Job Safety Assessment Form

Since ‘Design for Safety’ is one of the key factors in the
competition, we would like you to complete the attached Job

Safety Assessment (JSA) Form. Fill in as much data as available.
If data are not available, leave the field blank. The JSA should
be sent to usuntilFebruary 11st, 2018 as the deadline of
registration. If there will any revision for your JSA, it have to be
submitted until February 19th, 2018.
Job Safety Assessment Form

th
7 Indonesia Chem-E-Car Competition 2018
University: Diponegoro University

Vehicle Name: Alfarizi Eustass
JSA Author Contact Name: Rizky Laksmita Dewi
Author Email: rizkylaksmita@yahoo.com
Faculty Supervisor: Prof. Dr. Widayat, S.T., M.T.

Supervisor Email:
Revision #: Revision Date:
Supervisor Signature
Purpose of Experiment / Equipment: Briefly describe your

Chem-E-Car’s design, intended
mode for operation (source of
power), intended mode for
control (stopping), and major
hazards and their control.
Describe your car’s design:

‘Alfarizi’ consists of 2 components, the bottom part and body of the car. The bottom part
consists of wheels, boards, and dynamo. Besides, the body of the car consists of power
7th INDONESIA CHEM-E-CAR COMPETITION

CHERNIVAL 2018
1
source and stopping mechanism. At power source box (reactor), there is place for dry ice
on the bottom part, at the middle is TEG, then on top of TEG is place for hot reaction from
KMnO4 + glycerin. For stopping mechanism place, we use small box that can be open and
close. This box is placed behind the box of TEGs box. The reaction between KMnO4 +
glycerin causes smoke, so we design the reactor box with open-closed case. It’ll be tightly
closed when the reaction begin. We make a tiny hole in the middle of the case to inject the
glycerin. To make the car move, glycerin will be injected and reacts with KMnO4 to
produce a high temperature in order to TEG streams the electricity to dynamo from the
difference of the temperature.
We use KMnO4 3M (23,7 grams dilute in 50 mL aquadest). It’ll be react with glycerin 50
mL. This reaction produce high temperature because it is an exothermic reaction. The
temperature in which we measure shown in the graphic below.
Power Source
KMnO4(s) + C3H8O3(l)
140 121
120 105
Temperature (°C)
95
100 84
71.5 73
80
60
40
20
0
0 0.5 1 1.5 2 2.5 3 3.5
Concentratioin (M)
Based on the graphic, the highest temperature is from the experiment of KMnO4 3M with
glycerin 50 mL. Besides, we use dry ice for the cold. Its temperature is minus 78 Celsius
degree. So, the difference temperature between hot and cold is 199 Celcius degree. The
voltage which we got is 1.3 volt and the electric current is 600 mA.
Furthermore, economical aspects of the car consist of the chemical aspect and components
of the car prices. Here is the list:
Material Amount Price

Potassium Permanganate
23,7 grams IDR 9,480
(3M)
Glycerin 50 mL IDR 1,280
Aquadest 150 mL IDR 105
Dry Ice 150 grams IDR 2,550
Sulfuric Acid (0,05 M) 1,6 mL IDR 208

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2
Mg plate 7 cm IDR 5
TOTAL IDR 13,628
Component Amount Price

TEG (Thermoelectric
6 pcs IDR 443,328
Generator)
Acrylic (Body of the Car
- IDR 30,650
and the Tires)
Dynamo 1 pc IDR 5,000
Lunch Box 1 pc IDR 19,490
Injector 1 pc IDR 8,000
Cable - IDR 2,000
Glass Wool - IDR 500
TOTAL IDR 531,478
So, the sum of all prices is IDR 545,106
Power source:
‘Alfarizi’ uses TEG, based on concept of difference of temperature. A thermoelectric
generator (TEG), also called a Seebeck generator which is a solid state device that converts
heat flux (temperature differences) directly into electrical energy through a phenomenon
called the Seebeck effect (a form of thermoelectric effect). Thermoelectric generator has
function like heat engines, but are less bulky and have no moving parts. However, TEGs
are typically more expensive and less efficient. The heat which we use is from a reaction
between KMnO4 and glycerin.
14KMnO4 (s) + 4C3H8O3 (l) + H2O (l) →14MnO2 + 7K2CO3 (s) + 5CO2(g) + 17H2O(g)
The temperature in which we measure is 121 Celsius degree for KMnO4 3M based on the
graphic below. The amount of KMnO4 is 23,7 grams. It is diluted in 50 ml aquadest. Then,
KMnO4 will be react with 50 mL glycerin. For the cool part, we use up 150 grams of dry
ice. Its temperature is minus 78 Celsius degree. The difference temperature between hot
and cold is 199 Celsius degree. After we measured, the total voltage that can be produced
is 1.3 volt and the electric current is 600 mA.
Here is the graphic about our experiment, therefore we decide to use KMnO4 3M.

CHERNIVAL 2018
3
Power Source
KMnO4(s) + C3H8O3(l)
140 121
Temperature (°C)
120 105
95
100 84
71.5 73
80
60
40
20
0
0 0.5 1 1.5 2 2.5 3 3.5
Concentratioin (M)
Stopping mechanism:
In stopping mechanism, we use the reaction between magnesium and sulfuric acid with the
reaction below;
Mg(s) + H2SO4(aq) → MgSO4(aq) + H2(g)
Mg plate, which has length 7 cm, being dipped to H2SO4 0,5 M liquid. Mg will react with
H2SO4, thus Mg gradually runs out. One of the Mg plateis connected to the dynamo’s cable
and the other connected to TEG’s cable. Therefore, if Mg reacted out with H2SO4 and
gradually runs out, the circuit would be disconnected and the car stopped automatically.
Here is the graphic about our stopping mechanism controlling;
Stopping Mechanism
H2SO4(l) + Mg(s)  MgSO4 (aq) + H2(g)
700 615
600
500
Times (s)
400
300
200
68 5352 50
100 25
0
0 0.2 0.4 0.6 0.8 1 1.2
Concentration (M)

CHERNIVAL 2018
4
Based on the graphic above, the longest time which has been spend to react Mg plate with
H2SO4 until Mg gradually runs out is surely 68 seconds. So, we decide to use H2SO4 0.5 M
for stopping mechanism.
Hazards inherent in design:

There is no hazard inherent in design of the car. We use safety components in designing
the car. For the body of the car, we use acrylic which is heat resistant. For the front tires,
we use acrylic that coated with rubber so the car can’t be sliding by itself due to slick
acrylic. For the rear tires, we use plastic tires. The reactor box of the car is made by a
plastic lunch box that heat and cold resistant. It is tightly closed so the gas, product of the
reaction, wouldn’t be out. Moreover, we use glass wool as an isolator to make a borderline
between hot and cold temperatures. For the cable, we isolate it with adhesive tape, in order
to no electric sparks occur.
Safety measures:
To protect our body from the hazard of the substances, we use PPE (Personal Protective
Equipment).
Power source which contains potassium permanganate, glycerin, and dry ice has their each
handling. For potassium permanganate which has hazards in skin contact (irritant), eye
contact (irritant), ingestion and inhalation so we have to wear lab-coat, safety glasses, long
pants and sleeves, also mask. For glycerin which has possibility to be combustible at high
temperature, so we need a fire extinguisher in every experiment. Beside that, dry ice has a
temperature under 0 celcius degree, to avoid the effect we have to wear a chemical gloves
to protect the hand.
For the stopping mechanism we use sulfuric acid which is very hazardous in case of skin
contact (corrosive, irritant, permeator), eye contact (irritant, corrosive), ingestion, and
inhalation so we have to wear gloves, full suit, and mask.
Expected Operating Conditions:
Temperature Pressure
Maximum: 121oC Maximum : -
Minimum : -78oC Minimum : -
MAWP Design: MAWP Design: -
Personal Protective Equipment (PPE) : Check all PPE worn

during operation of this ChemE-Car. Do not list these in the
procedure section

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5
Long Pants Safety Hard Hat Lab-Coat
Glasses
Long Sleeves Splash Insulated Ear

Goggles Gloves Protection
Non-Porous Face Shield Chemical Other:

Shoes Gloves Mask
This page applies to your home institution – not the

competition site. Please attach a floor diagram of the
laboratory where you will be building and testing your vehicle.
List the location of available safety equipment and spill
response supplies on this diagram.
Available Safety Equipment – Provide the location of each item

shown below at your home institution where your vehicle will
be operated and tested. Show the location of this equipment on
your provided floor plan. If not available, type “NA” in the
field.

CHERNIVAL 2018
6
Item Location
Fire Extinguisher: Near the exit door and beside the spill containment
Eyewash: In the middle of sink and oxygen tank
Safety Shower: Beside the sink
Telephone: In the next room above the assistant laboratory’s desk
First Aid Kit: Hanging near the assistant laboratory’s room
Spill Beside fire extinguisher

Containment:
Other: NA
Spill Response Supplies - Provide the location of each item

shown below at your home institution where your vehicle will
be operated and tested. Show the location of this equipment on
the attached floor plan. If not available, type “NA” in the field.
Item Location
Spill Kit: Beside fire extinguisher
Floor-Dri: Near the rack of chemical tool
Sodium inside of the chemical showcase

Bicarbonate:
Drain Plugs: NA
Spill Pillows: Inside of the spill-kit box
Mercury Spill Kit: NA
Other: NA

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7
Fabrication & Operation Additional Hazard Detail Check List: Check all hazards that are likely to
be encountered during your Chem.-Car construction and operation. List the major source(s) of the
hazard and describe how the hazard(s) will be controlled. If both construction and hazard columns
are checked in an individual row, then the hazards should be identified separately for both the
construction and operation
Hazard Present During Control Method(s)1 PPE Required1
Construction Operation
Pressure NA NA
Toxicity To not inhale the substances directly We have to wear a mask and
make the design of the car tightly
closed
Flammability NA NA
Reactivity / NA NA
Instability
Hot Surfaces/ For not touching the body of the car It is important to coat the reactor
while the chemical reactions occur with glass wool as an isolator. We
High need also a chemical glove to
protect our hand.
Temp > 150 0F

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8
Cold Surfaces/ To not touch the dry ice directly We have to wear a chemical
without a chemical glove glove to protect our hand
Low
Temp < 0 0C
Electrical Every cable need to be coated with an We need to wear the insulated
adhesive tape gloves when handling the cable.
Arc welding NA NA
Gas welding NA NA
Lathe NA NA
Milling machine NA NA
Handheld Power tools which we need consist of PPE that we must wear are a long
a disc cutter or concrete saw to cut off sleeves and pants, a glove, and a
power tools the dry ice and we need a multi tool safety shoes to avoid the accident
for an important things. While using if the tools are falling down.
the tools above we have to be careful
in order to the accident may not
happen.
Drill press We need to be careful while using the A long sleeves, pants, and glove
drill. The hand-controlling must be are needed
stabilized.

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9
Other NA NA
mechanical
hazards
Paint spraying NA NA
Ionizing NA NA
radiation
Laser radiation NA NA
Asphyxiates NA NA
Open flames NA NA
Potential Spills Reactor is placed in a tightly closed To avoid the product of reactions
box, so the effect of the reaction flaring up or falling down, we
wouldn’t be out need a mask, chemical gloves,
and spill kit box.
Biohazards NA NA
Other NA NA

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10
Disallowed Activities: All activities listed below are not allowed.
Item
(a) No transport of chemicals in private, university or rental vehicles either
to or from the competition.
(b) Chemicals must not be stored in hotel rooms or other facilities not rated
for chemical storage. Approved chemical storage will be provided at the
host site.
(c) No vehicle testing in hotel or dorm hallways, warehouses, or other
facilities that are not designed for chemical handling. This includes your
university and the competition site.
(d) No improper disposal of chemicals at the conclusion of the competition.
All chemicals shipped to the competition site must be disposed of in a
safe and environmental fashion following all local, state and national
regulatory measures. Chemical disposal will normally be provided by the
host site.
Disallowed Vehicles: All of the items listed below are not allowed.
Item Explanation
(a) Flames and/or Both inside and outside the vehicle, except for
smoke commercial internal combustion engines. See Chem-
E-Car Rules for using commercial internal combustion
engines.
(b) Liquid Liquid may not be discharged under normal operating
Discharge conditions.
(c) Open and/or Containing chemicals having an NFPA rating of 2 or
improperlysecure greater.
d containers
No open containers allowed at the starting line or
during the operation of your vehicle. All containers
with these chemicals must have secure lids and must
be secured to the vehicle. All containers brought to
the starting line must have lids, be properly labeled,
and proper personal protective equipment must be

CHERNIVAL 2018
11
used.
(d) Chemical Any chemicals with an NFPA rating of 2 or greater.

pouring at Use a holding vessel on vehicle, with valve, to load
starting line starting chemicals.
(e) Regulated A number of chemicals are listed by OSHA as a special

Chemicals hazard. See list below. OSHA has a special regulation
for each chemical. See www.osha.gov for details.
(f) Highly Reactive Any chemical, raw material, intermediate or product

/ Unstable with an NFPA reactivity / instability rating of 4.
Chemicals
(g) Hydrogen Hydrogen peroxide at concentrations of greater than

peroxide 30% are not allowed.
Regulated chemicals:
Vehicle Primary Hazards Checklist: Check the left hand column box if the
hazards listed below exist on the vehicle. Then
check the applicable means of control for each
hazard.
Hazard
(check if Control
present)
(a) Pressure Anything greater than 1 psig? Must meet all requirements
below:
Pressure gauge (must read to 2x max. operating
pressure)
Emergency relief device set to no more than 1.1 times
max operating pressure. Relief sizing calculations must

CHERNIVAL 2018
12
be provided.
Emergency relief device in proper location.
Pressure certification – see Pressure Vessel Testing
Protocol
Proper management system to prevent over or mis-
charging.
All car components exposed to pressure must be
certified to operate at that pressure. Provide
manufacturer’s pressure specifications.
NoPVC, cPVC or polyethylene terephthalate (PETE or
PET) plastics in pressure service
Must have measurements or calculations to prove
maximum operating pressure.
See Chem-E-Car Rules for more details on these
requirements.
(b) Toxic Any chemicals with an NFPA toxicity of 2 or greater?

Doubly contained and handled properly.
(c) Any chemicals with an NFPA flammability rating of 2 or

Flammable higher?
Doubly contained and handled properly
(d) Reactive Any chemicals with an NFPA instability / reactivity rating

of 2 or 3?
Chemicals with a 4 rating are not allowed.
Doubly contained and handled properly.
(e) Any exposed surface greater than 150 deg. F or under

Temperature 32°F?
Insulation or barrier to prevent contact.

