Professional Documents
Culture Documents
Cementing Catalog PDF
Cementing Catalog PDF
Cementing Catalog PDF
Preface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ix
Reservoir solutions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ix
Research and development . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . x
Quality, health, safety and environment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xi
Training . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xi
Key cementing technology highlights . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xii
Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Services . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Deepwater cementing products and services . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Deepwater slurries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
DeepCRETE deepwater cementing solution . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
FlexSTONE Cement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
DeepCEM additives . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Well stress analysis software . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
CemCADE software . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Advanced plug placement module . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Offshore cementing skids . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
DeepSea EXPRES offshore plug launching system . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Benefits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Features . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Surface dart launcher . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
Subsea tool . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
A gas migration control service—GASBLOK service . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
Benefits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
Features . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
Gas flow risk analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
Routes for gas migration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
CemCADE software—placement and postplacement risk analysis . . . . . . . . . . 10
Cement slurry design . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
High risk . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
Low risk . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
Slurry properties for gas migration control . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Cement placement design and execution . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
Lost circulation systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
Lost Circulation Advisor . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
Reservoir solutions
Schlumberger has been supplying products and services to the oil and gas industry for more than
75 years. Our trained, highly qualified professionals team with operating companies to maximize
asset values with reservoir solutions that combine best practices and advanced oilfield tech-
nologies with service quality and environmentally sound operations.
As exploration and production activities have expanded, our relationships with operating
companies have evolved. Today, we provide many services which help in finding hydrocarbons,
constructing and completing wells to produce them, and stimulating the wells to maximize their
production. We do this from service locations in all oil- and gas-producing areas of the world. We
are committed to providing real-time solutions that make the finding and production of oil and
gas more cost effective and that maximize recoverable reserves.
With the movement toward a more holistic approach to oil and gas development, geoscientists
and engineers gain a thorough understanding of the reservoir by using exploration and produc-
tion product technology, field services, and project management skills along with software and
information management services integrated with information technology (IT). Using this
approach, the value of the reservoir is increased and the capital expenditures and negative cash
flow are minimized.
Maximize
production
+ Accelerate Maximize
production recovery
Cash
flow Time
Minimize Defer
Minimize opex abandonment
capex
–
Training
Schlumberger training is continuous—employees receive both formal and on-the-job training
throughout their careers. We periodically assess all our training programs for content, quality and
effectiveness, and we employ the latest technology to ensure that our training remains “best in
class.”
Our training emphasizes the use of IT. We have developed on-line and CD-ROM training modules
and achieve full use of IT by providing worldwide connectivity to the internal Schlumberger
communications network and to the Internet. Both new employees and those studying for
advancement can use the Internet for their training courses.
Schlumberger technical training programs sponsor on-line, in-house and field training in all
phases of equipment selection, application and operation, as well as effective design, execution
and evaluation. Structured training programs and seminars provide the latest information and
technical knowledge, and we conduct directed learning programs and seminars around the
world.
Within Schlumberger, no education is ever really complete. Methods and techniques change,
as do market conditions and regulatory guidelines. Following formal university and in-house
training, employees continue to gain knowledge through experience and pre- and postjob ses-
sions in which principles and practices are continually improved.
The NExT† Network of Excellence in Training, an alliance of Heriot-Watt University in
Scotland, Texas A&M University, the University of Oklahoma and Schlumberger, provides training
that fills a learning gap for working professionals, both within and outside the company, to help
them diversify their skill sets and learn about emerging technologies. Delivery methods include
traditional classrooms, mentor-supported on-line distance learning, CD-ROM self-study programs
and custom on-site courses.
Our policy is to attract the very best graduates, then train and develop them. The majority of
Schlumberger managers started in the field directly after graduating.
Preface xi
Key cementing technology highlights
Our high-quality cementing solutions are based on application of best practices, environmentally
sound wellsite operations and innovative technology with safety as a highest priority. That tech-
nology includes Advanced Cement Technology, CemSTREAK* rapid deployment cementers, deep-
water cementing with DeepCRETE* cement and DeepCEM* additives, and UniSLURRY* cement
systems.
Advanced Cement Technology increases the solids content of slurries by optimizing blends of
several particles with different sizes in which the smallest particles fill the spaces between larger
particles. Because of the higher solids content, the cement has greater strength, reduced per-
meability and greater resistance to corrosive fluids.
The CemSTREAK unit is a lightweight, low-maintenance truck with four-wheel drive. It can
handle almost any cementing application, even in hard-to-reach well locations. Equipment
design makes rig-up, rig-down, cleanup and movement to next location fast and efficient. This
design allows a single unit and crew to cement as many as six wells in one day.
In deepwater cementing, DeepCRETE slurries, with their excellent slurry and set-cement
properties, are combined with DeepCEM additives, providing improved rheology, rapid strength
development and high strength. Compared with conventional cement technology, these tech-
nologies reduce the risk of shallow flow and shorten the waiting-on-cement (WOC) time and its
associated high cost.
