Mains Set-A

FIITJEE - JEE (Mains)
PHYSICS, CHEMISTRY & MATHEMATICS

JEE - MAINS 2016
PHASE-III
SET-A
Time Allotted: 3 Hours Maximum Marks: 360
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4. The Test Booklet consists of 90 questions. The maximum marks are 360.
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having 30 questions in each part of equal weightage. Each question is allotted 4 (four) marks for correct
response.
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¼ (one fourth) marks will be deducted for indicating incorrect response of each question. No deduction from
the total score will be made if no response is indicated for an item in the answer sheet.
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JEE-MAINS -2016- PHASE -3-SET-A- PCM-2
Useful Data Chemistry:

1 1
Gas Constant R= 8.314 J K mol − −
1 1
= 0.0821 Lit atm K mol − −
1 1
= 1.987 ≈ 2 Cal K mol − −
23
Avogadro's Number Na = 6.023 × 10
–34
Planck’s Constant h = 6.626 × 10 Js
-27
= 6.25 x 10 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
-27
1 amu = 1.66 x 10 kg
-19
1 eV = 1.6 x 10 J
Atomic No : H=1, D=1, Li=3, Na=11, K=19, Rb=37, Cs=55, F=9, Ca=20, He=2, O=8,
Au=79.
Atomic Masses: He=4, Mg=24, C=12, O=16, N=14, P=31, Br=80, Cu=63.5, Fe=56,
Mn=55,
Pb=207,
Au=197, Ag=108, F=19, H=2, Cl=35.5, Sn=118.6
Useful Data Physics:
Acceleration due to gravity g = 10 m / s2
Section – I (Physics)
⎛ dV ⎞
−⎜
dP ⎟⎠
1. Which of the following graphs correctly represents the variation β = ⎝ with P for an
V
ideal gas at constant temperature?
(A) β (B) β
P P
(C) β (D) β
P P
2. If n moles of an ideal gas undergo a process 1-2 as shown in P 1

figure. Maximum temperature of gas during the process is 3P0
3P0 V0 4P0 V0
(A) (B)
nR nR P0 2
6P0 V0 9P0 V0 O
(C) (D) V0 3V0 V
nR nR
3. An ideal gas has adiabatic exponent γ. In some process, its molar heat capacity varies
α
as C = , where α is a constant. Work performed by one mole of gas during its heating
T
from T0 to nT0 will be
(A) α log n (B) α log n – (n – 1)RT0
(n − 1)
(C) α logn − RT0 (D) None of these
( γ − 1)
4. The wall of a straight tube of infinite length in thin. On passing current i through it, the
value of magnetic induction inside the tube will be
2i 2iµ 0 2r
(A) (B) (C) (D) Zero
r r i
Space for rough work
5. A uniform magnetic field B and a uniform electric field E act in a common region. An
electron is entering this region of space. The correct arrangement for it to escape
undeviated and unaccelerated is
r
(A) v (B) B
B
π /2
E
π /2 π /2
π /2 r
v
E
r r
(C) E Bv (D) E v
6. A thin disc (or dielectric) having radius r and charge q

distributed uniformly over the disc is rotated n rotations per
second about its axis. Find the magnetic field at the centre of
the disc. x
µ0 qn µ0 qn dx
(A) (B)
r 2r
µ0 qn 3µ0 qn
(C) (D)
4r 4r
7. A planet is revolving around the sun in elliptical orbit. Its closest distance from the sun is
r and the farthest distance is R. If the orbital velocity of the planet closest to the sun be v,
then what is the velocity at the farthest point?
1/2 1/2
⎛r ⎞ ⎛R⎞
(A) vr/R (B) vR/r (C) v ⎜ ⎟ (D) v ⎜ ⎟
⎝R⎠ ⎝r ⎠
8. A conical block, floats in water with 90% height immersed in it.

Height h of the block is equal to the diameter of the block i.e., h
20 cm. The mass to be kept on the block, so that the block just
floats at the surface of water, is
(A) 568 g (B) 980 g
(C) 112 g (D) 196 g
9. A soap bubble is blown slowly at the end of a tube by a pump supplying air at a constant
rate. Which one of the following graphs represents the correct variation of the excess of
pressure inside the bubble with time?
(A) (B)
p p
t t
(C) (D)
p p
t t
10. A conducting rod of length l moves with velocity ν a direction

parallel to a long wire carrying a steady current I. The axis of
the rod is maintained perpendicular to the wire with near end a
distance r away as shown in the fig. Find the emf induced in
the rod.
µ0Iυ ⎛ r + l ⎞ 2µ0Iυ ⎛ r + l ⎞
(A) ln ⎜ ⎟ (B) ln ⎜ ⎟
π ⎝ r ⎠ π ⎝ r ⎠
µ Iυ ⎛ l ⎞ µ Iυ ⎛ r + l ⎞
(C) 0 ln ⎜ ⎟ (D) 0 ln ⎜
π ⎝r +l⎠ 2π ⎝ r ⎟⎠
11. The mutual inductance between the rectangular loop and the long
straight wire as shown in figure is M, then
µ0 a ⎛ c ⎞
(A) M = Zero (B) M = ln 1 +
2π ⎜⎝ b ⎟⎠
µ0b ⎛ a + c ⎞ µ a ⎛ b⎞
(C) M = ln (D) M = 0 ln ⎜ 1 + ⎟
2π ⎜⎝ b ⎟⎠ 2π ⎝ c ⎠
12. Two long conductors are arranged as shown above to form

