Chang Skarns China

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World Skarn Deposits - China

ZHAOSHAN CHANG†
Centre for Ore Deposit Research (CODES), University of Tasmania, Private Bag 79, Hobart, TAS 7001, Australia

Introduction TABLE 2.1. Official Definition of Relative Size of


Some Ore Deposits in China
There are numerous skarns and skarn deposits in China
and they are one of the major sources of China’s ore reserves. Large size Medium size Small size Measurements
According to government statistics to the end of 1984, skarns
Fe > 100 Mt 10 – 100 Mt < 10 Mt Ore
contain about 70 percent of China’s total reserve of tin, ~61 Cu > 0.5 Mt 0.1 – 0.5 Mt < 0.1 Mt Cu
percent of W, ~31 percent of Cu, 22.7 percent of Mo, ~ 20 Pb > 0.5 Mt 0.1 – 0.5 Mt < 0.1 Mt Pb
percent of Au, ~18 percent of Pb-Zn, and ~11 percent of Fe Zn > 0.5 Mt 0.1 – 0.5 Mt < 0.1 Mt Zn
(Zhao Yiming et al., 1990). Skarn deposits are the major Mo > 0.1 Mt 0.01 – 0.1 Mt < 0.01 Mt Mo
sources of Sn, W, rich Fe ore, rich Cu ore, and B. They are W > 50,000 10,000 – 50,000 t < 10,000 t WO3
Sn > 40,000 t 5,000 – 40,000 t < 5,000 t Sn
also one of the important sources of Mo, Be, Bi, Pb-Zn, and Au > 20 t 5 – 20 t <5t Au
Au (Zhao Yiming et al., 1990). All types of skarns, including
Fe, Cu, Pb-Zn, W, Sn, Mo, and Au are present in China (Ta-
bles 2.1. 2.2). Both calcic skarns and magnesian skarns are ex-
tensively developed. In addition, some skarns especially rich
in Mg and Al (Cao Zhengmin et al., 1990) are also recorded. Spatial and Temporal Distributions of Skarn Deposits
To help the reader with locality names, mostly written in Chi- The locations of representative skarn deposits in China are
nese Pinyin, Figure 2.1 shows the administrative divisions of shown in Figure 2.4. In general, there are many more skarn
China, and Figure 2.2 shows the major mountain ranges. deposits in eastern China than in western China, which may
simply relect the relative lack of geological work in the west-
Tectonic Setting ern part of China (Chen Yuchuan and Tao Weiping, 1995).
China can be divided into nine tectonic domains (Wang Spatially, skarn deposits occur in clusters and are concen-
Hongzhen and Mo Xuanxue, 1995). Each domain consists of trated in several districts (Fig. 2.4). In eastern China (roughly
a core of Precambrian craton(s) and is surrounded by fold east of longitude 105˚E), the skarn-rich districts include the
belts. The tectonic domains are separated by crust-consum- following:
ing convergent zones, mostly indicated by the presence of A) The Xiaoxing’anling-Zhangguangcailing-Laoyeling dis-
ophiolite zones and/or ophiolitic melange zones. From north trict (#1-#6). Tungsten, Mo (e.g., medium-size Wudaoling;
to south, the nine tectonic domains are: 1) the Altai-Xing’an size defined in Table 2.1), Cu (e.g., Cuihongshan, not shown
Belt (AXB) that is the southern part of the Siberia-Mongolia on Table 2.2), Pb-Zn, and Au skarns are present. B) The
Domain; 2) the Junggar-Tianshan Belt (JTB) that is the east- southern Daxing’anling district (#7-#9), containing Sn-Fe,
ern part of the Kazakhstan Domain; 3) the Jamus-Bureya Belt and Pb-Zn skarns. C) The Changbaishan district (#10-#13),
(JBB) that is the southern part of the North-east Asian Do- within which B-Fe, Cu, Au-Cu, and U skarns are well devel-
main; 4) the Tarim Domain (TD); 5) the Sino-Korea Domain oped. D) The Yanshan district (#14-#18), with many Mo, Cu,
(SKD); 6) the Yangtz-Qiangtang Domain (YQD); 7) the and Pb-Zn skarns. E) The northern Taihang mountains (#19-
Cathaysian Domain (CD); 8) the Tibet-Burma Domain #25), hosting various Cu, Fe, and Pb-Zn skarns. F) The south-
(TBD), and 9) the Circum-Pacific Domain (CPD) (Fig. 2.3). ern Taihang mountain district (#26-#41) with abundant in Fe-
The Precambrian cores can be divided into five stages; the only skarns. G) The central Shandong district (#43-#46) with
Qianxian stage (3.9 – 3.2 Ga), the Fupingian stage (3.2 – 2.8 many Fe and Au skarns. H) The eastern Qinling district (#47-
Ga), the Wutaian stage (2.8 – 2.5 Ga), the Lvliangian stage 52) hosting large Mo-W and Fe deposits, as well as some Cu
(2.5 – 1.8 Ga), and the Jinningian stage (1.8 Ga – 800 Ma). and Au skarns. I) The Lower Changjiang (Yangzi/Yangtze
Between 800 Ma and 210 Ma, the platiforms or cratons un- River) metallogenic belt (#54-86), famous for its rich Cu, Fe,
derwent several cycles of separation and collision, and by 210 and Au (Au-Cu) skarns. J) The Nanling district (#88-#96), one
Ma were finally welded together into the Eurasian supercon- of the world’s largest W and Sn mineralization districts. In ad-
tinent. The tectonic evolution during this period is generally dition it contains large Pb-Zn, Mo, and Cu-polymetallic
divided into three stages; the Caledonian stage (800 - ~410 skarns. K) The Wuyishan district (Zhejiang-Fujian-Guang-
Ma), the Hercynian stage (~410 Ma – 270 Ma), and the In- dong) district contains mainly Fe skarns (#98). L) The
dosinian stage (270 – 210 Ma). Along many of the subduc- Dachang district (#99-#100), one of the world’s richest Sn dis-
tion/collision zones magmatic belts were formed and these tricts, also has some Cu and Zn mineralization. M) The Wen-
can be divided into two stages, the Yanshanian stage (210 – 90 shan-Gejiu-Debao district (#101-#102), famous for its Sn
Ma, Jurassic to Late Cretaceous) and the Himalayan stage (90 skarns, supplemented by W and Cu-Pb-Sb mineralization.
Ma - present). In western China (roughly east of longitude 105˚E), skarn
deposits are concentrated in the following districts: N) The
Altai district (#103-#106), with Cu, Fe, and Pb-Zn skarns. O)

