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chp3 PDF
chp3 PDF
chp3 PDF
4R
3.3 This problem calls for a demonstration of the relationship a = for BCC. Consider the BCC unit
3
cell shown below
(NP) 2 = a 2 + a 2 = 2a 2
(4R) 2 = a 2 + 2a 2
or
4R
a =
3
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3-9
3.8 We are asked to determine the radius of a palladium atom, given that Pd has an FCC crystal structure.
For FCC, n = 4 atoms/unit cell, and VC = 16R 3 2 (Equation 3.4). Now,
nAPd
ρ =
VC N A
nAPd
=
(16R 3 2 ) N A
⎛ nA ⎞1/3
R = ⎜⎜ Pd ⎟⎟
⎝ 16 ρN A 2 ⎠
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3-10
3.9 This problem asks for us to calculate the radius of a tantalum atom. For BCC, n = 2 atoms/unit cell,
and
⎛ 4 R ⎞3 64 R 3
VC = ⎜ ⎟ =
⎝ 3⎠ 3 3
nATa
ρ =
VC N A
nATa
=
⎛ 64 R 3 ⎞
⎜⎜ ⎟⎟ N A
⎝ 3 3 ⎠
⎛ 3 3nA ⎞1/3
R = ⎜⎜ Ta ⎟
⎟
⎝ 64ρ N A ⎠
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students enrolled in courses for which the textbook has been adopted. Any other reproduction or translation of this work beyond that permitted
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3-18
3.15 In order to determine the APF for U, we need to compute both the unit cell volume (VC) which is just
the product of the three unit cell parameters, as well as the total sphere volume (VS) which is just the product of the
volume of a single sphere and the number of spheres in the unit cell (n). The value of n may be calculated from
Equation 3.5 as
ρVC N A
n =
AU
⎛4 ⎞
(4) ⎜ π R 3 ⎟
VS ⎝3 ⎠
APF = =
VC (a)(b)(c)
⎡4 ⎤
(4)⎢ (π)(1.385Źx 10-8 cm) 3⎥
⎣3 ⎦
=
(2.86) (5.87)(4.95)(xŹ10-24 cm3)
= 0.536
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students enrolled in courses for which the textbook has been adopted. Any other reproduction or translation of this work beyond that permitted
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