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Cumene Production (Group 11) - Individual Task (Separator)
Cumene Production (Group 11) - Individual Task (Separator)
Evaluated by:
_______________________________________
Date:
INDIVIDUAL REPORT
55213114011
S01 - SEPARATOR
1. INTRODUCTION
The goal of this design process is to produce cumene product at 100,000 metric tons per year
with a purity of at least 99.5 mol%. The mechanism for production of cumene in this process is
by the Friedel-Crafts alkylation of benzene with propylene. A secondary reaction involved in
this process is the formation of a byproduct, p-diisopropylbenzene (DIPB), from propyleneand
cumene. If the purity of DIPB exceeds 98 mol%, the byproduct can be sold for profit.
The separation of cumene from this mixture involves a multistage distillation process. This
appendix provides the detailed separation process for cumene purification, the approach behind
the design, and an overall cost analysis for the separation portion of cumene production.
MASS BALANCE
P, Pr
B, P, Pr, C
and DIPB
𝐵8 = 𝐵7 − (𝐵𝑅𝑒𝑎𝑐𝑡𝑒𝑑 ) 13 B, C, DIPB
𝐵8 = 𝐵7 − (𝑃𝑅𝑒𝑎𝑐𝑡𝑒𝑑 )
𝐵8 = 222.548387 − (110.1614516)
𝑘𝑚𝑜𝑙
𝐵8 = 112.3869354
ℎ𝑟
2
𝐷8 = 33 × 110.1614516
𝑘𝑚𝑜𝑙
𝐷8 = 6.676451612
ℎ𝑟
31
𝐶8 = ( × 110.1614516) + 𝐶7
33
31
𝐶8 = ( × 110.1614516) + 2.17449264
33
𝐶8 = (103.485) + 2.17449264
𝑘𝑚𝑜𝑙
𝐶8 = 105.6594926
ℎ𝑟
𝑃8 = 𝑃7 − (𝑃7 × 99%)
𝑘𝑚𝑜𝑙
𝑃8 = 1.112741935
ℎ𝑟
Table 5.7: Molar fraction of each components in the streams in the separator (S01).
Stream 11 12 13
Benzene (mol B/ mol 0.499 - 0.512
Total)
Propylene (mol P/ mol 0.005 0.16 -
Total)
Propane (mol Pr/ mol 0.025 0.84 -
Total)
Cumene (mol C/ mol 0.456 - 0.470
Total)
DIPB (mol D/ mol 0.015 - 0.018
Total)
Mw 11 12 13
vapor outlet
1 ft
6"
dN = 0.3474 in
inlet feed
HT= 130.6274 ft
HLIN = 12.3474 in
HLL
Hs= 38.71 ft
Hs
NLL
HH= 77.50 ft
LLL
HLLL= 15"
Liquid outlet
3. SPECIFICATION DATASHEET
DATE : 15
IDENTIFICATION: SEPARATOR COLUMN JUNE 2017
NO REQUIRED: 1
OPERATION: CONTINUOS
DETAIL SPECIFICATION
HLLL : 15 inch
= 0.387 kg/m3
= 1.98 kg/m3
= 0.1478 lb/ft3
= 411.55 kg/m3
= 374.03 kg/m3
= 15.426 kg/m3
= 50.005 lb/ft3
Settling velocity
𝜌𝑙 −𝜌𝑣 1
𝑢𝑡 = 0.07[ 𝜌𝑣
]2
Where;
𝜌𝐿 = 801.006 𝑘𝑔/𝑚3
𝜌𝑉 = 2.367 𝑘𝑔/𝑚3
801.006−2.367 1
𝑢𝑡 = 0.07[ 2.367
]2
𝑢𝑡 = 1.286 𝑚/𝑠
𝑢𝑠 = 0.15 × 1.286 𝑚/𝑠
= 0.193 m/s
= 0.6332 ft/s
= 𝟎. 𝟎𝟑𝟓𝟖 𝒎𝟑 /𝒔
= 𝟏. 𝟐𝟔𝟒𝟑 𝒇𝒕𝟑 /𝒔
Vertical separator
𝟒 𝑽𝒗
𝑫𝒗 = √( )
𝝅𝒖𝒔
𝟒 (𝟎.𝟎𝟑𝟓𝟖)
= √( )
𝝅(𝟎.𝟏𝟗𝟑)
= 𝟎. 𝟓 𝒎
= 𝟏. 𝟔𝟒 𝒇𝒕
= 𝟕. 𝟕𝟐𝟗 × 𝟏𝟎−𝟑 𝒎𝟑 /𝒔
= 𝟎. 𝟐𝟕𝟑 𝒇𝒕𝟑 /𝒔
Allow a minimum of 10 minutes hold up
= 𝟒. 𝟔𝟑𝟕𝟒 𝒎𝟑
= 𝟏𝟔𝟑. 𝟕𝟓 𝒇𝒕𝟑
Volume surge
= 𝟐. 𝟑𝟏𝟖𝟕 𝒎𝟑
= 𝟖𝟏. 𝟖𝟕 𝒇𝒕𝟑
HLLL = 15 inch
163.75𝑓𝑡 3
= 𝜋
( ×1.642 )
4
= 𝟕𝟕. 𝟓𝟎 𝒇𝒕
81.87 𝑓𝑡 3
= 𝜋
( ×1.642 )
4
= 𝟑𝟖. 𝟕𝟏 𝒇𝒕
Liquid inlet, HLIN
12 + dN
Where;
4 𝑄𝑚 1
dN ≥ [ 𝜋60 ]2
√𝜌𝑚
𝑄𝑚 = 𝑄𝑙 + 𝑄𝑣
𝑄𝑚 = 0.273 + 1.2643
= 1.5373 ft3/s
𝜌𝑚 = 𝜌𝑚 ⋋ +𝜌𝑣 (1 − ⋋)
𝑄𝑙
⋋= 𝑄𝑙 − 𝑄𝑣
0.273
⋋ = |0.273 − 1.2643 |
⋋ = 0.2754
𝜌𝑚 = 50.005(0.2754) + 0.1478 (1 − 0.2754)
= 13.88
4 (1.5373) 1
dN = [ 𝜋60 ]2
√13.88
= 0.3474
HLIN = 12 + dN
= 12.3747 ft
Disengagement height, HD
HD = 0.5 (Dv)
= 0.82 ft
Height tank, HT
= 130.6274 ft
REFERENCES
Design Two Phase Separators Within the Right Limits_CEP Oct 1993.pdf. (n.d.).
Monnery, D., & Svrcek, Y. (n.d.). Successfully Specify Separators, (l), 29–40.
Practice, E. (2007). MANUAL GAS / LIQUID SEPARATORS - TYPE SELECTION AND DESIGN RULES,
2007(December).
Towler, G., & Sinnott, R. A. Y. (n.d.). CHEMICAL ENGINEERING Principles , Practice and Economics of
Plant and Process Design.