overlapping cylinders, each of radius r, whose centers are
separated by a distance d. Current of density J flows into the
plane of the page along the shaded part of one conductor and an
equal current flows out of the plane of the page along the shaded
portion of the other, as shown. What are the magnitude and
direction of the magnetic field at point A?
(A) (µ0 / 2π)πdJ , in the + y- direction
(B) (µ0 / 2π)d2 / r , in the + y- direction
(C) (µ0 / 2π)4d2J / r , in the –y- direction
(D) (µ0 / 2π)Jr 2 / d, in the –y- direction
13. A particle with charge +Q and mass m enters a magnetic field of

magnitude B, existing only to the right of the boundary YZ. The
direction of the motion of the particle is perpendicular to the
m
direction of B. Let T = 2π . The time spent by the particle in the
QB
field will be
(A) Tθ (B) 2Tθ
⎛ π + 2θ ⎞ ⎛ 2π − 2θ ⎞
(C) T ⎜ ⎟ (D) T ⎜ ⎟
⎝ 2π ⎠ ⎝ 2π ⎠
14. A cylindrical vessel open at the top is 20cm high and 10cm in diameter. A circular hole
whose cross-sectional area 1 cm2 is cut at the centre of the bottom of the vessel. Water
flows from a tube above it into the vessel at the rate 100 cm3s-1. The height of water in
the vessel under steady state is (Take g=1000 cms–2)
(A) 20 cm (B) 15 cm (C) 10 cm (D) 5 cm
15. A ball of mass m and radius r is gently released in a viscous liquid. The mass of the
liquid displaced by it is m' such that m > m'. The terminal velocity is proportional to
m − m' m + m' (m + m')
(A) (B) (C) 2
(D) (m – m')r2
r r r
16. A satellite is in a circular orbit very close to the surface of a planet. At some point it is
given an impulse along its direction of motion, causing its velocity to increase h times. It
now goes into an elliptical orbit. The maximum possible value of h for this to occur is
1
(A) 2 (B) 2 (C) 2 +1 (D)
2 −1
17. Starting from the same initial conditions, an ideal gas expands from volume V1 to V2 in
three different ways. The work done by the gas is W1 if the process is purely isothermal,
W2 if purely isobaric and W3 if purely adiabatic. Then
(A) W2 > W1 > W3 (B) W2 > W3 > W1 (C) W1 > W2 > W3 (D) W1 > W3 > W2
18. A small spherical ball of radius r falls freely under gravity through a distance h before
entering a tank of water. If, after entering the water, the velocity of the ball does not
change, then h is proportional to
2 3 4 5
(A) r (B) r (C) r (D) r
19. A uniform but time−varying magnetic field B(t) exists in a circular region B (t)
of radius a and is directed into the plane of the paper, as shown. The P
magnitude of the induced electric field at point P at a distance r from the X X
X a X X
centre of the circular region X X
(A) is zero (B) decreases as 1 / r X O X
X
(C) increases as r (D) decreases as 1 / r 2 X X
20. A battery is connected between two points A and B on the circumference of a uniform
conducting ring of radius r and resistance R. One of the arcs AB of the ring subtends an
angle θ at the centre. The value of the magnetic induction at the centre due to the
current in the ring is
(A) proportional to 2(180° – θ) (B) inversely proportional to r
(C) zero, only if θ = 180° (D) zero for all values of θ
21. If the radii of two soap bubbles are R1 and R2, then the ratio of the respective masses of
air in them will be
( σ = surface tension and P0 = atmospheric pressure)
4σ 4σ
P0 + P0 + 3
R1 R2 R1 R1 ⎡ R1 ⎤
(A) (B) (C) (D) ⎢ ⎥
R2 R1 4σ 4σ ⎣ R2 ⎦
P0 + P0 +
R2 R2
22. Three identical rings move with the same speed on a horizontal surface in a uniform
horizontal magnetic field normal to the plane of the rings. The first (A) slips without
rolling, the second (B) rolls without slipping, and the third rolls with slipping.
(A) The same emf is induced in all three rings.
(B) No emf is induced in any of the rings.
(C) In each ring all points are at the same potential.
(D) B develops the maximum induced emf, and A, the least.
23. Three moles of an ideal gas performs a 2 3

cycle shown in figure. If the
temperature are T1 = 600 K, T2 = 800 P
K, T3 = 2200 K and T4 = 1200 K, the 1
4
work done per cycle is
T
(A) 20 kJ (B) 30 kJ (C) 40 kJ (D) 60 kJ
24. Imagine a light planet revolving around a very massive star in a circular orbit of radius R
with a period of revolution T. If the gravitational force of attraction between the planet
and the star is proportional to R–5/2, then:
(A) T2 is proportional to R2 (B) T2 is proportional to R7/2
2 3/2
(C) T is proportional to R (D) T2 is proportional to R3.75
25. A drop of liquid of density ρ is floating half-immersed in a liquid of density d. If σ is the