CHERNIVAL 2018
13
(f) Electrical Exposed wiring and electrically energized components are
ignition, electrocution, and a shorting / fire hazard.
Alligator clips and twisted wire connections are not
allowed – use binding posts or banana plugs for a more
secure connection.
Proper electrical insulation and connections provided.
(g) Any fast moving parts (meshing gears, belts or chains)

Mechanical that are pinch hazards?
Guards present and adequate.
(h) Oxygen All components exposed to oxygen must be

Certified for oxygen service.
Thoroughly cleaned of contaminants as per instructions
in rules.
Not used previously for other types of service.
(i) No biohazards greater than biohazard level 1 either

Biohazards during the design, development, preparation or
competition phases of your car.
Chemical Information Page

Fill in as much data below as available. If data are not available, leave the
field blank.
Chemical Quantities: List below the chemical names, concentrations, and
total quantity of chemical required for the competition

CHERNIVAL 2018
14
Total
Quantity
Chemical Concentration Required
State Required for
Competition
Chemical Name Solid, Liquid, Be sure to list the
Gas units! Be sure to
list the
units!
KMnO4 (Potassium Solid 23,7 gram 100 gram

Permanganate)
Glycerin Liquid 50 ml 150 ml
Aquadest Liquid 150 ml 500 ml
Mg plate Solid 7 cm 1m
H2SO4 (Sulfuric Acid) Liquid 0,05 M 100 ml
Dry Ice Solid 150 gram 2 kg
Chemical Properties and Hazards for ALL CHEMICALS, including reactants,

intermediates and products.
Incompatib
le Flammability
NFPA Limits
Chemic Physical Chemicals Flash
Ratings*
al State Point
List
Name S, L, G Temp.
chemicals
H F S Sp. LFL UFL
present
within the

CHERNIVAL 2018
15
laboratory,
and any
others that
may come
in contact.
KMnO4 S 1 0 0 OX organic Not Not Not
materials, applicable applicable applicable
metals, acids.
Glycerin L 1 0 0 Not oxidizing CLOSED Not Not
availabl agents. CUP: 97°C available. available.
e
(206.6°F).
Aquadest L 0 0 0 A Not available. Not Not Not
applicable. applicable applicable.
.
Mg plate S 0 1 1 Not oxidizing Not Not Not
availabl agents, acids, available available available
e
moisture
H2SO4 L 3 0 2 W oxidizing Not Not Not
agents, reducing applicable applicable applicable
agents,
combustible
materials,
organic
materials,
metals, acids,
alkalis, moisture
Dry Ice S 3 0 0 SA No reaction with Not Not Not
any common applicable applicable applicable
materials in dry
or wet
conditions
K2CO3 S 2 0 0 E Reactive with Not Not Not
oxidizing applicable applicable applicable
agents, metals,
acids. Slightly
reactive to
reactive with
moisture.
CO2 G 2 0 0 SA Alkali metals, No data Non- Non-
Alkaline earth available flammabl flammable
metals, e gas gas
Acetylide

CHERNIVAL 2018
16
forming metals,
Chromium,
Titanium >
1022°F
(550°C),
Uranium (U) >
1382°F (750°C),
Magnesium >
1427°F (775°C).
H2 G 0 4 0 - Oxidizing Not 4.0% 75.0%
agents, lithium, available
halogens
MgSO4 S 1 0 0 E Not available Not Not Not
applicable applicable applicable
*
NFPA Ratings: H – Health, F – Flammability, S – Stability, Sp. – Special
Chemical Toxicology, Regulation and Disposal: List the same chemicals that
appear above, in the same order.
Toxicology
Hazardous OSHA Personal

Protective
Chemical Oth Waste Regulated
TWA PEL Equipment
Name er Number
Specific to
this Chemical
KMnO4 5 Consult 5mg/m3 Not Risks of OSHA: Splash goggles.
local availa explosion of Hazardous by Synthetic apron.
authorities ble the product in definition of Vapor and dust
for presence of Hazard respirator. Be sure
acceptable mechanical Communication to use an
exposure impact: Not Standard (29 approved/certified
limits available. CFR respirator or
Risks of 1910.1200). equivalent. Gloves.
explosion of
the product in
presence of
static
discharge: Not
available.
Explosive in

CHERNIVAL 2018
17
presence of
organic
materials, of
metals.
Gliserol Not Not Not Hazardous in Not available Splash goggles.
available available availa case of skin Lab coat. Vapor
ble contact respirator. Be sure
(irritant), of to use an
eye contact approved/certified
(irritant), of respirator or
ingestion, of equivalent. Gloves.
inhalation
Aquades Not Not Not Non-hazardous Not available Safety glasses. Lab
available available availa coat
ble
Pita Mg Not Not Not Slightly Hazardous by Safety glasses. Lab
available available availa hazardous in definition of coat. Dust
ble case of skin Hazard respirator. Be sure
contact Communication to use an
(irritant), of Standard (29 approved/certified
eye contact CFR 1910.1200) respirator or
(irritant), of equivalent.
ingestion, of
Gloves.
inhalation
H2SO4 TWA: 1 STEL: 3 Not Extremely TWA: 1 STEL: Face shield. Full
(mg/m3) availa hazardous in 3 (mg/m3) suit. Vapor
ble case of [Australia] respirator. Be sure
inhalation Inhalation to use an
(lung TWA: 1 approved/certified
corrosive). (mg/m3) respirator or
Very equivalent. Gloves.
hazardous in Boots.
case of skin
contact
(corrosive,
irritant,
permeator), of
eye contact
(corrosive), of
ingestion,
Dry Ice CO2 5,000 ppm 15,000 ppm Not HAZARDOUS OSHA PEL Safety glasses,
9,150 27,400 availa COMBUSTIO (United States, Wear cold
ble N 6/2016). insulating gloves,
mg/m3 mg/m3
PRODUCTS: Wear apron or
TWA: 9000
Not applicable. protective clothing

CHERNIVAL 2018
18
Thermal mg/m³ 8 hours. in case of contact,
decomposition Wear safety shoes
TWA: 5000
releases carbon while handling
ppm 8 hours
containers
monoxide and
oxygen.
K2CO3 Not Not Not Hazardous in OSHA: Splash goggles.
available available availa case of skin Hazardous by Lab coat. Dust
ble contact definition of respirator. Be sure
(irritant), of Hazard to use an
eye contact Communication approved/certified
(irritant), of Standard (29 respirator or
ingestion, of CFR equivalent. Gloves.
inhalation. 1910.1200).
Slightly
hazardous in
case of eye
contact
(corrosive).
CO2 9000 5000 ppm Non Electrical OSHA-H01 - Self-contained
mg/m³ availa discharges and MAY breathing apparatus
ble high DISPLACE should always be
temperatures OXYGEN AND worn when
decompose CAUSE RAPID
entering area where
carbon dioxide SUFFOCATIO
oxygen depletion
into carbon N
may have occurred.
monoxide and
Safety
oxygen. The
goggles, gloves and
welding
shoes, or boots,
process may
should be worn
generate
when handling
hazardous
fumes and cylinders.
gases.
H2 Simple Not Not Flammable This material is
work gloves Select
asphyxiant Established availa considered in accordance with
high-pressure
ble hazardous byOSHA 29 CFR
gas. Use only
the OSHA 1910.132 and
in a closed
Hazard 1910.133, Eye/Face
system. Use
Protection. Select
piping and Communication
in accordance with
equipment s Standard (29
OSHA 29 CFR
adequately CFR 1910.1200)
1910.133,
designed to Respiratory
withstand protection must
pressures and conform to OSHA
temperatures to rules as specified in

CHERNIVAL 2018
19
be 29
encountered.
CFR 1910.134.
Use a backflow
Select per OSHA
prevention 29 CFR 1910.134
device in the and ANSI Z88.2.
piping. Gas can
cause rapid
suffocation due
to oxygen
deficiency.
MgSO4 Not Not Not Hazardous in Not available Safety glasses. Lab
available available availa case of coat. Dust
ble ingestion. respirator. Be sure
Slightly to use an
hazardous in approved/certified
case of skin respirator or
contact equivalent.
(irritant), of
Gloves
inhalation.
Chemical Reactions:
In our car, there are two reactions occurred. They are in power source and stopping
mechanism.
The chemical reaction between potassium permanganate and glycerin in power source is:
14 KMnO4 (s) + 4 C3H5(OH)3 (l) + H2O (l) → 7 K2CO3 (s) + 5 CO2(g) + 16 H2O(g)
The chemical reaction between magnesium and sulfuric acid in stopping mechanism is:
Mg(s) + H2SO4(aq) → MgSO4(aq) + H2(g)
Biohazards: Provide details below on any biological hazards that may occur
during the design, development, preparation or competition
phases of your car. Please list the biological hazards, the
biohazard level, and a description of how these agents will be
safety handled.

CHERNIVAL 2018
20
There is no biohazard in our car because we don’t use any biological things in the reaction even in the
mechanical design.
Job Safety Assessment Form

Safe Operating Procedures Page
Provide step-by-step details for each of the sections shown below. Identify
the hazards, the control methods and the personal protective equipment
(PPE) required. Provide adequate detail so that the reviewers of this
document will have adequate understanding of your procedure to pass
judgment on the safety of your vehicle.
 The Emergency Shutdown section should have only one or two steps
required to stop your vehicle and bring it to a safe state.
 The Start-Up Procedure section should list all the steps required to
prepare your chemicals and vehicle.
 The Run Time Procedure should describe all steps to operate your vehicle
at the starting line of the competition.
 The Shutdown Procedure should describe the steps normally taken to

shut down your vehicle at the end of your competitive run.
 The Cleanup / Waste Disposal section should list all the steps required to
clean your vehicle of all chemicals and proper chemical disposal.
PPE or
Sequence of Steps Potential Procedure to Control Equipment
Hazards Hazard Required
The emergency shutdown section If KMnO4 + Use complete PPE and use a Mask, Splash
(We handle it manually with a wet glycerol solution wet cloth while handle it. goggles, gloves,
cloth and use complete PPE in spill on the floor lab coat, non-
circuit area). and exposed to porous shoes, and
skin, it can make a wet cloth.
irritant to skin.
The smoke that
caused by this

CHERNIVAL 2018
21
reaction can
infect the
respiratory.
The Start-Up Procedure section (We KMnO4 + To control fog , we use the Mask, Splash
set the power source TEG Thermal Glyserol will closed box with the open closed goggles, gloves,
Electric Generator with the hot place cause fog. Dry door to inject the glycerol for lab coat, non-
is on the top, and cool place is on the Ice is very cool if react with KMnO4 and for dry porous shoes,
bottom. we hold it, it can ice we use gloves. closed box.
We use KMnO4 + glycerol for the penetrate the
hot reaction and dry ice for the cool skin. For the
reaction. Put it in the closed box. Put stopping , Mg +
the stopping mechanism behind this H2SO4 can cause
box. an explosive,
because it
products
Hydrogen gas.
The Run Time Procedure (Inject the The circuit if not Be careful while designing the Gloves, safety
glycerol to react with KMnO4 at the connected well, it circuit. Wrap the cable with the goggle, mask, lab
closed box, react the Mg with H2SO4 will cause electric scotch tape. coat, non- porous
at the other box, set the cable from short circuit. shoes, scotch tape.
TEG, one contact with the dynamo
and the other contact the stopping
mechanism. Then, the other stopping
mechanisms cable contact the
dynamo).
The Shutdown Procedure (We use This reaction We use the low concentration Lab coat, safety
reaction between Mg and H2SO4. We cause a smoke of Sulfuric acid and we set the goggles, mask,
set Mg plat to make U shape. that danger the open-closed box for the reactor. gloves, non-
Connect the U shape to the cable that skin and porous shoes,
connected to dynamo and TEG. If hazardous in case open-closed box.
Mg finish to react with the H2SO4, of inhalation.
the circuit will stop, so the car will
stop).
The Cleanup / Waste Disposal This cleanup can Be careful while pouring the Lab coat, safety
section (Dilute the concentration of cause spill on the chemical waste to the garbage, goggles, mask,
the H2SO4+ Mg with water, and floor and make an use the lab coat, and PPE well. gloves, non-
dilute the hot reaction, that is irritation on skin porous shoes,
KMnO4 + glycerol with water. Pour if exposed garbage.
the chemical waste to the chemical directly.
garbage that provided in the
competition place, wash both the box
of stopping mechanism and TEGs
reaction).

CHERNIVAL 2018
22
Notes:
Please insert supplement documents such as:
- Arduino and electrical circuit
- Specific design vessel tank or pressurize tank
- Specific design reactor (if you do not use vessel tank or pressurerize
tank, please sketch the reactor design)
- Specific design safety valve
- MSDS
- Others
without any straight format and just insert them all in the folowing page
after this.

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Electrical Circuit
TEG Thermal
Heat Box Electric
Generator
TEG (Thermal
Electric Generator)
Cold Box
Safety Box
Reactor

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24
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 02/04/2014 Version: 1.0
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Substance
Substance name : Potassium Permanganate
CAS No : 7722-64-7
Product code : LC19850
Formula : KMnO4
Synonyms : permanganate of potash / potassium salt permanganic acid
BIG no : 10297
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Oxidant
Bleaching agent
Reagent
Disinfectant
Deodorizer
Algicide
Dyestuff/pigment: component
Medicine
Laboratory chemical
Food industry: additive
Insecticide
Germicide
1.3. Details of the supplier of the safety data sheet
LabChem Inc
Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court
Zelienople, PA 16063 - USA
T 412-826-5230 - F 724-473-0647
info@labchem.com - www.labchem.com
1.4. Emergency telephone number
Emergency number : CHEMTREC: 1-800-424-9300 or 011-703-527-3887

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SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
GHS-US classification
Ox. Sol. 2 H272
Acute Tox. 4 (Oral) H302
Aquatic Acute 1 H400
Aquatic Chronic 1 H410
2.2. Label elements
GHS-US labelling
Hazard pictograms (GHS-US) :
GHS03 GHS07 GHS09
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H272 - May intensify fire; oxidiser
H302 - Harmful if swallowed
H410 - Very toxic to aquatic life with long lasting effects

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Precautionary statements (GHS-US) : P210 - Keep away from heat, sparks, open flames, hot surfaces. - No smoking
P220 - Keep/Store away from clothing, combustible materials
P221 - Take any precaution to avoid mixing with combustibles
P264 - Wash exposed skin thoroughly after handling
P270 - Do not eat, drink or smoke when using this product

P273 - Avoid release to the environment
02/04/2014 EN (English) Page 1

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Safety Data Sheet
P280 - Wear protective gloves, protective clothing, eye protection, face protection
P301+P312 - IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell
P330 - If swallowed, rinse mouth
P391 - Collect spillage
P501 - Dispose of contents/container to comply with local, state and federal regulations
2.3. Other hazards
Other hazards not contributing to the : None under normal conditions.

classification
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3: Composition/information on ingredients
3.1. Substance
Substance type : Mono-constituent
Name Product identifier % GHS-US classification
Potassium Permanganate (CAS No) 7722-64-7 100 Ox. Sol. 2, H272
(Main constituent) Acute Tox. 4 (Oral), H302
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
Full text of H-phrases: see section 16
3.2. Mixture
Not applicable
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory

