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ik CHAPTER 4 arc Equilibrium Phase Diagrams and the lron-Carbon System 4,1 Introduction sour stuf of enppsing mater becomes more ests onspeticmetsand alls fs icensingy important hat we acquire an undestndng of hi nail share es ard prope Win he ester of the ate athe material yor tougaut or 2 mle ot {wo or more tint eampeners there re multis co panes, ow much each pret, and hat arte d- feet chemists? (thr a conpnent hat may ipa. uncesed proper ochraceises? What wl Mpg # tampeatue is ieeie Sere, ries rans, orchestra The anette ne tenor ‘antqusins con obtained tag ese fel pasedagars, | | 4.2 Phases Sel we more to 2 scion qin pe poss npoar tat we et deve wang ce- tion he tp. es ang deft, hose inp oor of trl psesing a howe tue tue and characters properties Unto of eis, Sucre and popes une oupat «pase Nore ero paseas gente, uo reaches ne compen, 28 Site rons rite ta pet om hr eet hase. **yphase canbe cats iether ooo comission bea, urs nsdn apace anes ure sae oF 2 alton poe tht te Sucre composts se ‘aon haut Aa aterm ht pepo 2nd rt ma Sh phe when contin Thee te no todas srs which rare anlar ehisy ‘hangs OF and wate on he ter hand td separate no egos ith iinet boundaries ad mst be reps two sinc pase x cates muster sete poe sytem because thre are te die atures wih inte fae betwee he, 4.3 Equilibrium Phase Diagrams bo egal phate gram» gape mapping ofthe stl nde fs mater os mate ste su ing tht culo fas been ataled oral ps on irs. Tere are tee pinay wuts o be conse ‘ampere, pressure, ard compton. The senplet phte aayanisapresure-temperture(?-7) agra 3a compan ata Ara he saga tained the ‘aris ase hte bunds ineatng te ells Constansf arin. ‘As an irduco, consider the presuetenperoue haga for wat, preset 8 Fgue 4, With te com poston fd 510, he Bagram maps te able frm of ater fr various cartons temperature and presi f ‘he presi ons ndtarpetire arith ‘ein boundaries denote the ming and baling pins. Far eampl, st tmargher presi, the gr srone ‘hata lea OC Bnd Be at 10. Si ether ses re pss Locate a temperature where the sole pase ' liu at atmosphere restr Maing the pressure ‘one atmoipher, op the tempera ntl th mater foes rom iui sate, ie No, malta that ew Temperature ard beg ta decease he resin. anton willbe escutee where sal aes ret tga thst ring bimsion Th combined poco ete, t i was ; “cn B | er : OY ota i ‘rasa TEE resueterpeanrereutoingtoe don toon as feae dying. senpoydin he manactre of numerous dehydrated rods, With an appropriate phase lagi, ores conden can be detemined tht might ‘ede the amount of eured cali nd the agtude of pressure hop requedfor slain. A process ape {tng about he ple oltre the tee poses ome toptier wuld be mos ficient, Temperature-Composition Diagrams Athough the P- gam or waters anette ton to phase ogra, 7 phase agama aerate used lorengneringaplations, ost enginning proces re ound andi speas asa silver iin th kphae lagam Note: Ry esol ef ths te Foon ci that appears at 6 tb ctton nh upeoning ior-con uit erm) sme deg of enema ceiton tole te vat ne expands ita a singe pase ee, anctheconpound liaoun ss ontlianetre interme tale compound Fre £8 sors shen eestor, tet slchiomente an estcheetie compos oie, ch #8, 8 Bs AB, they ted ke har, tle mates because hese rperes aa coseutace ft oicar «cexsent bonding they ae presen pe quartes ore long rin bounds th om coo ln, ‘veal aley an Be etemely bite the same compound ‘sspenetreughou the aloyn he frm sal dst pervs, herteansescensieabeengheingat tne 3, ng Complex Diagrams ‘Theequtbrm apa frau say eemsmaybe one ofthese pss dicusied aoe ombinatn cl en, Ie sre cases the dre sppsrt