UniSLURRY systems can be used for all types of cementing operations, including casing, liner,
squeeze and plug cementing. Similarly, the additives are functional throughout the range of appli-
cation conditions. This versatility simplifies the logistics of offshore cementing by reducing the
number and quantity of additives that have to be transported and stored.
Schlumberger provides high-quality services for well construction and remedial applications.
These services are based on best practices, environmentally sound wellsite operations and
innovative technology and always have safety as a first priority.
Cementing is a process used to support and protect the casings in a well and to achieve or
renew zonal isolation. Zonal isolation is required to prevent liquids or gases from flowing from
one zone to another within the wellbore. This isolation allows the completion and production
and subsequent abandonment of the well at the lowest possible cost. Isolation allows more
accurate well testing to define the reservoir, maximum recovery at the least cost (reduced costs
for produced water and disposal), more effective stimulation through placement focused on the
reservoir, more effective enhanced recovery and reduced abandonment costs. Without isolation,
the cost of each of these processes is increased and its effectiveness is reduced.
When isolation is not achieved by the primary cement job (cementation of the casing string)
a squeeze job is required to correct the deficiency. Squeeze jobs are also used during the well’s
life to meet changing objectives as the well and field age.
Occasionally, cement plugs are set in the well to allow changes in drilling. Plugs are also used
to isolate intervals within the well when it is depleted and abandoned.
All these cementing treatments require careful design of the cement systems to provide the
required properties of the slurry before setting and of the cement once it is in place and set.
Designs must consider the conditions in the well at the time of cement placement as well as
conditions that may occur at any time during the life of the well. In addition to the design of the
slurry and set-cement properties, the mechanics of the placement process must be designed to
accomplish optimal mud removal and cement placement. On location, the cement must be
properly mixed to achieve the required properties and pumped into place, maintaining the
integrity of the well.
To achieve the cementing objectives, various additives can be used to modify the slurry and
set-cement properties. Specific cement slurry systems are employed to meet especially demand-
ing applications. A new, innovative approach to cementing is Advanced Cement Technology. This
technology utilizes principles from the concrete industry, specially adapted for oilfield use, to for-
mulate slurries with lower water content. These advanced principles eliminate the problems of
conventional slurries, which require high water content for optimal pumpability that ultimately
reduces the compressive strength of the set cement.
This Advanced Cement Technology has two families; CemCRETE* concrete-based oilwell
cementing technology and CemSTONE* technology. CemCRETE technology increases the solids
content of the slurry using a custom-designed particle-size distribution. More solids in the
cement mean greater compressive strength, reduced permeability and greater resistance to
corrosive fluids. CemSTONE technology uses this high solids content together with particles
having specific properties to modify the set-cement performance (such as durability, flexibility
and expansion) to the needs of the well. Using stress analysis modeling software, cements can
be designed with properties to provide isolation for the life of the well.
FlexSTONE Cement
FlexSTONE systems offer mechanical properties that can be engineered to meet the changing
stresses in the wellbore; excellent flexibility and chemical resistance while maintaining lower
permeability and good compressive strength. FlexSTONE systems, with these properties cus-
tomized to the well, will resist stresses and maintain isolation. These slurries also expand to seal
any microannulus. FlexSTONE cements are engineered to be more flexible than the formation
they seal, and expansion of the cement sheath occurs both outwards (toward the formation) and
inwards (toward the casing), thus assuring complete hydraulic isolation.
See page 48 for additional information on FlexSTONE Advanced Cement Technology.
DeepCEM additives
DeepCEM liquid cementing additives were created for short transition time and early compres-
sive strength development. Such properties are necessary for isolation and early casing release
to ensure successful cementation in the unconsolidated, low-temperature environment of the
surface and conductor casings in deepwater wells. When combined with Schlumberger GASBLOK
gas migration control technology, DeepCEM slurries provide the solution to shallow gas or water
flow control. These additives can be used in foamed cement slurries.
Use of these systems allows elimination of the special blends often needed to overcome chal-
lenges related to low temperature in deep ocean drilling.
DeepCEM additives include the nonretarding dispersant (D185) and cement set enhancer
(D186). The nonretarding dispersant provides the dispersion required for good slurry design
without retardation at low temperatures. Even at the low temperatures encountered in deep-
water wells, D186 set enhancer is more effective for early strength development than standard
cement accelerators such as calcium chloride.
CemCADE software
CemCADE software can be used to design all primary cementing operations, from large-diameter
conductor casing to the deepest liners. Use of CemCADE software helps the engineer ensure that
well security is respected at all times and at all points in the well during the cementing treat-
ment. By coupling centralization calculations with a numerical fluid placement simulator,
CemCADE software allows easy flow regime and annular flow rate selection. It also aids in design
of wash, spacer and slurry for optimum displacement of mud and cement placement.
