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Safety Data Sheet

EMSEAL Joint Systems, Ltd.


SEISMIC COLORSEAL
25 Bridle Lane, Westborough, MA 01581 USA
www.emseal.com
Preparation Date March 15, 2015 Revision Date May 31, 2015

1. Identification of the Substance / Preparation


Product identifier SEISMIC COLORSEAL

Other identifier or names COS Foam


UN ID number None

Manufacturer Address EMSEAL LLC


120 Carrier Drive
Toronto, Ontario M9W 5R1 Canada

Company Phone (508) 836-0280 M-F 9am - 5pm


Emergency Phone CHEMTREC (800) 424-9300 (24 Hours)
CHEMTREC International Phone +1 703-527-3887 (24 Hours)

2. Hazardous Indentification
Hazardous Classification This product is not classified as hazardous when used as intended.
Signal Word None
Pictograms None
Emergency Overview: No emergency requirements.

3. Composition / Information on Ingredients


EMSEAL SEISMIC COLORSEAL is composed of polyurethane foam impregnated with a proprietary solid acrylic polymer bonded
to a fully cured silicone sealant. It is classified as Non-Hazardous.

NOTE: Silicone facing is fully cured. The composition of the silicone in its liquid state is comprised of the following:

Chemical Name CAS # % by Weight



Titanium Dioxide 13463-67-7 1 - 5

Methylvinyl bis(N-thylacetamido) silane 87855-59-2 1-5

Antimony nickel titanium oxide yellow 8007-18-9 1-5

Dimethyl, methylhydrogen siloxane,


dehydrogenated reaction with hydroxydiethylamine 68952-53-4 1-5

Carbon black 1333-86-4 0.1 - 1

Quartz 14808-60-7 0.1 - 1

Cobalt titinate green spinel 68186-85-6 0.1 - 1

N-ethylacetamide 625-50-3 0.1 - 1

Octamethylcyclotetrasiloxane 556-67-2 0.1 - 1

www.EMSEAL.com PAGE 1 OF 3
Safety Data Sheet SEISMIC COLORSEAL
Revision Date May 31, 2015

4. First Aid Measures


4.1 EYES: Flush with water for at least 15 minutes, and call physician if problems persist.
4.2 SKIN: Product may leave a sticky residue, and mild irritation if prolonged exposure.
Scrub with soapy water until adhesive is removed.
4.3 INGESTION: Do not eat – call physician if ingested.

5. Fire-fighting Measures
5.2 FLAMMABILITY: Slight. Material can support an open flame or smoldering ignition. The foam can
melt while burning which can contribute fire to spread.
5.2 FLASH POINT: Unknown.
5.3 AUTO-IGNITION TEMPERATURE: Unknown.
5.4 EXTINGUISHING MEDIA: Large volumes of water, or ABC chemical may be appropriate for initial control or
small volumes of impregnated foam.
5.5 HAZARDOUS DECOMPOSITION PRODUCTS: Carbon di/mon oxides will be formed as well as other noxious and toxic fumes
upon combustion – do not breath combustion products.

6. Accidental Release Measures


If material is unusable pick up pieces and dispose of in accordance with local regulations; material and all components are non-
toxic and normal landfill will most often be acceptable.

7. Handling and Storage


Store in original packaging below 35°C. There are no special handling instructions.

8. Exposure Controls / Personal Protection


8.1 RESPIRATORY PROTECTION: Not required
8.2 EYE PROTECTION: Not required
8.3 SKIN PROTECTION: Gloves of any material are suitable if desired, but not required. No other protection is required.

9. Physical and Chemical Properties


9.1 APPEARANCE: Dark grey / charcoal colored foam and colored silicone with product identifying packaging.
9.2 ODOR: Slight characteristic odor.
9.3 PERCENT SOLIDS BY WEIGHT: 100%
9.4 PHYSICAL STATE: Solid
9.5 PERCENT VOLATILE: <1% wt/wt
9.6 DENSITY: 0.4g/cm3
9.7 DECOMPOSITION: > 300°C
9.8 SOLUBILITY IN WATER: None

www.EMSEAL.com PAGE 2 OF 3
Safety Data Sheet SEISMIC COLORSEAL
Revision Date May 31, 2015

10. Stability and Reactivity


Stable under normal conditions – avoid temperatures in excess of 300°C, strong acids and bases, and open flame.

11. Toxicological Information


Unknown.

12. Ecological Information


Unknown

13. Disposal Considerations


No known hazard. Dispose of in accordance with local regulations; material and all components are non-toxic and disposal in
normal landfill will most often be acceptable.

14. Transportation Information


Not hazardous – safe for non-hazardous shipping.

15. Regulatory Information


Unknown.

16. Other Information


No other information provided.

www.EMSEAL.com PAGE 3 OF 3
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SAFETY DATA SHEET

1. PRODUCT IDENTIFICATION
IDENTIFICATION of the SUBSTANCE or PREPARATION
TRADE NAME (AS LABELED): Pecora 890 NST Non-Staining Technology™
PRODUCT DESCRIPTION: Non-Staining, Ultra Low-Modulus Silicone Sealant
CHEMICAL NAME/CLASS: Silicone
SYNONYMS: 890 NST
RELEVANT USE: Non-Staining Silicone Sealant/Caulking Compound
USES ADVISED AGAINST: Other Than Relevant Use
COMPANY/UNDERTAKING IDENTIFICATION:
SUPPLIER/MANUFACTURER'S NAME: Pecora Corporation
ADDRESS: 165 Wambold Road, Harleysville, PA 19438
EMERGENCY PHONE: 800-424-9300 (CHEMTREC, 24-hours)
BUSINESS PHONE: 215-723-6051 (Mon–Fri, 8 AM–5 PM ET)

PREPARATION DATE: May 2005


REVISION DATE: March 27, 2014
This product is sold for commercial use. This MSDS has been developed to address safety concerns of those individuals working with bulk quantities of this material, as well as those of
potential users of this product in industrial/occupational settings. ALL United States Occupational Safety and Health Administration Standard (29 CFR 1910.1200), U.S. State equivalent
Standards, and Canadian WHMIS [Controlled Products Regulations] and the Global Harmonization Standard required information is included in appropriate sections based on the U.S. ANSI
Z400.1-2008 format. This product has been classified in accordance with the hazard criteria of the countries listed above.

2. HAZARD IDENTIFICATION
GLOBAL HARMONIZATION LABELING AND CLASSIFICATION: This product has been classified per GHS Standards.
Classification: Acute Oral Toxicity Cat. 5, Eye Irritation Cat. 2B, Skin Irritation Cat. 3, Skin Sensitization Cat. 1, Aquatic Chronic Toxicity Cat. 4
Signal Word: Warning Hazard Statement Codes: H303, H316, H320, H317, H413
Precautionary Statement Codes: P261, P264, P272, P273, P280, P305 + P351 + P338, P337 + P313, P302 + P352, P321, P333 + P313, P362 + P364,
P501
Hazard Symbols/Pictogram: GHS07

EMERGENCY OVERVIEW:
PHYSICAL DESCRIPTION: This product is a smooth paste with a slightly medicinal odor and comes in various colors, including
Black, Tru-White, Aluminum Stone, Translucent, and Bronze.
HEALTH HAZARDS: CAUTION! May cause eye, skin, and respiratory tract irritation, especially if exposure is prolonged. May
be harmful if ingested. May cause skin sensitization in susceptible individuals. Contains trace amounts of crystalline silica, a
known human carcinogen by inhalation.
FLAMMABILITY HAZARD: This product is combustible and can ignite if exposed to high temperature or direct flame.
REACTIVITY HAZARD: This product is not reactive.
ENVIRONMENTAL HAZARD: This product has not been tested for environmental impact. This product contains a compound that
can cause chronic aquatic toxicity.
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS®)
Health 1* See Section 16 for definitions of ratings
0 = Minimal 3 = Serious
Flammability 1 1 = Slight 4 = Severe
2 = Moderate * = Chronic
Physical Hazard 0
®
HMIS is a registered trademark of the National Paint and Coatings Association.
CANADIAN WHMIS CLASSIFICATION: Class D2B. See Section 15 (Regulatory Information) for all classification details.
U.S. OSHA REGULATORY STATUS: This material has a classification under the Global Harmonization Standard, as applied under
OSHA regulations, as given earlier in this Section.