surface tension, then the diameter of the drop of the liquid is
σ 2σ 6σ 12σ
(A) (B) (C) (D)
g ( 2ρ − d ) g ( 2ρ − d ) g ( 2ρ − d ) g ( 2ρ − d )
26. A double star system consists of two stars A and B which have time period TA and TB.
Radius RA and RB and mass MA and MB. Choose the correct option
(A) If TA > TB then RA > RB (B) If TA > TB then MA > MB
2 3
⎛T ⎞ ⎛R ⎞
(C) ⎜ A ⎟ = ⎜ A ⎟ (D) TA = TB
⎝ TB ⎠ ⎝ R B ⎠
27. A square loop ABCD, carrying a current i, is placed Y D C

near and coplanar with a long straight conductor XY i
L
carrying a current I.
I
(A) There is not net force on the loop. A B
(B) The loop will be attracted by the conductor only if L
the current in the loop flows clockwise. L/2
(C) The loop will be attracted by the conductor only if X
the current in the loop flows anticlockwise.
(D) None of these
28. Two particles X and Y having equal charges, after being accelerated through the same
potential difference, enter a region of uniform magnetic field and describe circular paths
of radii R1 and R2 respectively. The ratio of mass of X to the mass of Y is
1/2 2
⎛R ⎞ R ⎛R ⎞ R1
(A) ⎜ 2 ⎟ (B) 2 (C) ⎜ 1 ⎟ (D)
⎝ R1 ⎠ R1 ⎝ R2 ⎠ R2
29. Three identical coils A, B and C carrying currents

are placed coaxially with their planes parallel to
one another. A and C carry currents as shown in
Fig. B is kept fixed, while A and C both are
moved towards B with the same speed. Initially, I I
B is equally separated from A and C. The A B C
direction of the induced current in the coil B is
(A) same as that in coil A
(B) same as that in coil B
(C) zero
(D) none of these
30. In the circuit shown in Fig., if both the bulbs B1 and B2

are identical, then
C = 500 µF B1
(A) their brightness will be the same
(B) B2 will be brighter than B1 L = 10 mH B2
(C) B1 will be brighter than B2
(D) only B2 will glow because the capacitor has
infinite impedance
~
220 V, 50 Hz
Section – II (Chemistry)
1. After completion of reactions (I and II), the organic compound(s) in the reaction mixture
is (are)
O
Reaction I:
Br 2 (one mole)
C
aqueous NaOH
CH3 CH3
O
Br2 (1.0 mole )
Reaction II: C
CH 3 COOH
CH 3 CH 3
(1.0 mole)
O O O
C C C
H3 C CH 2Br H3 C CBr 3 Br3C CBr 3
(P) (Q) (R)
O O
CHBr3
C C
Br H2C CH 2Br H3C ONa

(U)
(S) (T)
(A) Reaction I: P and Reaction II: P
(B) Reaction I: U and Reaction II: P
(C) Reaction I: T, U, acetone and Reaction II: P
(D) Reaction I: R, acetone and Reaction II: S, acetone
(i) CH3MgBr H2SO4 / Δ HBO

2. CH3CHO ⎯⎯⎯⎯⎯
(ii) H3O
→ ( A ) ⎯⎯⎯⎯ → (B ) ⎯⎯⎯ → (C);
(A) and (C) are related as
(A) identical (B) position isomers
(C) functional isomers (D) optical isomers
3. Butanone can be best obtained by the ozonolysis of
(A) (B) (C) (D)
4. The first step in the formation of ester from an alcohol and a carboxylic acid in the
presence of conc. H2SO4 is
(A) protonation of O-atom of O---H group
(B) protonation of O-atom of C O group
(C) formation of resonance structure of acid
(D) removal of α-H from alcohol
5. The main product of the following reaction is.

O O
+
,H O H
NH 2 LiAlH4 2 /..............
(A) OH (B) OH OH
CH 2 CH
NH 2 NH 2
(C) OH O (D) O
NH 2 NH 2
6. CH3 CH2 CH COOH (A), CH3 CH CH2 COOH(B) and CH2 CH2 CH2 COOH(C)
Cl Cl Cl
Which order is correct for pKa?
(A) A > B > C (B) C > B > A

(C) B > A > C (D) C > A > B
7. CH3 NH2 + CHCl3 + KOH → nitrogen containing compound + KCl + H2O. Nitrogen
containing compound is
(A) CH3 − C ≡ N (B) CH3 – NH – CH3
Θ ⊕ ⊕ Θ
(C) CH3 − N ≡ C (D) CH3 − N ≡ C
Br2 /H2O NaNO2 /HCl H3PO2 /H2O

8. A ⎯⎯⎯⎯ → B ⎯⎯⎯⎯⎯
0 − 5° C
→ C ⎯⎯⎯⎯⎯D
→ 1, 3, 5-tribromobenzene.
What is ‘A’?
(A) (B) NH 2 (C) OH (D) COOH
OH
9. The correct order of increasing basis strength is

