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    set chemistry

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    SET15-Chemical Sciences -P III-A West Bengal 2015

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    set chemistry

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    © All Rights Reserved
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    Download as pdf
    14 views16 pages

    SET15-Chemical Sciences - P III-A West Bengal 2015

    Uploaded by

    Deepan Kumar
    set chemistry

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    Download as pdf
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    Roll No. LEEP EEL) Signature of Invigilators Ro (Waite Roll Number from left side exactly atin the Admit Card) 2 (1215) Question Booklet Series | A PAPER-II Question Booklet Ne Subject Code : 12 OMR Sheet No. {Fo be filled by the CHEMICAL SCIENCES Candle) Time : 2 Hours 30 Minutes ‘Maximum Marks: 150 Instructions for the Candidates 1. Write your Roll Number in the space provided on the top of this page as well as on the OMR Sheet provided. 2. At the commencement of the examination, the question booklet will be given to you. In the first 5 minutes, you are requested (0 open the booklet and verify it (@ To have access to the Question Booklet, tear off the paper seal on the edge of this cover page. (i) Faulty booklet, if detected, should be got replaced immediately by a correct booklet from the invigilator within the period of $ minutes. Afterwards, neither the Question Booklet will be replaced nor any extra time will be given. (Gli) After this verification is over, the Question Booklet Series and Question Booklet Number should be entered on the OMR Sheet and the OMR Sheet Number should be entered on this Question Booklet. 3. This paper consists of seventy-five (75) multiple-choice type questions, All the questions are compulsory. Each question carries two marks. 4, Bach Question has four altemative responses marked (@) (B) © (B). You have to daken the cicle as indicated below on the correct response agtins each question Example. @® W @ ©) where © is the comet response 5. Your responses to the questions are to be indicated correctly in the OMR Sheet. If you mark your response at any place other than in the circle in the OMR Sheet, it will not be evaluated, 6. Rough work is to be done at the end of this booklet. 7. If you write your Name, Roll Number, Phone Number or put any mark on any part of the OMR Sheet, except for the space allotted for the relevant entries, which may disclose your identity, or use abusive language or employ any other unfair means, such as change of response by scratching or using white fluid, you will render yourself liable to disqualification. Do not tamper or fold the OMR Sheet in any way. If you do so, your OMR Sheet will not be evaluated. You have to retum the Original OMR Sheet to the invigilator at the end of the examination compulsorily and must not carry it with you outside the Examination Hall. You are, however, allowed to carry question booklet and duplicate copy of OMR Sheet after completion of examination. 10. Use only Blue/Black Ball point pen. 11. Use of any calculator or log table or mobile phone ete. is strictly prohibited. 12, There are no negative marks for incorrect answers. [ Please Turn Over ] AB 1215-1 (CHEMICAL SCIENCES Paper IIL L. Identify the major product (P) formed in the following sequence of reactions ro 1. NaBH - CC1,7H,0 GOH / 10 seo; ane oo See . > \ | Oo 2. Predict the structure of products (Pand Q) formed, in the following sequence of reactions Se0: if tens rma 3. An organic compound exhibited the following 'H and °C NMR spectral data: "HNMR: 8,,24 (8), 7-2 (d, J= 8 Hz), 71 (4, J=8 Hz), EC NMR: 6, 21-0, 129-0, 1300, 136-0, 141-0, 190-0 The structure of the compound is 4. In the following sequence of reactions, the structure of compounds (P and Q) formed are SS P= oe (©) P= CL , OL we [ Please Turn Over ] 1218-1 5, Predict the structure of compounds X and Y formed in the following sequence of reactions AA, if : Litg(@A6),in ap eae wx- OL and ¥ = db ~ 6. Consider the following reaction sequence and identify the major product ‘P” OL Lacs, 2c, cor cH, “ ® (ale ocwcns ele ©, hgh on oct, 7. Consider the following reactions Which one among the sowing is comrect? » AA ¥ cy) 2 (D) Both X’ and “Y' = 8. The major product in the following reaction is «@ @B) © ©) AS 9. Identify the major product from amongst the choices given below in the following reaction sequence ° Ay my” “0 i 1. Nall wh o CLA wi EAD “~ “A © AK ° 0D) nN A ii, A 10. Which statement amongst the following regarding kinetic isotope effect observed for nitration (HNO /H, SO, of benzene and foriodination (1/NaOH) of phenol is correct?” “ 2) aivation thenene > 1S iodination of phenol nitration of enzene AF 5 2 1215-1 LL. Identify the major product in the following reaction: 12. The correct IUPAC nomenclature for the following compound is (A) 10~[5}-annulene (B) 10~[10}-annulene (©) 10-[18}-annulene (D) 10~(20}-annulene 13. The number of possible products from the allylic bromination of the following cyclohexene (X) with N-bromosuccinimide (NBS) is O ow (3 @)4 ©2 M1 [ Please Turn Over ] 1215-1 AG 14. An aromatic compound C,H, Cl, (X) gives AgCl with alcoholic AgNO, solution and yields C,H,OCI on treatment with NaOH. Compound gives monochlorobenzoic acid. The correct structure of compound “X” is, O “X” on oxidation ay a (B) a ou cua, ) Oo “ D OG 15. In the following reaction sequence, the major product is 9 ow (a) 1 Me MgCl/ CuCl 16. Consider the following reaction sequence and identify the major product: Ho LN, a PPR, THT "GNaBH,CN OO eC Cre OF © cK 17. Inthe following asymmetric synthesis, the major product is: om 18. Consider the following reaction and identify the major product fo \ A Btotune 2 ZaT HORS ANG 19. ‘The major product in the following reaction is Lor y 1 pee 20, Predict the product obtained in the following sequence of reactions COM 1.1, Faq, NaHCO, 2baw 3. mCPBA 3b 21. Inthe following sequence of reactions predict the major product formed 1. MeMal He 3. mCPBA 22. The major product formed in the following reaction sequence is 1. AX coMetbe, Saliba 1 2 AT 1215-1 23. In the following sequence of reactions oH Sc crc cath, plOvd « OQ) + CH,CH,CH,CL RES 84 the correct structure of compounds R and $ are respectively ® 24, Reagents that can be used in the following conversion are COM a“ : cHO a oe (A) (i) Ph,P = CH, (ii) HCN, (iii) HO. Oo ®) @HS (CH),SH, Gi)» Buti, (ai) BrCH,COOH © @ BMegr, Gi) KMn0, ©) (@Ph,P, CBr,, Gi) n-BuLi, (ii) CO,., @ Gv) HO [ Please Turn Over ] 1218-1 AS 25, In the following two-step reaction sequence, the major product Q is F I 2H0® gout foo wh xo, Nos No, No; 26. In the nuclear reaction 1 1 n—— pt? 0 1 ‘The missing particle is (A) HT @) Yray © fe @) Je 27. A radioactive nucleous ***Th disintegrates to give 2°Po as the final product How many o and 6 particles are emitted during this process? (A) 6 mand 7B (B) Taand 8p (C) Taand7B (D) 6 mand 6B 28, "The Square pyramidal molecular shapeis adopted by (A) SOF, (B) XeOF, © seocl, (D) PES 29. ‘The number of pairs of framework electrons in the closo borane [B, H,)? is (A) n4t (B) n+2 (© 243 @) +4 30. The correct order of Stability in water is (A) Lil < Nal Nal > KI> CSI (C) CSI> Lil > Nal > KI (D) Lil > Nal

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