be gute cmp snd femidole Hower by foci ona parca cameston and ashing Seti pits ugh ene ad eet ‘aes osc nit ok oe samt rn ge cence, even hemos conple agra canbe intra and widesond, the properties of he aos components are own, pase agar can en beet pete bear of teresa srt, ‘AL ofthe preceaig mts fs been onary pha ‘agrams, whee the napeng for combinations of two sleet comport Tree compen yes be rapped by temary phase daprams, ich athe oe three dimenienal les where chemi is an equate anglebase, and terete ascends upward ecu he compet of bese aga one te tee companies cen uedandtheremaang oar vate The sting Issmply 2 vera sl ugh he tema dogma an Deprsented ona fat sheets sry gam Tera [varsidatbecondrdin ttt 4.4 |ron-Carbon Equilibrium Diagram Stel composed sary tn ard can, ley the ‘notimparat lhe enginering reas Fr rezone Iron-carbon equim diagram asunes spi ire ‘ance The daom mest Hee encurtee, howe rottheful irop-caon arom bithe re cari. ‘gam sown i Figure 49, Hr, a stliomete interme Teconpauné, Fe, used tterinte th carbo ange at ‘Tt cron Thenames ay phot andstutre nd the specie nttns ad in ted have woe i> tery andl baat geaay scgtem, There are or snl pase sls within the apm ‘The of hese acum pure on, an he rh ton 1 vevie ft at ring pint unknown, and he iis tne reais uréatmied in he ih eb aon ofeaagan ‘Thre distinct thre phase reaction en ao Deleted. case Ta a pete ae tin occurs forall ith 3 low weght pert 236 of carbn. Because of in ember ad te extensive singe pha austen regan Inmedatal belo te ertecerecton ey sums ary egg sgn. A ate Us observed at 14° OBE, wth eevee conpottion of 3 eon. ally cntain- Ing more han 211% eon wl experts the tute recon noe aid the genera {emcastrons.Theiralthve phase reactonea eect at 727°C 380 wh ett com tion of 0.7 we carbon Aloe th es tan 211% ean miss the ete ean fom, Wilttpratxton Teo albiamphs aga Singhs a, Fema omtente6 r cot ‘aie Inemetac that os a 667% carbon, Upon ook ing un soli 9 body cece od that ‘ssl conn to 18 (2547, Krom ac delta, tis pases present ont 2 enenely sets epetues and sil geen portance. rom i 91° ed to 16747) pue ton stsmes a fcecrtreé-catle sve "ure Inonn as austenite in one of the ed metals Fabes-usten of gad. sate byte ek eter stent eh the igh ormbity ati characte the facecerteredube structure ad ical of dseing ‘er 28 carbon in sige pase sols. Hot omingo steal takesadhantgeof te on ete igh uc aod erica tory of autre Met ft et eter ste bepny fring the high terpert austenite uc ‘ure Apo rite mare commonly us tert ste stale fom of ronat tempers bow S154) Ts bay. ceneed-caic str an hl erly wt eon in Soli slam and frees the cretion as pace mire 'n mot ste. Upon further cotng tT UAL), Fon inderpes a taniton fom nenmagnecie-nagetc The {emgentrcfthistastion know the Cai pelt bet ecausetnetsscsed ith any cheep btson stoic tansiton it dos at ppt onthe equim pe apn, The out single phase the salen terme tale compound Fe orton abl, and pes he me cmon. Le mot tral, tae had a ie ‘hance shoslabeenreseen convoy the srucaein hich tcc. los with excess amount cement or cement in undesinle form te hae itl character. nis. Because crete dsocites rerto ling seat becneen ses and ost ons 4.5 Steels and the Simplified lron-Carbon Diagram fwefouso thematridsremaly own aslo thephase Slogan of Five 43 canbe singed consi. Tove orton earthed pas (pict eon ae ft ‘he sicane and the higher catbon region othe ete 'eacton on apes cast ns By deleting these sepmets nd fcsng onthe eatectireacon wecanise he sil fedagamot igure4.0 to povde nuendo! oe opertesard pracesngote. athe than bepning wth Gud, cur consiertons erly begin wth hgstempeatirs, fc ete bi