ε

L/ mol*cm
Analito: Fe

Complejo: Fe-Morina 68500.00

Concentracion
Concentracion (ppm) Transmitancia % Transmitancia
(mol/L) (A/ε*b)
1.6306569343 0.00002920 0.010 1
1.3852186094 0.00002480 0.020 2
1.241646393 0.00002223 0.030 3
1.1397802844 0.00002041 0.040 4
1.0607667921 0.00001899 0.050 5
0.8153284672 0.00001460 0.100 10
0.6717562508 0.00001203 0.150 15
0.5698901422 0.00001020 0.200 20
0.4908766499 0.00000879 0.250 25
0.4263179259 0.00000763 0.300 30
0.3717343025 0.00000666 0.350 35
0.3520574264 0.00000630 0.370 37
0.3244518173 0.00000581 0.400 40
0.2827457096 0.00000506 0.450 45
0.2454383249 0.00000439 0.500 50
0.2116896904 0.00000379 0.550 55
0.180879601 0.00000324 0.600 60
0.1525370662 0.00000273 0.650 65
0.1262959776 0.00000226 0.700 70
0.1018661086 0.00000182 0.750 75
0.0790134924 0.00000141 0.800 80
0.0702700196 0.00000126 0.820 82
0.0575467591 0.00000103 0.850 85
0.0493116751 0.00000088 0.870 87
0.0373073846 0.00000067 0.900 90
0.0256967492 0.00000046 0.930 93
0.0181625788 0.00000033 0.950 95
1.000 100

Twiman-Lothian plot
25.000

20.000
 Twiman-Lothian plot
25.000

20.000

15.000

(dC/C)/dT
10.000

5.000

0.000
0 10 20 30 40 50 60 70
%T

Curva de calibración
2.500

2.000

1.500
Absorbancia

1.000

0.500

0.000
0.00000000 0.00000500 0.00001000 0.00001500 0.00002000 0.00002500 0.00
Concentracion mg/L
 ε
L/ mg*cm

Absorbancia (dC/C)/dT LogFe

C de
Log T 100-%T
(-log T)
2.000 -2.000 21.700 -4.535 99
1.699 -1.699 12.772 -4.606 98
1.523 -1.523 9.500 -4.653 97
1.398 -1.398 7.761 -4.690 96 100 Cu
1.301 -1.301 6.672 -4.721 95
90
1.000 -1.000 4.340 -4.836 90
0.824 -0.824 3.512 -4.920 85 80
0.699 -0.699 3.105 -4.991 80
0.602 -0.602 2.883 -5.056 75 70
0.523 -0.523 2.767 -5.117 70
60
0.456 -0.456 2.720 -5.177 65

100-%T
0.432 -0.432 2.716 -5.200 63 50
0.398 -0.398 2.727 -5.236 60
0.347 -0.347 2.781 -5.296 55 40
0.301 -0.301 2.883 -5.357 50
30
0.260 -0.260 3.039 -5.421 45
0.222 -0.222 3.260 -5.490 40 20
0.187 -0.187 3.569 -5.564 35
0.155 -0.155 4.003 -5.646 30 10
0.125 -0.125 4.632 -5.739 25
0
0.097 -0.097 5.598 -5.849 20 -7.000 -6.500
0.086 -0.086 6.141 -5.900 18
0.071 -0.071 7.234 -5.987 15
0.060 -0.060 8.248 -6.054 13
0.046 -0.046 10.539 -6.175 10
0.032 -0.032 14.807 -6.337 7
0.022 -0.022 20.508 -6.488 5
#¡DIV/0! #¡NUM!
ANÁLISIS PARA HIERRO

Lothian plot
Lothian plot

40 50 60 70 80 90 100
%T

libración

00001500 0.00002000 0.00002500 0.00003000 0.00003500

Concentracion mg/L
00 Curva de Ringbom
90

80

70

60
100-%T

50

40

30

20

10

0
-7.000 -6.500 -6.000 -5.500 -5.000 -4.500 -4.000

Log C
 Absorbancia ( Y cal Yi-Ycal (Yi-Ycal )2
Solución Fe(III) nm)
1 0.81532847 1.000 1.000 0.000051 2.55E-09
2 0.56989014 0.699 0.699 -0.000017 3.02E-10
3 0.49087665 0.602 0.602 -0.000139 1.93E-08
4 0.37173430 0.456 0.456 -0.000058 3.41E-09
5 0.35205743 0.432 0.432 0.000067 4.55E-09
6 0.28274571 0.347 0.347 0.000051 2.56E-09
7 0.21168969 0.260 0.260 0.000172 2.97E-08
8 0.12629598 0.155 0.155 -0.000126 1.60E-08

Suma 3.22 3.95 3.951 4.16E-16 7.83E-08

pendiente 1.2261
Intercepto 0.0003
Xpro 0.40258 Corrección
n 8 1.200

1.000
Sy/x 0.0001
Absorbancia (nm)

0.800
Sm 0.0002
0.600
So 0.0001
0.400

LOD 0.200

0.000
0.0E+00 1.0E-01 2.0E-01 3.0E-01 4.0E-01 5.0E-01
Concentracion Fe(II) (mol
 Xi2 (Xi-Xpro)2

6.65E-01 1.70E-01
3.25E-01 2.80E-02
2.41E-01 7.80E-03
1.38E-01 9.51E-04
1.24E-01 2.55E-03
7.99E-02 1.44E-02
4.48E-02 3.64E-02
1.60E-02 7.63E-02

1.63 0.34

Corrección

3.0E-01 4.0E-01 5.0E-01 6.0E-01 7.0E-01 8.0E-01 9.0E-01

Concentracion Fe(II) (mol/L)
Resumen

Estadísticas de la regresión
Coeficiente de correlación múltiple 0.9999860375
Coeficiente de determinación R^2 0.9999720753
R^2 ajustado 0.9999674212
Error típico 0.0017779411
Observaciones 8

ANÁLISIS DE VARIANZA
Grados de libertad Suma de cuadrados
Promedio de los cuadrados
Regresión 1 0.6791801326 0.67918013
Residuos 6 1.89664465121E-05 3.16107E-06
Total 7 0.6791990991

Coeficientes Error típico Estadístico t

Intercepción 0.0013389402 0.0009186857 1.45745189
Variable X 1 0.8450219313 0.001823026 463.527096

Análisis de los residuales

Observación Pronóstico para Y Residuos

1 0.0013389402 -0.0003389402
2 0.0351398175 0.0019361825
3 0.0858411334 0.0001588666
4 0.1703433265 -0.0023433265
5 0.2548455196 0.0001544804
6 0.4238499059 -0.0008499059
7 0.6773564853 0.0026435147
8 0.8463608716 -0.0013608716
 Variable X
0.003

0.002

0.001
F Valor crítico de F
214857.3689353 6.8048910749749E-15

Residuos
0

-0.001

Probabilidad Inferior 95% Superior 95%Inferior 95,0%Superior 95,0% -0.002

0.1952583122 -0.0009090027 0.00358688 -0.000909 0.00358688
6.80489107E-15 0.8405611475 0.84948272 0.84056115 0.84948272 -0.003
0.00000000 0.200000
 Variable X 1 Gráfico de los residuales
0.003

0.002

0.001

-0.001

-0.002

-0.003
0.00000000 0.20000000 0.40000000 0.60000000 0.80000000 1.00000000
Variable X 1
LOD