Chapter 23 Separations

◼ #1

Printed by Wolfram Mathematica Student Edition

2 Sapling.nb

◼ #2

◼ #3

Printed by Wolfram Mathematica Student Edition

Sapling.nb 3

Part a

7.6 - 3.8
3.8

1.

Part b

3.8
7.6

0.5

Part c

vm
k /. {k → 1, vs → 0.1 vm}
vs

10.

◼ #4

Printed by Wolfram Mathematica Student Edition

4 Sapling.nb

T 2
Na ⩵ 16 /. {T → 5.17, W → 0.446}
W

Na ⩵ 2149.96

T 2
Nb ⩵ 16 /. {T → 13.2, W → 1.07}
W

Nb ⩵ 2435.01

T 2
Nc ⩵ 16 /. {T → 14.2, W → 1.17}
W

Nc ⩵ 2356.81

T 2
Nd ⩵ 16 /. {T → 23.2, W → 1.82}
W

Nd ⩵ 2599.88

1
Average ⩵ 2149.96480 + 2435.00742 + 2356.81203 + 2599.87924
4

Average ⩵ 2385.42

L
H⩵ /. {L → 50, Average → 2385.415872}
Average

H ⩵ 0.0209607

Printed by Wolfram Mathematica Student Edition

Sapling.nb 5

◼ #5

196.4 - 38.1
k⩵
38.1

k ⩵ 4.15486

vm
KK ⩵ k /. {k → 4.15485564304462`, vm → 7 vs}
vs

KK ⩵ 29.084

Printed by Wolfram Mathematica Student Edition

6 Sapling.nb

◼ #6

◼ #7

Printed by Wolfram Mathematica Student Edition

Sapling.nb 7

◼ #8

Part a

tprA ⩵ 12.42 - 1.070

tprA ⩵ 11.35

Printed by Wolfram Mathematica Student Edition

8 Sapling.nb

tprA
/. tprA → 11.35`
1.070

10.6075

tprB ⩵ 13.18 - 1.070

tprB ⩵ 12.11

tprB
/. tprB → 12.11`
1.070

11.3178

Part b

tprB
α⩵ /. {tprA → 11.35`, tprB → 12.11`}
tprA

α ⩵ 1.06696

Part c

trA 2
Na ⩵ 5.55 /. {trA → 12.42, w → 0.145}
w

Na ⩵ 40 719.3

L
Ha ⩵ /. {L → 30, Na → 40719.28751486326`}
Na

Ha ⩵ 0.000736752

trB 2
Nb ⩵ 5.55 /. {trB → 13.18, w → 0.286}
w

Nb ⩵ 11 786.7

L
Hb ⩵ /. {L → 30, Nb → 11786.686635043281`}
Nb

Hb ⩵ 0.00254524

Part d

Printed by Wolfram Mathematica Student Edition

Sapling.nb 9

Na Nb
Resolution ⩵ α - 1 /.
4
13.18
α→ , Na → 40719.28751486326`, Nb → 11786.686635043281`
12.42

Resolution ⩵ 2.26428

◼ #9

Printed by Wolfram Mathematica Student Edition

10 Sapling.nb

Chapter 23 Band Broadening

◼ #1

20 - tm
α⩵ /. tm → 1.75 // N
15 - tm

α ⩵ 1.37736

Printed by Wolfram Mathematica Student Edition

Sapling.nb 11

◼ #2

◼ #3

2 Nu
r2 γ-1
4
Solve ⩵ , r2
r1 Nu
γ-1
4

r2 → 2 r1

Printed by Wolfram Mathematica Student Edition

12 Sapling.nb

◼ #4

11 Nu α-1 k2 5.91
Solve r ⩵ , Nu /. r → 1.79, α → , k2 → 5.91
4 α 1 + k2 5.67

{{Nu → 3863.38}}

L
H⩵ /. L → 0.25 × 106 , Nu → 3863.375939646464`
Nu

H ⩵ 64.7102

3 Nu α-1 k2 5.91
r⩵ /. Nu → 3863.375939646464`, α → , k2 → 5.91
4 α 1 + k2 5.67

r ⩵ 0.934797

Printed by Wolfram Mathematica Student Edition

Sapling.nb 13

◼ #5

◼ #6

Part a

175 - tm
α⩵ /. tm → 26.9 // N
108.7 - tm

α ⩵ 1.81051

Printed by Wolfram Mathematica Student Edition

14 Sapling.nb

Part b

108.7 - tm tcaffeine - tm
Solve 0.72 ⩵ /. tm → 26.9 // Quiet
tm tm

{{tcaffeine → 85.796}}

175 - tm taspartame - tm
Solve 0.72 ⩵ /. tm → 26.9 // Quiet
tm tm

{{taspartame → 133.532}}

◼ #7

tr 2
Ntp ⩵ 5.55 /. {tr → 9.8, w → 0.22}
w

Ntp ⩵ 11 012.9

L
H⩵ /. {Ntp → 11012.851239669424`, L → 106}
Ntp

H ⩵ 0.00962512

Printed by Wolfram Mathematica Student Edition

Sapling.nb 15

◼ #8

◼ #9

Printed by Wolfram Mathematica Student Edition

16 Sapling.nb

◼ # 10

Printed by Wolfram Mathematica Student Edition

Sapling.nb 17

◼ # 11

◼ # 12

Printed by Wolfram Mathematica Student Edition

18 Sapling.nb

◼ # 13

Chapter 24 Gas Chromatography

◼ #1

Printed by Wolfram Mathematica Student Edition

Sapling.nb 19

◼ #2

◼ #3

0.247 × 1000
β⩵
4 × 0.657

β ⩵ 93.9878

7.74 - 2.8 vm
KK ⩵ /. vm → 93.98782343987823` vs
2.8 vs

KK ⩵ 165.821

Printed by Wolfram Mathematica Student Edition

20 Sapling.nb

tr - 2.8 vm 0.247 × 1000

Solve KK ⩵ /. vm → vs, KK → 165.82137421178518`
2.8 vs 4 × 0.329

{{tr → 5.27376}}

◼ #4

◼ #5

Printed by Wolfram Mathematica Student Edition

Sapling.nb 21

◼ #6

Log[10, tupr ] - Log[10, tnpr ]