E-mail, Zhaoshan.chang@utas.edu.au The Tianshan district (#107-#108), containing Cu and Au

1
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FIG. 2.1. Administrative divisions of China (no distinction of provinces, autonomous regions, central administrative mu-
nicipalities and special administrative regions)

skarns. P) The eastern Xinjiang – northern Gansu district #120) and Yanshanian (e.g., Huitongshan Cu skarn, 192 Ma,
(#109-#113) host Cu, Fe, and Au skarns. Q) The Qilianshan #113; Tongchangshan Pb-Zn skarn, 138-118 Ma, #122; Lian-
district (#114), with large Cu-W skarns. R) The eastern Kun- long Sn skarn, 87 Ma, #119) to Himalayan (e.g., Jiama Cu
lun – Western Qinling (#115-#117) district, with Cu and Au skarn, 10-13 Ma, #123).
skarns. S) The Kandian (Sichuan-Yunnan) block district
(#118), mostly Sn skarns. T) The Sanjiang (Three Rivers: Nu- Skarn Types
jiang, Lancangjiang, and Jinshajiang) district (#119-#122), All types of skarns are present in China, including W, Sn,
hosting Sn, Cu, and Pb-Zn skarn deposits. U) The Tibet dis- Mo, Cu, Fe, Pb-Zn, Au, B, Bi, Be, and U. The major skarn
trict (#123), with large Cu skarns. types are summarized below with reference to Table 2.2.
In eastern China, the majority of the skarns are formed
during the Yanshanian stage (Jurassic to Early Cretaceous, Fe skarns
210 Ma – 90 Ma), associated with extensive magmatism at Fe skarns in China are mostly located in the southern Tai-
that time. This is after the annealing of the Eurasian Super- hang Mountains, central Shandong Province, the Lower
continent when interaction with the Pacific Plate became a Changjiang belt, and the Wuyishan district, although they are
major tectonic factor. A few exemptions, such as the Yangbis- also sparsely found in the southern Daxing’anling mountains,
han W skarn (#2) and the Wenquangou B-Fe skarn (#12), are the northern Taihang mountains, the east Qinling montains,
associated with Proterozoic migmatite. In western China, the the Altai mountains, and the eastern Xinjiang area. Some Fe
ages of the skarns and associated igneous rocks are not well skarns contain only Fe, whereas others also have Cu, Mo, or
constrained. The available dating work shows that the skarns Sn mineralization. The Fe-only skarns occur mostly in the
are formed from Proterozoic (e.g., Chahe Sn skarn, ~ 1 Ga, southern Taihang mountains (#26-41), central Shandong (#43-
#118) through Hercynian (e.g., Yangla Cu skarn, 227-208 Ma, 44), Jiangsu-Anhui section (specifically, the Nanjing-Wuhu

