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Binil Sir Lectures
Binil Sir Lectures
Binil Sir Lectures
7
Subtracting,
8
You should remember these eigenvalue equations:
We know that the eigenvalue equation for angular
momentum ladder operator is,
zero 10
Let s = ½, ms = -½ >>
11
zero
Let s = ½, ms = -½ >>
12
Let s = ½, ms = ½ >>
13
Now, applying state function in equation (7),
10 13
14
14
Combining equation (13) and (14), we get,
15
Similarly, when applying state function in
equation (7), we get,
16
The eigenvalue equations of the components of the
spin vectors are,
6th postulate
18
19
20
21
Applying state function in (19), we find
22
24
Similarly z-component of Pauli spin matrix is,
25
Therefore, our required Pauli spin matrices are as
follows:
Identical property
of ladder operator
State sixth postulate of Quantum
Mechanics and set up eigenvalue
equations for the components of
spin vectors. Use these eigenvalue
equations and find Pauli Spin
matrices.
HOME WORK
Question No. 1
Find the matrix elements of spin operators Sx, Sy &
Sz using relation
where and
are orthogonal.
Question No. 2
Show that
also find matrix element for S2.
Show that Pauli spin matrix together with identity
matrix make basis in 2 x 2 matrix spin space.
AND
Show that Pauli spin matrices are complex,
traceless, Hermitian, unitary, anti-commuting
with the determinant '-1' and have two
eigenvalues +1 and -1. Explain the physical
meaning of each.
Properties (1) sx2 = sy2 = sz2 = I
(2) s2 = sx2 + sy2 + sz2= 3I
(3) sx sy sz= iI
(4) s+2 = s-2 = 0 (s± = sx ± isy)
(5) s+s- = (I + sz)
(6) s-s+ = (I - sz)
(7) s+s- + s-s+ = 4I 1
You can see here that the multiplication of Pauli
spin matrices yield identity matrix in various ways.
Therefore, the identity matrix is sometimes called
zeroth Pauli matrix (s0)
Show that Pauli spin matrix together with identity
matrix make basis in 2x2 matrix spin space.
The set {sx, sy, sz, I} forms a basis in 2 x 2 matrix
spin space only when
(a) These are linearly independent with each other.
(b) These vectors should span matrix space.
(a) Consider a equation,
5
Here sx, sy, sz, and I are linearly independent if
a=b=g=k=0
On solving,
we get >>
Therefore, sx, sy, sz, and I are linearly
independent.
(b) Consider an arbitrary matrix of 2 x 2 matrix space,
If the set {sx, sy, sz, I} span the above matrix space, then A
must uniquely be expressed as a linear combination of
On solving, we get
Anti-commutation
s xs y + s ys x = 0
Lets try to understand [sxsy]+= 0
anti-commutation
property………………..
[sysz]+= 0 & [szsx]+= 0
All of them (equ. 1) can be written in a compact form,
2
Anti-symmetric part Symmetric part
All of them (equ. 1) can be written in a compact form,
2
Anti-symmetric part Symmetric part
Here,
3
Commutator Anti-commutator
Similarly, for Pauli spin matrices,
4
Commutator Anti-commutator
On comparing (2) and (4), we have commutation and
anti-commutation relations for Pauli spin matrices.
We can verify anti-commutation relation using eigenvalue
equations for sx, sy and sz, i.e.,
Therefore,
Expanding,
The probability of finding spin-up and spin down in
the z-direction are,
Question No. 2
Schaum Series:
solved problems (p-124)
7.1/7.2/7.6/7.7/7.8
Exercises (p-138)
7.13/7.14/7.15
Today you studied…..
Discuss properties of Pauli spin
matrices
AND
State Born rule for spin
probability.
SPINORS
Taking x-component,
3
3
Expanding
cosa sina
4
Expanding
6
NUMERICAL
According to sixth postulate,
2
Now we define ladder operator,
3
Similarly,
Heisenberg proposed,
Applying these representations to the ladder operator,
Similarly,
7
Charge operator is used to find the charge of a nucleon!
Charge of neutron!