(A) NH3 < CH3 NH2 < (CH3)2 NH (B) CH3 NH2 < (CH3)2 NH < NH3
(C) CH3 NH2 < NH3 < (CH3)2 NH (D) (CH3)2 NH<NH3 < CH3NH2
10. The correct order of reactivity towards the electrophilic substitution of the compounds
aniline (I), benzene (II) and nitrobenzene (III) is
(A) I > II > III (B) III > II > I
(C) II > III > I (D) I < II > III
11. In vulcanised rubber, sulphur forms

(A) cross links (B) new sulphide product
(C) sulphur sheets (D) anticorrosive layer
12. The term anomers of glucose refers to

(A) a mixture of D-glucose and L-glucose
(B) enantiomers of glucose
(C) isomers of glucose that differ in configuration at carbon one (C-1)
(D) isomers of glucose that differ in configuration at carbon one and four (C-1 and C-4)
13. β – pleated sheet structure of proteins refers to

(A) primary structure (B) secondary structure
(C) tertiary structure (D) quaternary structure
14. A decapeptide (mol. wt. 796) on complete hydrolysis gives glycine (mol. wt. 75), alanine
and phenylalanine. Glycine contributes 47.0% to the total weight of the hydrolysed
products. The number of glycine units present in the decapeptide is
(A) 3 (B) 5
(C) 6 (D) 7
15. Copper is heated with dilute and concentrated nitric acid separately. The oxides of
nitrogen product are, respectively
(A) N2O, NO2 (B) NO, NO2
(C) NO2, N2O5 (D) NO2, NO
16. Brown ring test is for NO3− . Here, FeSO4 reacts with NO to produce
[Fe(H2O)5(NO)]SO4. The oxidation state of Fe is
(A) zero (B) +1
(C) +2 (D) +3
17. The correct order of bond angle (smallest first) in H2S, NH3, BF3 and SiH4 is
(A) H2S < SiH4 < NH3 < BF3 (B) NH3 < H2S < SiH4 < BF3
(C) H2S < NH3 < SiH4 < BF3 (D) H2S < NH3 < BF3 < SiH4
18. Which is thermodynamically the most stable allotropic form of phosphorus?

(A) Red (B) White
(C) Black (D) Yellow
19. What fraction of air will be expelled when a flask is heated from 27°C to 477°C?
(A) 1/5 (B) 2/5
(C) 3/5 (D) 2/3
20. The pay-load when a balloon of radius 10 m and mass 100 kg is filled with He at 1.66
bar and 27°C. (Density of air is 1.2 kg m-3 and R = 0.83 bar dm3K-1) is
(A) 1138.12 kg (B) 3811.12 kg
(C) 1381.12 kg (D) 3112.38 kg
21. A mixture H2 and O2 gases at 1 bar pressure contains 20% by weight of hydrogen.
Partial pressure of H2 gas is
(A) 0.2 bar (B) 0.4 bar
(C) 0.6 bar (D) 0.8 bar
22. Critical temperatures of some gases are

H2 = 33.2 K, He = 5.3 K, O2 =154.3 K, N2 = 126 K.
Which of the following order is correct for ease of liquefaction?
(A) He > H2 > N2 > O2 (B) N2 > O2 > He > H2
(C) O2 > N2 > H2 > He (D) O2 > H2 > N2 > He
23. van der Waals’ equation for 0.2 mol of a gas is

⎛ a ⎞ ⎛ a ⎞
(A) ⎜ P + 2 ⎟ + ( V − 0.2b ) = 0.2RT (B) ⎜ P + ( V − b ) = 0.02RT
⎝ V ⎠ ⎝ 0.04V 2 ⎟⎠
⎛ 0.2a ⎞ ⎛ 0.04 a ⎞
(C) ⎜ P + 2 ⎟(
V − 0.2b ) = 0.2RT (D) ⎜ P + ( V − 0.2b ) = 0.2RT
⎝ V ⎠ ⎝ V 2 ⎟⎠
24. What weight of 35% HCl (by mass) is required to react completely with 10L of 0.1 M
KOH?
(A) 36.5 g (B) 79.2 g
(C) 104.29 g (D) 115.7 g
25. From 490 mg of H2SO4, 1020 molecules are removed. The number of molecules left
is
(A) 6.02×1021 (B) 4.9×1021
(C) 3.01×1021 (D) 2.91×1021
26. Molecular weight of H3PO4 is 98. Its equivalent weight related to the given reaction
is
H3PO4 + NaOH→H2O + NaH2PO4
(A) 98 (B) 49
(C) 294 (D) 32.47
27. In the reaction,