Ii ⩵ 100 n + (Nu - n) /.
Log[10, tNupr ] - Log[10, tnpr ]
{n → 8, Nu → 9, tupr → 14 - 1.5, tnpr → 13 - 1.5, tNupr → 19.4 - 1.5}

Ii ⩵ 818.845

◼ #7

2 - pentenone 773 Hexane

1 - Nitropropane 867 Heptane
Benzene 746 ; Butanol ;
Butanol 733 Benzene
Heptane 700 2 - pentenone
Hexane 600 1 - Nitropropane

Printed by Wolfram Mathematica Student Edition

22 Sapling.nb

◼ #8

Printed by Wolfram Mathematica Student Edition

Sapling.nb 23

◼ #9

◼ # 10

Printed by Wolfram Mathematica Student Edition

24 Sapling.nb

◼ # 11

Part a

Ax As 215 × 10-3 267 × 10-3

Solve ⩵F /. Cs → , Cx → , As → 0.885 Ax // Quiet
Cx Cs 88.15 × 10 × 10-3 102.17 × 10 × 10-3

{{Ax → 0.}, {F → 1.05459}}

Part b

AreaP ⩵ 1.064 height w /. {height → 39.8, w → 3.9}

AreaP ⩵ 165.154

AreaD ⩵ 1.064 height w /. {height → 87.8, w → 1}

AreaD ⩵ 93.4192

Printed by Wolfram Mathematica Student Edition

Sapling.nb 25

Part c

Ax As
Solve ⩵F /. {F → 1.0545932920765124`, Cs → 56.2, As → 165.15408`, Ax → 93.4192`} //
Cx Cs
Quiet

{{Cx → 30.1438}}

Chapter 22 Mass Spectrometry

◼ #1

1.66054 × 10-24 kg
58.6 kDa
1 kDa

9.73076 × 10-23 kg

◼ #2

m
RP ⩵ /. {m → 502.9, dm → 0.0441}
dm

RP ⩵ 11 403.6

Printed by Wolfram Mathematica Student Edition

26 Sapling.nb

m
RP ⩵ /. {m → 502.9, dh → 0.0230}
dh

RP ⩵ 21 865.2

◼ #3

1
100 × 63.9291 + 57.4 × 65.9260 + 38.6 × 67.9248
100 + 57.4 + 38.6

65.3008

Printed by Wolfram Mathematica Student Edition

Sapling.nb 27

◼ #4

Printed by Wolfram Mathematica Student Edition

28 Sapling.nb

◼ #5

Printed by Wolfram Mathematica Student Edition

Sapling.nb 29

◼ #6

◼ #7

Printed by Wolfram Mathematica Student Edition

30 Sapling.nb

a ⩵ 0.50692

a ⩵ 0.256948

b ⩵ 2 × 0.5069 × 0.4931

b ⩵ 0.499905

c ⩵ 0.49312

c ⩵ 0.243148

Printed by Wolfram Mathematica Student Edition

Sapling.nb 31

◼ #8

Printed by Wolfram Mathematica Student Edition

32 Sapling.nb

◼ #9

Printed by Wolfram Mathematica Student Edition

Sapling.nb 33

◼ # 10

Chapter 25 HPLC Part 1

◼ #1

Printed by Wolfram Mathematica Student Edition

34 Sapling.nb

◼ #2

tr 2
Nu ⩵ 5.45 /. {tr → 0.631 × 60, w → 2.2}
w

Nu ⩵ 1614.03

L
H⩵ /. Nu → 1614.0328140495865`, L → 30 × 103
Nu

H ⩵ 18.587

H
/. {H → 18.586982704973888`, d → 1.74}
d

10.6822

Printed by Wolfram Mathematica Student Edition

Sapling.nb 35

◼ #3

◼ #4

Printed by Wolfram Mathematica Student Edition

36 Sapling.nb

◼ #5

Polarity ⩵ Phenol > ANisole > p - xylene > napthalene;

Printed by Wolfram Mathematica Student Edition

Sapling.nb 37

◼ #6

Printed by Wolfram Mathematica Student Edition

38 Sapling.nb

◼ #7

◼ #8

More polar, the greater the eluent strength

Printed by Wolfram Mathematica Student Edition

Sapling.nb 39

◼ #9

Printed by Wolfram Mathematica Student Edition

40 Sapling.nb

◼ # 10

◼ # 11

Printed by Wolfram Mathematica Student Edition

Sapling.nb 41

Chapter 25 HPLC Part 2

◼ #1

◼ #2

Printed by Wolfram Mathematica Student Edition

42 Sapling.nb

◼ #3

◼ #4

Printed by Wolfram Mathematica Student Edition

Sapling.nb 43

◼ #5

Lab

Printed by Wolfram Mathematica Student Edition