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JEE Advanced 2018 Chemistry Sample Question Paper2
JEE Advanced 2018 Chemistry Sample Question Paper2
JEE Advanced 2018 Chemistry Sample Question Paper2
PAPER−2
Roll No.
Br
1. At what does the following cell have its reaction at equilibrium ?
CO
Ag(s) | Ag2CO3(s) | Na2CO3(aq) | | KBr(aq) | AgBr(s) | Ag(s)
KSP = 8×10−12 for Ag2CO3 and KSP = 4×10−13 for AgBr
(a) ×10−7
(b) ×10−7
(c) ×10−7
(d) ×10−7
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JEE Advanced Sample Question paper for Chemistry
2.
Infinite number of flasks are connected to one another as shown above. The volume and
pressure in each flask vary as shown. The stopcocks are initially closed. The common pressure,
when all the stopcocks are opened, is : (Assume constant temperature)
(a) P
(b) P
P
(c)
(d) P
CH3
4. One pink solid (X) has the formula CoCl3.5NH3.H2O. A solution of this salt (X) in water is also
pink and precipitates 3 mole AgCl on treatment with silver nitrate solution. When the pink solid
(X) is heated, it loses 1 mole H2O to yield a purple solid (Y) with the same molar ratio of
NH3 : Cl : Co. The purple solid releases two of its chlorides rapidly on dissolution and after
treatment with AgNO3 solution. The coordination number of cobalt in complexes (X) and (Y) is
six. The IUPAC name of pink (X) and purple (Y) complexes respectively are :
(a) Tetraamminechloridoaquacobalt(III) chloride and pentaamminechloridocobalt(III) chloride.
(b) Pentaamminechloridocobalt(III) chloride and pentaammineaquacobalt(III) chloride.
(c) Pentaamminechloridocobalt(III) chloride and pentaamminechloridocobalt(III) chloride.
(d) Pentaamminechloridocobaltate(III) chloride and pentaamminechloridocobaltate (III) chloride.
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JEE Advanced Sample Question paper for Chemistry
5. A hydrocarbon (R) has six membered ring in which there is no unsaturation. Two alkyl groups
are attached to the ring adjacent to each other. One group has 3 carbon atoms with branching at
1st carbon and another has 4 carbon atoms. The larger alkyl group has main chain of three
carbon atoms of which second carbon is substituted. Correct IUPAC name of compound (R) is
(a) 1-(1-Methylethyl)-2-(1-methylpropyl)cyclohexane
(b) 1-(2-Methylethyl)-2-(1-methylpropyl)cyclohexane
(c) 1-(1-Methylethyl)-2-(2-methylpropyl)cyclohexane
(d) 1-(1-Methylethyl)-2-butylcyclohexane
CH3
(a) Ph−CH2−CH2−O−CH−Ph
CH3 CH3
(b) Ph−CH−O−CH−Ph
(c) Ph-CH2-O-CH2-CH2-Ph
(d)
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JEE Advanced Sample Question paper for Chemistry
(a) `R` gives an aldol condensation reaction on heating with NaOH solution
(b) The compound `Q` gives a yellow precipitate in acetone
(c) Step `4` is an aromatic nucleophilic substitution reaction
(d) The end product is a mixture of three compounds
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JEE Advanced Sample Question paper for Chemistry
10. Following three planes (P1, P2, P3,) in an FCC unit cell are shown. Consider the following
statements and choose the correct option that follow :
12. Peroxodisulphate salts (Na2S2O8) are strong oxidizing agents used as bleaching agents for fats,
oil etc. Given
O2(g) + 4H+(aq) + 4e- → 2H2O() E° = 1.23 V
S2O8-2 + 2e- → 2SO4-2 (aq) E° = 2.01 V
Which of the following statements is (are) correct ?
(a) Oxygen gas can oxidize sulphate ion to per-oxo disulphate ion (S2O8-2) in acidic solution.
(b) O2(g) is reduced to water
(c) Water is oxidised to O2
(d) S2O8-2 ions are reduced to SO4-2 ions.
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JEE Advanced Sample Question paper for Chemistry
(a)
(b)
(c)
(d)
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JEE Advanced Sample Question paper for Chemistry
14. For certain substances such as ammonium chloride, nitrogen peroxide, phosphorus pentachloride,
etc. the measured densities are found to be less than those calculated from their molecular
formula. The observed densities decrease towards a limit as the temperature is raised. This is
due to the splitting of the molecules into simpler once. The process is reversible and is called
thermal dissociation.
Examples : NH4Cl ⇌ NH3 + HCl I2 ⇌ 2I
N2O2 ⇌ 2NO2 PCl5 ⇌ PCl3 + Cl2
With increase in the number of molecules, the volume increases (pressure remaining constant)
and, in consequence, the density decreases. As the temperature rises, more and more
dissociation takes place, and when practically complete dissociation occurs the density reaches
its lowest limit.
The extent of dissociation, i.e. the fraction of the total number of molecules which suffers
dissociation is called the degree of dissociation. Gas density measurements can be used to
determine the degree of dissociation. Let us take by general case where one molecule of a
substance A splits up into n molecule of A on heating; i.e.,
An(g) ⇌ nA(g)
t = 0 a 0
x
t = teq a−x n.x α = ⇒ x = aα.
a
a−aα naα
Total no. of moles = a − aα + naα
= [1 + (n – 1) α]a
Observed molecular weight or molar mass of the mixture
mA n
Mmixture = , MA n = Molar mass of gas An
n
(i) A sample of mixture of A(g), B(g) and C(g) under equilibrium has a mean molecular
weight (observed) is 80. The equilibrium is
A(g) ⇌ B(g) + C(g)
(mol. wt. = 100) (mol. wt. = 60) (mol. wt. = 40)
Find the degree of dissociation α for A(g).
(a) 0.25
(b) 0.5
(c) 0.75
(d) 0.8
(ii) If the total mass of the mixture in the above case is 300 gm, the moles of C(g) present
are.
(a) mole
(b) mole
(c) mole
(d) None
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JEE Advanced Sample Question paper for Chemistry
(iii) The Kp for the reaction N2O4 ⇌ 2NO2 is 640 mm at 775 K. The percentage dissociation
N2O4 at equilibrium pressure of 160 mm is :
(a) 80%
(b) 30%
(c) 50%
(d) 70%
D
(iv) x(degree of dissociation) varies with in the above reaction according to:
d
(a) (c)
(b) (d)
Dd
(v) The equation α = is correctly matched for :
n d
(a) A ⇌ nB/2 + nC/3
(b) A ⇌ nB/2 + (2n/3)C
(c) A → (n/2)B + (n/4)C
(d) A ⇌ (n/2)B + C
15. Two alophatic aldehydes P and Q react in the presence of aqueous K2CO3 to give compound
R, which upon treatment with HCN provides compound S. On acidification and heating, S gives
the product shown below.
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JEE Advanced Sample Question paper for Chemistry
(a)
(b)
(c)
(d)
(a) (c)
(b) (d)
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JEE Advanced Sample Question paper for Chemistry
(a) (c)
(b) (d)
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