BB chemes Equttriom by Gt | BH iru
oO
xt
tt
i
is used together withthe calculated (yi} to give anew and more neaty conect set (4, for
‘sein Ea. (13.43). Then anew set} is determined, The process is repeated until sucessive
iterations produce no significant change in (y). All alelations are well suited to computer
solution, including the calculation of {4,} by equations suchas Ea. (11.61).
In the procedure just described, the question of what chemical reactions ar involved
never enters directly into any ofthe equations. However, the choice of a set f species is
cently equivalent tothe choice of a set of independent rections among the species-in any
event, asetof species or an equivalent st of independent reactions must alvays be assumed,
and dlferent assumptions produce diferent esl
Example 13.14
‘Calculate the équilbrium|compositions at'1000 K Arid 1 bar of a gas-phase bas