2Al(s) + 6HCl(aq) ⎯⎯ → 2Al3+(aq)+ 6Cl-(aq) + 3H2(g)
(A) 6L HCl(aq) is consumed for every 3L of H2(g) produced
(B) 11.2 L H2(g) at STP is produced for every mole HCl(aq) consumed
(C) 3.36 L H2(g) is produced at any temperature and pressure for every mole of Al
that reacts
(D) 67.2 L H2(g) at STP is produced for every mole of Al that reacts
28. 1.0 g of a sample of brass, on reacting with excess of HCl produces 120 mL of H2
gas at STP. The percentage of Zn in the sample of brass is (Zn = 65.3)
(A) 32% (B) 35%
(C) 38% (D) 40%
29. →R Br
CH COOH is called
The reaction, R – CH2 –COOH ⎯⎯⎯ 2
Re d P
Br
(A) Hell Volhard Zelinsky reaction (B) Hunsdiecker reaction

(C) Curtius reaction (D) Swarts reaction
30. The increasing order of the rate of addition of HCN to compounds is

(I) HCHO (II) CH3COCH3 (III) PhCOCH3 (IV) PhCOPh
(A) IV < III < II < I (B) III < IV < II < I
(C) I < II < III < IV (D) IV < II < III < I
Section – III (Mathematics)

1. If x2 + 2x + 2xy +my – 3 has two rational factors, then the value of m will be
(A) –6, –2 (B) –6, 2
(C) 6, –2 (D) 6, 2
2. If α, β are the roots of x2 – ax + b = 0 and if αn + βn = Vn, then

(A) Vn + 1 = aVn + bVn – 1 (B) Vn + 1 = aVn + aVn – 1
(C) Vn + 1 = aVn – bVn – 1 (D) Vn + 1 = aVn – 1 – bVn
3. The area of the region in the Argand Plane for which z satisfy the inequality 1 £ z - 1 £ 4
and z + z ≥ 2 is
(A) π (B) 6π
(C) 16π (D) None of these
4. If |z| ≤ 4, then the maximum value of |iz + 3 – 4i| is equal to

(A) 2 (B) 4
(C) 8 (D) 9
p
5. A(z1), B(z2), C(z3) are the vertices of the ΔABC (in anticlockwise order). If – ABC = and
4
AB = 2 BC, then z2 =
(A) z3 – i(z1 – z3) (B) z3 + i(z1+ z2)
(C) z3 + i(z1 – z3) (D) None of these
6. If a, b, c ϵ R+ such that a + b + c = 18, then the maximum value of a2b3c4 is equal to

(A) 218 .32 (B) 218 . 33
19 2
(C) 2 . 3 (D) 219 . 33
Ê 1ˆÊ 1 ˆÊ 1ˆ Ê 1 ˆ
7. The value of Á1+ ˜˜ Á1+ 2 ˜˜ Á1+ 4 ˜˜ ....Á1+ 2 ˜˜ is
Á
Á ˜ÁÁË ˜ÁÁ 3 ¯Ë˜ Á Á
3 ¯Ë ˜
3 ¯ Ë 3 ¯
n
Ï ¸ Ï ¸
3Ô Ô 3Ô Ô
2n + 1 2n
Ô Ê1ˆ˜ Ô Ô Ê1 ˆ˜ Ô
(A) Ô
Ì 1- Á
Á ˜ Ô
˝ (B) Ô
Ì 1- Á
Á ˜ Ô
˝
2Ô
Ô Ë3 ¯˜
Á Ô
Ô 2Ô
Ô Ë3 ¯˜
Á Ô
Ô
Ô
Ó ˛Ô Ô
Ó ˛Ô
Ï 2n+ 1 ¸Ô
3Ô
Ô Ê1 ˜ˆ Ô
(C) Ô
Ì 1- Á Ô (D) None of these
2Ô Á3 ˜˜¯ ˝Ô
Á
Ë
Ô
Ô
Ó Ô
˛Ô
8. Let p = (8 + 3 7)n and f = p – [p], where [.] denotes the greatest integer function. Then
the value of p(1 – f) is equal to
(A) 1 (B) 2
(C) 2n (D) 22n
7 5
35 42 −r 47 −r
9. The value of C8 + ∑ C7 + ∑ C40 −r is equal to
r =1 r =1
(A) 47C8 (B) 47C9
(C) 47C7 (D) None of these
10. Two numbers are selected simultaneously from the set {6, 7, 8, 9, …., 39}. If the sum of
selected numbers is even then the probability that both the selected numbers are odd, is
equal to
11 40
(A) (B)
51 51
51
(C) (D) None of these
91
11. The probability that the persons P1 and P2 will die in a year are p and q respectively. The
probability that at the end of the year only of them will be alive, is equal to
(A) p + q – pq (B) p + q – p2 – q2
(C) p + q – 2pq (D) pq(p + q – pq)
12. Angular polygon of 10 sides is constructed. In how many ways can 3 vertices to be
selected so that no two vertices are consecutive
(A) 120 (B) 70
(C) 50 (D) None of these
1 1 1
13. If n ϵ N, then 1+ + + ...... + =
1+ 2 1+ 2 + 3 1+ 2 + 3 + ... + n
n 2n
(A) (B)
n+ 1 n+ 1
3n
(C) (D) None of these
n+ 1
14. In the sequence 1, 2, 2, 4, 4, 4, 4, 8, 8, 8, 8, 8, 8, 8, 8, ….., where n consecutive terms