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arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with
laboured breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting:
prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up).
Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain.
Depending on the victim's condition: doctor/hospital.
First-aid measures after inhalation : Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.
First-aid measures after skin contact : Wash immediately with lots of water (15 minutes)/shower. Do not apply (chemical) neutralizing
agents. Remove clothing while washing. Do not remove clothing if it sticks to the skin. Cover
wounds with sterile bandage. Consult a doctor/medical service. If burned surface > 10%: take
victim to hospital.
First-aid measures after eye contact : Rinse immediately with plenty of water for 15 minutes. Do not apply neutralizing agents. Take
victim to an ophthalmologist.
First-aid measures after ingestion : Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce
vomiting. Immediately consult a doctor/medical service. Call Poison Information Centre
(www.big.be/antigif.htm). Take the container/vomit to the doctor/hospital. Ingestion of large
quantities: immediately to hospital.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : AFTER INHALATION OF DUST: Dry/sore throat. Coughing. Irritation of the respiratory tract.
Irritation of the nasal mucous membranes. EXPOSURE TO HIGH CONCENTRATIONS:
Respiratory difficulties. FOLLOWING SYMPTOMS MAY APPEAR LATER: Risk of lung oedema.
Symptoms/injuries after skin contact : Tingling/irritation of the skin. May stain the skin. ON CONTINUOUS EXPOSURE/CONTACT:
Caustic burns/corrosion of the skin.
Symptoms/injuries after eye contact : Corrosion of the eye tissue. Inflammation/damage of the eye tissue. ON CONTINUOUS
EXPOSURE/CONTACT: Permanent eye damage.
Symptoms/injuries after ingestion : Nausea. Vomiting. Diarrhoea. Irritation of the gastric/intestinal mucosa. AFTER ABSORPTION
OF HIGH QUANTITIES: Possible esophageal perforation. Shock. Slowing heart action. Low
arterial pressure. Possible laryngeal spasm/oedema. Respiratory difficulties.
Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Respiratory difficulties. Impairment of
the nervous system. Movement disturbances. Coordination disorders. Myasthenia. Tremor.
Paralysis. Cramps/uncontrolled muscular contractions. Impaired memory. Emotional instability.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available
02/04/2014 EN (English) 2/9

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Safety Data Sheet
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : EXTINGUISHING MEDIA FOR SURROUNDING FIRES: All extinguishing media allowed.
Preferably: quantities of water.
Unsuitable extinguishing media : No unsuitable extinguishing media known.
5.2. Special hazards arising from the substance or mixture
Fire hazard : DIRECT FIRE HAZARD. Non combustible. INDIRECT FIRE HAZARD. Promotes combustion.
Reactions involving a fire hazard: see "Reactivity Hazard".
Explosion hazard : INDIRECT EXPLOSION HAZARD. Reactions with explosion hazards: see "Reactivity Hazard".
Reactivity : Decomposes on exposure to temperature rise: oxidation which increases fire hazard. Reacts
with combustible materials: risk of spontaneous ignition. Violent to explosive reaction with (some)
acids: release of toxic and corrosive gases/vapours. Reacts violently with many compounds e.g.:
with organic material and with (strong) reducers. With (some) metals. With (increased) risk of
fire/explosion.
5.3. Advice for firefighters
Precautionary measures fire : Exposure to fire/heat: keep upwind. Exposure to fire/heat: consider evacuation.
Firefighting instructions : Cool tanks/drums with water spray/remove them into safety. Do not move the load if exposed to
heat. Take account of environmentally hazardous firefighting water. Use water moderately and if
possible collect or contain it.
Protection during firefighting : Heat/fire exposure: compressed air/oxygen apparatus.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Face-shield. Protective clothing. Dust cloud production: compressed air/oxygen
apparatus. Dust cloud production: dust-tight suit. Reactivity hazard: compressed air/oxygen
apparatus. Reactivity hazard: gas-tight suit.
Emergency procedures : Mark the danger area. Prevent dust cloud formation. No naked flames. Keep containers closed.
Wash contaminated clothes. In case of hazardous reactions: keep upwind. In case of reactivity

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hazard: consider evacuation.
Measures in case of dust release : In case of dust production: keep upwind. Dust production: have neighbourhood close doors and
windows.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection. Do not breathe dust.
Emergency procedures : If a major spill occurs, all personnel should be immediately evacuated and the area ventilated.
Stop release. Ventilate area.
6.2. Environmental precautions
Prevent soil and water pollution. Prevent spreading in sewers.
6.3. Methods and material for containment and cleaning up
For containment : Contain released substance, pump into suitable containers. Consult "Material-handling" to select
material of containers. Plug the leak, cut off the supply. Dam up the solid spill. Knock down/dilute
dust cloud with water spray. If reacting: dilute toxic gas/vapour with water spray. Take account of
toxic/corrosive precipitation water.
Methods for cleaning up : Stop dust cloud by covering with sand/earth. Scoop solid spill into closing containers. Carefully
collect the spill/leftovers. Spill must not return in its original container. See "Material-handling" for
suitable container materials. Clean contaminated surfaces with an excess of water. Wash
clothing and equipment after handling.
6.4. Reference to other sections
SECTION 7: Handling and

storage
7.1. Precautions for safe handling
Precautions for safe handling : Comply with the legal requirements. Remove contaminated clothing immediately. Clean
contaminated clothing. Keep the substance free from contamination. Use corrosionproof
equipment. Thoroughly clean/dry the installation before use. Do not discharge the waste into the
drain. Avoid raising dust. Keep away from naked flames/heat. Observe very strict hygiene - avoid
contact. Keep container tightly closed. Measure the concentration in the air regularly. Carry
operations in the open/under local exhaust/ventilation or with respiratory protection.
02/04/2014 EN (English) 3/9

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Safety Data Sheet
7.2. Conditions for safe storage, including any incompatibilities
Heat and ignition sources : KEEP SUBSTANCE AWAY FROM: heat sources.
Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: combustible materials. reducing agents. (strong) acids.
metal powders. cellulosic materials. organic materials. alcohols. peroxides.
Storage area : Store at ambient temperature. Keep out of direct sunlight. Store in a dry area. Fireproof
storeroom. Unauthorized persons are not admitted. Keep only in the original container. Store
only in a limited quantity. Meet the legal requirements.
Special rules on packaging : SPECIAL REQUIREMENTS: closing. clean. correctly labelled. meet the legal requirements.
Secure fragile packagings in solid containers.
Packaging materials : SUITABLE MATERIAL: steel. aluminium. glass. stoneware/porcelain. MATERIAL TO AVOID:
wood. cellusosic material.
7.3. Specific end use(s)
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Potassium Permanganate (7722-64-7)
USA ACGIH ACGIH TWA (mg/m³) 0.1 mg/m³
USA OSHA OSHA PEL (Ceiling) (mg/m³) 5 mg/m³ as Mn
8.2. Exposure controls
Appropriate engineering controls : Emergency eye wash fountains and safety showers should be available in the immediate vicinity
of any potential exposure. Ensure adequate ventilation.
Materials for protective clothing : GIVE EXCELLENT RESISTANCE: polyethylene. GIVE GOOD RESISTANCE: butyl rubber.
PVC. polyethylene/ethylenevinylalcohol.
Hand protection : Gloves.
Eye protection : Face shield. In case of dust production: protective goggles.
Skin and body protection : Protective clothing. In case of dust production: head/neck protection. In case of dust production:
dustproof clothing.

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Respiratory protection : Dust production: dust mask with filter type P3. High dust production: self-contained breathing
apparatus.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Solid
Appearance : Crystalline solid. Crystalline powder.
Molecular mass : 158.03 g/mol
Colour : Dark violet-brown.
Odour : Odourless.
Odour threshold : No data available
pH : 7.0 - 8.5 (1.6 %)
pH solution : 1.6 %
Relative evaporation rate (butylacetate=1) : No data available
Melting point : > 240 °C
Freezing point : No data available
Boiling point : Not applicable
Flash point : Not applicable
Self ignition temperature : Not applicable
Decomposition temperature : > 240 °C
Flammability (solid, gas) : No data available
Vapour pressure : < 0.10 hPa
Relative vapour density at 20 °C : No data available
Relative density : 2.7
Density : 2700 kg/m³
02/04/2014 EN (English) 4/9

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Safety Data Sheet
Solubility : Moderately soluble in water. Substance sinks in water. Soluble in ethanol. Soluble in methanol.
Soluble in acetone. Soluble in acetic acid. Soluble in sulfuric acid. Soluble in pyridine.
Water: 6.4 g/100ml
Log Pow : -1.73 (Estimated value)
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : May intensify fire; oxidiser.
Explosive limits : No data available
9.2. Other information
Minimum ignition energy : Not applicable
SADT : Not applicable
VOC content : Not applicable
Other properties : Opaque. Substance has basic reaction.
SECTION 10: Stability and reactivity
10.1. Reactivity
Decomposes on exposure to temperature rise: oxidation which increases fire hazard. Reacts with combustible materials: risk of spontaneous ignition.
Violent to explosive reaction with (some) acids: release of toxic and corrosive gases/vapours. Reacts violently with many compounds e.g.: with organic
material and with (strong) reducers. With (some) metals. With (increased) risk of fire/explosion.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
Reacts exothermically with combustible materials: (increased) risk of fire.
10.4. Conditions to avoid

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Incompatible materials.
10.5. Incompatible materials
Strong reducing agents. Organic compounds. combustible materials. metals.
10.6. Hazardous decomposition products
manganese.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Harmful if swallowed.
Potassium Permanganate ( \f )7722-64-7
LD50 oral rat 1090 mg/kg (Rat)
Skin corrosion/irritation : Not classified
pH: 7.0 - 8.5 (1.6 %)
Serious eye damage/irritation : Not classified
pH: 7.0 - 8.5 (1.6 %)
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated : Not classified
exposure)
Aspiration hazard : Not classified
02/04/2014 EN (English) 5/9

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Safety Data Sheet
Symptoms/injuries after inhalation : AFTER INHALATION OF DUST: Dry/sore throat. Coughing. Irritation of the respiratory tract.
Irritation of the nasal mucous membranes. EXPOSURE TO HIGH CONCENTRATIONS:
Respiratory difficulties. FOLLOWING SYMPTOMS MAY APPEAR LATER: Risk of lung oedema.
Symptoms/injuries after skin contact : Tingling/irritation of the skin. May stain the skin. ON CONTINUOUS EXPOSURE/CONTACT:
Caustic burns/corrosion of the skin.
Symptoms/injuries after eye contact : Corrosion of the eye tissue. Inflammation/damage of the eye tissue. ON CONTINUOUS
EXPOSURE/CONTACT: Permanent eye damage.
Symptoms/injuries after ingestion : Nausea. Vomiting. Diarrhoea. Irritation of the gastric/intestinal mucosa. AFTER ABSORPTION
OF HIGH QUANTITIES: Possible esophageal perforation. Shock. Slowing heart action. Low
arterial pressure. Possible laryngeal spasm/oedema. Respiratory difficulties.
Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Respiratory difficulties. Impairment of

the nervous system. Movement disturbances. Coordination disorders. Myasthenia. Tremor.
Paralysis. Cramps/uncontrolled muscular contractions. Impaired memory. Emotional instability.
Likely routes of exposure : Skin and eye contact;Inhalation
SECTION 12: Ecological information
12.1. Toxicity
Ecology - general : Dangerous for the environment.
Ecology - air : TA-Luft Klasse 5.2.2/III.
Ecology - water : Severe water pollutant (surface water). Ground water pollutant. Toxic to fishes. Very toxic to
invertebrates (Daphnia).
LC50 fishes 1 0.261 mg/l (96 h; Ictalurus punctatus)
EC50 Daphnia 1 0.235 mg/l (24 h; Daphnia magna)
LC50 fish 2 1.22 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss)
EC50 Daphnia 2 0.5 mg/l (96 h; Crustacea)
TLM fish 1 5.4 ppm (48 h; Lepomis macrochirus)
Threshold limit other aquatic organisms 1 > 0.64 mg/l (Plankton)
Threshold limit algae 1 10 mg/l (4 h; Chlorella sp.)

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12.2. Persistence and degradability
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
BOD (% of ThOD) Not applicable
12.3. Bioaccumulative potential
Log Pow -1.73 (Estimated value)
Bioaccumulative potential Bioaccumulation: not applicable.
12.4. Mobility in soil
12.5. Other adverse effects
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste disposal recommendations : Remove waste in accordance with local and/or national regulations. Hazardous waste shall not
be mixed together with other waste. Different types of hazardous waste shall not be mixed
together if this may entail a risk of pollution or create problems for the further management of the
waste. Hazardous waste shall be managed responsibly. All entities that store, transport or handle
hazardous waste shall take the necessary measures to prevent risks of pollution or damage to
people or animals. Recycle/reuse. Immobilize the toxic or harmful components. Remove to an
authorized dump (Class I).
Additional information : LWCA (the Netherlands): KGA category 06. Hazardous waste according to Directive
2008/98/EC.
02/04/2014 EN (English) 6/9

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Safety Data Sheet
SECTION 14: Transport information
In accordance with DOT
Transport document description : UN1490 Potassium permanganate, 5.1, II
UN-No.(DOT) : 1490
DOT NA no. : UN1490
DOT Proper Shipping Name : Potassium permanganate
Department of Transportation (DOT) Hazard : 5.1 - Class 5.1 - Oxidizer 49 CFR 173.128
Classes
Hazard labels (DOT) : 5.1 - Oxidiser
Packing group (DOT) : II - Medium Danger
DOT Special Provisions (49 CFR 172.102) : IB8 - Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics
(11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1
and 31HZ2); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3,
13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2).
IP2 - When IBCs other than metal or rigid plastics IBCs are used, they must be offered for
transportation in a closed freight container or a closed transport vehicle.
IP4 - Flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with
a sift-proof and water-resistant liner.
T3 - 2.65 178.274(d)(2) Normal............. 178.275(d)(2)
TP33 - The portable tank instruction assigned for this substance applies for granular and
powdered solids and for solids which are filled and discharged at temperatures above their
melting point which are cooled and transported as a solid mass. Solid substances transported or
offered for transport above their melting point are authorized for transportation in portable tanks
conforming to the provisions of portable tank instruction T4 for solid substances of packing group
III or T7 for solid substances of packing group II, unless a tank with more stringent requirements
for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or
bottom outlets are assigned in which case the more stringent tank instruction and special

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provisions shall apply. Filling limits must be in accordance with portable tank special provision
TP3. Solids meeting the definition of an elevated temperature material must be transported in
accordance with the applicable requirements of this subchapter.
DOT Packaging Exceptions (49 CFR 173.xxx) : 152
DOT Packaging Non Bulk (49 CFR 173.xxx) : 212
DOT Packaging Bulk (49 CFR 173.xxx) : 240
DOT Quantity Limitations Passenger aircraft/rail : 5 kg
(49 CFR 173.27)
DOT Quantity Limitations Cargo aircraft only (49 : 25 kg
CFR 175.75)
DOT Vessel Stowage Location : D - The material must be stowed ‘‘on deck only’’ on a cargo vessel and on a passenger vessel
carrying a number of passengers limited to not more than the larger of 25 passengers or one
passenger per each 3 m of overall vessel length, but the material is prohibited on passenger
vessels in which the limiting number of passengers is exceeded.
DOT Vessel Stowage Other : 56 - Stow ‘‘separated from’’ ammonium compounds,58 - Stow ‘‘separated from’’ cyanides
Marine pollutant : P
Additional information
Other information : No supplementary information available.
State during transport (ADR-RID) : as solid.
ADR
Transport document description : UN 1490 Potassium permanganate, 5.1, II, (E)
Packing group (ADR) : II
02/04/2014 EN (English) 7/9

