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Denka Suspending Agent For PVC Synthesis
Denka Suspending Agent For PVC Synthesis
Denka Suspending Agent For PVC Synthesis
19
DENKR
O€['KI KAGAKU KOGYO XAR.'sHIKI KA'SHA
TR-13'1103
I
C=O
I
CH,
VinylAcetate
t g=o
C=t
:ly V inyl,Acetate
I
CHt
CH )
I
H X Hydrolysis Degree
-[.r, F
gl-lr-9 (Saponification Degree)
m
o HD= x100
I m+n
C=O
LO I
CHu
X Polymerization Degree
tO,-- m + n
Poly Vinyl Alcohol (PVA)
z
DENKA POVAL for PVC Polymerizalion
100
G
:-o 90
UE
o
o
!-
d)
6UU
.2
u)
o
L
!
J-
:'70
Vofatiles (%) < 5.0 < 5.0 < 5.0 < 5.0
Viscosity r) (mPa.s) 37-43 44-55 9.0-13.0 6.0-9.0
Hydrolysis (mol%) 78. 78.5-80.5 70.5-74.5 70.5-74.5
2)
PH 5.0-7.0 5.0-7.0 5.0-7.0 5.0-7.0
Sodium Acetate f/") s 0.5 < 0.5 < 2.0 < 2.0
nCrL
1) 4% aqueoussolution, 20"C, JIS K-6726
2) 4%aqueous solution, 25'C
Comparison with Competitor's Grades
DENKA (Japan)
--r
g0 Alcotex 72'5
synthomer (u.K.) Atcotex
Alcotex 872
INTRODUCTION of W Type
(Polymer Structure of W-type)
gHs
t
Ac :
-C-.\b
Standard PVA
(w-20N, w-24N)
Performance of W-20h1
as Primal Dispersant (Paddle)
)VA recipe PVA only PVA/MC=87/13 with secondarv
I samnle name W-2ON other's W-2ON oiher's W.2ON of har's
rvc Pantcte slze 4-c_!lH_q!_qn v.4 u.4 0.2 o.6 v.z u.4
% 180um on 14.8 21.2 8.0 9.2 19.3 23.0
150um on 22.4 26.4 19.2 .:|"9..?- ."-q9,L"- ""-"q.:!, "_"
-
1009m on 45.6 38.8 53.4 52.0 41.4 38.1
75Um on 14.2 11.0 16.6 16.2 8.0 6.6
75um nass 2.6 22 2.6 2.8 1.0 0.6
Average pant"t"
llm 140 148 132 132 149 154
Distribution um * 63 b4 52 53 57 57
Bulk densitv lo/mll 0.513 0.491 0.481 0.497 0.479 0.477
Frsn eye ,mtn z4v z5z
!min 184 172 33 95 1 1
/min 4 6 4 3
CPA ** ohr ln=21 15.1 17.5 19.8 18.7 24.2 24.4
* d(80%)-d(209il
** PVC,/D OP,/stabili zer / luh ric ants /TO2,zcarbon= 1 00,/50 / 2 / O. B /
i 0. 4 / 0.04lphrl
roll temperature 150 Centigrade, lBrpm, pieces in 100cm2
*** plastic:zer: DOP
rr . i n l""a-{l84\,.
Cf A , ,Jf,, 'lL'6\+'q"Yt- f)ea
l
Performance of W-20N
as Primal Dispersant (Pfaudler)
PVA recipe PVA onlv PVA/MC=87/13 with secondarv
| <rmnla W-2ON other's W.2ON other's W-2ON other's
)VG .LU 't,4
Particle size igllH!:.n.9n. 0.6 u.6 u.4 u,4
% 160Fm on 16.0 16.2 11.2 20.4 11.8 24.5
1509m on 26.2 25.3 26.1 28.3 35.2
100um on
"4L!i'"' "g-,{
43.4 42.3 35.8 48.1 33.9
75gm on 11.4 12.8 13.4 9.4 10.2 9,?
75um pass 2.2 2.6 3.8 2.6 12 o8
Averaqe particle
um 144 144 140 152 143 158
stze
Distribution um * 60 63 59 62 53 56
Bulk densitv (q/ml) 0.466 o.457 o.475 0.489 0.459 0.457
Fish eye * 3min 368 848
5min 100 136 152 352
Tmin 13 35
5
"19 "
+ d(809;)-d(20%)
++ PVC,/DOP,/stabilizer/lubricants,/fiO2/car6on:100/50/2/0.8/0.4/0.04lphrl
roll temperature 150 Centigrade, lBrpm, pieces in 100cm2
+++ olasticizer: DOP
Performance of W-X€ru
as Primal Dispersant (Paddle)
PVA recipe PVA only PVA/MC=87/13 with secondary
| <rmnla W-24N r)f her's W-24N other's W.24N olher's
|-antcte stze u.b u.b 't.u 't.u 0.4 0.2
Pr vPEr r %
{?-uIqr__o_ll
l-9-orn-g-n - -ad.i
is:.4 E.A 9.2 11.6 ic.2
l50um on 24.5 22.6 13.2 14.5 21.8 27.5
l00um on 43.0 42.6 51.0 qg,? 52.0 44.7
l-9u"n"p-n 10.6 12.2 22.8 21.7 13.2 8.8
75rrm nacs 26 AL 36 3.4 1.0 0.6
AVerage pant"t"
lra 144 142 126 128 136 146
Dislrihulian rrm * 64 66 55 56 53 58
Bulk densitv lo/mll 0.488 0.497 0.488 o.482 0.480 0.477
Fish eye * 3min 6C6 c1z
5mtn 17 28 65 57 10 6
Tmin 0 1 1 1 1 1
CPA * phr {n=21 16.9 16.6 18.6 17.9 21.8 21.6
l2s
,---3''-'** -r
L
o'y!-L:*P:19-!c-=c-l-i - L--D9-*1"--Brg!9:c)
r
i
t
=*S
End-group
Solvent or Initiator or VinytncetaL
1;16*fu--1
i eno-group i
yOru-4
/ ct
,-- a\=lIC- L -ci{
lmages of Suspension
Polymerization with MP type
1L
I
lmage of strength i
at skin layer Graft point with PVC
(wider is strong)
14
Formation of PVG Particles
MP.1O Other
-^, O 0-''",.
