After a bit of hunting around the Internet and doing some research of my own I found that the

service http.sys was the culprit and all I needed to do was disable it but I could not find this
service listed in the Services control panel applet. So what’s the solution?

You have to disable the http.sys service manually via the registry:

1) Launch RegEdit:

2) Go to: HKEY_LOCAL_MACHINE\SYSTEM\CurrentControlSet\Services\HTTP

3) Add a new DWORD (32-bit) value

4) Name it ‘NoRun’ not including the quotes

5) Double click the new property

6) In the Value data field type ’1′ not including quotes and click OK

7) Re-boot your computer

You should now find that Apache will start on port 80!