have the value n, the 1025th term is
(A) 28 (B) 129
10
15. If |z1 + z2|2 = |z1 – z2|2 where z1 and z2 are non zero complex numbers, then
(A) Re (z1/z2) = 0 (B) Im (z1/z2) = 0
(C) Re (z1 + z2) = 0 (D) None of these
16. If the equation x2 – 3xk + 2e2ln k – 1 = 0 has real roots such that the product of root is 7,
then the value of k is
(A) ±1 (B) ±2
(C) ±3 (D) None of these
17. The number of non-negative integers that are less than 1000 that can be formed using
the digits 0, 1, 2, 3, 4, 5 such that no digit is being repeated in the formed number, is
equal to
(A) 130 (B) 131
(C) 156 (D) 155
n
n
18. In the triangle ABC, the value of the expression ∑ Cr ar .bn−r .cos(rB − (n − r)A) is equal to
r =0
(A) cn (B) Zero
(C) an (D) bn
n
19. The value of ∑ ∑ i. C is equal toj
0 ≤i < j ≤n
n–3
(A) n(n + 1).2 (B) n2.2n – 3
(C) n(n – 1).2n – 3 (D) None of these
20. The coefficient of a3b4c in the expansion of (1 + a – b + c)9 is equal to

9! 9!
(A) (B)
3!6! 4!5!
9! 9!
(C) (D)
3!5! 3!4!
21. Total number of positive integral solutions of x1 + x2 + 2x3 = 15 is equal to

(A) 42 (B) 70
22. There are 10 persons among whom two are brothers. The total number of ways in which
these persons can be seated around a round table so that exactly one person sit
between the brothers, is equal to
(A) (2!)(7!) (B) (2!)(8!)
(C) (3!)(7!) (D) (3!)(8!)
x 2 + 14x + 9
23. If x is real, then the maximum and minimum values of expression will be
x 2 + 2x + 3
(A) 4, –5 (B) 5, –4
(C) –4, 5 (D) –4, –5
24. The value of E = {arg(z) + arg(- z) - 2p }{arg(- z) + arg(z)} , " Z = x + iy and x, y > 0 is
(A) –π (B) π
25. A fair coin is tossed ‘n’ number of times. The probability that head will turn up an even
number of times, is equal to
n −1 1
(A) (B)
2n 2
n +1 2n−1 − 1
(C) (D)
2n 2n
26. A man alternatively tosses a fair coin and rolls a fair ordinary dice. He starts with the
coin. The probability that he gets a tail on the coin before getting 5 or 6 on the dice, is
equal to
3 1
(A) (B)
4 2
1 2
(C) (D)
3 3
27. a, b, c are distinct positive real numbers such that a2 + b2 + c2 = 1, then ab + bc + ca is

always
(A) < 1 (B) > 1
(C) = 1 (D) None of these
28. z1, z2 be two roots of the equation z2 + az + b = 0, z being complex. (a, b ϵ R) Assume
that the origin, z1 and z2 from an equilateral triangle, then a2 =
(A) 2b (B) 3b
(C) 4b (D) None of these
29. Which of the following statement is a tautology?

(A) (~ q ˄ p) ˄ q (B) (~ q ˄ p) ˄ (p ˄~ p)
(C) (~ q ˄ p) ˅ (p ˅~ p) (D) (p ˄ q) ˄ (~ (p ˄ q))
lm(z1 )
30. Let A1(z1), A2 (z1) are the adjacent vertices of a regular polygon. If = 1 − 2 , then
Re(z1 )
number of sides of the polygon is equal to
(A) 6 (B) 8
(C) 16 (D) 12
FIITJEE - JEE (Mains)
PHYSICS, CHEMISTRY & MATHEMATICS

JEE - MAINS 2014
PHASE-III
SET-A
ANSWERS
PHYSICS
1. A 2. B 3. C 4. D 5. A
6. A 7. A 8. A 9. B 10. D
11. D 12. A 13. C 14. D 15. A
16. B 17. A 18. C 19. B 20. D
21. D 22. A 23. A 24. B 25. D
26. D 27. B 28. C 29. C 30. B
CHEMISTRY
1. C 2. B 3. B 4. B 5. A
6. B 7. D 8. B 9. A 10. A
11. A 12. C 13. B 14. C 15. B
16. B 17. C 18. C 19. C 20. B
21. D 22. C 23. D 24. C 25. D
26. A 27. B 28. B 29. A 30. A
MATHEMATICS
1. C 2. C 3. D 4. D 5. C
6. D 7. C 8. A 9. A 10. D
11. C 12. C 13. B 14. C 15. A
16. B 17. B 18. A 19. C 20. D
21. A 22. B 23. A 24. B 25. B
26. A 27. A 28. B 29. C 30. B
HINTS & SOLUTIONS