lmage 't '\oc
Qt 1/ ll l^' ir
---::€ O f\
g.,;-- ''L- ('
Graft Point Many (Random in Chain) Few (Terminal of Chain)
Skin Layer Hard & Stable Soft & unstable
Frequency of
Coalescence and Low & Stable High & unstable
Re-dispersion
among Particles
MP-10
other
Difference of function of MP-10(R)
and PVC particle formation
. Pores will be created In uniform system and
less irregular big pores or hollows on the
surface. Network of pores reaches to the
surface of aggregated PVC particle
r IMP-10(R) will promote stable formation of
relatively smaller droplets and domain
particles.
--) Low CPA but better fish eye characteristics
and higher strippability
J.U
=
=-
.& 2.0
@
o
EL
1.0
(E
(L
Low
Stirre 650rpm
Temperature ("c) 57.5
K Value 64-66
Reaction Time (hr) 4
Pressure (Finished) (MPa) 0.765
lJ)
)Beclpe (1) (21 s
r f-
ct)
N
Water (kg) 14 12
VCM (kg) 65
PVA (%rucM) 0.05-0.16
In itiato r (%rucM)
BND 0.046
CND 0.010
{D"l
ii
il
i-j
luz 19
PVA
(%A/CM) 0.050 0.065 0.100 0.065 0.080 0.100 0.120 0.160 0.100 0.160
Particle %)
Size 250pm on 2.0 0.8 0.2 18.8 1.0 2.0 0.2 0.2 20.0 0.8
180pm on 16.6 5.0 '1,2 34.2 12.0 12.O 1.8 1.4 36.4 9.2
150pm on 25.3 '13.2 4.8 19.2 2',t.0 17.8 8.6 6.2 16.8 '17.2
100pm on 46.3 57.O 52.',| 23.8 54.4 48.0 61.9 53.2 21.0 46.4
75pm on 8.8 21.6 37.7 3.6 10.8 18.2 25.3 35.0 5.4 22.8
75pm pass 1.0 2.4 4.0 0.4 0.8 2.0 2.2 4.0 0.4 3.6
Average (pm) 144 125 112 186 138 135 120 113 '192 128
dro-dro (pm) 60 46 40 105 53 63 39 41 110 60
B.D. (g/ml) 0.475 0.456 0.461 0.472 0.464 0.453 0.465 0.454 0.445 0.397
CPA (phr) 27.5 28.4 25.3 27.4 28.2 29.7 26.6 27.7 29.3 33.4
Fish (counts
Eye /100cm2)
3 min
14 I 5 59 14 6 4 '17 14 4
2 0 0 4 0 0 0 0 0 0
5 min
0 0 0 I 0 0 0 0 0 0
7 min
PVC Properties of DOH 70-72% type
57.5"C, Water/VCM=1Z5kg, DOH 70-72% only
250 40
E
o
200
o
(L b X
o
@ o MP-10
.! At
@
o
150 Y30 . MP-10R
o .L X
o v,. rLB
E a ,' A
(!
o '€", :.. u.t " AL9
o a 4.,
A L1O
Ht roo 25
X Alcotex 72.5
x
x Alcotex B72
50 20
0.00 0.05 0.10 0.15 0.20 100 150 200 250
PVA ("/"^/cM) Average particle size of PVC (Um)
21
E
180
=. a
o 160
.N
o . MP-10R
o
.9 140 r MP-10
L
(E
,t A
(L o a Acotex 872
o 120 lan
ct)
Cl I
o
100
80
0.05 0.10 0.1s
IE 2.s 4 . MP-10,/MC
jll
l+ Ncotex72.5.zMC
i
E,O
6
o 1.5
o
o-
,'.0 ;{
E
o
fo '^,.
o.s
0.0
( /F\* )j 0.50
100
I o.so
o
o
L 0.20
F
o
.E 0.10
o
0.00
20
lmage of Porosity distribution
Conversion
Water (porosity)
- {D7"
PVC particle
Waler
Yr/alEf
V I
Porosi0t sharp broad
- 90% distribtrtion;
DENKA POVAL
8006-type
Grade B-24 W-2ON W.24N
Appearance granure granure granule gra nule gra nure
Competitions t I t t
Kuraray (Japan) 224 420,420H 424H 18, 19. L1 0. 111
[FNKN
28
TR No. 150606
Denka (2015.06.1 0)
1. PVA Sample
1) DENKA POVAL W-20N
2) Nippon Gosei Gosenol KH-17