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FIG. 2.2. Names of major mountain ranges of China

area) of the Lower Changjiang belt (#57-60), and eastern Xin- porphyries. Many of the intrusions associated with Cu skarns
jiang (#110-111). They are mostly associated with diabase- also host porphyry Cu mineralization, with or without Mo
diorite-monzodiorite. Copper-bearing Fe skarns are found in (e.g., Xiaosigou, #15; Tongguanshan, #68; Chengmenshan,
the northern Taihang mountains (#21), and the Hubei-Jiangxi #86). Many Cu skarns also have significant Fe, Mo, Au, Zn, or
section of the Lower Changjiang belt (#71-73, #78), and are W mineralization.
mostly associated with quartz monzodiorite-granodiorite. Some Cu mineralization is hosted in stratiform skarnoids
Molybdenum-bearing Fe skarns, including those in eastern within slightly metamorphosed strata containing marble and
Qinling (#47-48) and those in the Wuyishan mountains (#98), siliceous rock, meta-sandstone, phyllite, slate, or volcanic
are mostly associated with granodiorite-granite. Some Fe rocks (e.g., Tongyugou, #116). Some of such skarns are close
skarns associated with granite also have significant Sn miner- to intrusive rocks (e.g. Yangla, #120), whereas in other
alization, such as the Huanggang Sn-Fe skarn (#9). The ig- skarnoid areas intrusive rocks have not been found (e.g.,
neous rocks are of calc-alkaline, I-type rocks. Some magne- Tongyugou, #116). A sea floor exhalative origin is advocated
sian skarn Fe deposits also have B mineralization, such as the by some researchers (e.g., Lu Yuanfa et al., 1998; Pan Jiayong
Zhijiazhuang Fe skarn (#25). Although most skarns have car- et al., 2001). For some Cu skarns within the Lower
bonate wall rocks, some only have volcanic rocks as the pro- Changjiang belt, some researchers (e.g., Zhao Bin et al., 1993;
tolith, e.g., Meishan (#57). For the Fe skarns in the Lower Zhang Shuzhen and Zhao Jinsong, 1993; Zhao Bin et al.,
Changjiang belt, some Chinese researchers have proposed 1995; Wu Yanchang and Chang Yinfo, 1998) propose a mag-
that the iron ore bodies crystallized from iron melt injected matic rather than hydrothermal origin.
into the skarns, instead of precipitation from hydrothermal
fluids (Zhai et al., 1992, 1996; Zhai and Deng, 1996, and ref- Au skarns
erences therein). Skarns containing Au include Au-only skarns and also
skarns having Au as a byproduct, such as many Cu skarns.
Cu skarns Most skarns containing Au are associated with diorite or gra-
Cu skarns are associated with diorite, granodiorite, and nodiorite, many of which are shallow porphyries. A few ex-
granite, with granodiorite being the most common associa- emptions include the Huaniushan (#112) Au skarn that is as-
tion. The intrusive rocks are generally shallow and many are sociated with granite and the Kendekoke Au deposit where

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FIG. 2.3. Tectonic framework of China (simplified from Wang and Mo, 1995)