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Safety Data Sheet
Class (ADR) : 5.1 - Oxidizing substances
Hazard identification number (Kemler No.) : 50
Classification code (ADR) : O2
Danger labels (ADR) : 5.1 - Oxidizing substances
Orange plates :
Tunnel restriction code : E
Transport by sea
UN-No. (IMDG) : 1490
Class (IMDG) : 5.1 - Oxidizing substances
EmS-No. (1) : F-H
EmS-No. (2) : S-Q
Air transport
UN-No.(IATA) : 1490
Class (IATA) : 5 - Oxidizing substances
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Listed on SARA Section 313 (Specific toxic chemical listings)

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RQ (Reportable quantity, section 304 of EPA's 100 lb
List of Lists) :
SARA Section 311/312 Hazard Classes Reactive hazard
15.2. International regulations
CANADA
Listed on the Canadian DSL (Domestic Sustances List) inventory.
WHMIS Classification Class C - Oxidizing Material
Class D Division 2 Subdivision B - Toxic material causing other toxic effects
EU-Regulations
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Ox. Sol. 2 H272
Acute Tox. 4 (Oral) H302
Aquatic Acute 1 H400
Aquatic Chronic 1 H410
Classification according to Directive 67/548/EEC or 1999/45/EC
O; R8
Xn; R22
N; R50/53
02/04/2014 EN (English) 8/9

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Safety Data Sheet
Full text of R-phrases: see section 16
15.2.2. National regulations
Listed on the Canadian Ingredient Disclosure List
15.3. US State regulations
SECTION 16: Other information
Full text of H-phrases: see section 16:
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Aquatic Acute 1 Hazardous to the aquatic environment — AcuteHazard, Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category
Ox. Sol. 2 Oxidising Solids, Category 2
H272 May intensify fire; oxidiser
H302 Harmful if swallowed
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
NFPA health hazard : 1 - Exposure could cause irritation but only minor residual
injury even if no treatment is given.
NFPA fire hazard : 0 - Materials that will not burn.
NFPA reactivity : 0 - Normally stable, even under fire exposure conditions,

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and are not reactive with water.
NFPA specific hazard : OX - This denotes an oxidizer, a chemical which can
greatly increase the rate of combustion/fire.
HMIS III Rating
Health : 1 Slight Hazard - Irritation or minor reversible injury possible
Flammability : 0 Minimal Hazard
Physical : 0 Minimal Hazard
Personal Protection : F
SDS US (GHS HazCom 2012)
Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this
SDS. The user must determine suitability of this information for his application.
02/04/2014 EN (English) 9/9

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Glycerin
Safety Data Sheet
Date of issue: 12/17/2013 Version: 1.0
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Substance name : Glycerin
Chemical name : 1,2,3-Trihydroxypropane
CAS No : 56-81-5
Formula : HOCH2CH(OH)CH2OH
Synonyms : Glycerol
Use of the substance/mixture : For laboratory and manufacturing use only.
LabChem Inc
: 412-826-5230 - F 724-473-0647
SECTION 2: Hazards identification
Not classified

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2.2. Label elements
GHS-US labelling
No labelling applicable
2.3. Other hazards
Other hazards not contributing to the : None.
classification
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3: Composition/information on ingredients
3.1. Substance
Glycerin (CAS No) 56-81-5 100 Not classified
(Main constituent)
3.2. Mixture
Not applicable
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation : Assure fresh air breathing. Allow the victim to rest.
First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by
warm water rinse.
12/17/2013 EN (English) Page 1

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Glycerin
Safety Data Sheet
First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness
persist.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use.
SECTION 5: Firefighting
measures
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Avoid (reject) fire-fighting water to enter environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
Protective equipment : Safety glasses. Gloves.
Emergency procedures : Evacuate unnecessary personnel.
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.

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Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation of
vapour.
Storage conditions : Keep container closed when not in use.
Incompatible products : Strong bases. Strong acids. Strong oxidizers.
Incompatible products : Sources of ignition. Direct sunlight.
Glycerin (56-81-5)
USA ACGIH ACGIH TWA (mg/m³) 10 mg/m³ mist
USA OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³ respirable
12/17/2013 EN (English) 2/6

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Glycerin
Safety Data Sheet
Appropriate engineering controls : Emergency eye wash fountains and safety showers should be available in the immediate vicinity
of any potential exposure. Provide adequate general and local exhaust ventilation.
Personal protective equipment : Avoid all unnecessary exposure.
Hand protection : Wear protective gloves.
Eye protection : Chemical goggles or safety glasses.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.
Flammability (solid, gas)

Physical state
Vapour pressure
Molecular mass
Vapour pressure at 50 °C
Colour
Relative vapour density at 20 °C

Odour
Relative density
Odour threshold
Density
pH
Solubility
Relative evaporation rate (butylacetate=1)
Log Pow
Melting point
Log Kow
Freezing point
Viscosity, kinematic
Boiling point
Viscosity, dynamic
Flash point
Explosive properties
Self ignition temperature
Oxidising properties
Decomposition temperature

CHERNIVAL 2018
48
Explosive limits
: Liquid
: 92.11 g/mol
: Colourless.
: characteristic.
: No data available
: 5 10% solution
: No data available
: 20 °C
: No data available
: 182 °C
: 160 °C
: 400 °C
: 290 °C
: No data available
: No data available
: 0.003 hPa
: 3.18
: No data available
: 1.2613 g/ml
: Soluble in water. Soluble in ethanol.
: 0
: No data available
: 1181.3 cSt
: No data available
: No data available
: No data available
: ≥ 1.1 vol %
10.1. Reactivity

CHERNIVAL 2018
49
Not established.
Direct sunlight. Extremely high or low temperatures.
Strong acids. Strong bases. Strong oxidizers.
12/17/2013 EN (English) 3/6

CHERNIVAL 2018
50
Glycerin
Safety Data Sheet
fume. Carbon monoxide. Carbon dioxide.
Acute toxicity : Not classified
Glycerin ( \f )56-81-5
LD50 oral rat 12600 mg/kg
LD50 dermal rat 21900 mg/kg
pH: 5 10% solution
pH: 5 10% solution
Respiratory or skin sensitisation : Not classified
exposure)
Potential Adverse human health effects and : Based on available data, the classification criteria are not met.
symptoms
SECTION 12: Ecological

information

CHERNIVAL 2018
51
12.1. Toxicity
Glycerin (56-81-5)
LC50 fishes 1 64 - 72 g/l
Glycerin (56-81-5)
Persistence and degradability Not established.
Glycerin (56-81-5)
Log Pow 0
Bioaccumulative potential Not established.
Other information : Avoid release to the environment.
SECTION 13: Disposal

considerations
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.
Ecology - waste materials : Avoid release to the environment.
No dangerous good in sense of transport regulations
12/17/2013 EN (English) 4/6

CHERNIVAL 2018
52
Glycerin
Safety Data Sheet
ADR
Transport document description :
Transport by sea
Air transport
Glycerin (56-81-5)
CANADA
Glycerin (56-81-5)
Listed on the Canadian DSL (Domestic Sustances List) inventory.
WHMIS Classification Uncontrolled product according to WHMIS classification criteria
EU-Regulations

CHERNIVAL 2018
53
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified
Classification according to Directive 67/548/EEC or 1999/45/EC
Not classified
Glycerin (56-81-5)
Not listed on the Canadian Ingredient Disclosure List
Other information : None.
NFPA health hazard : 1 - Exposure could cause irritation but only minor residual
injury even if no treatment is given.

CHERNIVAL 2018
54
2013 E

CHERNIVAL 2018
55
Glycerin
Safety Data Sheet
HMIS III Rating
Health : 1 Slight Hazard - Irritation or minor reversible injury possible
Personal Protection : E
SDS US (GHS HazCom 2012)
Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this SDS. The user
must determine suitability of this information for his application.
12/17/2013 EN (English) 6/6

CHERNIVAL 2018
56
He a lt h 0
0
Fire 0
0 0 Re a c t iv it
y 0
P e rs o n a l
P ro t e c t io A
n
Material Safety Data Sheet

Water MSDS
Section 1: Chemical Product and Company Identification

Product Name: Water Contact Information:
Sciencelab.com, Inc.
Catalog Codes: SLW1063
14025 Smith Rd.
CAS#: 7732-18-5 Houston, Texas 77396
US Sales: 1-800-901-
RTECS: ZC0110000 7247
TSCA: TSCA 8(b) inventory: International Sales: 1-281-441-4400

Water
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: Dihydrogen oxide 1-800-424-9300
Chemical Name: Water International CHEMTREC, call: 1-703-527-3887
For non-emergency assistance, call: 1-281-441-
Chemical Formula: H2O 4400
Section 2: Composition and Information on Ingredients
Composition:

CHERNIVAL 2018
57
Name CAS # % by Weight
Water 7732-18-5 100
Toxicological Data on Ingredients: Not applicable.
Section 3: Hazards Identification
Potential Acute Health Effects:
Non-corrosive for skin. Non-irritant for skin. Non-sensitizer for skin. Non-permeator by skin. Non-irritating to the
eyes. Non-hazardous in case of ingestion. Non-hazardous in case of inhalation. Non-irritant for lungs. Non-
sensitizer for lungs. Non-corrosive to the eyes. Non-corrosive for lungs.
Potential Chronic Health Effects:
Non-corrosive for skin. Non-irritant for skin. Non-sensitizer for skin. Non-permeator by skin. Non-irritating to the eyes.
Non-hazardous in case of ingestion. Non-hazardous in case of inhalation. Non-irritant for lungs. Non-sensitizer for
lungs.
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not
available.
DEVELOPMENTAL TOXICITY: Not available.
Section 4: First Aid Measures
Eye Contact: Not applicable.
p. 1

CHERNIVAL 2018
58
Skin Contact: Not applicable.
Serious Skin Contact: Not available.
Inhalation: Not applicable.
Serious Inhalation: Not available.
Ingestion: Not Applicable
Serious Ingestion: Not available.
Section 5: Fire and Explosion Data
Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances: Not Applicable
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.

CHERNIVAL 2018
59
Section 6: Accidental Release Measures
Small Spill: Mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Section 7: Handling and Storage
Precautions: No specific safety phrase has been found applicable for this product.
Storage: Not applicable.
Section 8: Exposure Controls/Personal Protection
Engineering Controls: Not Applicable
Personal Protection: Safety glasses. Lab coat.
Personal Protection in Case of a Large Spill: Not Applicable
Exposure Limits: Not available.
Section 9: Physical and Chemical Properties
Physical state and appearance: Liquid.
p.
2

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Odor: Odorless.
Taste: Not available.
Molecular Weight: 18.02 g/mole
Color: Colorless.
pH (1% soln/water): 7 [Neutral.]
Boiling Point: 100°C (212°F)
Melting Point: Not available.
Critical Temperature: Not available.
Specific Gravity: 1 (Water = 1)
Vapor Pressure: 2.3 kPa (@ 20°C)
Vapor Density: 0.62 (Air = 1)
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: Not applicable
Solubility: Not Applicable
Section 10: Stability and Reactivity Data

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61
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Not available.
Corrosivity: Not available.
Special Remarks on Reactivity: Not available.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.
Section 11: Toxicological Information
Routes of Entry: Absorbed through skin. Eye contact.
Toxicity to Animals:
LD50: [Rat] - Route: oral; Dose: > 90 ml/kg LC50: Not available.
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans:
Non-corrosive for skin. Non-irritant for skin. Non-sensitizer for skin. Non-permeator by skin. Non-hazardous in case
of ingestion. Non-hazardous in case of inhalation. Non-irritant for lungs. Non-sensitizer for lungs. Non-corrosive to
the eyes. Non-corrosive for lungs.
Special Remarks on Toxicity to Animals: Not available.
p.
3

CHERNIVAL 2018
62
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Not available.
Section 12: Ecological Information
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may
arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Section 14: Transport Information
DOT Classification: Not a DOT controlled material (United States).
Identification: Not applicable.
Special Provisions for Transport: Not applicable.

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Section 15: Other Regulatory Information
Federal and State Regulations: TSCA 8(b) inventory: Water
Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical
Substances.
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
This product is not classified according to the EU regulations. Not applicable.
HMIS (U.S.A.):
Health Hazard: 0
Fire Hazard: 0
Reactivity: 0
Personal Protection: a
National Fire Protection Association (U.S.A.):
Health: 0
Flammability: 0
Reactivity: 0
Specific hazard:

CHERNIVAL 2018
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p.
4

CHERNIVAL 2018
65
Protective Equipment:
Not applicable. Lab coat. Not applicable. Safety glasses.
Section 16: Other Information
References: Not available.
Other Special Considerations: Not available.
Created: 10/10/2005 08:33 PM
Last Updated: 05/21/2013 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us.
However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should make their own investigations to
determine the suitability of the information for their particular purposes. In no event shall ScienceLab.com be liable
for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental,
consequential or exemplary damages, howsoever arising, even if ScienceLab.com has been advised of the
possibility of such damages.

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He a lt h 2
0
Fire 0
2 0
Re a c t iv it
y 1
P e rs o n a l
P ro t e c t io E
n
Potassium carbonate, anhydrous MSDS
Product Name: Potassium carbonate, anhydrous Contact Information:
Catalog Codes: SLP4780, SLP1951, SLP3760, SLP5575 Sciencelab.com, Inc.
14025 Smith Rd.

CAS#: 584-08-7
Houston, Texas 77396
RTECS: TS7750000
US Sales: 1-800-901-7247
TSCA: TSCA 8(b) inventory: Potassium
carbonate, anhydrous International Sales: 1-281-441-4400

CI#: Not available.

Synonym: Salt of Tartar
1-800-424-9300
Chemical Name: Potassium Carbonate
International CHEMTREC, call: 1-703-527-3887

Chemical Formula: K2CO3
For non-emergency assistance, call: 1-281-441-4400

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Composition:
Potassium carbonate, anhydrous 584-08-7 100
Toxicological Data on Ingredients: Potassium carbonate, anhydrous: ORAL (LD50): Acute: 1870 mg/kg [Rat].
Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in
case of eye contact (corrosive).
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS:
Not available. DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to mucous membranes. The
substance may be toxic to skin, eyes. Repeated or prolonged exposure to the substance can produce target
organs damage.
Eye Contact:
p. 1

CHERNIVAL 2018
68
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Cold water may be used. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove
contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes
before reuse. Get medical attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek
immediate medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
clothing such as a collar, tie, belt or waistband.

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Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product
in
presence of static discharge: Not available.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading
water on the contaminated surface and allow to evacuate through the sanitary system.
Precautions:
p.
2

CHERNIVAL 2018
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Keep container dry. Do not ingest. Do not breathe dust. Never add water to this product. In case of insufficient
ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the
container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents,
metals, acids.
Storage:
Hygroscopic. Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 25°C
(77°F).
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure
to airborne contaminants below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Physical state and appearance: Solid. (Powdered solid. Deliquescent solid.)
Odor: Odorless.