sinjlephase austen. The hay tasiton willbe te conve sionof juste othe wo phe er pls abe ire ssthetampentre cops, Conl ofthe, icharies aresutl he acl ret caxton soe oe facecentred ane boyetred sce, eal wide, rane of ropertes tbe acid tough est eat. To beg to understand these processes, ceser 2 steal ofthe eateod conpstn, 77% carbon, being Show cooked lng ne Fg. the vp tee tires, ony ase Is reset, wth the 77% carbon bing dsl in sl sluon witin the fcecantred stuctre When he scoot thaugh 12 SHA se el cangs ec smataneuty Th ron wt to hangs Cosa stu eg te exceed ase he on 19 1 { S valitowcreeaton TEED sifiesioaton seam itt monsFeveds sume bod centered cab eit, butt ei can nly contin ‘a carbon in sal son. The eee abo jected and fms the cabevih intmealie (6) hon 2, cement The net econ tthe eet composton nd tamperttis Astrea CER Because the chia epoatin ecient within copie sos, heesar aca lature oe feand cement Specimens opted y ating, pling, andetchigl aes clon otc ac and shel eval lamer stuctrecomposd ol bring neo ie, asthma Figure 11 Bec nye ams om ed Conpottion hed vee te uur has tom setof characters gopeties eetneuhits compost ‘we dint pases rd pes byte name pert bene eves stow apnea, Stes having les thn he extol amount fein (ies than 077 areca hypeeutctié sl iype mes "les tho) Cons he aon 9 pic Rypoeuetd Aly alr tn a Fg 410. gh empath Ite onsuecotctrsepr dinate race eu sus outed wie jos apa igo Te eno ue sport emayteste and pee Seep ‘nates ene austenite. Upon coating howe ets tein where testable phase re ler ae tnt. Te {ne andeeraveaeltsshowthathelow cabot rules and pows lag he remsiningsuseterchein Caron. 12° AL he engin tet il hve aesumed te eteciéeamposton (77 eaten ad fo ‘he cooing wasnt pe, Te resulting ence, therfore, a mate of inary proach mary phases teens ator rete "eons ofpeateasstowr in Fgue 4.12, sresatntiottinn sae ef Onetlantenentronrmetiicron peasy nately carn conpostenaa miephete ecco see 20 ore Serta Hypertens peat tan) we thesethat oan more than the etc sour cabo, When sucha aco, as loging I Ft 410, te roves isso te hypoesecoie cae, net ht the inary orproetctod paslsrow cents "eas thecatonrenphase ucts id gos heen Ingoutnte decreases carbon cnt, gan aching he eect composton 3 27°C (347) Th austen rls peste upon sow coongtugh he etcld tempers Fred. sa phetamicnpahat eres suc, hich eons of par cenit an pert ‘hs case th comings enor a pay cement abit Ueinemetali compound wl ease te oeral mateo brent ble Ish noted that the anton ju deeb are ‘or eglvim conn, which canbe appointed by slow cong, Upon stow heatig the arn wl act in the reese manne When he alo are cold ai, home ete fran eu my oan base sfc time ay rot be prove forte ama hae ee ‘ions to cc these cases the eam phase dig Is olenger aval olrengerng als Beese te "apical pocses are impart Inte het eaten of stds and oer metals hecho wl be ised in Chapter 5, nd new tas wl be irc oo or srcesoneng. 4.6 Cast Irons ‘shown in Fig 43, xp-crbon lbs wth mre tan 218 cao eerencs th ete easondng slg These alos are own a cas. geal ego Sie gpd ity and ahr ow Ug leg) tangents, they realy cet and py an imprant Dlaeinengeeigaplcatns, Weshoul net Ronee, atest commerciales slo conn a signet amount of sa, Cst Fons ‘alycomain 20-40% exon. 05-20% sons than LI, manganese ard les than 6.2% au The leon proces several metalic fet By promoting the omaton of "ily adhering surae oie, ean enhances te zabon ane eon restance feat ve ene ‘rer nit level ef eeson reine aupeor tomostse, cause slcn partly subst xb botnhave four lene eects in th xterra shel, the te ‘onponettn-crbor-siicon toma) pase daa canbe ‘edeedtoamuch ipl brary the weehepeent