Displacement optimization helps to prevent channeling, ensuring zonal isolation.
The program utilities and underlying physics are enhanced continually to reflect the latest
developments in cementing technology. Of particular interest for deepwater operations are the
temperature simulator, gas migration predictor, and swab and surge pressures calculator. The
temperature simulator allows a calculation of fluid and wellbore temperatures that considers
wellbore environment parameters such as seawater temperature and current. Better knowledge
of the temperature makes selection of retarder or accelerator concentration more accurate as
well as allows WOC time determination based on modeled wellbore temperatures.
Services 5
Cement mixing and pumping units are specially designed for use on offshore drilling rigs.
Liquid additive metering systems provide versatility in the ability to adjust cement slurry prop-
erties right up to the time of the cementing treatment. This is especially beneficial in deepwater
operations, because the requirements may not be known until the hole section is drilled. If dry-
blended cements were used, there would be considerable time spent waiting for testing, blend-
ing and delivery if requirements are not known until the section is drilled.
Applications
■ Casings hung from subsea hangers
■ Top and bottom plug operation in casing sizes from 244 to 508 mm [95⁄8 to 20 in.]
Benefits
■ Dart release takes only seconds, reducing rig time.
■ Uninterrupted pumping improves mud removal.
■ High pumping rates allow improved mud removal.
■ Casing pressure test can be combined with bump.
■ Casing running tool can be activated without removing treating lines.
■ Remote operation improves safety.
Features
■ Wiper plugs are efficiently designed.
■ Fluids are not pumped through the plugs.
■ Plugs do not contact casing wall during rig-up.
■ Surface pressure provides positive indication of each plug release.
■ Plug launch qualified at flow rates up to 1.9 m3/min [12 bbl/min].
■ Optional three plugs separate up to four fluids.
DeepSea EXPRESS offshore plug launching system is a reliable tool for releasing cement wiper
plugs when subsea hangers are used.
Services 7
Subsea tool
The subsea tool (SST) retains the casing wiper plugs until they are released by the arrival of the
darts. Hydraulic pressure acting through the dart and a rod releases the plugs. The SST accepts
up to three plugs for 219- to 340-mm [85⁄8- to 133⁄8-in.] casing or two plugs for 406- to 508-mm
[16- to 20-in.] casing.
The deepwater cementing products and services portfolio of Schlumberger provides all the
components required to provide zonal isolation for the life of the well.
Applications
■ Zonal isolation in gas wells
■ Prevention of annular gas migration from nuisance gas stringers
Benefits
■ Minimized risk of gas migration
■ Long-term solution
■ Reduced exposure to hazardous gas flow
■ More trouble-free operations
Features
■ Tailored to specific well conditions
■ Effective at any density
■ Effective at any temperature
■ Compatible with CemCRETE and CemSTONE technologies
■ Integrated solution employing materials and techniques
■ Materials with low environmental impact
■ Engineering tools to assess risk and tailor treatment to severity
Services 9
Gas flow risk analysis
A risk analysis is an important element in the design for gas migration control. Such an analysis
incorporates knowledge of all the gas sources (from openhole logs and drilling logs), the poten-
tial for gas flow from each source and the potential routes through which gas can migrate.
25 Pa 75 Pa 150 Pa 250 Pa
50 lbf/100 ft2 150 lbf/100 ft2 300 lbf/100 ft2 500 lbf/100 ft2
Postplacement analysis provides the design engineer with a relative degree of risk for use in selection of
methods of controlling gas migration.
High risk
Schlumberger slurries for high-risk gas migration scenarios have very special properties. These
slurries are called GASBLOK slurries, proven for over two decades. GASBLOK slurries are part of
the overall GASBLOK technology, a systematic approach to solving the gas migration problem.
These slurries use either a specially designed and patented latex additive or a customized micro-
gel polymer.
The latex provides unique properties to cement slurries and the set cement. Being a suspen-
sion of solids, the latex provides excellent rheological properties and control of gelation without
affecting the hydration process. Free fluid is easily controlled and setting is rapid. The finely
divided latex particles provide efficient pore-blocking in the developing cement matrix during the
transition from liquid to solid and in the set cement. This pore-blocking minimizes the invasion
of the cement by gas and prevents its movement. Microgels provide similar effects, but with spe-
cially designed hydrated polymer particles.
The GASBLOK family of additives includes D500 GASBLOK LT additive, D600G GASBLOK MT
additive, and D700 GASBLOK HT additive for low, moderate and high temperatures, respectively.
A surfactant, D701 GASBLOK stabilizer, is used to control transition time and setting in certain
cases. These additives, used so successfully in controlling gas migration for the past two decades,
have been modified to make them acceptable in more environmentally sensitive areas, such as
the North Sea.
