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Process Engineering Material Balances
Process Engineering Material Balances
Process Engineering Material Balances
CLOSED BOOK
Instructions to Students
• Answer all FOUR questions.
• Full marks will be awarded for obtaining 100 marks of a potential 110 marks.
• Begin each answer on a new page in the answer book.
• Use one side of each page.
• Box your answers.
• Show all calculations and assumptions in the answer book.
• The marks for each question are indicated. These should be used as a guide to the time to be
spent on each question and the content of your answer.
Mark Summary
10 30 30 30 10 110
Page 1 of 11
QUESTION 1: (10 marks)
Based upon the written description which follows, prepare a block flow diagram. All unit operations,
including any splitters and mixers, should be labelled. Indicate the direction of flow of all streams and
number each stream. Indicate the species present in each of the streams.
An aqueous solution of nitric acid contains a small amount of Fe(NO3)2 as an impurity. This stream is fed
into a mixer together with a makeup stream containing Mg(NO3)2 and a recycle stream containing Mg(NO3)2,
Fe(NO3)2 and 20.0 % H2O. The resultant mixture is fed to the first of three distillation columns. The
overheads stream from this first column is fed directly to a second distillation column. This second column
produces two product streams, a stream of concentrated nitric acid (99.0 % HNO3, balance water) which is
the bottoms stream and an overheads stream containing pure water. The bottoms stream from the first
distillation column is fed to the third distillation column. The overheads stream produced by this third column
contains pure water while the bottoms product stream contains Mg(NO3)2, Fe(NO3)2 and 20.0 % H2O. To
prevent unwanted accumulation of the impurity Fe(NO3)2 a portion of the bottoms stream is split off and
purged while the remainder is the recycle stream mentioned above.
SOLUTION: 11 streams x 0.5 = 5.5 marks. 4.5 marks for 4 units and label clearly. (Total = 10 marks)
Page 2 of 11
QUESTION 2: (30 marks)
The analysis of a coal indicates 75 wt% C, 17% H, 2% S, and the balance noncombustible ash. The coal is
burned at a rate of 6000 kg/h, and the feed rate of air to the furnace is 850 mol/s. All of the ash and 8% of
the carbon in the fuel leave the furnace as a molten slag; the remainder of the carbon leaves in the stack
gas as CO and CO2; the hydrogen in the coal is oxidized to water, and the sulfur emerges as SO2. The
selectivity of CO2 to CO production is 10:1. Calculate:
a) the theoretical air required; [14 marks]
b) the percent excess air fed to the reactor; [2 marks]
c) the mole fractions of the gaseous pollutants CO and SO2 in the stack gas; [10 marks]
d) the yield of carbon dioxide; [2 marks]
e) the ratio of water to dry flue gas. [2 marks]
SOLUTION
a) Basis: 6000 kg coal/h; 850 mol air/s = 3060 kmol/h 5 marks for proper block diagram
6000 kg kg
5000 coal/h
coal / h
0.75 kg C / kg
n1 (kmol O2 / h)
0.17 kg H / kg
n2 (kmol N2 / h)
0.02 kg S / kg
C + 02 --> CO2 n3 (kmol CO2 / h)
0.06 kg ash / kg
2H + 1/2 O2 -->H2O 0.1 n3 (kmol CO / h)
S + O2 --> SO2 n4 (kmol SO2 / h)
850 mol./s
3000 kmol air / h C + 1/2 O2 --> CO n5 (kmol H2O / h)
Theoretical O2 :
0.75 ( 6000 ) kg C 1 kmol C 1 kmol O2
C:
h 12.01 kg C 1 kmol C
=374.64 kmol O2 h
374.64 kmol 1000 mol h
=
h 1 kmol 3600s
=104.07 mol/s
2 marks
Page 3 of 11
0.02 ( 6000 ) kg S 1 kmol S 1 kmol O2
S: = 3.7 kmol O2/h = 1.028 mol /s 2 marks