Pecora 890 NTS Page 1 of 9 March 27, 2014


3. MATERIAL IDENTIFICATION
GHS Classification
Chemical Name CAS # W/W%
Hazard Statements
SELF CLASSIFICATION
Proprietary Silicone Polymer 30.0-60.0
Classification: Not Applicable
SELF CLASSIFICATION
Calcium Carbonate (Limestone) 1317-65-3 15.0–40.0
Classification: Not Applicable
Classification: STOT RE Cat. 2, Skin Sensitization Cat. 1, Aquatic
Proprietary Crosslinker 3.0–7.0 Chronic Toxicity Cat. 3
Hazard Statement Codes: H373, H317, H412
SELF CLASSIFICATION
Silicon Dioxide, Fumed 112945-52-5 3.0–7.0
Classification: Not Applicable
Classification: Carcinogenic Cat. 1B, Mutagenic Cat. 1B,
Mineral Spirits 8052-41-3 1.0-5.0 Aspiration Hazard Cat. 1
Hazard Statement Codes: H350, H340, H304
SELF CLASSIFICATION
Quartz 14808-60-7 Trace Classification: Carcinogenic Cat. 1B
Hazard Statement Codes: H350
Other components. Each of the other components is present in less than 1 percent concentration (0.1%
Balance Classification: Not Applicable
concentration for potential carcinogens, reproductive toxins, respiratory tract sensitizers, and mutagens).
See Section 16 for full text of classification

4. FIRST-AID MEASURES
PROTECTION OF FIRST AID RESPONDERS: Rescuers should not attempt to retrieve victims of exposure to this material without
adequate personal protective equipment. Rescuers should be taken for medical attention, if necessary.
DESCRIPTION OF FIRST AID MEASURES: Remove victim(s) to fresh air, as quickly as possible. Only trained personnel should
administer supplemental oxygen and/or cardio-pulmonary resuscitation, if necessary. Remove and isolate contaminated clothing and
shoes. Seek immediate medical attention. Take copy of label and MSDS to physician or other health professional with victim(s).
INHALATION: If dusts of this material are inhaled, remove victim to fresh air. If necessary, use artificial respiration to support vital functions.
SKIN EXPOSURE: If the material contaminates the skin, immediately begin decontamination with running water. Minimum flushing is for 20
minutes. Do not interrupt flushing. Remove exposed or contaminated clothing, taking care not to contaminate eyes. Victim must seek immediate
medical attention.
EYE EXPOSURE: If this product enters the eyes, open victim's eyes while under gently running water. Use sufficient force to open eyelids. Have
victim "roll" eyes. Minimum flushing is for 20 minutes. Do not interrupt flushing.
INGESTION: If this material is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. DO
NOT INDUCE VOMITING, unless directly by medical personnel. Have victim rinse mouth with water or give several cupfuls of water, if
conscious. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or unable to swallow. If
vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Dermatitis or other pre-existing skin disorders may be aggravated by
overexposures to this product.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT IF NEEDED: Treat symptoms and
eliminate overexposure.
5. FIRE-FIGHTING MEASURES
FLASH POINT: > 140°C (> 300°F) AUTOIGNITION: Unknown.
FLAMMABLE LIMITS IN AIR: Unknown.
EXTINGUISHING MEDIA: NFPA RATING
SUITABLE EXTINGUISHING MEDIA: Use extinguishing material suitable to FLAMMABILITY
the surrounding fire, including foam, halon, carbon dioxide and dry chemical.
UNSUITABLE EXTINGUISHING MEDIA: None known.
1
PROTECTION OF FIREFIGHTERS:
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE: This product is 1 0
combustible and can be ignited when exposed to its flashpoint. Not sensitive to HEALTH INSTABILITY
mechanical impact under normal conditions. Not sensitive to static discharge
under normal conditions. Closed containers may develop pressure and rupture in
event of fire.
OTHER
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS: Incipient fire See Section 16 for
responders should wear eye protection. Structural firefighters must wear Self- Definitions of Ratings
Contained Breathing Apparatus and full protective equipment. Move containers
from fire area if it can be done without risk to personnel. If possible, prevent
runoff water from entering storm drains, bodies of water, or other environmentally
sensitive areas.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS AND EMERGENCY PROCEDURES: An accidental release can result in a fire. Uncontrolled releases
should be responded to by trained personnel using pre-planned procedures. Proper protective equipment should be used. Eliminate any
possible sources of ignition, and provide maximum explosion-proof ventilation.

Pecora 890 NTS Page 2 of 9 March 27, 2014


6. ACCIDENTAL RELEASE MEASURES (Continued)
PERSONAL PRECAUTIONS AND EMERGENCY PROCEDURES (continued): Use only non-sparking tools and equipment during
the response. The atmosphere must at least 19.5 percent Oxygen before non-emergency personnel can be allowed in the area without
Self-Contained Breathing Apparatus and fire protection.
PERSONAL PROTECTIVE EQUIPMENT: Responders should wear the level of protection appropriate to the type of chemical
released, the amount of the material spilled, and the location where the incident has occurred.
Small Spills: For releases of 1 drum or less, Level D Protective Equipment (gloves, chemical resistant apron, boots, and eye protection)
should be worn.
Large Spills: Minimum Personal Protective Equipment should be rubber gloves, rubber boots, face shield, and Tyvek suit. Minimum level of
personal protective equipment for releases in which the level of oxygen is less than 19.5% or is unknown must be Level B: triple-gloves
(rubber gloves and nitrile gloves over latex gloves), chemical resistant suit, fire-retardant clothing and boots, hard hat, and Self-
Contained Breathing Apparatus.
METHODS FOR CLEAN-UP AND CONTAINMENT:
All Spills: Access to the spill area should be restricted. Spread should be limited by gently covering the spill with polypads. Scrape up or pick-up
spilled material, placing in suitable containers. Absorb any residual on appropriate material, such as sand. All contaminated absorbents and other
materials should be placed in an appropriate container and seal. Do not mix with wastes from other materials. Dispose of in accordance with
applicable Federal, State, and local procedures (see Section 13, Disposal Considerations). Dispose of recovered material and report spill per
regulatory requirements. Remove all residue before decontamination of spill area. Clean spill area with soap and copious amounts of water.
ENVIRONMENTAL PRECAUTIONS: Minimize use of water to prevent environmental contamination. Prevent spill or rinsate from
contaminating storm drains, sewers, soil or groundwater. Place all spill residues in a suitable container and seal. Do not discharge
effluent containing this product into streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a
National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to
discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment
plant authority. For guidance, contact your State Water Board or Regional Office of the EPA.
OTHER INFORMATION: U.S. regulations may require reporting of spills of this material that reach surface waters if a sheen is
formed. If necessary, the toll-free phone number for the US Coast Guard National Response Center is 1-800-424-8802.
REFERENCE TO OTHER SECTIONS: See information in Section 8 (Exposure Controls – Personal Protection) and Section 13
(Disposal Considerations) for additional information.
7. HANDLING and STORAGE
PRECAUTIONS FOR SAFE HANDLING: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash thoroughly
after handling this product. Do not eat or drink while handling this material. Avoid contact with eyes, skin, and clothing. Avoid
breathing fumes, dusts, vapors or mist. Do not taste or swallow. Use only with adequate ventilation. Keep away from heat and
flame. In the event of a spill, follow practices indicated in Section 6: ACCIDENTAL RELEASE MEASURES.
CONDITIONS FOR SAFE STORAGE: This product is stable under ordinary conditions of handling, use and storage. Store containers
in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away from incompatible
materials (see Section 10: STABILITY AND REACTIVITY). Keep container tightly closed when not in use. Inspect all incoming
containers before storage, to ensure containers are properly labeled and not damaged. To prolong shelf life, store at temperatures below
26°C (80°F).
PRODUCT END USE: This product is used as a sealant. Follow all industry standards for use of this product.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
EXPOSURE LIMITS/CONTROL PARAMETERS:
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below the limits
provided below.
OCCUPATIONAL/WORKPLACE EXPOSURE LIMITS/GUIDELINES:
Chemical Name CAS # Guideline Value
Proprietary Crosslinker AIHA WEEL TWA 10 ppm (Dermal Sensitizer)
Exposure limits given are for decomposition product methylethyl DFG MAK TWA Skin, Danger of Sensitization of the skin.
ketoxime
Calcium Carbonate, Natural 1317-65-3 OSHA PEL TWA 15 mg/m3 total dust
5 mg/m3 respirable fraction
NIOSH REL TWA 10 mg/m3 total dust
5 mg/m3 respirable fraction
Proprietary Silicone Polymer NE NE
Mineral Spirits 8052-41-3 ACGIH TLV TWA 525 mg/m3
OSHA PEL TWA 2900 mg/m3
NIOSH REL TWA 350 mg/m3
NIOSH REL STEL 1800 mg/m3 (15 min.)
Quartz 14808-60-7 ACGIH TLV TWA 0.025 mg/m3 Respirable Fraction
OSHA PEL TWA 30 mg/m3 / % Sio2 + 2 Total Dust; 10 mg/m3 / % Sio2 + 2 Respirable Fraction
NIOSH REL TWA 0.05 mg/m3 (Respirable Dust)
NE = Not Established. See Section 16 for Definitions of Terms Used.