Charge of proton!
and,
p - p 0 + e- + n e
Isospin is mathematically similar to spin, though it has
nothing to do with angular momentum. The spin term is
tacked on because the addition of the isospins follows the
same rules as spin.
NUMERICAL 1
Consider two identical fermions, both in the spin-up state
in a one-dimensional infinitely deep well of width 2a.
Write the wave function for the lowest energy state. For
what values of position, does the wave function vanish?
>> The wavefunction and energies of a particle in an
infinite potential well of width 2a is.
angular momentum
angular momentum
According to Pauli
3
Substituting
in (5), we get,
Here, 6
6
Independent of time!
Therefore, general solution of (6) is,
+
+ 8
On solving,
We get,
11
Laws of Classical Mechanics holds for the expectation value of the QM!
Bra Ket
We know the time dependent schrodinger equation are,
1
Bra Ket
We know the time dependent schrodinger equation are,
Laws of Classical Mechanics holds for the expectation value of the QM!
Here, the operator F can be a vector!
This equation represents the equation of motion for an
observable F. If F does not depend on time, then
4
According to classical mechanics, for a system of particle,
dynamical variable F(q,p) can be expressed as,
6
Su stituti g Ha ilto s e uatio of otio i e uatio 5
Action-angle (Jecobi)
Second Quantization
However, quantum mechanics differs from other physical theories because, while its
formulation has been accepted and used for 80 years, its interpretation remains a matter of
controversy and debate.
Schrodinger Picture Heisenberg Picture
>> Operator is time independent >> Operator is time dependent
>> wavefunction is time >> Wavefunction is time
dependent independent
>> Time dependent wavefunction >> Time independent
can be obtained by the unitary wavefunction can be obtained by
transformation of the time the unitary transformation of the
independent wave function time dependent wave function
Here, Here,
Equation of motion for an Equation of motion for an
observable, observable,
Interaction Picture
>> Both operator and wavefunction
are is time dependent
Eigenvalues
If l = +1, then the wavefunction is said to have even parity.
If l = -1, then the wavefunction is said to have odd parity.
Parity in Classical Mechanics:
EVEN ODD
Mass, Energy, Power, Charge Position, Velocity, Acceleration,
Density, Electric Potential, Angular Linear Momentum, Force,
Momentum, Magnetic Field, Current Density, Electric Field,
Maxwell Stress Tensor, etc Vector Potential, etc
Parity Conservation in Classical Mechanics
Newton's equation of motion F = ma (if the mass is constant)
equates two vectors, and hence is invariant under parity.
The law of gravity also involves only vectors and is also,
therefore, invariant under parity.
Parity in Quantum Mechanics (revisit these!)
1. Show that Parity Operator is a linear operator.
2. Show that Parity Operator is hermitian.
3. Show that Parity Operator Commutes with Hamiltonian
if potential is symmetric.
4. Discuss the condition under which total parity of a
system is conserved.
5. Show that the eigenvalue of parity operator is always ±1.
6. Parity is not conserved in the weak interaction.
Parity is a multiplicative quantum number.
Postulates II Operator
Every measurable physical quantity is described by an
operator acting on the state space. This operator is
observable in nature.
Heisenberg
uncertainty
W. Pauli
exclusion
Max Born
statistical
interpretation of the
wave function
Atomic World
Neumann
?
collapse of the
wave function
N. Bohr
complementarity
Scientists are badly divided into two groups……
Einstein vs Heisenburg……..
Can Quantum Mechanical Description of Physical
reality be considered complete?
A. Einsten et al. Vs W. Heisenberg et al.
The main controversy is because of the postulates of
QM, particularly the presence of imaginary quantities
in Quantum Mechanics, Uncertainty and Probabilistic
approach.
Physics is finished,
young man. It's a
dead-end street.
• We have to remember
that what we observe is
not nature itself but
nature exposed to our
method of questioning.
The main controversy is because of the postulates of
QM, particularly the presence of imaginary quantities
in Quantum Mechanics, Uncertainty and Probabilistic
approach.
Subjectivity
Uncertainty
Probabilistic
Complimentarity
High
High Energy Underground Surface Space
Intensity
Accelerators Experiments Experiments Experiments
Accelerators
B. Aryal