intrusive rocks have not been found. Auriferous skarns in- Bin et al., 2000). Silver is a common metal hosted in Pb-Zn
clude both calcic skarns and magnesian skarns (e.g., Huatong skarns, but other metals, such as W, Sn, Mo, and Cu also are
#13; Yinan #46; Yinjiagou #49; Sanpu #53). Gold occurs important in some deposits. A distinctive feature of Pb-Zn
mainly as native gold and electrum. In addition, there are skarns is the high Mn content of skarn minerals, such as spes-
usually many As, Te, Bi, Sb, and Se minerals. sartine, johannsenite, rhodonite, etc. Also there typically is
more pyroxene than garnet, especially in the distal, stratiform
Pb-Zn skarns skarns.
Lead-zinc skarns are mostly associated with granodiorite
and granite, and to a lesser extent, quartz diorite (e.g., Bajiazi, Mo skarns
#18). Most of the skarns are associated with I-type rocks, but There are both calcic skarn and magnesian skarns that con-
some have S-type associations (e.g., Shuikoushan #88, tain significant Mo mineralization. The associated igneous
Huangshaping #94, and Fozichong #97 in the Nanling moun- rocks are mostly I-type granodiorite to granite but there are
tains). The emplacement depth may be shallow, as indicated also S-type plutons (e.g., Baoshan, #93). Most of the intrusive
by the porphyritic texture and coexisting volcanic rocks in rocks are porphyries, or porphyritic rock with fine to medium
some examples (e.g., Baiyinnuo #8, Bajiazi #18, Huangshap- crystalline groundmass (e.g., Sandaozhuang, #50), indicating
ing #94), or moderately deep in other cases. Some of the Pb- shallow to medium emplacement depth, respectively. Fluo-
Zn skarns are close to intrusive bodies (e.g., Shuikoushan rite is common in these skarns. Skarn and mineralization may
#88), whereas others are distal from the intrusive bodies (e.g., be proximal, or relatively distal in stratiform shape. Some Mo
Pb-Zn skarns near the Makeng Fe-skarn #98). But in most skarn also contain significant W (e.g., Sandanzhuang, #50) or
ore fields, ore bodies are present in near-intrusion to distal Cu (e.g., Baoshan, #93) mineralization.
position (e.g., Bajiazi, #18). Some Pb-Zn skarns show strong
control by faults (e.g., Bajiazi, #18), and others are distal Pb- W skarns
Zn skarns with stratiform shapes and seem to be skarnoids Most W skarns in China are located in the Nanling
(e.g., Fozichogn #97). Some researchers favor a sea floor ex- mountains and are associated with S-type granodiorite or
halative origin for such stratiform skarns/skarnoids (e.g., Yang granite. Tungsten skarns are also present in northeast

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FIG. 2.4. Skarn deposits in China

China, the Xiaoxing’anling-Zhangguangcailing mountains K-feldspar and/or albite alteration first, and were then over-
(e.g., Yangbishan #2; Songjiang, previously called Gong- printed by greisen alteration composed of mostly quartz, mus-
pengzi, #3), and northwest China in the Qilian mountains covite, minor fluorite, with or without tourmaline and topaz.
(e.g., Xiaoliugou, #114). The Yangbishan W skarn is unusual Overprinting of greisen veins on skarns is typical and impor-
in that it is associated with Proterozoic migmatitic granite. tant. Although skarns are mostly confined to the contact zone,
Generally, all W skarns are associated with highly evolved ig- Sn mineralization may extend beyond into the wall rocks (e.g.,
neous rocks and fluorite is always present in the alteration as- Gejiu #101; Dachang #99). Most of the Sn mineralization is in
semblages. Some intrusions are batholiths emplaced at depth the form of cassiterite + sulfides, whereas in some deposits it
(e.g., Xintianling, #90). Others are smaller stocks with coarse appears as cassiterite + magnetite (e.g., Huanggang, #9).
or fine grain size indicating a shallower depth (e.g., Yao-
gangxian #92, Shizhuyuan #91). In deep systems such as rep- Other skarns
resented by the Xintianling deposit (#90), skarns are confined Uranium skarns are usually associated with alkaline intru-
to the intrusive contact zone, with a narrow and long shape, sive rocks (e.g., Saima #11). Boron skarns are generally hosted
whereas in shallower systems such as Yaogangxian (#92), in dolomite or dolomitic limestone wall rock, and are domi-
skarns extend far from the intrusion, roughly along lithologic nantly magnesian skarns. Ore minerals include szaibelyite,
strata boundaries. Some intrusions have greisen alteration ludwigite, fluoborite, suanite, sakhaite.
composed of quartz, muscovite, albite, and minor tourmaline
± topaz ± beryl Conclusions
All types of skarns are present in China, and skarn deposits
Sn skarns contribute greatly to the country’s ore reserves. Some skarns,
Tin skarns are typically associated with S-type high-silica such as the Sn and W skarns, are also among the largest in the
granites, and most of them are also high in Al (Pei and Hong, world. The potential to find new skarn deposits is still great,
1995). The intrusive rocks normally have various amount of especially in the western part of China.

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Acknowledgments Chen Yuchuan, Huang Minzhi, Xu Yu, Ai Yongde, Li Xiangming, Tang Shao-
hua, and Meng Lingku, 1985, Geologic characteristics and metallogeny se-
Assistance from Professors Yusheng Zhai, Jianping Wang, ries of the Dachang cassiterite-sulfide polymetallic belt: Acta Geologica
Yongfu Ai, and Yiming Zhao and Dr. Guangjun Guo is greatly Sinica, v. 59, p. 229–233
appreciated. Chen, J., Halls, C., and Stanley, C.J., 1992, tin-bearing skarns of South China:
Geological setting and mineralogy: Ore Geology Reviews, v. 7, p. 225–248
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