Pecora 890 NTS Page 3 of 9 March 27, 2014


8. EXPOSURE CONTROLS - PERSONAL PROTECTION (Continued)
PERSONAL PROTECTIVE EQUIPMENT (PPE): The following information on appropriate Personal Protective Equipment is
provided to assist employers in complying with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132, including the
Respiratory Protection Standard (29 CFR 1910.134), Eye Protection Standard 29 CFR 1910.13, the Hand Protection Standard 29
CFR 1910.138, and the Foot Protection Standard 29 CFR 1910.136), equivalent standards of Canada (including the Canadian CSA
Respiratory Standard Z94.4-93-02, the CSA Eye Protection Standard Z94.3-M1982, Industrial Eye and Face Protectors and the
Canadian CSA Foot Protection Standard Z195-M1984, Protective Footwear). Please reference applicable regulations and standards
for relevant details.
EYE/FACE PROTECTION: Use approved safety goggles or safety glasses. If necessary, refer to appropriate regulations and standards.
SKIN PROTECTION: Wear chemical impervious gloves (e.g., Nitrile or Neoprene). Use triple gloves for spill response. If necessary, refer to
appropriate regulations and standards.
BODY PROTECTION: Use body protection appropriate for task (e.g., lab coat, coveralls, Tyvek suit). If necessary, refer to the OSHA Technical
Manual (Section VII: Personal Protective Equipment) or appropriate Standards of Canada. If a hazard of injury to the feet exists due to falling
objects, rolling objects, where objects may pierce the soles of the feet or where employee’s feet may be exposed to electrical hazards, use foot
protection, as described in appropriate regulations and standards.
RESPIRATORY PROTECTION: If mists or sprays from this product are created during use, use appropriate respiratory protection. If necessary, use
only respiratory protection authorized in appropriate regulations. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres,
use of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is required under
appropriate regulations and standards.
9. PHYSICAL and CHEMICAL PROPERTIES
FORM: Smooth paste. COLORS: Black, Tru-White, Aluminum Stone, Translucent, and Bronze
MOLECULAR WEIGHT: Mixture. MOLECULAR FORMULA: Mixture.
ODOR: Mildly medicinal. ODOR THRESHOLD: Not available.
SPECIFIC GRAVITY: 1.1-1.3 VAPOR PRESSURE, mm Hg @ 20°C: Not established.
RELATIVE VAPOR DENSITY (air = 1): Heavier than air. EVAPORATION RATE (BuAc = 1): < 1
SOLUBILITY IN WATER: Insoluble. OTHER SOLUBILITIES: Not available.
MELTING/FREEZING POINT: Not available. BOILING POINT: Not established.
VOC (less water and exempt): < 100 g/L WEIGHT % VOC: ~ 10%
FLASH POINT: > 140°C (> 300°F) AUTOIGNITION TEMPERATURE: Not established.
pH: Not available.
FLAMMABLE LIMITS (in air by volume, %): Lower: Not established; Upper: Not established.
COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not established.
HOW TO DETECT THIS SUBSTANCE (IDENTIFYING PROPERTIES): The appearance of this product may act as an identifying
property in the event of an accidental release.
10. STABILITY and REACTIVITY
CHEMICAL STABILITY: Stable under normal circumstances of use and handling. Methylethyl Ketoxime is generated during curing.
CONDITIONS TO AVOID: Avoid contact with incompatible chemicals and exposure to extreme temperatures.
INCOMPATIBLE MATERIALS: This product is not compatible with strong acids and oxidizers and may have some compatibility with
aluminum, ammonium salts and mercury/hydrogen mixtures.
HAZARDOUS DECOMPOSITION PRODUCTS: Combustion: Thermal decomposition of this product can generate dusts, irritating
fumes, and toxic gases (e.g., carbon, nitrogen and silicone oxides, formaldehyde, various hydrocarbons). Hydrolysis: Methylethyl
ketoxime.
POSSIBILITY OF HAZARDOUS REACTIONS/POLYMERIZATION: This product is not expected to undergo hazardous
polymerization, decomposition, condensation, or self-reactivity.
11. TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS: The most significant routes of occupational overexposure are inhalation and contact with skin and
eyes. The symptoms of overexposure to this product are as follows:
CONTACT WITH SKIN or EYES: Contact may mildly irritate the skin and cause redness and discomfort. Prolonged or repeated skin contact may
cause dermatitis (dry, red skin). Eye contact may cause redness, pain, and tearing.
SKIN ABSORPTION: The components of this product are not known to be absorbed through intact skin. Skin contact may cause sensitization and
allergic reaction in susceptible individuals. Symptoms may include redness, itching and rash.
INGESTION: If the product is swallowed, it may mildly irritate the mouth, throat, and other tissues of the gastro-intestinal system and may cause
nausea, vomiting, and diarrhea.
INHALATION: Overexposure to vapors of this product generated during curing, or dusts of this product generated during use after curing may mildly
irritate the respiratory tract and cause coughing and sneezing. Vapors or fumes when used in an enclosed space, if heated or during curing may cause
irritation of the respiratory system. Symptoms include nose irritation, dry or sore or burning throat, runny nose, shortness of breath, dizziness,
incoordination.
INJECTION: Accidental injection of this product (e.g. puncture with a contaminated object) may cause burning, redness, and swelling in addition to
the wound.
TARGET ORGANS: Acute: Skin, eyes, central nervous system. Chronic: Skin.
CHRONIC EFFECTS: Prolonged or repeated skin contact may cause dermatitis (dry, red skin), sensitization to the skin or adverse liver or kidney
effects.

