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Chemistry PDF
Q.51 If ‘n’ represents total number of asymmetric carbon atoms in a compound, the possible
number of optical isomers of the compound is
(A) 2n
(B) n2
(C) 2n
(D) 2n 2
Q.52 The equation that represents van’t Hoff general solution equation is
n
(A) RT
V
(B) nRT
V
(C) RT
n
(D) nVRT
Q.58 The compound which is NOT formed when a mixture of n-butyl bromide and ethyl bromide
treated with sodium metal in presence of dry ether is
(A) Butane
(B) Octane
(C) Hexane
(D) Ethane
Q.59 What is the general molecular formula of the products obtained on heating lanthanoids (Ln)
with sulphur ?
(A) LnS
(B) LnS3
(C) Ln3S2
(D) Ln2S3
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Q.61 In the cell represented by Pb(s) |Pb (1M) ||Ag (1M) |Ag(s) , the reducing agent is
(A) Pb
(B) Pb2+
(C) Ag
(D) Ag+
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Q.63 The amine ‘A’ when treated with nitrous acid gives yellow oily substance. The amine A is
(A) triethylamine
(B) trimethylamine
(C) aniline
(D) methylphenylamine
Q.65 While assigning R, S configuration the correct order of priority of groups attached to chiral
carbon atom is
(A) CONH2 COCH3 CH2OH CHO
(B) CONH2 COCH3 CHO CH2OH
(C) COCH3 CONH2 CHO CH2OH
(D) CHO CH2OH COCH3 CONH2
Q.68 Isopropyl methyl ether when treated with cold hydrogen iodide gives
(A) isopropyl iodide and methyl iodide
(B) isopropyl alcohol and methyl iodide
(C) isopropyl alcohol and methyl alcohol
(D) isopropyl iodide and methyl alcohol
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Q.69 In face centred cubic unit cell, what is the volume occupied ?
4 3 8 3 16 3 64r 3
(A) r (B) r (C) r (D)
3 3 3 3 3
Q.70 Glucose on oxidation with bromine water yields gluconic acid. This reaction confirms presence of
(A) six carbon atoms linked in straight chain
(B) secondary alcoholic group in glucose
(C) aldehyde group in glucose
(D) primary alcoholic group in glucose
Q.71 How is sodium chromate converted into sodium dichromate in the manufacture of potassium
dichromate from chromite ore ?
(A) By the action of concentrated sulphuric acid
(B) By roasting with soda ash
(C) By the action of sodium hydroxide
(D) By the action of lime stone
Q.73 Select the compound which on treatment with nitrous acid liberates nitrogen.
(A) Nitroethane
(B) Triethylamine
(C) Diethylamine
(D) Ethylamine
Q.74 5.0 g of sodium hydroxide (molar mass 40 g mol–1) is dissolved in little quantity of water
and the solution is diluted up to 100 ml. What is the molarity of the resulting solution ?
(A) 0.1 mol dm – 3
(B) 1.0 mol dm – 3
(C) 0.125 mol dm – 3
(D) 1.25 mol dm – 3
Q.75 Which of the following compounds when treated with dibenzyl cadmium yields benzyl
methyl ketone ?
(A) Acetone (B) Acetaldehyde
(C) Acetic acid (D) Acetyl chloride
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Q.76 Which halide of magnesium has highest ionic character ?
(A) Chloride
(B) Bromide
(C) Iodide
(D) Fluoride
Q.79 The relation between solubility of a gas in liquid at constant temperature and external pressure
is stated by which law ?
(A) Raoult’s law
(B) van’t Hoff Boyle’s law
(C) van’t Hoff Charles’ law
(D) Henry’s law
Q.80 Which among the following phenolic compounds is most acidic in nature ?
(A) p-aminophenol
(B) phenol
(C) m-nitrophenol
(D) p-nitrophenol
Q.86 The rate constant and half life of a first order reaction are related to each other as
0.693
(A) x t 1 .
2 K
(B) t 1 0.693K
2
(C) K 0.693 t 1
2
1
(D) Kt 1
2 0.693
Q.87 What is the combining ratio of glycerol and fatty acids when they combine to form triglyceride ?
(A) 3 : 4
(B) 3 : 2
(C) 1 : 3
(D) 1 : 2
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Q.88 The molecular formula of Wilkinson catalyst, used in hydrogenation of alkenes is
(A) Co(CO)8
(B) (Ph3P)3 RhCl
(C) [Pt(NH3 )2 Cl2 ]
(D) K[Ag(CN)2 ]
Q.93 Identify the compound amongst the following of which 0.1 M aqueous solution has highest
boiling point.
(A) Glucose
(B) Sodium chloride
(C) Calcium chloride
(D) Ferric chloride
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Q.94 What is the reagent used in Etard reaction ?
(A) Chromyl chloride
(B) Ethanoyl chloride
(C) SnCl2 and HCl
(D) Cadmium chloride
Q.99 What is the amount of work done when 0.5 mole of methane, CH4(g), is subjected to combustion at
300 K ? (given, R = 8.314 J K-1 mol-1)
(A) -2494 J
(B) -4988 J
(C) + 4988 J
(D) + 2494 J
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Q.100 Primary nitroalkanes are obtained in good yield by oxidising aldoximes with the help of
(A) trifluoroperoxyacetic acid
(B) acidified potassium permanganate
(C) concentrated nitric acid
(D) potassium dichromate and dilute sulphuric acid
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