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Color: White.
pH (1% soln/water): Not available.
Boiling Point: Decomposes.
Melting Point: 891°C (1635.8°F)
Specific Gravity: 2.29 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Dispersion Properties: See solubility in water.
Solubility: Soluble in cold water.
p.
3

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72
Conditions of Instability: Dust generation, moist air, water, incompatible materials
Incompatibility with various substances:
Reactive with oxidizing agents, metals, acids. Slightly reactive to reactive with moisture.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Hygroscopic. Reacts with water to evolve heat. Incompatible with KCO, chlorine trifluoride, calcium oxide, and
magnesium.
Routes of Entry: Eye contact. Inhalation. Ingestion.
Toxicity to Animals: Acute oral toxicity (LD50): 1870 mg/kg [Rat].
Chronic Effects on Humans:
Causes damage to the following organs: mucous membranes. May cause damage to the following organs: skin,
eyes.
Hazardous in case of skin contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of eye contact
(corrosive).

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Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: Causes severe skin irritation. Eyes: It is severely irritating to the eyes and its
mucous membranes. It may cause corneal injury. It may cause burns and loss of vision. It may cause permanent
damage. The amount of tissue damage depends on the length of contact. Ingestion: It causes gastrointestinal
irritation with nausea, vomiting, abdominal pain, swollen glottis, increased respiration, and possible burns to the
lips, tongue, oral mucosa, hypopharynx, stomach, or esophagus. It may affect the cardiovascular
system(circulatory collapse), urinary system, and metabolism. Inhalation: Causes respiratory tract and mucous
membrane irritation. Exposure can cause coughing, chest pains, and difficulty breathing (dyspnea).
arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Waste Disposal:

CHERNIVAL 2018
74
p.
4

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75
Federal and State Regulations: TSCA 8(b) inventory: Potassium carbonate, anhydrous
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This
product is on the European Inventory of Existing Commercial Chemical Substances.
WHMIS (Canada):
CLASS D-2B: Material causing other toxic effects (TOXIC). CLASS E: Corrosive solid.
DSCL (EEC):
R22- Harmful if swallowed. R37/38- Irritating to respiratory system and skin. R41- Risk of serious damage to eyes.
S2- Keep out of the reach of children. S26- In case of contact with eyes, rinse immediately with plenty of water
and seek medical advice. S37/39- Wear suitable gloves and eye/face protection. S46- If swallowed, seek medical
advice immediately and show this container or label.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 0
Reactivity: 1

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Personal Protection: E
Health: 2
Flammability: 0
Reactivity: 0
Specific hazard:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear
appropriate respirator when ventilation is inadequate. Splash goggles.
Created: 10/10/2005 11:40 AM
Last Updated: 05/21/2013 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we make no
warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine the suitability of the information for
p.
5

CHERNIVAL 2018
77
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any
third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever
arising, even if ScienceLab.com has been advised of the possibility of such damages.

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Carbon Dioxide, Solid or Dry Ice
Safety Data Sheet P-4575
This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.
Date of issue: 01/01/1997Revision date: 10/17/2016Supersedes: 01/12/2015
SECTION: 1. Product and company identification
Name : Carbon Dioxide, Solid or Dry Ice
CAS No : 124-38-9
Formula : CO2
Other means of identification : Dry ice (nuggets, pellets, or blocks), carbonice, carbonic anhydride
Use of the substance/mixture : Industrial use. Use as directed.
Praxair, Inc.
10 Riverview Drive
Danbury, CT 06810-6268 - USA
T 1-800-772-9247 (1-800-PRAXAIR) - F 1-716-879-2146
www.praxair.com
Emergency number : Onsite Emergency: 1-800-645-4633
CHEMTREC, 24hr/day 7days/week
— Within USA: 1-800-424-9300, Outside USA: 001-703-527-3887

(collect calls accepted, Contract 17729)
SECTION 2: Hazard identification

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79
2.2. Label elements
GHS-US labeling
No labeling applicable
2.3. Other hazards
Other hazards not contributing to the : Refrigerated solidified gas. CONTACT WITH PRODUCT MAY CAUSE COLD BURNS OR
classification FROSTBITE
Dry ice sublimes to carbon dioxide vapor at -109°F (-78°C). VAPOR MAY DISPLACE OXYGEN
AND CAUSE RAPID SUFFOCATION.
2.4. Unknown acute toxicity (GHS US)
No data available
SECTION 3: Composition/Information on ingredients
3.1. Substance
Name Product identifier %
Carbon Dioxide, Solid or Dry Ice (CAS No) 124-38-9 100
(Main constituent)
3.2. Mixture
Not applicable
EN (English US) SDS ID: P-4575 1/7

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This document is only controlled while on the Praxair, Inc. website and a copy of this controlled version is available for download. Praxair cannot assure the integrity or
accuracy of any version of this document after it has been downloaded or removed from our website.

CHERNIVAL 2018
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Date of issue: 01/01/1997 Revision date: 10/17/2016 Supersedes: 01/12/2015
First-aid measures after inhalation : Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep
victim warm and rested. Call a doctor. Apply artificial respiration if breathing stopped.
First-aid measures after skin contact : In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes.
First-aid measures after eye contact : Immediately flush eyes thoroughly with water for at least 15 minutes. Hold the eyelids open and
away from the eyeballs to ensure that all surfaces are flushed thoroughly. Contact an
ophthalmologist immediately.. Get immediate medical attention.
First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.
None.
Reactivity : None.
Firefighting instructions : Evacuate all personnel from danger area. Do not discharge sprays onto solid carbon dioxide.
Solid carbon dioxide will freeze water rapidly. NEVER HANDLE SOLID CARBON DIOXIDE
WITH YOUR BARE HANDS. USE GLOVES OR DRY ICE TONGS OR A DRY SHOVEL OR
SCOOP. Move packages away from fire area if safe to do so. Self-contained breathing

CHERNIVAL 2018
82
apparatus may be required by rescue workers. On-site fire brigades must comply with OSHA
29 CFR 1910.156 and applicable standards under 29 CFR 1910 Subpart L—Fire Protection.
General measures : Use protective clothing. Wear cold-insulating gloves/face shield/eye protection. Chemical
asphyxiant. Exposure to low concentrations for extended periods may result in dizziness or
unconsciousness, and may lead to death. Wear self-contained breathing apparatus when
entering area unless atmosphere is proven to be safe. NEVER HANDLE SOLID CARBON
DIOXIDE WITH YOUR BARE HANDS. USE GLOVES OR DRY ICE TONGS OR A DRY
SHOVEL OR SCOOP.
Prevent waste from contaminating the surrounding environment. Prevent soil and water pollution.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Contact supplier for any special requirements.
See also sections 8 and 13.

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83

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84
Precautions for safe handling : Avoid materials incompatible with cryogenic use; some metals such as carbon steel may
fracture easily at low temperature. Vapor can cause rapid suffocation due to oxygen
deficiency. Never allow any unprotected part of your body to touch solid carbon dioxide or to
touch uninsulated pipes or vessels containing solid or liquid carbon dioxide or cold carbon
dioxide gas. Not only can you suffer frostbite, your skin may stick fast to the cold surfaces.
Use tongs or insulated gloves when handling solid carbon dioxide or objects in contact cold
carbon dioxide in any form. Wear protective clothing and equipment as prescribed in section 8.
For other precautions in using carbon dioxide, see section 16.
Storage conditions : Store and use with adequate ventilation. Do not store in tight containers or confined spaces.
Storage areas should be clean and dry. Solid carbon dioxide is generally delivered to
customers in 50-lb (22.7-kg), ½-cubic ft (0.0142 cubic meter) blocks (approximate dimensions),
wrapped in kraft paper. Small pellets or nuggets are also produced. The product should be
stored in insulated containers that open from the top. Lids should fit loosely so the carbon
dioxide vapor given off as the solid sublimes can escape into the atmosphere. Carbon dioxide
gas is about 1½ times as heavy as air and will accumulate in low-lying areas, so ventilation
must be adequate at floor or below grade level.
None.
Carbon Dioxide, Solid or Dry Ice (124-38-9)
ACGIH ACGIH TLV-TWA (ppm) 5000 ppm
ACGIH ACGIH TLV-STEL (ppm) 30000 ppm

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USA OSHA OSHA PEL (TWA) (mg/m³) 9000 mg/m³
USA OSHA OSHA PEL (TWA) (ppm) 5000 ppm
USA IDLH US IDLH (ppm) 40000 ppm
Appropriate engineering controls : Oxygen detectors should be used when asphyxiating gases may be released. Ensure exposure
is below occupational exposure limits (where available). Systems under pressure should be
regularly checked for leakages. Provide adequate general and local exhaust ventilation.
Consider work permit system e.g. for maintenance activities.
Hand protection : Cold-insulating gloves.
Eye protection : Wear safety glasses with side shields.
Respiratory protection : When workplace conditions warrant respirator use, follow a respiratory protection program that
meets OSHA 29 CFR 1910.134, ANSI Z88.2, or MSHA 30 CFR 72.710 (where applicable).
Use an air-supplied or air-purifying cartridge if the action level is exceeded. Ensure that the
respirator has the appropriate protection factor for the exposure level. If cartridge type
respirators are used, the cartridge must be appropriate for the chemical exposure. For
emergencies or instances with unknown exposure levels, use a self-contained breathing
apparatus (SCBA).
Thermal hazard protection : Wear cold insulating gloves.
Environmental exposure controls : None necessary.
Other information : Wear safety shoes while handling containers.
Physical state : Solid
Appearance : Opaque. White crystalline solid.
Molecular mass : 44 g/mol
Color : White.
Odor : No odor warning properties.

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Viscosity, kinematic
Odor threshold
Viscosity, dynamic
pH
Explosive properties
Relative evaporation rate (butyl acetate=1)

Oxidizing properties
Relative evaporation rate (ether=1)
Explosion limits
Melting point
Freezing point
Boiling point
Flash point
Critical temperature
Auto-ignition temperature
Decomposition temperature
Flammability (solid, gas)
Vapor pressure
Critical pressure
Relative vapor density at 20 °C

Relative density Density
Relative gas density
Solubility
Log Pow
Log Kow

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87
: 7375 kPa
: No data available
: No data available
: 3.7 (carbonic acid) : 0.82
: No data available
: 1562 kg/m³
: Not applicable. : 1.52
: -78.5 °C : Water: 2000 mg/l Completely soluble.
: No data available : 0.83
: -78.4 °C : Not applicable.
: Not applicable. : Not applicable.
: 30 °C : Not applicable.
: Not applicable.
: Not applicable.
: No data available : None.
: No data available
: Not applicable.
: 5730 kPa
Sublimation point : -78.5 °C Expansion ratio for solid to gas at sublimation point is 1 to 554.
Additional information : Gas/vapor heavier than air. May accumulate in confined spaces, particularly at or below ground
level
10.1. Reactivity
None.
None.
None under recommended storage and handling conditions (see section 7).

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88
Alkali metals, Alkaline earth metals, Acetylide forming metals, Chromium, Titanium >
1022°F (550°C), Uranium (U) > 1382°F (750°C), Magnesium > 1427°F (775°C).
Electrical discharges and high temperatures decompose carbon dioxide into carbon monoxide
and oxygen.

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pH: 3.7 (carbonic acid)
pH: 3.7 (carbonic acid)
Respiratory or skin sensitization : Not classified
exposure)

information
12.1. Toxicity
Ecology - general : No ecological damage caused by this product.
Persistence and degradability No ecological damage caused by this product.
BCF fish 1 (no bioaccumulation)
Log Pow 0.83

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Log Kow Not applicable.
Bioaccumulative potential No ecological damage caused by this product.
Mobility in soil No data available.
Ecology - soil No ecological damage caused by this product.
Other adverse effects : Can cause frost damage to vegetation.
Effect on ozone layer : None
Global warming potential [CO2=1] : 1
Effect on the global warming : When discharged in large quantities may contribute to the greenhouse effect

considerations
Waste treatment methods : See Section 6.
Waste disposal recommendations : Dispose of contents/container in accordance with local/regional/national/international
regulations. Contact supplier for any special requirements.
SECTION 14: Transport

information
Transport document description : UN1845 Carbon dioxide, solid, 9
UN-No.(DOT) : UN1845
Proper Shipping Name (DOT) : Carbon dioxide, solid

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Class (DOT) : 9 - Class 9 - Miscellaneous hazardous material 49 CFR 173.140
Hazard labels (DOT) : 9 - Class 9 (Miscellaneous dangerous materials)
DOT Symbols : A - Material is regulated as a hazardous material only when transported by air,W - Material is
regulated as a hazardous material only when transported by water
Emergency Response Guide (ERG) Number : 120 (UN1013)
Special transport precautions : Avoid transport on vehicles where the load space is not separated from the driver's
compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows
what to do in the event of an accident or an emergency. Before transporting product containers:
- Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure
cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided)
is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.
Transport by sea
Proper Shipping Name (IMDG) : CARBON DIOXIDE, SOLID (DRY ICE)
Class (IMDG) : 9 - Miscellaneous dangerous compounds
Air transport
UN-No. (IATA) : 1845
Proper Shipping Name (IATA) : Carbon dioxide, solid
Class (IATA) : 9 - Miscellaneous Dangerous Goods

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SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
CANADA
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)

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Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on the Canadian IDL (Ingredient Disclosure List)
Listed on INSQ (Mexican National Inventory of Chemical Substances)
Listed on CICR (Turkish Inventory and Control of Chemicals)
Carbon Dioxide, Solid or Dry Ice(124-38-9)
U.S. - California - Proposition 65 - Carcinogens List No
U.S. - California - Proposition 65 - Developmental No
Toxicity
U.S. - California - Proposition 65 - Reproductive No
Toxicity - Female
Toxicity - Male
State or local regulations U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List

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U.S. - Pennsylvania - RTK (Right to Know) List
NFPA health hazard : 3 - Short exposure could cause serious temporary or
residual injury even though prompt medical attention was
given.
NFPA specific hazard : SA - This denotes gases which are simple asphyxiants.
HMIS III Rating
Health : 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is
given
SDS US (GHS HazCom 2012) - Praxair
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as
guaranteeing any specific property of the product.

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This document is only controlled while on the Praxair, Inc. website and a copy of this controlled version is available for download. Praxair cannot assure the integrity or accuracy
of any version of this document after it has been downloaded or removed from our website.

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He a lt h 1
1
Fire 3
0 1 Re a c t iv it
y 2
P e rs o n a l
P ro t e c t io E
n

Magnesium MSDS

Product Name: Magnesium Contact Information:
Catalog Codes: SLM4408, SLM2263, SLM3637
14025 Smith Rd.
US Sales: 1-800-901-
RTECS: OM2100000 7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Magnesium
CI#: Not applicable.
Synonym: Magnesium ribbons, turnings or sticks 1-800-424-9300
Chemical Name: Magnesium International CHEMTREC, call: 1-703-527-3887
Chemical Formula: Mg 4400
Composition:

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Magnesium 7439-95-4 100
Toxicological Data on Ingredients: Magnesium LD50: Not available. LC50: Not available.
Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of
ingestion, of inhalation.
available.
DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical
condition.
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical attention if irritation occurs.
Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation
develops.
p. 1

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Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth
resuscitation. Seek medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
clothing such as a collar, tie, belt or waistband.
Flammability of the Product: Flammable.
Auto-Ignition Temperature: Not available.
Flash Points: Not available.
Flammable Limits: Not available.
Products of Combustion: Some metallic oxides.
Fire Hazards in Presence of Various Substances:
Highly flammable in presence of open flames and sparks, of heat. Flammable in presence of acids, of
moisture. Non-flammable in presence of shocks.