Pecora 890 NTS Page 4 of 9 March 27, 2014


11. TOXICOLOGICAL INFORMATION (Continued)
TOXICITY DATA: There are currently no toxicity data available for this product; the following toxicology information is available for
components greater than 1% in concentration. Due to the large amount of data for the Carbon Black component, only LD50 Oral-Rat
and LD50 Skin-Rabbit data are presented in this SDS. Contact Pecora for additional information.
PROPRIETARY CROSSLINKER: FUMED SILICA (continued):
LD50 (Oral-Rat) > 8000 mg/kg TDLo (Intratracheal-Mouse) 2 mg/kg: Lungs, Thorax, or Respiration: other changes;
LD50 (Dermal-Rat) > 4000 mg/kg Biochemical: Enzyme inhibition, induction, or change in blood or tissue levels: peptidases
LC50 (Inhalation-Rat) > 8000 mg/m3, 4 hours TDLo (Intratracheal-Mouse) 2 mg/kg: Lungs, Thorax, or Respiration: fibrosing alveolitis;
CALCIUM CARBONATE, NATURAL: Biochemical: Enzyme inhibition, induction, or change in blood or tissue levels: peptidases,
TDLo (Intravenous-Rat) 30 mg/kg: Vascular: BP lowering not characterized in autonomic Metabolism (Intermediary): effect on inflammation or mediation of inflammation
section; Lungs, Thorax, or Respiration: changes in lung weight; Blood: other changes LDLo (Intratracheal-Rat) 50 mg/kg
TCLo (Inhalation-Rat) 84 mg/m3/4 hours/40 weeks-intermittent: Lungs, Thorax, or LDLo (Intratracheal-Rat) 10 mg/kg
Respiration: fibrosis (interstitial); Liver: other changes; Kidney/Ureter/Bladder: other LDLo (Intratracheal-Mouse) 96.77 mg/kg: Lungs, Thorax, or Respiration: acute pulmonary
changes edema, dyspnea, other changes
TCLo (Inhalation-Rat) 250 mg/m3/2 hours/24 weeks-intermittent: Lungs, Thorax, or MINERAL SPIRITS:
Respiration: fibrosis, focal (pneumoconiosis) TDLo (Oral-Rat) 10 mg/kg: Biochemical: Metabolism (Intermediary): effect on
FUMED SILICA: inflammation or mediation of inflammation
LD50 (Oral-Rat) 3160 mg/kg Standard Draize Test (Eye-Human) 100 ppm: Mild
LD50 (Intravenous-Rat) 15 mg/kg: Lungs, Thorax, or Respiration: acute pulmonary edema Standard Draize Test (Eye-Rabbit) 500 mg/24 hours: Moderate
TCLo (Inhalation-Rat) 154 mg/m3/6 hours/4 weeks-intermittent: Lungs, Thorax, or LC50 (Inhalation-Rat) > 1400 ppm/8 hours
Respiration: structural or functional change in trachea or bronchi; Biochemical: Enzyme LD (Oral-Rat) > 5 gm/kg: Behavioral: somnolence (general depressed activity)
inhibition, induction, or change in blood or tissue levels: dehydrogenases, Metabolism LD (Skin-Rabbit) > 3 gm/kg
(Intermediary): other proteins LC (Inhalation-Rat) > 5500 mg/m3/4 hours: Behavioral: somnolence (general depressed
TCLo (Inhalation-Rat) 5.41 mg/m3/5 days-intermittent: Lungs, Thorax, or Respiration: activity)
other changes, changes in lung weight; Biochemical: Metabolism (Intermediary): effect LC (Inhalation-Dog) > 8 gm/m3/8 hours-continuous: Behavioral: tremor, convulsions or
on inflammation or mediation of inflammation effect on seizure threshold
TCLo (Inhalation-Rat) 1.39 mg/m3/5 days-intermittent: Nutritional and Gross Metabolic: 8200 mg/m3/8 hours: Behavioral: tremor
weight loss or decreased weight gain LCLo (Inhalation-Cat) 1700 ppm/7 hours: Behavioral: tremor, convulsions or effect on
TDLo (Intratracheal-Mouse) 96.77 mg/kg: Lungs, Thorax, or Respiration: acute seizure threshold
pulmonary edema, other changes; Biochemical: Metabolism (Intermediary): effect on LCLo (Inhalation-Dog) 8000 mg/m3/3 hours......Behavioral: alteration of classical
inflammation or mediation of inflammation conditioning
TDLo (Intratracheal-Mouse) 50 mg/kg: Lungs, Thorax, or Respiration: changes in lung TCLo (Inhalation-Rat) 330 ppm/65 days-intermittent: Kidney/Ureter/Bladder: changes in
weight tubules (including acute renal failure, acute tubular necrosis); Blood: other changes
TDLo (Intratracheal-Mouse) 2 mg/kg: 2 mg/kg: Lungs, Thorax, or Respiration: fibrosis, TCLo (Inhalation-Rat) 480 mg/m3/65 days-intermittent: Blood: normocytic anemia
focal (pneumoconiosis), other changes; Biochemical: Metabolism (Intermediary): effect TCLo (Inhalation-Rat) 1100 mg/m3/65 days-intermittent: Kidney/Ureter/Bladder: renal
on inflammation or mediation of inflammation function tests depressed; Blood: normocytic anemia
TDLo (Skin-Rabbit) 2 gm/kg/4 weeks-intermittent: Skin and Appendages: dermatitis, other
(after systemic exposure)
CARCINOGENIC POTENTIAL: The following table summarizes the carcinogenicity listing for the components of this product.
“NO” indicates that the substance is not considered to be or suspected to be a carcinogen by the listed agency, see section 16 for
definitions of other ratings.
CHEMICAL EPA IARC NTP NIOSH ACGIH OSHA PROP 65
Proprietary Crosslinker No No No No No No No
Calcium Carbonate (Natural) No No No No No No No
Mineral Spirits No No No No No No No
Quartz No 1 K Ca A2 No Yes (airborne, unbound particles of respirable size)
Silicon Dioxide, Fumed No No No No No No No
IARC 1: Carcinogenic to Humans. NTP-K: Known to Be a Human Carcinogen. NIOSH-Ca: Potential Occupational Carcinogen, with No Further Categorization. ACGIH
TLV-A2: Suspected Human Carcinogen.
IRRITANCY OF PRODUCT: This product may mildly irritate contaminated tissue, especially if contact is prolonged. Eye irritation
may be more pronounced.
SENSITIZATION TO THE PRODUCT: This product may cause skin sensitization and allergic reaction in susceptible individuals due to
the Proprietary Crosslinker component.
TOXICOLOGICAL SYNERGISTIC PRODUCTS: None known.
REPRODUCTIVE TOXICITY INFORMATION: This product has not been tested for reproductive toxicity.
MUTAGENICITY/EMBRYOTOXICITY/ TERATOGENICITY/REPRODUCTIVE TOXICITY: No information available.
BIOLOGICAL EXPOSURES INDICES (BEIs): There are no BEI’s established for any component of this product at this time.
12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
MOBILITY: This product has not been tested for mobility in soil.
PERSISTENCE AND BIODEGRADABILITY: This product has not been tested for persistence or biodegradability.
BIO-ACCUMULATION POTENTIAL: This product has not been tested for bio-accumulation potential.
ECOTOXICITY: This product has not been tested for aquatic or animal toxicity. Although no data is available, under the Global
Harmonization Standard, the Proprietary Crosslinker component is classified as having chronic aquatic toxicity.
OTHER ADVERSE EFFECTS: This material is not expected to have any ozone depletion potential.
ENVIRONMENTAL EXPOSURE CONTROLS: Controls should be engineered to prevent release to the environment, including
procedures to prevent spills, atmospheric release and release to waterways.

Pecora 890 NTS Page 5 of 9 March 27, 2014


13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: As supplied, this product would not be a hazardous waste as defined by U.S. federal
regulation (40 CFR 261) if discarded or disposed. State and local regulations may differ from federal regulations. The generator of
the waste is responsible for proper waste determination and management.
U.S. EPA WASTE NUMBER: Not applicable.
14. TRANSPORTATION INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION: This product is NOT classified as Dangerous Goods, per U.S. DOT regulations,
under 49 CFR 172.101.
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is NOT classified as
Dangerous Goods, per regulations of Transport Canada.
INTERNATIONAL AIR TRANSPORT ASSOCIATION SHIPPING INFORMATION (IATA): This product is NOT classified as
dangerous goods, per the International Air Transport Association.
INTERNATIONAL MARITIME ORGANIZATION SHIPPING INFORMATION (IMO): This product is not classified as dangerous
goods, per the International Maritime Organization.
15. REGULATORY INFORMATION
ADDITIONAL U.S. REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS: No component of this product is subject to the reporting requirements of Sections 302,
304, and 313 of Title III of the Superfund Amendments and Reauthorization Act.
U.S. SARA HAZARD CATEGORIES (SECTION 311/312, 40 CFR 370-21): ACUTE: Yes; CHRONIC: Yes; FIRE: No; REACTIVE: No;
SUDDEN RELEASE: No
U.S. TSCA INVENTORY STATUS: All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic
Substances Control Act (TSCA) Chemical Substance Inventory.
U.S. CERCLA REPORTABLE QUANTITY (RQ): Not applicable.
U.S. CLEAN AIR ACT (CA 112r) THRESHOLD QUANTITY (TQ): Not applicable.
OTHER U.S. FEDERAL REGULATIONS: Not applicable.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): The trace Quartz component (airborne,
unbound particles of respirable size) is found on the Proposition 65 List of chemicals known to the state to cause cancer. Due to the form of the
product, the Proposition 65 warning is not applicable to this compound in this product.
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are listed on the DSL Inventory.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: No component of this product is on the
CEPA Priorities Substances Lists.
CANADIAN WHMIS REGULATIONS: This product is classified as a Controlled Product, Hazard Class D2B (Immediate Acute Toxicity/Irritation &
Sensitization) as per the Controlled Product Regulations.

