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Chem 110 Test 2 Solution 2012
Chem 110 Test 2 Solution 2012
Surname: Initials:
Student No:
Tutorial Day:
Tutorial Group:
Tutor’s Name:
INSTRUCTIONS:
1. Answer ALL questions.
2. For Section A which contains the multiple choice questions, follow the instructions
given in the question.
3. Calculators may be used but all working must be shown.
4. Your answers for Section B must be written on the question paper in the spaces
provided. The left-hand pages may be used for extra space or for rough work.
5. Marks will be deducted for the incorrect use of significant figures and the omission of
units.
6. You must write legibly in black or blue ink. Pencils and Tipp-Ex are not allowed.
7. This test consists of 11 pages including a data sheet and a periodic table.
8. Please check that you have them all.
Mark
1
School of Chemistry and Physics, University of KwaZulu-Natal, Westville Campus, Durban
CHEM110/CHEM195: General Principles of Chemistry
TEST 2: Thursday, 29 March 2012
A 0.38 moles
B 2.0 moles
C 2.7 mol
2. A 5.72 g sample if magnesium nitride is reacted with excess water in the following
reaction:
Mg3N2 + 3H2O → 2NH3 + 3MgO
A 6.85 g
B 2.28 g
C 0.170 g
D 4.75 g (1)
2
School of Chemistry and Physics, University of KwaZulu-Natal, Westville Campus, Durban
CHEM110/CHEM195: General Principles of Chemistry
TEST 2: Thursday, 29 March 2012
3. The actual yield of MgO in question (2) above is 4.90 g. What is the percentage yield for
this reaction?
A 97.4%
B 71.5%
C 49.4%
D 87.3% (1)
3
School of Chemistry and Physics, University of KwaZulu-Natal, Westville Campus, Durban
CHEM110/CHEM195: General Principles of Chemistry
TEST 2: Thursday, 29 March 2012
5. In this reaction
+ 2+
3Mg + 2HNO3(dilute) + 6H 3Mg + 2NO + 4H2O
the magnesium acts as a reducing agent. How many electrons does each magnesium atom
lose?
A 1
B 2
C 3
D 4 (1)
A Pb
B PbSO4
C PbO2
D H2SO4 (1)
7. Equal volumes of all gases, under the same conditions of temperature and pressure,
contain very nearly the same number of molecules. This is
A Avogadro’s Principle.
B Boyle’s Law.
C Dalton’s Law.
4
School of Chemistry and Physics, University of KwaZulu-Natal, Westville Campus, Durban
CHEM110/CHEM195: General Principles of Chemistry
TEST 2: Thursday, 29 March 2012
8. Which of the following pairs of aqueous solutions will give a precipitate when mixed?
9. Consider the following equation and select the correct net ionic equation.
+ - 2+ -
Li + Br + Pb + NO3 →
A PbBr2(s) + LiNO3(s)
2+ -
B Pb + 2Br + LiNO3(s)
+ -
C Pb(NO3)2(s) + Li + 2Br
+ -
D PbBr2(s) + Li + NO3 (1)
10. In the reaction between aqueous potassium hydroxide and aqueous nitric acid, which are
the so-called "spectator" ions?
+ -
A K and OH
+ -
B H and NO3
+ -
C K and NO3
+ -
D H and OH (1)
[10]
End of Section A
5
School of Chemistry and Physics, University of KwaZulu-Natal, Westville Campus, Durban
CHEM110/CHEM195: General Principles of Chemistry
TEST 2: Thursday, 29 March 2012
SECTION B
QUESTION 1
Copper(II) chloride reacts with sodium nitrate to form copper(II) nitrate and sodium chloride
according to the equation below:
CuCl2 + 2NaNO3 → Cu(NO3)2 + 2NaCl
1.1 If 15.0g of copper(II) chloride reacts with 20.0g of sodium nitrate, calculate how much of
sodium chloride is formed?
(2½)
nNaCl = nCuCl2
2 1
Moles of NaCl = 2 x Moles of CuCl2
Mass of NaCl = 2 x nCuCl2 x molar mass of NaCl
= 2 x 15.0g/ 134.45g mol-1 x 58.44g mol-1
= 13.0g
nNaCl = nNaNO3
2 2
Moles of NaCl = Moles of NaNO3
Mass of NaCl = nNaNO3 x molar mass of NaCl
= 20.0g/85.0g mol-1 x 58.44g mol-1
= 13.8g
The limiting reagent determines how much product is formed so 13.0g of NaCl is formed.
6
School of Chemistry and Physics, University of KwaZulu-Natal, Westville Campus, Durban
CHEM110/CHEM195: General Principles of Chemistry
TEST 2: Thursday, 29 March 2012
1.3 Determine how much of the excess reagent is left over at the end of the reaction.
(1)
Mass of NaNO3 = nNaCl x molar mass of NaNO3
= 13g/58.44g mol-1 x 85g mol-1
= 18.9g
Excess reagent remaining = 20g – 18.9g = 0.88g
QUESTION 2
Balance the following equation in basic medium. Show the balanced oxidation and
reduction half-reactions and the balanced overall reaction
(4)
Oxidation half-reaction:
Cr(OH)3 + H2O CrO42− + 5H+ + 3e−
2(Cr(OH)3 + H2O CrO42− + 5H+ + 3e− )
Reduction half-reaction:
7
School of Chemistry and Physics, University of KwaZulu-Natal, Westville Campus, Durban
CHEM110/CHEM195: General Principles of Chemistry
TEST 2: Thursday, 29 March 2012
QUESTION 3
From the balanced equation the reacting ratio of NaOH to C2O42- is 2:1
i.e moles of NaOH / moles of C2O42- = 2/1
i.e MNaOH × VNaOH = 2/1 × moles of C2O42-
i.e. MNaOH = 2/1 × moles of C2O42- / VNaOH
= 2/1 × (0.3126 g /90.04 g mol-1) / 0.02621 dm-3
= 0.2649 mol dm-3
QUESTION 4
8
School of Chemistry and Physics, University of KwaZulu-Natal, Westville Campus, Durban
CHEM110/CHEM195: General Principles of Chemistry
TEST 2: Thursday, 29 March 2012
PH2 = 0.947 atm x 101325 Pa atm-1
= 9.46 x 104 Pa
b) What is the density, in g L-1, of a sample of oxygen gas at 0.987 atm and 25 oC?
Given R = 8.314 m3 Pa mol-1 K-1 (2)
Density = MP/RT
= (1.00 × 105 Pa x 32.00 g mol-1)/8.314 m3 Pa mol-1 K-1 x 298.15 K.
= 1291 g m-3 (convert volume from cubic meters to litres)
= 1.29 g L-1
[15]
End of Section B