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in
presence of static discharge: Not available. Explosive in presence of acids, of moisture.
Fire Fighting Media and Instructions:
Flammable solid. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray or fog. Cool
containing vessels with water jet in order to prevent pressure build-up, autoignition or explosion.
Special Remarks on Fire Hazards:
Magnesium turnings, chips or granules, ribbons, are flammable. They can be easily ignited. They may
reignite after fire is extinguished. Produces flammable gases on contact with water and acid. May ignite on
contact with water or moist air. Magnesium fires do not flare up violently unless moisture is present.
Special Remarks on Explosion Hazards: Reacts with acids and water to form hydrogen gas with is highly
flammable and eplosive
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Flammable solid. Stop leak if without risk. Do not touch spilled material. Use water spray curtain to divert vapor drift. Prevent entry
into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal.
Precautions:
p.
2

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Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not breathe
dust.
Keep away from incompatibles such as oxidizing agents, acids, moisture.
Storage:
Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid
all possible sources of ignition (spark or flame). Moisture sensitive. Dangerous when wet.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or
equivalent.
Gloves.
Physical state and appearance: Solid. (Metal solid)
Odor: Odorless.

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Color: Silver-white
pH (1% soln/water): Not applicable.
Boiling Point: 1100°C (2012°F)
Melting Point: 651°C (1203.8°F)
Specific Gravity: 1.74 (Water = 1)
Dispersion Properties: Not available.
Solubility:
Very slightly soluble in hot water. Insoluble in cold water. Insoluble in chromium trioxides, and mineral acids,
alkalies. Slightly soluble with decomposition in hot water. Soluble in concentrated hydrogen fluoride, and
ammonium salts.

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p.
3

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Conditions of Instability: Heat, incompatible materials, water or moisture, moist air.
Incompatibility with various substances: Reactive with oxidizing agents, acids, moisture.
Special Remarks on Reactivity:
Violent chemical reaction with oxidizing agents. Reacts with water to create hydrogen gas and heat. Must be kept
dry. Reacts with acids to form hydrogen gas which is highly flammable and explosive. Magnesium forms
hazardous or explosive mixtures with aluminum and potassium perchlorate; ammonium nitrate; barium nitrate,
barium dioxide and zinc; beryllium oxide; boron phosphodiiodide; bromobenzyl trifluoride; cadmium cyanide;
cadmium oxide; calcium carbide; carbonates; carbon tetrachloride; chlorine; chlorine trifluoride; chloroform; cobalt
cyanide; copper cyanide; copper sulfate(anhydrous), ammonium nitrate, potassium chlorate and water; cupric
oxide; cupric sulfate; fluorine; gold cyanide; hydrogen and calcium carbonate; hydrogen iodide; hydrogen
peroxide; iodine; lead cyanide; mercuric oxide; mercury cyanide; methyl chloride; molybdenum trioxide; nickel
cyanide; nitric acid; nitrogen dioxide; oxygen (liquid); performic acid; phosphates; potassium chlorate; potassium
perchlorate; silver nitrate; silver oxide; sodium perchlorate; sodium peroxide; sodium peroxide and carbon dioxide;
stannic oxide; sulfates; trichloroethylene; zinc cyanide; zinc oxide.
Routes of Entry: Inhalation. Ingestion.
LD50: Not available. LC50: Not available.
Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.

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Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: May cause skin irritation by mechanical action. May get mechanical injury or
embedding
of chips/particles in skin. The particles that are embedded in the wounds may retard healing. Eyes: May cause eye
irritation by mechanical action. Mechanical injury may occur. Particles or chips may embed in eye and retard
healing. Inhalation: Low hazard for ususal industrial handling. It may cause respiratory tract irritation. However, it is
unlikely due to physical form. When Magnesium metal is heated during welding or smelting process, Metal Fume
Fever may result from inhalation of magnesium fumes. Metal Fume Fever is a flu-like condition consisting of fever,
chills, sweating, aches, pains, cough, weakness, headache, nausea, vomiting, and breathing difficulty. Other
symptoms may include metallic taste, increased white blood cell count.
There is no permanent ill-effect. Ingestion: Low hazard for usual industrial handling. There are no known
reports of serious industrial poisonings with Magnesium. Ingeston of large amounts of chips, turnings or ribbons
may cause gastrointestinal tract irritation with nausea, vomiting, and diarrhea. Acute ingestion may also result
in Hypermagnesia. Hypermagnesia may cause hypotension, bradycardia, CNS depression, respiratory
depression, and impairment of neuromuscular transmission (hyporeflexia, paralysis).
p.
4

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arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Waste Disposal:
DOT Classification: CLASS 4.1: Flammable solid.
Identification: : Magnesium UNNA: 1869 PG: III
Special Provisions for Transport: Not available.
Federal and State Regulations:
Connecticut hazardous material survey.: Magnesium Rhode Island RTK hazardous substances: Magnesium
Pennsylvania
RTK: Magnesium Massachusetts RTK: Magnesium Massachusetts spill list: Magnesium New Jersey: Magnesium
TSCA 8(b)
inventory: Magnesium
Other Regulations:

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OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This
product is on the European Inventory of Existing Commercial Chemical Substances.
WHMIS (Canada):
CLASS B-4: Flammable solid. CLASS B-6: Reactive and very flammable material.
DSCL (EEC):
R11- Highly flammable. R15- Contact with water liberates extremely flammable gases. S7/8- Keep container tightly
closed and dry. S43- In case of fire, use dry chemical. Never use water.
HMIS (U.S.A.):
Health Hazard: 1
Fire Hazard: 3
Reactivity: 2
Health: 0
Flammability: 1
Reactivity: 1
Specific hazard:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear
appropriate respirator when ventilation is inadequate. Safety glasses.

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p.
5

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Created: 10/09/2005 06:00 PM
Last Updated: 05/21/2013 12:00 PM

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Sulfuric Acid
Safety Data Sheet

Date of issue: 10/01/1998 Revision date: 01/23/2018 Supersedes: 01/23/2018 Version: 1.2
SECTION 1: Identification
1.1. Identification
Substance name : Sulfuric Acid
CAS-No. : 7664-93-9
Formula : H2SO4
Synonyms : battery acid / brown acid / brown oil of vitriol / dihydrogen sulfate / dipping acid / electrolyte acid
/ nordhausen acid / oil of vitriol / sulphuric acid
1.2. Recommended use and restrictions on use
Use of the substance/mixture : Industrial use
Laboratory chemical
Battery: component
Recommended use : Laboratory chemicals
Restrictions on use : Not for food, drug or household use
1.3. Supplier
LabChem Inc
T 412-826-5230 - F 724-473-0647
SECTION 2: Hazard(s) identification

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Skin corrosion/irritation H314 Causes severe skin burns and eye damage
Category 1A
Serious eye damage/eye H318 Causes serious eye damage
irritation Category 1
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS-US labeling
GHS05
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H314 - Causes severe skin burns and eye damage
H318 - Causes serious eye damage
Precautionary statements (GHS-US) : P260 - Do not breathe dust/fume/gas/mist/vapors/spray.

P264 - Wash hands, forearms and face thoroughly after handling.
P280 - Wear protective gloves, protective clothing, eye protection, face protection.
P301+P330+P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower.
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a poison center or doctor/physician.
P363 - Wash contaminated clothing before reuse.
P405 - Store locked up.
P501 - Dispose of contents/container to comply with local, state and federal

regulations If inhaled: Remove person to fresh air and keep comfortable for breathing
01/29/2018 EN (English US) Page 1

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Sulfuric Acid
Safety Data Sheet
2.3. Other hazards which do not result in classification
classification
Not applicable
3.1. Substances
Sulfuric Acid (CAS-No.) 7664-93-9 96 Skin Corr. 1A, H314
(Main constituent) Eye Dam. 1, H318
Full text of hazard classes and H-statements : see section 16
3.2. Mixtures
Not applicable
SECTION 4: First-aid measures
First-aid measures general : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory
arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious
with labored breathing: half-seated. Victim in shock: on his back with legs slightly raised.
Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no
warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid
physical strain. Depending on the victim's condition: doctor/hospital.
First-aid measures after inhalation : Remove the victim into fresh air. Immediately consult a doctor/medical service.

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First-aid measures after skin contact : Wash immediately with lots of water (15 minutes)/shower. Do not apply (chemical) neutralizing
agents. Remove clothing while washing. Do not remove clothing if it sticks to the skin. Cover
wounds with sterile bandage. Consult a doctor/medical service. If burned surface > 10%: take
victim to hospital.
First-aid measures after eye contact : Rinse immediately with plenty of water for 15 minutes. Take victim to an ophthalmologist. Do
not apply neutralizing agents.
First-aid measures after ingestion : Rinse mouth with water. Do not induce vomiting. Do not give activated charcoal. Immediately
consult a doctor/medical service. Call Poison Information Centre (www.big.be/antigif.htm). Take
the container/vomit to the doctor/hospital. Ingestion of large quantities: immediately to hospital.
Do not give chemical antidote.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects after inhalation : Dry/sore throat. Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous
membranes. ON CONTINUOUS EXPOSURE/CONTACT: Corrosion of the upper respiratory
tract. FOLLOWING SYMPTOMS MAY APPEAR LATER: Possible laryngeal spasm/oedema.
Risk of pneumonia. Risk of lung edema. Respiratory difficulties.
: Caustic burns/corrosion of the skin.
Symptoms/effects after skin contact : Corrosion of the eye tissue. Permanent eye damage.
: Nausea. Abdominal pain. Blood in stool. Blood in vomit. Burns to the gastric/intestinal mucosa.
Symptoms/effects after eye contact AFTER ABSORPTION OF LARGE QUANTITIES: Shock.
: ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Red skin. Dry skin. Itching. Skin
rash/inflammation. Affection/discolouration of the teeth. Inflammation/damage of the eye tissue.
Symptoms/effects after ingestion
Chronic symptoms
4.3. Immediate medical attention and special treatment, if necessary
Obtain medical assistance.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Quantities of water. BC powder. ABC powder. Carbon dioxide.
Unsuitable extinguishing media : EXTINGUISHING MEDIA FOR SURROUNDING FIRES: Water. Water spray.
5.2. Specific hazards arising from the chemical
Fire hazard : DIRECT FIRE HAZARD. Non combustible. INDIRECT FIRE HAZARD. Reactions involving a
fire hazard: see "Reactivity Hazard".
Explosion hazard : INDIRECT EXPLOSION HAZARD. Reactions with explosion hazards: see "Reactivity Hazard".

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01/29/2018 EN (English US) 2/9

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Sulfuric Acid
Safety Data Sheet
Reactivity : Violent exothermic reaction with water (moisture): release of corrosive gases/vapours. Reacts
on exposure to water (moisture) with (some) metals: release of highly flammable
gases/vapours (hydrogen). On heating/burning: release of toxic and corrosive gases/vapours
(sulphur oxides). Reacts violently with (some) bases: heat release resulting in increased fire or
explosion risk. Reacts with many compounds e.g.: with (strong) reducers, with organic material
and with combustible materials: (increased) risk of fire/explosion.
5.3. Special protective equipment and precautions for fire-fighters
Precautionary measures fire : Exposure to fire/heat: keep upwind. Exposure to fire/heat: consider evacuation. Exposure to
fire/heat: seal off low-lying areas. Exposure to fire/heat: have neighbourhood close doors and
windows.
Firefighting instructions : Cool tanks/drums with water spray/remove them into safety. When cooling/extinguishing: no
water in the substance. Dilute toxic gases with water spray.
Protection during firefighting : Heat/fire exposure: compressed air/oxygen apparatus.
Protective equipment : Gloves. Face-shield. Corrosion-proof suit. Large spills/in enclosed spaces: compressed air
apparatus. Large spills/in enclosed spaces: gas-tight suit. See "Material-Handling" to select
protective clothing.
Emergency procedures : Mark the danger area. No naked flames. Keep containers closed. Avoid ingress of water in the
containers. Wash contaminated clothes. Large spills/in confined spaces: consider evacuation.
In case of hazardous reactions: keep upwind. In case of reactivity hazard: consider evacuation.
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Stop leak if safe to do so. Ventilate area.
Prevent soil and water pollution. Prevent spreading in sewers.

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For containment : Contain released substance, pump into suitable containers. Consult "Material-handling" to
select material of containers. Plug the leak, cut off the supply. Dam up the liquid spill.
Hazardous reaction: measure explosive gas-air mixture. Reaction: dilute combustible
gas/vapour with water curtain. Take account of toxic/corrosive precipitation water. Heat
exposure: dilute toxic gas/vapour with water spray.
Methods for cleaning up : Take up liquid spill into inert absorbent material, e.g.: dry sand/earth/vermiculite. Scoop
absorbed substance into closing containers. Carefully collect the spill/leftovers.
Damaged/cooled tanks must be emptied. See "Material -handling" for suitable container
materials. Clean contaminated surfaces with an excess of water. Take collected spill to
manufacturer/competent authority. Wash clothing and equipment after handling.
Precautions for safe handling : Comply with the legal requirements. Remove contaminated clothing immediately. Clean
contaminated clothing. Keep the substance free from contamination. Thoroughly clean/dry the
installation before use. Do not discharge the waste into the drain. Never add water to this
product. Never dilute by pouring water to the acid. Always add the acid to the water. Keep away
from naked flames/heat. Observe very strict hygiene - avoid contact. Keep container tightly
closed. Measure the concentration in the air regularly. Carry operations in the open/under local
exhaust/ventilation or with respiratory protection.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Wash contaminated clothing before reuse. Do not eat, drink or
smoke when using this product.
Incompatible products : Strong bases. metals. combustible materials.
Heat-ignition : KEEP SUBSTANCE AWAY FROM: heat sources.
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Sulfuric Acid
Safety Data Sheet
Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: combustible materials. reducing agents. (strong) bases.
highly flammable materials. metals. cellulosic materials. organic materials. alcohols. amines.
water/moisture.
Storage area : Store in a dry area. Ventilation at floor level. Keep locked up. Provide for a tub to collect spills.
Unauthorized persons are not admitted. Meet the legal requirements.
Special rules on packaging : SPECIAL REQUIREMENTS: closing. dry. clean. correctly labelled. meet the legal
requirements. Secure fragile packagings in solid containers.
Packaging materials : SUITABLE MATERIAL: stainless steel. carbon steel. polyethylene. polypropylene. glass.
stoneware/porcelain. MATERIAL TO AVOID: monel steel. lead. copper. zinc.
Sulfuric Acid (7664-93-9)
ACGIH ACGIH TWA (mg/m³) 0.2 mg/m³ (Sulfuric acid; USA; Time-weighted average
exposure limit 8 h; TLV - Adopted Value; Thoracic
fraction)
OSHA OSHA PEL (TWA) (mg/m³) 1 mg/m³
IDLH US IDLH (mg/m³) 15 mg/m³
NIOSH NIOSH REL (TWA) (mg/m³) 1 mg/m³
8.2. Appropriate engineering controls
Appropriate engineering controls : Emergency eye wash fountains should be available in the immediate vicinity of any potential
exposure. Provide adequate general and local exhaust ventilation.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:

