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Pedogenic Carbonates
Pedogenic Carbonates
• C from OM/CaCO3
• O from CaCO3
• Check- offset in C
right?
• C-veg. or ?
• O…rain?
Atmospheric CO2?
• “Paleosol barometer”
– 2 component mixing: atmospheric and soil CO2
• Weathering extent Æ
sequence of clays
– Muscovite/illite/chlorite
– Smectites
– Kaolinite
– Oxides
• Depends on other soil-forming
factors
– Grain size/mineral composition
of parent
– Temperature, seasonality of
rainfall, time
Indicator clays
• Palygorskite, Sepiolite
– Very dry (Morocco: all clays in soils <300mm
rain= palygorskite)
• Sodium smectites
– In dry climates specifically,
– Make domed columnar peds
• Palygorskite: Crystal Habits include
fibrous felted masses termed
"Mountain Leather"
• Kaolinite (clay), boehmite, gibbsite
(aluminum oxides)
– Very humid
– (tropics)
How to use?
• Ideally, use soils developed on igneous or
metamorphic bedrock
• Petrographic work
– “Bright clay fabric” = soil clays vs. alluvial clays
• Grain size
– Authigenic finer grained
• Crystallinity (XRD)
– More finely crystalline= authigenic
• Also check for burial alteration
– “Illitization”
– Lots of paleosols=illite dominant
– Alteration of smectite to illite during burial?
Burial illitization
• Not necessarily complete!
– Smectite often left
– Illitization spatially limited
• (Maybe you’re ok)
• Check:
– Crystallinity
• “metamorphic” illite= more crystalline
– Chemical variation
• Long story:
– Coupled variations in Na/Ca/Al/K different for weathering
process vs. illitization
Soil chemistry
• Idea: more water, fewer bases
• Won’t work for:
– Dry climate soils (evaporites)
– Wet climate soils (lots of kaolinite clay; Al
only, can’t change)
– Very weakly developed
– Very strongly developed
– Altered by burial illitization
Oxygen/hydrogen isotopes
• Clays!
– Must be authigenic (formed in soil)
– Temperature dependent fractionation- water to
clay
– Unknown water
– Possibility for post depositional alteration by
hydrothermal fluids
• Seems to work?
• Total Fe content of Fe-Mn nodules in
vertisols correlates to MAP (r2=.92)
– Not dependent on soil depth! (better than
carbonate!)
Pedogenic iron-
manganese nodules
in Vertisols: A new
proxy for
paleoprecipitation?
Cynthia A. Stiles, *
Claudia I. Mora, and
Steven G. Driese