ADDITIONAL MEXICAN REGULATIONS:


MEXICAN WORKPLACE REGULATIONS (NOM-018-STPS-2000): This product is not classified as hazardous.

16. OTHER INFORMATION


WARNINGS (per ANSI Z129.1): CAUTION! MAY CAUSE EYE, SKIN, AND RESPIRATORY TRACT IRRITATION,
ESPECIALLY IF EXPOSURE IS PROLONGED. MAY CAUSE SKIN SENSITIZATION AND ALLERGIC REACTION IN
SUSCEPTIBLE INDIVIDUALS. CONTAINS COMPOUND THAT MAY CAUSE CHRONIC AQUATIC ADVERSE EFFECTS.
COMBUSTIBLE – CAN IGNITE IF EXPOSED TO DIRECT FLAME. Avoid contact with eyes, skin, and clothing. Avoid
breathing fumes, dusts, vapors or mist. Do not taste or swallow. Wash thoroughly after handling. Keep container tightly closed.
Use only with adequate ventilation. Keep away from heat and flame. Wear gloves, eye protection, respiratory protection, and
appropriate body protection. FIRST-AID: In case of contact, immediately flush skin and eyes with plenty of water. Remove
contaminated clothing and shoes. Get medical attention if irritation develops or persists. If inhaled, remove to fresh air. If not
breathing, give artificial respiration. If breathing is difficult, give oxygen. If swallowed, do not induce vomiting. Get medical
attention. IN CASE OF FIRE: Use water fog, foam, dry chemical, or CO2. IN CASE OF SPILL: Absorb spilled product with
polypads or other suitable absorbing material. Place all spill residue in an appropriate container and seal. Dispose of in accordance
with U.S. Federal, State, and local hazardous waste disposal regulations and those of Canada.
GLOBAL HARMONIZATION LABELING AND CLASSIFICATION: Classified in accordance with the Global Harmonization
Standard.
Classification: Acute Oral Toxicity Category 5, Eye Irritation Category 2B, Skin Irritation Category 3, Skin Sensitization Category 1, Aquatic Chronic
Toxicity Category 4
Signal Word: Warning
Hazard Statements: H303: May be harmful if ingested. H316: Causes mild skin irritation. H320: Causes eye irritation. H317: May cause an allergic skin
reaction. H413: May be harmful to aquatic life with long-lasting effects.
Precautionary Statements:
Prevention: P261: Avoid breathing fume. P264: Wash thoroughly after handling. P272: Contaminated work clothing should not be allowed out of the
workplace. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection.

Pecora 890 NTS Page 6 of 9 March 27, 2014


16. OTHER INFORMATION (Continued)
GLOBAL HARMONIZATION LABELING AND CLASSIFICATION (continued):
Precautionary Statements (continued):
Response: P332 + P313: If skin irritation occurs, get medical attention. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. P337 + P313: If eye irritation persists: Get medical advice/attention. P302 + P352: IF ON
SKIN: Wash with plenty of soap and water. P333 + P313: If skin irritation or rash occurs: Get medical advice/attention. P362 + P364: Take off
contaminated clothing and wash it before reuse. P321: Specific treatment (remove from exposure and treat symptoms).
Storage: None.
Disposal: P501: Dispose of contents/containers in accordance with all local, regional, national and international regulations.
Hazard Symbols/Pictogram: GHS07
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES
The information presented in this Material Safety Data Sheet is presented in good faith based on data believed to be accurate as of the date this Material Safety Data Sheet was prepared.
HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED
REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS
INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. In no case shall the descriptions, information, data or designs
provided be considered a part of our terms and conditions of sale.
All materials may present hazards and should be used with caution. Because many factors may affect processing or application/use, we recommend that you make tests to determine the
suitability of a product for your particular purpose prior to use. No responsibility is assumed for any damage or injury resulting from abnormal use or from any failure to adhere to
recommended practices or applicable federal, state, or local laws or regulations. The information provided above, and the product, are furnished on the condition that the person receiving
them shall make their own determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk of their use. In addition, no
authorization is given nor implied to practice any patented invention without a license.
REFERENCES AND DATA SOURCES: Contact the supplier for information.
METHODS OF EVALUATING INFORMATION FOR THE PURPOSE OF CLASSIFICATION: Bridging principles were used to classify this product.
REVISION DETAILS: July 2012: Up-date and revise entire MSDS to include current GHS requirements.
DATE OF PRINTING March 27, 2014

DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these, which are commonly used, include the following:
KEY ACRONYMS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD
CHEMTREC: Chemical Transportation Emergency Center, a 24-hour emergency information and/or RATINGS: This rating system was developed by the National Paint and Coating Association and
emergency assistance to emergency responders. has been adopted by industry to identify the degree of chemical hazards.
CEILING LEVEL: The concentration that shall not be exceeded during any part of the working HEALTH HAZARD: 0 Minimal Hazard: No significant health risk, irritation of skin or eyes not
exposure. anticipated. Skin Irritation: Essentially non-irritating. Mechanical irritation may occur. PII or Draize =
DFG MAKs: Federal Republic of Germany Maximum Concentration Values in the workplace. 0. Eye Irritation: Essentially non-irritating, minimal effects clearing in < 24 hours. Mechanical
Exposure limits are given as TWA (Time-Weighted Average) or PEAK (short-term exposure) values. irritation may occur. Draize = 0. Oral Toxicity LD50 Rat: > 5000 mg/kg. Dermal Toxicity LD50 Rat or
DFG MAK Germ Cell Mutagen Categories: 1: Germ cell mutagens that have been shown to Rabbit: > 2000 mg/kg. Inhalation Toxicity 4-hrs LC50 Rat: > 20 mg/L. 1 Slight Hazard: Minor
increase the mutant frequency in the progeny of exposed humans. 2: Germ cell mutagens that have reversible injury may occur; may irritate the stomach if swallowed; may defat the skin and exacerbate
been shown to increase the mutant frequency in the progeny of exposed mammals. 3A: Substances existing dermatitis. Skin Irritation: Slightly or mildly irritating. PII or Draize > 0 < 5. Eye Irritation:
that have been shown to induce genetic damage in germ cells of human of animals, or which produce Slightly to mildly irritating, but reversible within 7 days. Draize > 0 ≤ 25. Oral Toxicity LD50 Rat: >
mutagenic effects in somatic cells of mammals in vivo and have been shown to reach the germ cells in 500–5000 mg/kg. Dermal Toxicity LD50 Rat or Rabbit: > 1000–2000 mg/kg. Inhalation Toxicity LC50
an active form. 3B: Substances that are suspected of being germ cell mutagens because of their 4-hrs Rat: > 2–20 mg/L. 2 Moderate Hazard: Temporary or transitory injury may occur; prolonged
genotoxic effects in mammalian somatic cell in vivo; in exceptional cases, substances for which there exposure may affect the CNS. Skin Irritation: Moderately irritating; primary irritant; sensitizer. PII or
are no in vivo data, but that are clearly mutagenic in vitro and structurally related to known in vivo Draize ≥ 5, with no destruction of dermal tissue. Eye Irritation: Moderately to severely irritating;
mutagens. 4: Not applicable (Category 4 carcinogenic substances are those with non-genotoxic reversible corneal opacity; corneal involvement or irritation clearing in 8–21 days. Draize = 26–100,
mechanisms of action. By definition, germ cell mutagens are genotoxic. Therefore, a Category 4 for with reversible effects. Oral Toxicity LD50 Rat: > 50–500 mg/kg. Dermal Toxicity LD50 Rat or
germ cell mutagens cannot apply. At some time in the future, it is conceivable that a Category 4 could Rabbit: > 200–1000 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 0.5–2 mg/L. 3 Serious Hazard:
be established for genotoxic substances with primary targets other than DNA [e.g. purely aneugenic Major injury likely unless prompt action is taken and medical treatment is given; high level of
substances] if research results make this seem sensible.) 5: Germ cell mutagens, the potency of which toxicity; corrosive. Skin Irritation: Severely irritating and/or corrosive; may cause destruction of
is considered to be so low that, provided the MAK value is observed, their contribution to genetic risk dermal tissue, skin burns, and dermal necrosis. PII or Draize > 5–8, with destruction of tissue. Eye
for humans is expected not to be significant. Irritation: Corrosive, irreversible destruction of ocular tissue; corneal involvement or irritation
DFG MAK Pregnancy Risk Group Classification: Group A: A risk of damage to the developing persisting for more than 21 days. Draize > 80 with effects irreversible in 21 days. Oral Toxicity LD50
embryo or fetus has been unequivocally demonstrated. Exposure of pregnant women can lead to Rat: > 1–50 mg/kg. Dermal Toxicity LD50 Rat or Rabbit: > 20–200 mg/kg. Inhalation Toxicity LC50 4-
damage of the developing organism, even when MAK and BAT (Biological Tolerance Value for hrs Rat: > 0.05–0.5 mg/L.4 Severe Hazard: Life-threatening; major or permanent damage may result
Working Materials) values are observed. Group B: Currently available information indicates a risk of from single or repeated exposures; extremely toxic; irreversible injury may result from brief contact.
damage to the developing embryo or fetus must be considered to be probable. Damage to the Skin Irritation: Not appropriate. Do not rate as a 4, based on skin irritation alone. Eye Irritation: Not
developing organism cannot be excluded when pregnant women are exposed, even when MAK and appropriate. Do not rate as a 4, based on eye irritation alone. Oral Toxicity LD50 Rat: ≤ 1 mg/kg.
BAT values are observed. Group C: There is no reason to fear a risk of damage to the developing Dermal Toxicity LD50 Rat or Rabbit: ≤ 20 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: ≤ 0.05 mg/L.
embryo or fetus when MAK and BAT values are observed. Group D: Classification in one of the FLAMMABILITY HAZARD: 0 Minimal Hazard: Materials that will not burn in air when exposure
groups A–C is not yet possible because, although the data available may indicate a trend, they are not to a temperature of 815.5°C (1500°F) for a period of 5 minutes. 1 Slight Hazard: Materials that must
sufficient for final evaluation. be pre-heated before ignition can occur. Material requires considerable pre-heating, under all ambient
IDLH: Immediately Dangerous to Life and Health. This level represents a concentration from which temperature conditions before ignition and combustion can occur. This usually includes the following:
one can escape within 30-minutes without suffering escape-preventing or permanent injury. Materials that will burn in air when exposed to a temperature of 815.5°C (1500°F) for a period of 5
LOQ: Limit of Quantitation. minutes or less; Liquids, solids and semisolids having a flash point at or above 93.3°C (200°F) (i.e.
NE: Not Established. When no exposure guidelines are established, an entry of NE is made for OSHA Class IIIB); and Most ordinary combustible materials (e.g. wood, paper, etc.). 2 Moderate
reference. Hazard: Materials that must be moderately heated or exposed to relatively high ambient temperatures
NIC: Notice of Intended Change. before ignition can occur. Materials in this degree would not, under normal conditions, form
NIOSH CEILING: The exposure that shall not be exceeded during any part of the workday. If hazardous atmospheres in air, but under high ambient temperatures or moderate heating may release
instantaneous monitoring is not feasible, the ceiling shall be assumed as a 15-minute TWA exposure vapor in sufficient quantities to produce hazardous atmospheres with air. This usually includes the
(unless otherwise specified) that shall not be exceeded at any time during a workday. following: Liquids having a flash-point at or above 37.8°C (100°F); Solid materials in the form of
NIOSH RELs: NIOSH’s Recommended Exposure Limits. course dusts that may burn rapidly but that generally do not form explosive atmospheres; Solid
PEL: OSHA's Permissible Exposure Limits. This exposure value means exactly the same as a TLV, materials in a fibrous or shredded form that may burn rapidly and create flash fire hazards (e.g.
except that it is enforceable by OSHA. The OSHA Permissible Exposure Limits are based in the cotton, sisal, hemp); and Solids and semisolids (e.g. viscous and slow flowing as asphalt) that readily
1989 PELs and the June, 1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: give off flammable vapors. 3 Serious Hazard: Liquids and solids that can be ignited under almost all
40191). Both the current PELs and the vacated PELs are indicated. The phrase, “Vacated 1989 PEL” ambient temperature conditions. Materials in this degree produce hazardous atmospheres with air
is placed next to the PEL that was vacated by Court Order. under almost all ambient temperatures, or, unaffected by ambient temperature, are readily ignited
SKIN: Used when a there is a danger of cutaneous absorption. under almost all conditions. This usually includes the following: Liquids having a flash point below
STEL: Short Term Exposure Limit, usually a 15-minute time-weighted average (TWA) exposure that 22.8°C (73°F) and having a boiling point at or above 38°C (100
should not be exceeded at any time during a workday, even if the 8-hr TWA is within the TLV-TWA, point at or above 22.8°C (73°F) and below 37.8°C (100°F) (i.e. OSHA Class IB and IC); Materials
PEL-TWA or REL-TWA. that on account of their physical form or environmental conditions can form explosive mixtures with
TLV: Threshold Limit Value. An airborne concentration of a substance that represents conditions air and are readily dispersed in air (e.g., dusts of combustible solids, mists or droplets of flammable
under which it is generally believed that nearly all workers may be repeatedly exposed without liquids); and Materials that burn extremely rapidly, usually by reason of self-contained oxygen (e.g.
adverse effect. The duration must be considered, including the 8-hour. dry nitrocellulose and many organic peroxides). 4 Severe Hazard: Materials that will rapidly or
TWA: Time Weighted Average exposure concentration for a conventional 8-hr (TLV, PEL) or up to completely vaporize at atmospheric pressure and normal ambient temperature or that are readily
a 10-hr (REL) workday and a 40-hr workweek. dispersed in air, and that will burn readily. This usually includes the following: Flammable gases;
WEEL: Workplace Environmental Exposure Limits from the AIHA. Flammable cryogenic materials; Any liquid or gaseous material that is liquid while under pressure
and has a flash point below 22.8°C (73°F) and a boiling point below 37.8°C (100°F) (i.e. OSHA Class
IA); and Materials that ignite spontaneously when exposed to air at a temperature of 54.4°C (130°F)
or below (pyrophoric).