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Gloves. Face shield. Chemical resistant apron. Safety glasses. Protective goggles. Gas mask with filter type E.
Materials for protective clothing:
GIVE EXCELLENT RESISTANCE: butyl rubber. polyethylene. tetrafluoroethylene. GIVE LESS RESISTANCE: neoprene. PVC. viton. GIVE POOR
RESISTANCE: natural rubber. nitrile rubber. PVA
Hand protection:
Gloves
Eye protection:
Face shield
Skin and body protection:
Corrosion-proof clothing
Respiratory protection:
Gas mask with filter type E at conc. in air >
exposure limit
Physical state : Liquid
Appearance : Liquid.
Color : Pure substance: colourless Unpurified: yellow to brown
Odor : Almost odourless

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Odor threshold : > 1 mg/m³
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Sulfuric Acid
Safety Data Sheet
pH : <1
Melting point : 10 °C
Boiling point : 288 °C
Flash point : Not applicable
Relative evaporation rate (butyl acetate=1) : No data available
Vapor pressure : < 1 hPa (20 °C)
Relative vapor density at 20 °C : 3.4
Relative density : 1.8
Specific gravity / density : 1840 kg/m³
Molecular mass : 98.08 g/mol
Solubility : Exothermically soluble in water. Soluble in ethanol.
Water: Complete
Log Pow : -2.2 (Estimated value)
Auto-ignition temperature : No data available
Decomposition temperature : > 340 °C
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : No data available.
Oxidizing properties : No data available.
VOC content : 0%
Other properties : Gas/vapour heavier than air at 20°C. Clear. Hygroscopic. Slightly volatile. Substance has acid
reaction.
10.1. Reactivity
Violent exothermic reaction with water (moisture): release of corrosive gases/vapours. Reacts on exposure to water (moisture) with (some) metals:
release of highly flammable gases/vapours (hydrogen). On heating/burning: release of toxic and corrosive gases/vapours (sulphur oxides). Reacts

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violently with (some) bases: heat release resulting in increased fire or explosion risk. Reacts with many compounds e.g.: with (strong) reducers, with
organic material and with combustible materials: (increased) risk of fire/explosion.
Unstable on exposure to moisture.
Reacts violently with water. Reacts violently with (some) bases: release of heat.
Incompatible materials. Moisture.
Water. Strong bases. Organic compounds. metals. Halogens. cyanides. combustible materials.
Sulfur compounds.
Likely routes of exposure : Skin and eye contact
LD50 oral rat 2140 mg/kg body weight (Rat; Experimental value)
ATE US (oral) 2140 mg/kg body weight
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Sulfuric Acid
Safety Data Sheet
Skin corrosion/irritation : Causes severe skin burns and eye damage.
pH: < 1
Serious eye damage/irritation : Causes serious eye damage.
pH: < 1
Additional information Strong inorganic acid mists containing sulfuric acid are carcinogenic to humans
IARC group 1 - Carcinogenic to humans
National Toxicology Program (NTP) Status 2 - Known Human Carcinogens
Specific target organ toxicity – single exposure : Not classified
Specific target organ toxicity – repeated : Not classified
exposure
Symptoms/effects after inhalation : Dry/sore throat. Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous
membranes. ON CONTINUOUS EXPOSURE/CONTACT: Corrosion of the upper respiratory
tract. FOLLOWING SYMPTOMS MAY APPEAR LATER: Possible laryngeal spasm/oedema.
Risk of pneumonia. Risk of lung edema. Respiratory difficulties.
Symptoms/effects after skin contact : Caustic burns/corrosion of the skin.
Symptoms/effects after eye contact : Corrosion of the eye tissue. Permanent eye damage.
Symptoms/effects after ingestion : Nausea. Abdominal pain. Blood in stool. Blood in vomit. Burns to the gastric/intestinal mucosa.
AFTER ABSORPTION OF LARGE QUANTITIES: Shock.
Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Red skin. Dry skin. Itching. Skin
rash/inflammation. Affection/discolouration of the teeth. Inflammation/damage of the eye tissue.
SECTION 12: Ecological information
12.1. Toxicity
Ecology - general : Classification concerning the environment: not applicable.

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Ecology - air : Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009).
Ecology - water : Mild water pollutant (surface water). Ground water pollutant. Maximum concentration in drinking
water: 250 mg/l (sulfate) (Directive 98/83/EC). Harmful to fishes. Harmful to invertebrates
(Daphnia). Toxic to plankton. pH shift. Inhibition of activated sludge.
LC50 fish 1 42 mg/l (LC50; 96 h)
EC50 Daphnia 1 29 mg/l (EC50; 24 h)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
Log Pow -2.2 (Estimated value)
Bioaccumulative potential Bioaccumulation: not applicable.
01/29/2018 EN (English US) 6/9

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Sulfuric Acid
Safety Data Sheet
SECTION 13: Disposal considerations
13.1. Disposal methods
Waste disposal recommendations : Remove waste in accordance with local and/or national regulations. Hazardous waste shall not
be mixed together with other waste. Different types of hazardous waste shall not be mixed
together if this may entail a risk of pollution or create problems for the further management of
the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or
handle hazardous waste shall take the necessary measures to prevent risks of pollution or
damage to people or animals. Recycle/reuse. Remove for physico-chemical/biological
treatment. Remove to an authorized dump (Class I). Treat using the best available techniques
before discharge into drains or the aquatic environment. Use appropriate containment to avoid
environmental contamination.
Additional information : LWCA (the Netherlands): KGA category 01. Hazardous waste according to Directive
2008/98/EC.
Ecology - waste materials : Avoid release to the environment.
Department of Transportation (DOT)
Transport document description : UN1830 Sulfuric acid (with more than 51 percent acid), 8, II
Proper Shipping Name (DOT) : Sulfuric acid
with more than 51 percent acid
Transport hazard class(es) (DOT) : 8 - Class 8 - Corrosive material 49 CFR 173.136
Packing group (DOT) : II - Medium Danger
Hazard labels (DOT) : 8 - Corrosive

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DOT Packaging Non Bulk (49 CFR 173.xxx) : 202
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Special Provisions (49 CFR 172.102) : A3 - For combination packaging, if glass inner packaging (including ampoules) are used, they
must be packed with absorbent material in tightly closed metal receptacles before packing in
outer packaging.
A7 - Steel packaging must be corrosion-resistant or have protection against corrosion.
B3 - MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks and
DOT 57 portable tanks are not authorized.
B83 - Bottom outlets are prohibited on tank car tanks transporting sulfuric acid in
concentrations over 65.25 percent.
B84 - Packaging must be protected with non-metallic linings impervious to the lading or have a
suitable corrosion allowance for sulfuric acid or spent sulfuric acid in concentration up to 65.25
percent.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
N34 - Aluminum construction materials are not authorized for any part of a packaging which is
normally in contact with the hazardous material.
T8 - 4 178.274(d)(2) Normal............. Prohibited
TP2 - a. The maximum degree of filling must not exceed the degree of filling determined by the
following: (image) Where: tr is the maximum mean bulk temperature during transport, tf is the
temperature in degrees celsius of the liquid during filling, and a is the mean coefficient of
cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and
the maximum mean bulk temperature during transportation (tr) both in degrees celsius. b. For
liquids transported under ambient conditions may be calculated using the formula: (image)
Where: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 C
(59 F) and 50 C (122 F), respectively.
TP12 - This material is considered highly corrosive to steel.
DOT Packaging Exceptions (49 CFR 173.xxx) : 154
DOT Quantity Limitations Passenger aircraft/rail : 1 L
(49 CFR 173.27)
01/29/2018 EN (English US) 7/9

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Sulfuric Acid
Safety Data Sheet
DOT Quantity Limitations Cargo aircraft only (49 : 30 L
CFR 175.75)
DOT Vessel Stowage Location : C - The material must be stowed ‘‘on deck only’’ on a cargo vessel and on a passenger vessel.
DOT Vessel Stowage Other : 14 - For metal drums, stowage permitted under deck on cargo vessels
Not subject to reporting requirements of the United States SARA Section 313
Subject to reporting requirements of United States SARA Section 313
RQ (Reportable quantity, section 304 of EPA's List of Lists) 1000 lb
SARA Section 302 Threshold Planning Quantity (TPQ) 1000 lb
SARA Section 311/312 Hazard Classes Health hazard - Skin corrosion or Irritation
Health hazard - Serious eye damage or eye irritation
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic
Substances Control Act (TSCA) inventory
Chemical(s) subject to the reporting requirements of Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of
1986 and 40 CFR Part 372.
Sulfuric Acid CAS-No. 7664-93-9 100%
CANADA

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EU-Regulations
National regulations
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
California Proposition 65 - This product does not contain any substances known to the state of California to cause
cancer, developmental and/or reproductive harm
Revision date : 01/23/2018
Full text of H-phrases: see section 16:
--- H314 Causes severe skin burns and eye damage
---
--- H318 Causes serious eye damage
---
NFPA health hazard : 3 - Materials that, under emergency conditions, can cause
serious or permanent injury.
NFPA fire hazard : 0 - Materials that will not burn under typical dire conditions,
including intrinsically noncombustible materials such as
concrete, stone, and sand.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
NFPA specific hazard : W - Materials that react violently or explosively with water.

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Sulfuric Acid
Safety Data Sheet
Hazard Rating
Health : 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is
given
Flammability : 0 Minimal Hazard - Materials that will not burn
Physical : 2 Moderate Hazard - Materials that are unstable and may undergo violent chemical changes at
normal temperature and pressure with low risk for explosion. Materials may react violently with
water or form peroxides upon exposure to air.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US LabChem
Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this
SDS. The user must determine suitability of this information for his application.

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He a lt h 1
0
Fire 0
1 0 Re a c t iv it
y 0
P e rs o n a l
P ro t e c t io E
n
Magnesium sulfate anhydrous MSDS
Product Name: Magnesium sulfate anhydrous Contact Information:

Catalog Codes: SLM2992, SLM2227
14025 Smith Rd.
RTECS: OM4500000 US Sales: 1-800-901-7247
TSCA: TSCA 8(b) inventory: Magnesium sulfate International Sales: 1-281-441-4400

anhydrous
CI#: Not available.
CHEMTREC (24HR Emergency Telephone),
call:
Synonym: 1-800-424-9300
Chemical Formula: MgSO4 International CHEMTREC, call: 1-703-527-3887
4400

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Composition:
Magnesium sulfate anhydrous 7487-88-9 100
Toxicological Data on Ingredients: Not applicable.
Hazardous in case of ingestion. Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of
inhalation.
available.
DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical
condition.
Eye Contact: Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold
water may be used.
Skin Contact:
After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin
with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold
water may be used. Cover the irritated skin with an emollient. If irritation persists, seek medical attention.

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p. 1

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Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Ingestion:
Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not
breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.
in
presence of static discharge: Not available.

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Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading
water on the contaminated surface and allow to evacuate through the sanitary system.
Precautions: No specific safety phrase has been found applicable for this product.
Storage:
No specific storage is required. Use shelves or cabinets sturdy enough to bear the weight of the chemicals. Be
sure that it is not necessary to strain to reach materials, and that shelves are not overloaded.
p.
2

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Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or
equivalent.
Gloves.
Physical state and appearance: Solid.
Odor: Not available.
Color: Not available.
pH (1% soln/water): Not available.
Boiling Point: Not available.
Melting Point: Not available.
Specific Gravity: Not available.

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Dispersion Properties: See solubility in water.
Solubility: Easily soluble in cold water.
Conditions of Instability: Not available.
Incompatibility with various substances: Not available.
Special Remarks on Reactivity: Not available.
Polymerization: No.

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p.
3

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Routes of Entry: Ingestion.
LD50: Not available. LC50: Not available.
Hazardous in case of ingestion. Slightly hazardous in case of skin contact (irritant), of inhalation.
Special Remarks on Chronic Effects on Humans: Human: passes through the placenta, excreted in maternal
milk.
Special Remarks on other Toxic Effects on Humans: Not available.
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are more toxic.

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Waste Disposal:
Federal and State Regulations: TSCA 8(b) inventory: Magnesium sulfate anhydrous
Other Regulations: Not available..
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
This product is not classified according to the EU regulations.
HMIS (U.S.A.):
Health Hazard: 1
Fire Hazard: 0
Reactivity: 0

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p.
4

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Health: 1
Flammability: 0
Reactivity: 0
Specific hazard:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Safety glasses.
Created: 10/10/2005 08:22 PM
Last Updated: 05/21/2013 12:00 PM

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Hydrogen, compressed
SECTION: 1. Product and company identification
Name : Hydrogen, compressed
CAS No : 1333-74-0
Formula : H2
Other means of identification : Dihydrogen, parahydrogen, refrigerant gas R702, water gas
Use of the substance/mixture : Industrial use. Use as directed.
Praxair, Inc.
10 Riverview Drive
Danbury, CT 06810-6268 - USA
T 1-800-772-9247 (1-800-PRAXAIR) - F 1-716-879-2146
www.praxair.com
Emergency number : Onsite Emergency: 1-800-645-4633
CHEMTREC, 24hr/day 7days/week
— Within USA: 1-800-424-9300, Outside USA: 001-703-527-3887

(collect calls accepted, Contract 17729)
SECTION 2: Hazard identification

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Flam. Gas 1 H220
Compressed gas H280
2.2. Label elements
GHS-US labeling
GHS02 GHS04
Signal word (GHS-US) : DANGER
Hazard statements (GHS-US) : H220 - EXTREMELY FLAMMABLE GAS
H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED

OSHA-H01 - MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION
CGA-HG04 - MAY FORM EXPLOSIVE MIXTURES WITH AIR CGA-HG08 -
BURNS WITH INVISIBLE FLAME
Precautionary statements (GHS-US) : P202 - Do not handle until all safety precautions have been read and understood
P210 - Keep away from Heat, Open flames, Sparks, Hot surfaces. - No smoking
P271+P403 - Use and store only outdoors or in a well-ventilated place
P377 - Leaking gas fire: Do not extinguish, unless leak can be stopped
safely P381 - Eliminate all ignition sources if safe to do so
CGA-PG05 - Use a back flow preventive device in the piping

CGA-PG10 - Use only with equipment rated for cylinder pressure
CGA-PG12 - Do not open valve until connected to equipment prepared for use
CGA-PG06 - Close valve after each use and when empty
CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52°C (125°F)

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2.3. Other hazards
classification
No data available
3.1. Substance
Name : Hydrogen, compressed
CAS No : 1333-74-0
Name Product identifier %
Hydrogen (CAS No) 1333-74-0 99.5 - 100
3.2. Mixture
Not applicable
First-aid measures after inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing. If not breathing,
give artificial respiration. If breathing is difficult, trained personnel should give oxygen. Call a
physician.
First-aid measures after skin contact : Adverse effects not expected from this product.
First-aid measures after eye contact
: Immediately flush eyes thoroughly with water for at least 15 minutes. Hold the eyelids open
and away from the eyeballs to ensure that all surfaces are flushed thoroughly. Contact an
ophthalmologist immediately.. Get immediate medical attention.
First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.

