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Latice Parameter and Magnetic Moment Claculation of CoZnFe2O4 PDF
Latice Parameter and Magnetic Moment Claculation of CoZnFe2O4 PDF
The magnetic
moments and lattice parameters of these spinel ferrite are given below:
CoFe2O4
=5 B =8 B
𝑀𝑜𝑙𝑒𝑐𝑢𝑙𝑎𝑟𝑤𝑒𝑖𝑔ℎ𝑡𝑥𝑀𝑠
nB =
𝑁𝑥𝐵
234.623 𝑥𝑀𝑠
3=
6.023 𝑥1023 𝑥0.927𝑥10−20
Ms = 70.78 emu/gm
Lattice parameter :
1 1
𝑟𝐵 = 2 [CBFe r (Fe3+)+CBCo r (Co2+)] =2 [ 0.745+0.645]= 0.695 Å
8
=3√3 [(0.645+1.32)+ √3 (0.695+1.32)]= 8.3986 Å
(Zn2+ 3+
0.1 𝐹𝑒0.9 )A [Co2+ 3+ 2−
0.9 𝐹𝑒1.1 ]B𝑂4
=4.5 B = 8.2 B
𝑀𝑜𝑙𝑒𝑐𝑢𝑙𝑎𝑟 𝑤𝑒𝑖𝑔ℎ𝑡 𝑥 𝑀𝑠
nB =
𝑁𝑥𝐵
235.263 𝑥 𝑀𝑠
3.7 =
6.023 𝑥1023 𝑥0.927𝑥10−20
Ms = 87.81 emu/gm
Lattice parameter
8
ath=3√3 [(0.6545+1.32)+ √3 (0.69+1.32)]=8.3999 Å
The calculation for x=0.2 and 0.3 can be done similarly as that of x=0.1.
(Zn2+ 3+
0.4 𝐹𝑒0.6 )A [Co2+ 3+ 2−
0.6 𝐹𝑒1.4 ]B𝑂4
=3B = 8.8B
nB=8.8 B – 3 B = 5.8 B
The addition of Zn2+ should decrease the magnetization .The downturn of magnetization can
be explained by triangular arrangements of spins which was proposed by Yafet and Kittel. Y-
K angles are calculated using the formula : nB =MB cos𝛼𝑌−𝐾 – MA
𝑀𝑜𝑙𝑒𝑐𝑢𝑙𝑎𝑟 𝑤𝑒𝑖𝑔ℎ𝑡 𝑥 𝑀𝑠
nB =
𝑁𝑥𝐵
Lattice parameter
1
𝑟𝐵 = 2 [( 0.6 x 0.745)+(1.4x 0.645]= 0.675 Å
8
ath=3√3 [(0.683+1.32)+ √3 (0.675+1.32)]=8.4038 Å
The calculation for x=0.5, 0.6, 0.7, 0.8 and 0.9 can be done similarly as that of x= 0.4.
For x=0.5
For x=0.6
𝑎𝑡ℎ = 8.4064 Å
For x=0.7
𝑎𝑡ℎ = 8.4076 Å
For x=0.8
𝑎𝑡ℎ = 8.4089 Å
For x=0.9
𝑎𝑡ℎ = 8.4103 Å
ZnFe2O4
(0 x1) (5x2)
=0 B =10B
Net Magnetic moment in Bohr magnetron nB = MB – MA= 10B
Ms = 0 emu/gm
𝑎𝑡ℎ = 8.4116 Å
ZnxCo1-xFe2O4 ferrites
Figure 1, 2 and 3 represent the variation of lattice parameters, magnetic moment and saturation
magnetization with the replacement of Co by Zn in CoFe2O4
8.412
8.410 ZnxCo1-xFe2O4
8.406
8.404
8.402
8.400
8.398
10 Traditional calculation
Using Yafet- Kittel'sformula
9
8
Magnetic moment (B)
6
𝑛𝐵
160
140
120
100
80
60
40
20