Pecora 890 NTS Page 7 of 9 March 27, 2014


DEFINITIONS OF TERMS (Continued)
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD NATIONAL FIRE PROTECTION ASSOCIATION HAZARD RATINGS
RATINGS (continued): (continued):
PHYSICAL HAZARD: 0 Water Reactivity: Materials that do not react with water. Organic HEALTH HAZARD (continued): 3 (continued): Materials with an LD50 for acute dermal toxicity
Peroxides: Materials that are normally stable, even under fire conditions and will not react with water. greater than 40 mg/kg but less than or equal to 200 mg/kg. Materials that are corrosive to the
Explosives: Substances that are Non-Explosive. Compressed Gases: No Rating. Pyrophorics: No respiratory tract. Materials that are corrosive to the eyes or cause irreversible corneal opacity.
Rating. Oxidizers: No 0 rating. Unstable Reactives: Substances that will not polymerize, decompose, Materials corrosive to the skin. Cryogenic gases that cause frostbite and irreversible tissue damage.
condense, or self-react.). 1 Water Reactivity: Materials that change or decompose upon exposure to Compressed liquefied gases with boiling points below -55°C (-66.5°F) that cause frostbite and
moisture. Organic Peroxides: Materials that are normally stable, but can become unstable at high irreversible tissue damage. Materials with an LD50 for acute oral toxicity greater than 5 mg/kg but less
temperatures and pressures. These materials may react with water, but will not release energy than or equal to 50 mg/kg. 4 Materials that, under emergency conditions, can be lethal. Gases with an
violently. Explosives: Division 1.5 & 1.6 explosives. Substances that are very insensitive explosives LC50 for acute inhalation toxicity less than or equal to 1,000 ppm. Any liquid whose saturated vapor
or that do not have a mass explosion hazard. Compressed Gases: Pressure below OSHA definition. concentration at 20°C (68°F) is equal to or greater than ten times its LC50 for acute inhalation toxicity,
Pyrophorics: No Rating. Oxidizers: Packaging Group III oxidizers; Solids: any material that in either if its LC50 is less than or equal to 1000 ppm. Dusts and mists whose LC50 for acute inhalation toxicity
concentration tested, exhibits a mean burning time less than or equal to the mean burning time of a is less than or equal to 0.5 mg/L. Materials whose LD50 for acute dermal toxicity is less than or equal
3:7 potassium bromate/cellulose mixture and the criteria for Packing Group I and II are not met. to 40 mg/kg. Materials whose LD50 for acute oral toxicity is less than or equal to 5 mg/kg.
Liquids: any material that exhibits a mean pressure rise time less than or equal to the pressure rise FLAMMABILITY HAZARD: 0 Materials that will not burn under typical fire conditions, including
time of a 1:1 nitric acid (65%)/cellulose mixture and the criteria for Packing Group I and II are not intrinsically noncombustible materials such as concrete, stone, and sand. Materials that will not burn
met. Unstable Reactives: Substances that may decompose condense, or self-react, but only under in air when exposed to a temperature of 816°C (1500°F) for a period of 5 minutes in according with
conditions of high temperature and/or pressure and have little or no potential to cause significant heat Annex D of NFPA 704. 1 Materials that must be preheated before ignition can occur. Materials in this
generation or explosion hazard. Substances that readily undergo hazardous polymerization in the degree require considerable preheating, under all ambient temperature conditions, before ignition and
absence of inhibitors. 2 Water Reactivity: Materials that may react violently with water. Organic combustion can occur: Materials that will burn in air when exposed to a temperature of 816°C
Peroxides: Materials that, in themselves, are normally unstable and will readily undergo violent (1500°F) for a period of 5 minutes in according with Annex D of NFPA 704. Liquids, solids, and
chemical change, but will not detonate. These materials may also react violently with water. semisolids having a flash point at or above 93.4°C (200°F) (i.e. Class IIIB liquids). Liquids with a
Explosives: Division 1.4 explosives. Explosive substances where the explosive effects are largely flash point greater than 35°C (95°F) that do not sustain combustion when tested using the Method of
confined to the package and no projection of fragments of appreciable size or range are expected. An Testing for Sustained Combustibility, per 49 CFR 173, Appendix H or the UN Recommendations on
external fire must not cause virtually instantaneous explosion of almost the entire contents of the the Transport of Dangerous Goods, Model Regulations (current edition) and the related Manual of
package. Compressed Gases: Pressurized and meet OSHA definition but < 514.7 psi absolute at Tests and Criteria (current edition). Liquids with a flash point greater than 35°C (95°F) in a water-
21.1°C (70°F) [500 psig]. Pyrophorics: No Rating. Oxidizers: Packing Group II oxidizers. Solids: any miscible solution or dispersion with a water non-combustible liquid/solid content of more than 85%
material that, either in concentration tested, exhibits a mean burning time of less than or equal to the by weight. Liquids that have no fire point when tested by ASTM D 92, Standard Test Method for
mean burning time of a 2:3 potassium bromate/cellulose mixture and the criteria for Packing Group I Flash and Fire Points by Cleveland Open Cup, up to the boiling point of the liquid or up to a
are not met. Liquids: any material that exhibits a mean pressure rise time less than or equal to the temperature at which the sample being tested shows an obvious physical change. Combustible pellets
pressure rise of a 1:1 aqueous sodium chlorate solution (40%)/cellulose mixture and the criteria for with a representative diameter of greater than 2 mm (10 mesh). Most ordinary combustible materials.
Packing Group I are not met. Reactives: Substances that may polymerize, decompose, condense, or Solids containing greater than 0.5% by weight of a flammable or combustible solvent are rated by the
self-react at ambient temperature and/or pressure, but have a low potential (or low risk) for significant closed cup flash point of the solvent. 2 Materials that must be moderately heated or exposed to
heat generation or explosion. Substances that readily form peroxides upon exposure to air or oxygen relatively high ambient temperatures before ignition can occur. Materials in this degree would not
at room temperature.3 Water Reactivity: Materials that may form explosive reactions with water. under normal conditions form hazardous atmospheres with air, but under high ambient temperatures
Organic Peroxides: Materials that are capable of detonation or explosive reaction, but require a strong or under moderate heating could release vapor in sufficient quantities to produce hazardous
initiating source or must be heated under confinement before initiation; or materials that react atmospheres with air. Liquids having a flash point at or above 37.8°C (100°F) and below 93.4°C
explosively with water. Explosives: Division 1.3 explosives. Explosive substances that have a fire (200°F) (i.e. Class II and Class IIIA liquids.) Solid materials in the form of powders or coarse dusts of
hazard and either a minor blast hazard or a minor projection hazard or both, but do not have a mass representative diameter between 420 microns (40 mesh) and 2 mm (10 mesh) that burn rapidly but
explosion hazard. Compressed Gases: Pressure ≥ 514.7 psi absolute at 21.1°C (70°F) [500 psig]. that generally do not form explosive mixtures with air. Solid materials in fibrous or shredded form
Pyrophorics: No Rating. Oxidizers: Packing Group I oxidizers. Solids: any material that, in either that burn rapidly and create flash fire hazards, such as cotton, sisal, and hemp. Solids and semisolids
concentration tested, exhibits a mean burning time less than the mean burning time of a 3:2 potassium that readily give off flammable vapors. Solids containing greater than 0.5% by weight of a flammable
bromate/cellulose mixture. Liquids: any material that spontaneously ignites when mixed with or combustible solvent are rated by the closed cup flash point of the solvent. 3 Liquids and solids that
cellulose in a 1:1 ratio, or which exhibits a mean pressure rise time less than the pressure rise time of can be ignited under almost all ambient temperature conditions. Materials in this degree produce
a 1:1 perchloric acid (50%)/cellulose mixture. Unstable Reactives: Substances that may polymerize, hazardous atmospheres with air under almost all ambient temperatures or, though unaffected by
decompose, condense, or self-react at ambient temperature and/or pressure and have a moderate ambient temperatures, are readily ignited under almost all conditions. Liquids having a flash point
potential (or moderate risk) to cause significant heat generation or explosion. 4 Water Reactivity: below 22.8°C (73°F) and having a boiling point at or above 37.8°C (100°F) and those liquids having a
Materials that react explosively with water without requiring heat or confinement. Organic Peroxides: flash point at or above 22.8°C (73°F) and below 37.8°C (100°F) (i.e. Class IB and IC liquids).
Materials that are readily capable of detonation or explosive decomposition at normal temperature and Materials that on account of their physical form or environmental conditions can form explosive
pressures. Explosives: Division 1.1 & 1.2 explosives. Explosive substances that have a mass explosion mixtures with air and are readily dispersed in air. Flammable or combustible dusts with representative
hazard or have a projection hazard. A mass explosion is one that affects almost the entire load diameter less than 420 microns (40 mesh). Materials that burn with extreme rapidity, usually by
instantaneously. Compressed Gases: No Rating. Pyrophorics: Add to the definition of Flammability reason of self-contained oxygen (e.g. dry nitrocellulose and many organic peroxides). Solids
4. Oxidizers: No 4 rating. Unstable Reactives: Substances that may polymerize, decompose, containing greater than 0.5% by weight of a flammable or combustible solvent are rated by the closed
condense, or self-react at ambient temperature and/or pressure and have a high potential (or high risk) cup flash point of the solvent. 4 Materials that will rapidly or completely vaporize at atmospheric
to cause significant heat generation or explosion. Pyrophorics: Add to the definition of Flammability pressure and normal ambient temperature or that are readily dispersed in air and will burn readily.
4. Oxidizers: No 4 rating. Unstable Reactives: Substances that may polymerize, decompose, Flammable gases. Flammable cryogenic materials. Any liquid or gaseous materials that is liquid while
condense, or self-react at ambient temperature and/or pressure and have a high potential (or high risk) under pressure and has a flash point below 22.8°C (73°F) and a boiling point below 37.8°C (100°F)
to cause significant heat generation or explosion. (i.e. Class IA liquids). Materials that ignite when exposed to air, Solids containing greater than 0.5%
NATIONAL FIRE PROTECTION ASSOCIATION HAZARD RATINGS by weight of a flammable or combustible solvent are rated by the closed cup flash point of the
HEALTH HAZARD: 0 Materials that, under emergency conditions, would offer no hazard beyond solvent.
that of ordinary combustible materials. Gases and vapors with an LC50 for acute inhalation toxicity INSTABILITY HAZARD: 0 Materials that in themselves are normally stable, even under fire
greater than 10,000 ppm. Dusts and mists with an LC50 for acute inhalation toxicity greater than 200 conditions. Materials that have an instantaneous power density (product of heat of reaction and
mg/L. Materials with an LD50 for acute dermal toxicity greater than 2000 mg/kg. Materials with an reaction rate) at 250°C (482°F) below 0.01 W/mL. Materials that do not exhibit an exotherm at
LD50 for acute oral toxicity greater than 2000 mg/kg. Materials essentially non-irritating to the temperatures less than or equal to 500°C (932°F) when tested by differential scanning calorimetry.1
respiratory tract, eyes, and skin. 1 Materials that, under emergency conditions, can cause significant Materials that in themselves are normally stable, but that can become unstable at elevated
irritation. Gases and vapors with an LC50 for acute inhalation toxicity greater than 5,000 ppm but less temperatures and pressures. Materials that have an instantaneous power density (product of heat of
than or equal to 10,000 ppm. Dusts and mists with an LC50 for acute inhalation toxicity greater than reaction and reaction rate) at 250°C (482°F) at or above 0.01 W/mL and below 10 W/mL. 2 Materials
10 mg/L but less than or equal to 200 mg/L. Materials with an LD50 for acute dermal toxicity greater that readily undergo violent chemical change at elevated temperatures and pressures. Materials that
than 1000 mg/kg but less than or equal to 2000 mg/kg. Materials that slightly to moderately irritate have an instantaneous power density (product of heat of reaction and reaction rate) at 250°C (482°F)
the respiratory tract, eyes and skin. Materials with an LD50 for acute oral toxicity greater than 500 at or above 10 W/mL and below 100W/mL. 3 Materials that in themselves are capable of detonation
mg/kg but less than or equal to 2000 mg/kg. 2 Materials that, under emergency conditions, can cause or explosive decomposition or explosive reaction, but that require a strong initiating source or that
temporary incapacitation or residual injury. Gases with an LC50 for acute inhalation toxicity greater must be heated under confinement before initiation. Materials that have an estimated instantaneous
than 3,000 ppm but less than or equal to 5,000 ppm. Any liquid whose saturated vapor concentration power density (product of heat of reaction and reaction rate) at 250°C (482°F) at or above 100 W/mL
at 20°C (68°F) is equal to or greater than one-fifth its LC50 for acute inhalation toxicity, if its LC50 is and below 1000 W/mL. Materials that are sensitive to thermal or mechanical shock at elevated
less than or equal to 5000 ppm and that does not meet the criteria for either degree of hazard 3 or temperatures and pressures. 4 Materials that in themselves are readily capable of detonation or
degree of hazard 4. Dusts and mists with an LC50 for acute inhalation toxicity greater than 2 mg/L but explosive decomposition or explosive reaction at normal temperatures and pressures. Materials that
less than or equal to 10 mg/L. Materials with an LD50 for acute dermal toxicity greater than 200 are sensitive to localized thermal or mechanical shock at normal temperatures and pressures.
mg/kg but less than or equal to 1000 mg/kg. Compressed liquefied gases with boiling points between Materials that have an estimated instantaneous power density (product of heat of reaction and reaction
-30°C (-22°F) and -55°C (-66.5°F) that cause severe tissue damage, depending on duration of rate) at 250°C (482°F) of 1000 W/mL or greater.
exposure. Materials that are respiratory irritants. Materials that cause severe, but reversible irritation FLAMMABILITY LIMITS IN AIR:
to the eyes or are lachrymators. Materials that are primary skin irritants or sensitizers. Materials Much of the information related to fire and explosion is derived from the National Fire Protection
whose LD50 for acute oral toxicity is greater than 50 mg/kg but less than or equal to 500 mg/kg. 3 Association (NFPA). Flash Point: Minimum temperature at which a liquid gives off sufficient vapor
Materials that, under emergency conditions, can cause serious or permanent injury. Gases with an to form an ignitable mixture with air near the surface of the liquid or within the test vessel used.
LC50 for acute inhalation toxicity greater than 1,000 ppm but less than or equal to 3,000 ppm. Any Autoignition Temperature: Minimum temperature of a solid, liquid, or gas required to initiate or cause
liquid whose saturated vapor concentration at 20°C (68°F) is equal to or greater its LC 50 for acute self-sustained combustion in air with no other source of ignition. LEL: Lowest concentration of a
inhalation toxicity, if its LC50 is less than or equal to 3000 ppm and that does not meet the criteria for flammable vapor or gas/air mixture that will ignite and burn with a flame. UEL: Highest
degree of hazard 4. Dusts and mists with an LC50 for acute inhalation toxicity greater than 0.5 mg/L concentration of a flammable vapor or gas/air mixture that will ignite and burn with a flame.
but less than or equal to 2 mg/L.

