Faizah Qurrata Aini, S.Pd., M.Pd.

JURUSAN KIMIA
FAKULTAS MATEMATIKA DAN ILMU PENGETAHUAN ALAM
UNIVERSITAS NEGERI PADANG
Textbook
Thermo : heat

Dynamic : movement or change

Thermodynamics is concerned with

the energy changes that accompany
chemical and physical processes
System
State of the object
Parameters of State of the object:
P
T State Function
V
Mass
Concentration
State: The complete list of properties that specify an object’s current
condition

State Function: Any property, like energy, that depends only on

an object’s current state
The internal energy is equal to the sum of all the energies
that the system possesses as a consequence of the kinetic
energy of its atoms, ions or molecules plus all the potential
energy that arise from the binding force between the particles
making up the system

∆E = Ek + EP
E is the state function. It cannot be determined.
 (J/oC)

Tergantung pada:
1.Jumlah zat
2.Komposisi zat
(J/ g oC)
Bomb Calorimeter and Coffee Cup Calorimeter
In Bomb Calorimeter

∆V = 0 → w = 0
∆E = q +w
∆E = qv
Bomb Calorimeter
In Coffee Cup Calorimeter
Constant Pressure → Psystem = Psurrounding
Coffee Cup Calorimeter
 P = 1atm
T = 25oC

(∆Hfo)
The Standard Heat of Dissosiation (∆Hdo)
The standard enthalpy of dissosiation of a substance is the amount of heat
absorbed or evolved when specifically one mole of the substance is
fdissosiated at 25 °C and 1 bar to its elements in their standard states.

The Standard Heat of Combustion (∆Hco)

Which one of the following equation shows the standard enthalpy of formation
HOW TO OBTAIN ∆H OF REACTION?
a.Experimentally
b.Theoritically:
1. Using ∆Hfo data
2. Using Hess’s Law
3. Using Bond Energies Data
Bond energy is the amount of energy needed to break a
chemical bond to give electrically neutral fragments