carton ‘eae sepaced with 3 carbon equalet. See forms tins eto campus numba, withthe simplest beng the weit pect carbon pls oni ofthe waht pe cents arom Equal) = (mt carbon) +t sen) yng carton equivalent, wocmnonen on-atin layam can be wed to éetetine meting plots and com ate mrstucues forthe tree component en-ibon- Seon aoys. | Stion 20 tends to promote fama of graphite ste caer pac ttead ofthe Fes inttalle,The tute ac, thors, hit wo iinet poses shonin the mie pase data of Fgwe 434: cud + Asante + Fee uid stent + Graphite Te fn mcs cease, tere il oe ‘anette cabonsich imme fund er sgn rahe Wait pen cupon ‘eamocensaln fa te-cetenagam tog ten psle exon ass Sle det a pahe se, dans de o-comete ie pre cabonin te fem ofapie. hich evo pnd nthe met cent and vrous ote roc arbi, Gogh the roe stb of he to ad the tee rom src. formations ponte by sow cin, ihc nd ean ares, boy thks, Ineuatoy reds Sd espn at, sesh ilar, pes, min, ope ie nd Cobat Cement Forman ered by toting lewcatonandshntces theses, ana afore Review Questions 1. ws hf apetrecan e lyeibsion pse seamen 2. Wistonsme iran cnn pt 2. Spl th ened non wth ter stig of Se ps bat hg cons, dice gen nd wate piano gee cote nq eovohencaren® | 6. vathepesuengente dep ran deste easyer, 1. Myisapese ington Pe sopentthattr stegeetegarsstit 1. Wtom teatime dpi snotcomernst 1 witiaceg oe 28 Wt arr ng i a ane insets tn Wt sepa saopeoore | 1 wt uaa 22 wats ncn ibesert 13 eae co cco ay pt hb ‘eon 14 Wtoprfeheprcargenclgthep etn? eine bo! 15, Wathen tetera Beulbnompaedopent ' 18, ta etn rtp a dagan geval 1 eons tee a antec ‘rom foes 1 tel en est corset i son fe ‘enonnhsrins no phen oe 13 Wats Under ae obit pnt 24 Witten ee ed se ad mac epic 2. st asin cn oye sri? sf tan, rota, 2teonum, oman manganese, ane oben. Costvonisrelyapevctrm tht ppl tatty fmt ays pediment ih catbon phe Ixpeen a he frm ornate tht phat the es os ante cassie 2 gay hte, maleate, dc, or alr ‘or empacad gaphte Th eros metal ng tel, sts ttl tl, andar lb reser ie rece detain Chater 22, what bthepenol mots enicteectin? 2, vhateepealtemotteeaic nt 24, ny aay eet conaston tac rated ‘siemens ate? 25, Farha reps ana ue “4 ens | 26, vata sooner mermttiecanpind ow wal appa tenpeatrecpenenpae gan How wad 21. wat ypest can pti wl eet ie ‘licconoias 21 net sigmoid onde ange eae nwt ns gt tye ata? 28, Yates ienon ce aa? Folie ghse apes noaton dt seen, 40, wht te fasten ma tai fr fing ‘ort heater sasarng ste 2, What rete tonto dag sel gh enceatinns mates? 22. wih fe hoo pce tn he an sige ‘sm matin nde traf sk rocanintems oan pae a cerpsios 53. Dezrbetheree sity insta canine ‘wens em foastent he cleanse hat Sd 2. wtp Des sat 25. wht typo el and snc Wane ‘pone cn a apr td ew Sucsedserfontstl sfpoues? 26, Whtareseneatactie propria? 1 nadtono inn and ate, hat smo et Inberupeanoaniinesten 1. whatbeatoneguiaintsthonlRconpe 28. wht postin pein ‘Suerte fenton es? 18, Whatua ea Problems 1. obtain uryveconsae phates gremnat ‘asses pe doa 2 Srgeohue DS teephseain 2. copra aluminum ot ery cil mos etch want opp ae adina quiwegtol operand sori ate meet pede sale andsletedinapel stapes poaching "ebay so 65 date The pe ‘snl bight, nt a toh ben cae pie en dppeona coc rf abuts phe, ‘theo atria made paces vor saat ene 4: Hon pou ea hs eth ain ‘compe dapam pod iFipee: of hie see Siete snare St ht pet lg] 5, Sol fe Nese seat minal e sumiun-agge aly En how easter ihe aetinpgthedesed petite ale 2. so can sand fine cnt vas me aie rc at enpent wlbdo he mel eget ffs sen blmmessn mete sci pes oun hop srg Aas paow aceon heh ‘he nis eps eit st oom temper bn nay we

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