Pecora 890 NTS Page 8 of 9 March 27, 2014


DEFINITIONS OF TERMS (Continued)
TOXICOLOGICAL INFORMATION: ECOLOGICAL INFORMATION:
Human and Animal Toxicology: Possible health hazards as derived from human data, animal EC: Effect concentration in water. BCF: Bioconcentration Factor, which is used to determine if a
studies, or from the results of studies with similar compounds are presented. LD50: Lethal Dose substance will concentrate in life forms that consume contaminated plant or animal matter. TLm:
(solids & liquids) that kills 50% of the exposed animals. LC50: Lethal Concentration (gases) that Median threshold limit. log KOW or log KOC: Coefficient of Oil/Water Distribution is used to assess a
kills 50% of the exposed animals. ppm: Concentration expressed in parts of material per million substance’s behavior in the environment.
parts of air or water. mg/m3: Concentration expressed in weight of substance per volume of air. REGULATORY INFORMATION: This section explains the impact of various laws and
mg/kg: Quantity of material, by weight, administered to a test subject, based on their body weight in regulations on the material.
kg. TDLo: Lowest dose to cause a symptom. TCLo: Lowest concentration to cause a symptom. U.S.:
TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCo: Lowest dose (or concentration) to cause lethal EPA: U.S. Environmental Protection Agency. ACGIH: American Conference of Governmental
or toxic effects. Cancer Information: IARC: International Agency for Research on Cancer. NTP: Industrial Hygienists, a professional association that establishes exposure limits. OSHA: U.S.
National Toxicology Program. RTECS: Registry of Toxic Effects of Chemical Substances. IARC Occupational Safety and Health Administration. NIOSH: National Institute of Occupational Safety
and NTP rate chemicals on a scale of decreasing potential to cause human cancer with rankings from and Health, which is the research arm of OSHA. DOT: U.S. Department of Transportation. TC:
1 to 4. Subrankings (2A, 2B, etc.) are also used. Other Information: BEI: ACGIH Biological Transport Canada. SARA: Superfund Amendments and Reauthorization Act. TSCA: U.S. Toxic
Exposure Indices, represent the levels of determinants which are most likely to be observed in Substance Control Act. CERCLA: Comprehensive Environmental Response, Compensation, and
specimens collected from a healthy worker who has been exposed to chemicals to the same extent as Liability Act. Marine Pollutant status according to the DOT; CERCLA or Superfund; and various
a worker with inhalation exposure to the TLV. state regulations. This section also includes information on the precautionary warnings that appear
REPRODUCTIVE INFORMATION: A mutagen is a chemical that causes permanent on the material’s package label.
changes to genetic material (DNA) such that the changes will propagate through generational CANADA:
lines. An embryotoxin is a chemical that causes damage to a developing embryo (i.e. within the WHMIS: Canadian Workplace Hazardous Materials Information System. TC: Transport Canada.
first eight weeks of pregnancy in humans), but the damage does not propagate across DSL/NDSL: Canadian Domestic/Non-Domestic Substances List.
generational lines. A teratogen is a chemical that causes damage to a developing fetus, but the
damage does not propagate across generational lines. A reproductive toxin is any substance that
interferes in any way with the reproductive process.

Pecora 890 NTS Page 9 of 9 March 27, 2014

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