PHYSICS
1. A
2. B
3. C
4. D
5. A
6. A
7. A
8. A
9. B
10. D
11. D
12. A
13. C
14. D
15. A
16. B
17. A
Sol. Area under the isobaric graph is more than the isothermal
and adiabatic process. Isobaric
P Isothermal
Hence W2 > W1 > W3
Adiabatic
v1 v2
18. C
4
Sol. (ρ − ρ f ) π r 3 g = 6πη r 2 gh
b
3
4
∴h ∝ r
19. B
dB
Sol. E 2π r = π a 2
dt
1
E∝
r
20. D
ρθ ρ ( 2π − θ )
Sol. R1 = , R2 =
A A
⎛ µ iθ ⎞ µ i ( 2π − θ )
B1 = − ⎜ 0 1 ⎟ , B2 = 0 2
⎝ 4π r ⎠ 4π r
⇒ Bnet = B1 + B2 = 0
21. D
⎛ 4σ ⎞4 3
⎜ P0 + ⎟ π R1
m1 PAVA ⎝ R1 ⎠3
Sol. = =
m2 PBVB ⎛ 4σ ⎞4 3
⎜ P0 + ⎟ π R2
⎝ R2 ⎠3
22. A
Sol. Emf depends on the translational velocity of the ring.
23. A
Sol. Process 1 – 2 and 3 – 4 are isochoric, ΔW = 0
Process 2 – 3 and 4 – 1 are isobaric, ΔW = nR (T3 − T2 ) + nR (T1 − T4 ) = 20 kJ
24. B
GMm
Sol. mω 2 R 2 = 5/2
⇒ T 2 ∝ R 7/2
R
25. D
⎛4 3 2 3 ⎞
Sol. ⎜ π r ρ − π r d ⎟ g = σ 2π r
⎝3 3 ⎠
12σ
⇒ D=
g ( 2ρ − d )
26. D
Sol. For binary star system ωA = ωB
∴TA = TB
27. B
Sol. For clockwise current sense, force on AD is towards the XY which is greater than force on BC.
28. C
2mK
Sol. R= ⇒ R∝ m
qB
29. C
Sol. Flux due to A in B increases while due to C in B decreases by same amount
Hence φ = constant
So i induced = 0
30. B
1
Sol. ωL < ⇒ Impedance of B2 Path < Impedance of B1 Path
ωC
⇒ I B2 > I B1
CHEMISTRY
1. C
2. B
3. B
4. B
5. A
6. B
7. D
8. B
9. A
10. A
11. A
12. C
13. B
14. C
Total amount of hydrolysed products = 796 + 9×18 = 958 g
amount of glycine = 958× 0.47 g = 450.26 g
number of glycine units = number of glycine molecules = 450.26/75 = 6
15. B
16. B
17. C
18. C
19. C
n1 T1 = n2 T2 or n1 ×300 = n2 ×750
n 2 n 2
Now 2 = or 1 − 2 = 1 −
n1 5 n1 5
3
Fraction of expelled air =
5
20. B
Mass of displaced air
4 22 3
= ×
3 7
(
× (10m ) × 1.2kgm−3 )
( )
= 4190.5m3 × 1.2kgm−3 = 5028.6kg
Mass of He filled = ( 4 × n ) moles
= 4×
(3
PV 4 × 1.66 bar × 4190.5 × 10 dm
=
3
)
RT RT 0.083bar dm3k −1 × ( 300K )
( )
= 1117.48 kg
Mass of filled balloon= 1117.48 + 100 = 1217.48 kg
Pay-load = Mass of air displaced – Mass of filled balloon
= 5028.6 – 1217.48 = 3811.12 kg
21. D
20 80
nH2 = = 10; no2 = = 2.5; Ptotal = 1 bar
2 32
10
PH2 = xH2 × Ptotal = × 1 = 0.8bar.
10 + 2.5
22. C
Higher the critical temperature, easier is the liquefaction of the gas.
23. D
24. C
10 L of 0.1 M KOH = 1 mol KOH
= 1 mol HCl (for reaction)
35 g of HCl is present in 100 g solution.
100 × 36.5
1 mol, i.e., 36.5 g HCl is present in , i.e., 104.285 g solution.
35
25. D
490 × 10−3
490 mg H2SO4 = 490 × 10-3 g H2SO4 = mol
98
490 × 10−3 × 6.02 × 1023
= molecules
98
=3.01×1021 molecules
Molecules left over = (3.01 × 1021) – (1020) = 3.01 × 1021 – 0.1 × 1021
= (3.01 – 0.1) × 1021 = 2.91 × 1021
26. A
Only one H of H3PO4 has been replaced. Hence,
Mol wt. 98
Eq. wt. of H3PO4 = = = 98
Basicity inreaction 1
27. B
6 mol HCl(aq) = 3×22.4 L H2(g) at STP
3 × 22.4
1 mol HCl(aq) = LH2 (g)
6
= 11.2 L H2(g) at STP
28. B
Zn + 2HCl ⎯⎯
→ ZnCl2 + H2
63.3 g 22400 mL
22400 mL H2 ≡ 65.3 g Zn
65.3 × 120
120 mL H2 = . g Zn
22400
65.3 × 120 × 100
Zn % in 1.00 g alloy = = 34.98 ≈ 35%
22400
29. A
30. A
MATHEMATICS
1. C
2
x + 2x(y + 1) + my – 3 = 0
λ = −(y + 1) ± (y + 1)2 − (my − 3)
2
(y + 1) – (my – 3) should be perfect square. So D = 0
2. C
3. D
Im
O (1,0)
Re
x =1
4. D
z1 − z2 | z1 − z2 | i 4
π A(z1)
= e
z3 − z 2 | z3 − z 2 |
π/4
B(z 2 ) C(z3 )
5. C
6. D
A.M ≥ G.M
7. C
⎛ 1⎞
Multiplying and divide by ⎜ 1 −
⎝ 3 ⎟⎠
8. A
9. A
n n n+1
Use Cr + Cr – 1 = Cr
10. D
11. C
12. C
10 10 6
C3 – 10 – C1 × C1
13. B
14. C
15. A
16. B
17. B
5
Required number of non-negative integers = 6 + 5 × 5 + 5 × P2 = 131,
18. A
n r n−r n
∑ n Cr (aeiB ) (be )
iA
(
= aeiB + be−eA ) = [(a cosB + b cos A) + i(a sinB − b sin A)] = c n
r =0
19. C
20. D
Use multinomial theorem.
21. A
22. B
Let A and B are two particular brothers, so there is 8 choices for A person to be seated between
8
them. C1 × 2 × 7!
23. A
24. B
Im
−π × −π = π
−z z
θ
Re
−z z
25. B
26. A
Series for success will be
T + H(Not 5 or 6) + ...............
1 ⎛1 2⎞ 1 ⎛1 2⎞ ⎛1 2⎞ 1
P= + × × + × × × × + .....∞
2 ⎜⎝ 2 3 ⎟⎠ 2 ⎜⎝ 2 3 ⎟⎠ ⎜⎝ 2 3 ⎟⎠ 2
P = 3/4.
27. A
2 2 2
a + b + c ≥ ab + bc + ca
28. B
z12 + z22 = z1z 2
29. C
30. B
Im Im ( z1 ) = −r sin θ
Re(z1) = r cos θ
z1
r So, tan θ = 2 −1
θ
Re 2 tan θ
O θ tan 2θ = =1
1 − tan2 θ
z1 2θ = π/4
If polygon is n sided, then
2nθ = 2π
⇒n = 8