h 32.06 kg S 1 kmol S
Total = (374.64 + 252.54 + 3.7) kmol O2/h = 630.88 kmol O 2 h = 175.2 mol/s 2 marks
Total (air) = 630.88 / 0.21 = 3004.2 kmol/h = 175.2 / 0.21 = 834.5 mol/s 1 marks
850 − 834.5
Excess air: ×100% = 1.86% excess air 2 marks
834.5
c) Balances:
C:
(0.92)(0.75)(6000) kg C react 1 kmol C
= n3 + 0.1n3
h 12.01 kg C
N2 (0.79)(3060) kmol N 2
h = n2
⇒ n2 = 2417.4 kmol N 2 h 1 mark
Page 4 of 11
Stack gas total
FLUE GAS (kmol/h) FLUE GAS (mol/s)
COMPONENT
S
CO2 313.64 87.12
CO 31.4 8.72
SO2 3.72 1.033
N2 2417.4 671.5
O2 57 15.84
H2O 505 140.28
TOTAL 3328.15 1 mark 924.5
Mole fractions:
31.4
xCO = = 9.4 ×10−3 mol CO mol 1 mark
3328
3.72
xSO = = 1.12 ×10−4 mol SO 2 mol 1 mark
2
3328
Page 5 of 11
QUESTION 3: (30 marks)
In the production of bean oil, beans containing 13 wt% oil and 87% solids are ground and fed to a stirred
tank (the extractor) along with a recycled stream of liquid n-hexane. The feed ratio to the extractor is 3 kg
hexane per kg beans. The ground beans are suspended in the liquid, and essentially all of the oil in the
beans is extracted into the hexane. The extractor effluent passes to a filter. The filter cake contains 75 wt%
bean solids and the balance bean oil and hexane, the latter two in the same ratio in which they emerge from
the extractor. The filter cake is discarded and the liquid filtrate is fed to a heated evaporator in which the
hexane is vaporized and the oil remains as a liquid. The oil is stored in drums and shipped. The hexane
vapour is subsequently cooled and condensed, and the liquid hexane condensate is recycled to the
extractor.
a) A process flowchart and a somewhat oversimplified description of what happens in the process is
shown in attachment 1 (page 9). Use this flowchart to label all the streams variables entering and
leaving each process unit. Make sure you provide the appropriate name for each stream and don’t
forget to insert this attachment into your answer book. [10 marks]
b) Choose a basis of calculation for this process and perform the degree-of-freedom analysis for EACH
process unit (indicate clearly the unknown stream variables for each stream). [10 marks]
c) Calculate the yield of bean oil product (kg oil/kg beans fed), the required fresh hexane feed (kg
C6H14/kg beans fed), and the recycled to fresh feed ratio (kg hexane recycled/kg fresh feed). [10
marks]
Solution:
a) Basis: 100 kg beans fed 1 mark for Streams 1, 2, 3, 5, 7,8 and 2 marks for streams 4, and 6
Page 6 of 11
b) Overall: 4 unknowns ( m1 , m3 , m6 , y3 ) Extractor: 3 unknowns ( m2 , x2 , y2 )
– 3 balances – 3 balances
1 DF 0 DF
1 mark
Mass of oil in filter cake = 0.0104 x 116 = 1.204kg
Mass of hexane in filter cake = 116 – 87 – 1.204 = 27.8 kg = 28 kg 2 marks
Mass of hexane in stream 7 = 300 – 27.8 = 272.2 kg
Mass of oil in stream 7 = 13 – 1.204 = 11.8 kg
Mass of oil in product stream (stream 6) = mass of oil in stream 7 = 11.8 kg 1 mark
Mass of hexane in fresh feed stream = mass of hexane in filter cake (stream 3) = 27.8 kg
m6 11.8 kg oil
Yield = = = 0.118 (kg oil/kg beans fed ) 1 mark
100 100 kg beans fed
m1 28 kg C6H14
Freshhexane feed = = = 0.28 (kg C6H14 / kg beans fed )
100 100 kg beans fed 2 marks
m5 272 kg C6H14 recycled
Recycleratio = = = 9.71( kg C6H14 recycled/kg C6H14 fed )
m1 28 kg C6H14 fed 2 marks
Page 7 of 11
QUESTION 4: (30 marks)
Formaldehyde (H2CO) is produced by partial oxidation of methanol (CH3OH). Several side reactions also
occur, producing formic acid (H2COO), CO, CO2, and H2O.
