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    曾瑋富
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    1. The document describes a mechanism for the thermal decomposition of acetaldehyde involving 6 elementary reactions. It asks to apply the steady state approximation to CH4 to obtain the rate equation. 2. It describes a series of elementary reactions A -> R -> S and asks to (a) plot the variation of concentrations over time and (b) find the maximum concentration of R and when it occurs. 3. It describes a mechanism for the oxidation of nitrogen over a catalyst involving two steps and asks to (a) calculate the rate expression for N2O formation using steady state approximation and (b) recalculate the rate expression assuming the first step is rate determining.

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    1. The document describes a mechanism for the thermal decomposition of acetaldehyde involving 6 elementary reactions. It asks to apply the steady state approximation to CH4 to obtain the rate equation. 2. It describes a series of elementary reactions A -> R -> S and asks to (a) plot the variation of concentrations over time and (b) find the maximum concentration of R and when it occurs. 3. It describes a mechanism for the oxidation of nitrogen over a catalyst involving two steps and asks to (a) calculate the rate expression for N2O formation using steady state approximation and (b) recalculate the rate expression assuming the first step is rate determining.

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    © All Rights Reserved
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    4 views1 page

    作業2 20170323

    Uploaded by

    曾瑋富
    1. The document describes a mechanism for the thermal decomposition of acetaldehyde involving 6 elementary reactions. It asks to apply the steady state approximation to CH4 to obtain the rate equation. 2. It describes a series of elementary reactions A -> R -> S and asks to (a) plot the variation of concentrations over time and (b) find the maximum concentration of R and when it occurs. 3. It describes a mechanism for the oxidation of nitrogen over a catalyst involving two steps and asks to (a) calculate the rate expression for N2O formation using steady state approximation and (b) recalculate the rate expression assuming the first step is rate determining.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as docx, pdf, or txt
    of 1

    1.

    A mechanism for the thermal decomposition of acetaldehyde


    CH 3 CHO 
    k1
    CH 3*  CHO *
    CHO * 
    k2
    CO  H *
    H *  CH 3 CHO 
    k3
    CH 3 CO*  H 2
    CH 3*  CH 3 CHO 
    k4
    CH 4  CH 3 CO*
    CH 3 CO* 
    k5
    CH 3*  CO
    2CH 3* 
    k6
    C2 H 6
    Apply the steady state approximation to CH4 to obtain the rate equation.

    2. For the elementary reactions in series

    k1 k2
    A R S
    at t=0, CA=CA0, CB0=CS0=CR0=0
    k3
    B
    (a) Plot a figure to illustrate the variation of concentration of A, B, R
    and S versus reaction time t.
    (b) Find the maximum concentration of R and when it’s reached.

    3. The oxidation of nitrogen over a certain catalyst is found to follow the


    following mechanisms:

    O2 2Oads (1)

    N2 + Oads N2O (2)

    (a) Calculate the rate expression for N2O formation using the steady
    state approximation. (Note: assume for this problem only that step
    (1) is irreversible, O2 2Oads
    (b) Assume that (1) in the above mechanism is the rate determining
    step, and recalculate the rate expression for N2O formation.

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