stage 2-a
x
0.3940070264
0.3321802558
Cp*= (25 °C)
E
9.2646E-11
3.6721E-11
 1.7501174878
0.6363791713

Top Section Bottom Section

Stage 1-a Stage 1-b Stage 1-a Stage 1-b

y x y x y x y
0.995574534 0.991342 0.995575 0.007264 0.007264 0.007264 0.014174
0.995574534 0.991342 0.992047 0.007264 0.014174 0.013148 0.014174

Stage 2-a Stage 2-b Stage 2-a Stage 2-b

y x y x y x y
0.9920471071 0.984493 0.992047 0.013148 0.014174 0.013148 0.02551
0.9920471071 0.984493 0.98634 0.013148 0.02551 0.022802 0.02551

Stage 3-a Stage 3-b Stage 3-a Stage 3-b

y x y x y x y
0.9863397564 0.973509 0.98634 0.022802 0.02551 0.022802 0.043838
0.9863397564 0.973509 0.977187 0.022802 0.043838 0.03841 0.043838

Stage 4-a Stage 4-b Stage 4-a Stage 4-b

y x y x y x y
0.9771865145 0.95614 0.977187 0.03841 0.043838 0.03841 0.072773
0.9771865145 0.95614 0.962713 0.03841 0.072773 0.06305 0.072773

Stage 5-a Stage 5-b Stage 5-a Stage 5-b

y x y x y x y
0.962712823 0.929281 0.962713 0.06305 0.072773 0.06305 0.116778
0.962712823 0.929281 0.94033 0.06305 0.116778 0.100524 0.116778

Stage 6-a Stage 6-b Stage 6-a Stage 6-b

y x y x y x y
0.9403297109 0.88914 0.94033 0.100524 0.116778 0.100524 0.180051
0.9403297109 0.88914 0.906879 0.100524 0.180051 0.154405 0.180051
Stage 7-a Stage 7-b Stage 7-a Stage 7-b
y x y x y x y
0.9068788546 0.832115 0.906879 0.154405 0.180051 0.154405 0.264045
0.9068788546 0.832115 0.859359 0.154405 0.264045 0.225933 0.264045

Stage 8-a Stage 8-b Stage 8-a Stage 8-b

y x y x y x y
0.8593586655 0.75668 0.859359 0.225933 0.264045 0.225933 0.364472
0.8593586655 0.75668 0.796495 0.225933 0.364472 0.311453 0.364472

Stage 9-a Stage 9-b Stage 9-a Stage 9-b

y x y x y x y
0.796495421 0.665771 0.796495 0.311453 0.364472 0.311453 0.470554
0.796495421 0.665771 0.720738 0.311453 0.470554 0.401791 0.470554

Stage 10-a Stage 10-b Stage 10-a Stage 10-b

y x y x y x y
0.7207384143 0.567759 0.720738 0.401791 0.470554 0.401791 0.56891
0.7207384143 0.567759 0.639062 0.401791 0.56891 0.485548 0.56891

Stage 11-a Stage 11-b Stage 11-a Stage 11-b

y x y x y x y
0.6390617869 0.473994 0.639062 0.485548 0.56891 0.485548 0.64967
0.6390617869 0.473994 0.560924 0.485548 0.64967 0.554322 0.64967

Stage 2-a Stage 2-b Stage 2-a Stage 2-b

y x y x y x y
0.5609240208 0.394007 0.560924 0.554322 0.64967 0.554322 0.709624
0.5609240208 0.394007 0.494268 0.554322 0.709624 0.605377 0.709624

Stage 2-a Stage 2-b Stage 2-a Stage 2-b

y x y x y x y
0.4942682776 0.33218 0.494268 0.605377 0.709624 0.605377 0.750884
0.4942682776 0.33218 0.442746 0.605377 0.750884 0.640513 0.750884