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FIITJEE - JEE (Mains)

PHYSICS, CHEMISTRY & MATHEMATICS

3. The test is of 3 hours duration.

Name of the Candidate (in Capital Letters) :_____________________________________

Enrolment Number :_________________________________________________________

Batch :________________________ Date of Examination : ________________________

Useful Data Chemistry:

2. If n moles of an ideal gas undergo a process 1-2 as shown in P 1

6. A thin disc (or dielectric) having radius r and charge q

8. A conical block, floats in water with 90% height immersed in it.

10. A conducting rod of length l moves with velocity ν a direction

12. Two long conductors are arranged as shown above to form

13. A particle with charge +Q and mass m enters a magnetic field of

Space for rough work

23. Three moles of an ideal gas performs a 2 3

25. A drop of liquid of density ρ is floating half-immersed in a liquid of density d. If σ is the

27. A square loop ABCD, carrying a current i, is placed Y D C

29. Three identical coils A, B and C carrying currents

30. In the circuit shown in Fig., if both the bulbs B1 and B2

H3 C CH 2Br H3 C CBr 3 Br3C CBr 3

(P) (Q) (R)

Br H2C CH 2Br H3C ONa

(i) CH3MgBr H2SO4 / Δ HBO

3. Butanone can be best obtained by the ozonolysis of

(A) (B) (C) (D)

5. The main product of the following reaction is.

(A) A > B > C (B) C > B > A

Br2 /H2O NaNO2 /HCl H3PO2 /H2O

(A) (B) NH 2 (C) OH (D) COOH

9. The correct order of increasing basis strength is

11. In vulcanised rubber, sulphur forms

12. The term anomers of glucose refers to

13. β – pleated sheet structure of proteins refers to

18. Which is thermodynamically the most stable allotropic form of phosphorus?

22. Critical temperatures of some gases are

23. van der Waals’ equation for 0.2 mol of a gas is

27. In the reaction,

(A) Hell Volhard Zelinsky reaction (B) Hunsdiecker reaction

30. The increasing order of the rate of addition of HCN to compounds is

Section – III (Mathematics)

2. If α, β are the roots of x2 – ax + b = 0 and if αn + βn = Vn, then

4. If |z| ≤ 4, then the maximum value of |iz + 3 – 4i| is equal to

6. If a, b, c ϵ R+ such that a + b + c = 18, then the maximum value of a2b3c4 is equal to

14. In the sequence 1, 2, 2, 4, 4, 4, 4, 8, 8, 8, 8, 8, 8, 8, 8, ….., where n consecutive terms

20. The coefficient of a3b4c in the expansion of (1 + a – b + c)9 is equal to

21. Total number of positive integral solutions of x1 + x2 + 2x3 = 15 is equal to

27. a, b, c are distinct positive real numbers such that a2 + b2 + c2 = 1, then ab + bc + ca is

29. Which of the following statement is a tautology?

PHYSICS, CHEMISTRY & MATHEMATICS

HINTS & SOLUTIONS

Mass of He filled = ( 4 × n ) moles

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Batch : Date of Examination :