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None.
Suitable extinguishing media : Carbon dioxide, dry chemical powder, water spray, fog.
Fire hazard : EXTREMELY FLAMMABLE GAS. The hydrogen flame is nearly invisible. Hydrogen has a low
ignition energy; escaping hydrogen gas may ignite spontaneously. A fireball forms if the gas
cloud ignites immediately after release. Hydrogen forms explosive mixtures with air and
oxidizing agents.
Explosion hazard : EXTREMELY FLAMMABLE GAS. Forms explosive mixtures with air and oxidizing agents.
Reactivity : No reactivity hazard other than the effects described below.
Firefighting instructions : If venting or leaking gas catches fire, do not extinguish flames. Flammable vapors may spread
from leak, creating an explosive reignition hazard. Vapors can be ignited by pilot lights, other
flames, smoking, sparks, heaters, electrical equipment, static discharge, or other ignition
sources at locations distant from product handling point. Explosive atmospheres may linger.
Before entering an area, especially a confined area, check the atmosphere with an appropriate
device
Evacuate all personnel from the danger area. Use self-contained breathing apparatus (SCBA)
and protective clothing. Immediately cool containers with water from maximum distance. Stop
flow of gas if safe to do so, while continuing cooling water spray. Remove ignition sources if
safe to do so. Remove containers from area of fire if safe to do so. On-site fire brigades must
comply with OSHA 29 CFR 1910.156 and applicable standards under 29 CFR 1910 Subpart
L—Fire Protection.

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Protection during firefighting : Compressed gas: asphyxiant. Suffocation hazard by lack of oxygen.
Special protective equipment for fire fighters : Standard protective clothing and equipment (Self Contained Breathing Apparatus) for fire
fighters.
Specific methods : Use fire control measures appropriate for the surrounding fire. Exposure to fire and heat
radiation may cause gas containers to rupture. Cool endangered containers with water spray jet
General measures from a protected position. Prevent water used in emergency cases from entering sewers and
drainage systems
Stop flow of product if safe to do so
Use water spray or fog to knock down fire fumes if possible.
: DANGER: EXTREMELY FLAMMABLE GAS. Forms explosive mixtures with air and
oxidizing agents. See section 5. Evacuate personnel to a safe area. Appropriate self-
contained breathing apparatus may be required. Approach suspected leak area with caution.
Remove all sources of ignition. if safe to do so. Reduce gas with fog or fine water spray.
Stop flow of product if safe to do so. Ventilate area or move container to a well-ventilated
area. Flammable gas may spread from leak. Before entering the area, especially a confined
area, check the atmosphere with an appropriate device.
Prevent waste from contaminating the surrounding environment. Prevent soil and water pollution.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Contact supplier for any special requirements.

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See also sections 8 and 13.
SECTION 7: Handling and

storage
Precautions for safe handling : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Use only non-sparking tools. Use only explosion-proof equipment
Wear leather safety gloves and safety shoes when handling cylinders. Protect cylinders from
physical damage; do not drag, roll, slide or drop. While moving cylinder, always keep in place
removable valve cover. Never attempt to lift a cylinder by its cap; the cap is intended solely to
protect the valve. When moving cylinders, even for short distances, use a cart (trolley, hand
truck, etc.) designed to transport cylinders. Never insert an object (e.g, wrench, screwdriver,
pry bar) into cap openings; doing so may damage the valve and cause a leak. Use an
adjustable strap wrench to remove over-tight or rusted caps. Slowly open the valve. If the valve
is hard to open, discontinue use and contact your supplier. Close the container valve after
each use; keep closed even when empty. Never apply flame or localized heat directly to any
part of the container. High temperatures may damage the container and could cause the
pressure relief device to fail prematurely, venting the container contents. For other precautions
in using this product, see section 16.

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Storage conditions : Store only where temperature will not exceed 125°F (52°C). Post “No Smoking/No Open
Flames” signs in storage and use areas. There must be no sources of ignition. Separate
packages and protect against potential fire and/or explosion damage following appropriate
codes and requirements (e.g, NFPA 30, NFPA 55, NFPA 70, and/or NFPA 221 in the U.S.) or
according to requirements determined by the Authority Having Jurisdiction (AHJ). Always
secure containers upright to keep them from falling or being knocked over. Install valve
protection cap, if provided, firmly in place by hand when the container is not in use. Store full
and empty containers separately. Use a first-in, first-out inventory system to prevent storing full
containers for long periods. For other precautions in using this product, see section 16
OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE: When handling product
under pressure, use piping and equipment adequately designed to withstand the pressures to
be encountered. Never work on a pressurized system. Use a back flow preventive device in the
piping. Gases can cause rapid suffocation because of oxygen deficiency; store and use with
adequate ventilation. If a leak occurs, close the container valve and blow down the system in a
safe and environmentally correct manner in compliance with all international, federal/national,
state/provincial, and local laws; then repair the leak. Never place a container where it may
become part of an electrical circuit.
None.
SECTION 8: Exposure controls/personal

protection
Hydrogen, compressed (1333-74-0)
ACGIH Not established
USA OSHA Not established
Hydrogen (1333-74-0)

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ACGIH Remark (ACGIH) Simple asphyxiant
USA OSHA Not established
Appropriate engineering controls : Use an explosion-proof local exhaust system. Local exhaust and general ventilation must be
adequate to meet exposure standards. MECHANICAL (GENERAL): Inadequate - Use only in
a closed system. Use explosion proof equipment and lighting.
Eye protection : Wear safety glasses with side shields.
Respiratory protection : An air-supplied respirator must be used while working with this product in confined spaces. The
respiratory protection used must conform with OSHA rules as specified in 29 CFR 1910.134.
Select per OSHA 29 CFR 1910.134 and ANSI Z88.2.
Thermal hazard protection : None necessary.
Other information : Consider the use of flame resistant anti-static safety clothing. Wear safety shoes while handling
containers.
Physical state : Gas
Appearance : Colorless gas.
Molecular mass : 2 g/mol
Color : Colorless.
Odor : Odorless.
Odor threshold : No data available
pH : Not applicable.
Relative evaporation rate (butyl acetate=1) : No data available
Relative evaporation rate (ether=1) : Not applicable.
Melting point : -259.2 °C (-434.56°F)

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Boiling point : -252.9 °C (-422.97°F)
Flash point : No data available
Critical temperature : -239.9 °C (-399.82°F)
Auto-ignition temperature : 566 °C (1051°F)
Decomposition temperature : No data available
Vapor pressure : Not applicable.
Relative vapor density at 20 °C : No data available
Relative density : No data available
Density : 0.089 g/l (0.0056 lb/ft3) (at STP = 0°C and 1atm)
Relative gas density : 0.07
Solubility : Water: 1.6 mg/l
Log Pow : Not applicable.
Log Kow : Not applicable.
Viscosity, kinematic : Not applicable.
Viscosity, dynamic : Not applicable.
Explosive properties : Not applicable.
Oxidizing properties : None.
Explosion limits : 4 - 77 vol %
Gas group : Compressed gas
Additional information : BURNS WITH INVISIBLE FLAME
10.1. Reactivity
No reactivity hazard other than the effects described below.

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Can form explosive mixture with air. May react violently with oxidants.
Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
Oxidizing agents. Lithium. Halogens.
Under normal conditions of storage and use, hazardous decomposition products should not be
produced.
Hydrogen, compressed ( \f )1333-74-0
LC50 inhalation rat (ppm) > 15000 ppm/1h
LC50 inhalation rat (ppm) > 15000 ppm/1h

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pH: Not applicable.
pH: Not applicable.
exposure)

information
12.1. Toxicity
Ecology - general : No ecological damage caused by this product.
BCF fish 1 (no bioaccumulation expected)

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Log Pow Not applicable.
BCF fish 1 (no bioaccumulation expected)
Log Pow Not applicable.
Effect on ozone layer : None
Effect on the global warming : No known effects from this product

considerations
Waste disposal recommendations : Dispose of contents/container in accordance with local/regional/national/international
regulations. Contact supplier for any special requirements.

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Transport document description : UN1049 Hydrogen, compressed, 2.1
Proper Shipping Name (DOT) : Hydrogen, compressed
Class (DOT) : 2.1 - Class 2.1 - Flammable gas 49 CFR 173.115
Hazard labels (DOT) : 2.1 - Flammable gas
DOT Special Provisions (49 CFR 172.102) : N89 - When steel UN pressure receptacles are used, only those bearing the “H” mark are
authorized
Emergency Response Guide (ERG) Number : 115 (UN1049)
Special transport precautions : Avoid transport on vehicles where the load space is not separated from the driver's
compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows
what to do in the event of an accident or an emergency. Before transporting product containers:
- Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure
cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided)
is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.
Transport by sea
Proper Shipping Name (IMDG) : HYDROGEN, COMPRESSED
Class (IMDG) : 2 - Gases
MFAG-No : 115
Air transport
UN-No. (IATA) : 1049

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Proper Shipping Name (IATA) : Hydrogen, compressed
Class (IATA) : 2
Civil Aeronautics Law : Gases under pressure/Gases flammable under pressure
SARA Section 311/312 Hazard Classes Sudden release of pressure hazard
Fire hazard
All components of this product are listed on the Toxic Substances Control Act (TSCA)
inventory.
This product or mixture does not contain a toxic chemical or chemicals in excess
of the applicable de minimis concentration as specified in 40 CFR §372.38(a)
subject to the reporting requirements of section 313 of Title III of the Superfund
Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.

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CANADA
EU-Regulations
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on INSQ (Mexican National Inventory of Chemical Substances)

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Hydrogen, compressed(1333-74-0)
U.S. - California - Proposition 65 - Carcinogens List No
U.S. - California - Proposition 65 - Developmental No
Toxicity
Toxicity - Female
Toxicity - Male
State or local regulations U.S. - Massachusetts - Right To Know List
California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer,
developmental and/or reproductive harm
U.S. - California - U.S. - California - U.S. - California - U.S. - California - Non-significant risk level
Proposition 65 - Proposition 65 - Proposition 65 - Proposition 65 - (NSRL)
Carcinogens List Developmental Toxicity Reproductive Toxicity - Reproductive Toxicity - Male
Female
No No No No
U.S. - Massachusetts - Right To Know List

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Other information : When you mix two or more chemicals, you can create additional, unexpected hazards. Obtain
and evaluate the safety information for each component before you produce the mixture.
Consult an industrial hygienist or other trained person when you evaluate the end
product. Before using any plastics, confirm their compatibility with this product
Praxair asks users of this product to study this SDS and become aware of the product hazards
and safety information. To promote safe use of this product, a user should (1) notify
employees, agents, and contractors of the information in this SDS and of any other known
product hazards and safety information, (2) furnish this information to each purchaser of the
product, and (3) ask each purchaser to notify its employees and customers of the product
hazards and safety information
The opinions expressed herein are those of qualified experts within Praxair, Inc. We believe
that the information contained herein is current as of the date of this Safety Data Sheet. Since
the use of this information and the conditions of use are not within the control of Praxair, Inc, it
is the user's obligation to determine the conditions of safe use of the product
Praxair SDSs are furnished on sale or delivery by Praxair or the independent distributors and
suppliers who package and sell our products. To obtain current SDSs for these products, contact
your Praxair sales representative, local distributor, or supplier, or download from www.praxair.com.
If you have questions regarding Praxair SDSs, would like the document number and date of the
latest SDS, or would like the names of the Praxair suppliers in your area, phone or write the
Praxair Call Center (Phone: 1-800-PRAXAIR/1-800-772-9247; Address: Praxair Call Center,
Praxair, Inc, P.O. Box 44, Tonawanda, NY 14151-0044)
PRAXAIR and the Flowing Airstream design are trademarks or registered trademarks of Praxair
Technology, Inc. in the United States and/or other countries.
NFPA health hazard : 0 - Exposure under fire conditions would offer no hazard
beyond that of ordinary combustible materials.
NFPA fire hazard : 4 - Will rapidly or completely vaporize at normal pressure
and temperature, or is readily dispersed in air and will burn
readily.
HMIS III Rating

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Health : 0 Minimal Hazard - No significant risk to health
Flammability : 4 Severe Hazard
Physical : 3 Serious Hazard
SDS US (GHS HazCom 2012) - Praxair
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as
guaranteeing any specific property of the product.

CHERNIVAL 2018
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CHERNIVAL 2018
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Job Safety Assessment Form

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Since ‘Design for Safety’ is one of the key factors in the

competition, we would like you to complete the attached Job

Job Safety Assessment Form

University: Diponegoro University

Faculty Supervisor: Prof. Dr. Widayat, S.T., M.T.

Purpose of Experiment / Equipment: Briefly describe your

Describe your car’s design:

7th INDONESIA CHEM-E-CAR COMPETITION

Material Amount Price

7th INDONESIA CHEM-E-CAR COMPETITION

Component Amount Price

So, the sum of all prices is IDR 545,106

7th INDONESIA CHEM-E-CAR COMPETITION

7th INDONESIA CHEM-E-CAR COMPETITION

Hazards inherent in design:

Expected Operating Conditions:

Personal Protective Equipment (PPE) : Check all PPE worn

7th INDONESIA CHEM-E-CAR COMPETITION

Long Sleeves Splash Insulated Ear

Non-Porous Face Shield Chemical Other:

This page applies to your home institution – not the

Available Safety Equipment – Provide the location of each item

7th INDONESIA CHEM-E-CAR COMPETITION

Eyewash: In the middle of sink and oxygen tank

Safety Shower: Beside the sink

Telephone: In the next room above the assistant laboratory’s desk

First Aid Kit: Hanging near the assistant laboratory’s room

Spill Beside fire extinguisher

Spill Response Supplies - Provide the location of each item

Spill Kit: Beside fire extinguisher

Floor-Dri: Near the rack of chemical tool

Sodium inside of the chemical showcase

Spill Pillows: Inside of the spill-kit box

Mercury Spill Kit: NA

7th INDONESIA CHEM-E-CAR COMPETITION

Hazard Present During Control Method(s)1 PPE Required1

7th INDONESIA CHEM-E-CAR COMPETITION

7th INDONESIA CHEM-E-CAR COMPETITION

7th INDONESIA CHEM-E-CAR COMPETITION

7th INDONESIA CHEM-E-CAR COMPETITION

(d) Chemical Any chemicals with an NFPA rating of 2 or greater.

(e) Regulated A number of chemicals are listed by OSHA as a special

(f) Highly Reactive Any chemical, raw material, intermediate or product

(g) Hydrogen Hydrogen peroxide at concentrations of greater than

7th INDONESIA CHEM-E-CAR COMPETITION

(b) Toxic Any chemicals with an NFPA toxicity of 2 or greater?

(c) Any chemicals with an NFPA flammability rating of 2 or

(d) Reactive Any chemicals with an NFPA instability / reactivity rating

(e) Any exposed surface greater than 150 deg. F or under

7th INDONESIA CHEM-E-CAR COMPETITION

(g) Any fast moving parts (meshing gears, belts or chains)

(h) Oxygen All components exposed to oxygen must be

(i) No biohazards greater than biohazard level 1 either

Chemical Information Page

7th INDONESIA CHEM-E-CAR COMPETITION

KMnO4 (Potassium Solid 23,7 gram 100 gram

Glycerin Liquid 50 ml 150 ml

Aquadest Liquid 150 ml 500 ml

H2SO4 (Sulfuric Acid) Liquid 0,05 M 100 ml

Dry Ice Solid 150 gram 2 kg

Chemical Properties and Hazards for ALL CHEMICALS, including reactants,

7th INDONESIA CHEM-E-CAR COMPETITION

7th INDONESIA CHEM-E-CAR COMPETITION