You are the process engineer at a formaldehyde plant. In this plant, 333 kmol/h air is mixed with 100 kmol/h
fresh methanol plus additional recycled methanol and fed to a reactor. Your job is to evaluate how well the
process is working. You take samples at several points in the process and find that (1) the reactor inlet
streams is 35 mol% CH3OH, (2) the recycled methanol is pure, (3) the offgas contains 10.9 mol% H2, 6.0
mol% CO2, 0.3 mol% CO, 81.9 mol% N2, and 0.9 mol% O2, and (4) the liquid product stream contains
H2CO, H2COO and H2O. A block diagram for the entire process is provided below.
a) Calculate the single-pass and overall fractional conversion of methanol. [10 marks]
b) Calculate the production rate of formaldehyde and formic acid (kmol/hr). [15 marks]
c) Calculate the selectivity of formaldehyde production relative to formic acid production. [5 marks]
Separator
Separator
Mixer Reactor
Recycled methanol
SOLUTION
Basic : 1 hour of operation
Page 8 of 11
Given that mole fraction of methanol in stream 4 = 0.35
100 + S3
0.35 =
100 + S3 + 333 4 marks
0.35 (100 + S3 + 333 ) = (100 ) + S3
S3 = 79.31 kmol
mole (CH3OH) in S 4 − mole (CH3OH) in S 5
single pass conversion= x100% !
mole (CH3OH) in S 4
C: 100 = (0.06+0.003)(321.21) + X + Y
X + Y = 79.76 3 marks
Page 9 of 11
BONUS QUESTION: (10 marks)
A batch of a mixed solvent has been prepared in a blending plant from three pure liquids: acetone,
nitrobenzene and glycerol. The batch was dispatched to a customer before all the mass and analytical
information was recorded and the only information available from the plant and laboratory is:
i) 24 L of nitrobenzene was used
ii) the batch of mixed solvent contains 33 % w/w of glycerol
iii) the batch of mixed solvent contains 1.3 mole of acetone per mole of glycerol.
Calculate:
a) Total mass of the batch (kg)
b) Total volume of the batch (L)
It may be assumed that the compounds are completely miscible and that there is no volume change on mixing.
Data:
Mol. Wt. Spec. Grav. 20°/4°
G Mixer
M
33% G
N = 24L
Page 10 of 11
From the information supplied we know that the actual volume of nitrobenzene in the mixture is 24 L. The
specific gravity of nitrobenzene is 1.205 20°/4°.
So, actual mass of nitrobenzene = (1.205 kg/L ) × ( 24 L ) = 28.9 kg 1 mark
a) Total mass of batch = (28.9) / (0.4) = = 72.3 kg 1 mark
b) Assuming no volume change on mixing,
⎛ Total Volume ⎞ ⎛ Volume of ⎞ ⎛ Volume of ⎞ ⎛ Volume of ⎞
⎜⎜ ⎟⎟ = ⎜⎜ ⎟⎟ + ⎜⎜ ⎟⎟ + ⎜⎜ ⎟⎟
⎝ of Solution ⎠ ⎝ Nitrobenzene ⎠ ⎝ Glycerol ⎠ ⎝ Acetone ⎠
The volume of nitrobenzene is known to be 24 L.
⎛ Volume of ⎞
⎜⎜ ⎟⎟ =
(Mass of Glycerol) = 23.9 kg = 23.9 L
⎝ Glycerol ⎠ (Density of Glcerol) 0.998 kg/L
1 mark
⎛ Volume of ⎞
⎜⎜ ⎟⎟ =
(Mass of Acetone) = 19.5 kg = 24.6 L
⎝ Acetone ⎠ (Density of Acetone) 0.792 kg/L
1 mark
So, Total Volume of Solution = 24 L + 23.9 L + 24.6 L = 72.5 L 1 mark
Page 11 of 11