Low risk
When the risk of gas migration is judged to be low, less-aggressive designs are required. Slurries
can be designed with more conventional fluid loss additives in place of the GASBLOK latices or
microgel. Besides fluid loss control, excellent slurry and set properties must still be maintained.
Services 11
Poor mud High Gel
Free Cement
removal fluid strength
fluid hydration
(rheology) loss development
Bulk Chemical
shrinkage contraction
Result Gas
Gas
■ Interzonal channeling
channeling
communication within
along
■ Pressure-charged cement
interfaces
formations matrix
■ Gas to surface
■ Blowout
Unplanned costs
■ Remedial work
■ Lost production
■ Damage to
equipment
and facilities
Many slurry properties must be correctly designed for success in cementing across
gas-bearing formations.
Fluid loss control is important, because maintaining the proper ratio of water to solids is crit-
ical to maintaining the rheological properties for effective placement of the slurry as well as pre-
venting premature gelation. Premature gelation will lead to long transitions to a set matrix and
result in unacceptably early hydrostatic pressure decay. Such hydrostatic pressure decay would
in turn lead to an underbalanced condition. If occurring before the cement develops a solid
matrix, this situation can easily lead to gas invasion of the cement and migration along the annu-
lus to points of lower pressure.
Simultaneously, the proper water/cement ratio must be designed and maintained to control
slurry stability. An unstable slurry can allow the development of free fluid and/or solid sedimen-
tation. Free fluid can create a water channel in the column of cement, leading to gas flow.
Sedimentation can lead to changes in density of the slurry and result in inadequate fluid pres-
sure to control the formation pressure. An additional impact of the water/cement ratio is that of
the slurry and set-cement permeability. As the water/cement ratio increases, so does the perme-
ability of the cement matrix. A permeable cement matrix makes control of gas more difficult; if
permeability is sufficiently high, there may be migration through the matrix after setting.
Services 13
Lost circulation systems
Lost circulation is a frustrating, costly and time-consuming problem. Some of the major conse-
quences of lost circulation include increased cost resulting from
■ poor or no removal of cuttings, requiring additional wiper trips
■ stuck drill pipe
■ excessive mud lost
■ remedial work to cure losses
■ rig time required to cure losses.
Reservoir damage and loss of well are also possible as a result of
■ lack of zonal isolation caused by poor cement coverage
■ formation damage resulting from mud losses
■ blowout after a drop in hydrostatic pressure.
To select the correct technique to effectively solve lost circulation, it is necessary to know the
reasons for the losses; i.e., the type of loss and the drilling history.
Very often lost circulation treatments fail because of a lack of information such as the types of
losses and their relative depths. A lack of knowledge can lead to selection of the wrong treatment,
which usually results in poor success, excessive costs and time, and the frustration caused by
repetitive failures.
Lost circulation can occur at any time in the life of the well. During construction, lost circu-
lation can be encountered while drilling and while cementing. These problems are solved by dif-
ferent methods. A tool for identifying the best solution is the Lost Circulation Advisor.
Applications
■ All types of lost circulation
Benefits
■ A simple software based on knowledge management, not complicated mathematical models
■ A systematic and analytical approach to lost circulation
■ A guide to the best lost circulation treatment and the relative depths
■ Validated cases for more precise solutions
■ A low-cost solution to complex problem
InstanSeal system
The InstanSeal‡ system is a unique technology for combating high mud losses. It is often more
time- and cost-effective than other lost circulation control methods. The InstanSeal system uses
shear activation to trigger formation of a rigid gel. This unique activation method saves crucial
drilling time and money over other lost circulation methods.
The base fluid for InstanSeal lost circulation control is an emulsion. The emulsion contains
gelling polymer and crosslinker in separate phases. The emulsion is converted when the slurry is
pumped through the nozzles in the bit, crosslinking the polymer. This results in rapid action and
excellent control of polymer placement into the loss zone.
Activation of the InstanSeal system is by shearing force rather than chemical action.
This technology makes placement across the loss zone more certain.
Applications
■ Severe lost circulation
Benefits
■ Internally activated
■ Valuable rig time savings
■ Downhole mixing of fluids not required
Features
■ Use to 95°C [200°F]
■ Set time independent of bottomhole temperature (BHT)
■ Can be weighted to 1440 kg/m3 [12 lbm/gal]
■ Requires no tripping
■ Set time short and adjustable
■ Is acid-soluble when set
■ Can be mixed up to 3 weeks before use
Services 15
InstanSeal Cement system
The InstanSeal Cement system is similar to the InstanSeal system, but has powdered cement
added to the oil phase. Once the emulsion is broken and the system forced into the loss zone, the
cement will become wet with water and will set. This system is used when a more permanent
solution is required. InstanSeal Cement is stable to 110°C [230°F].
Applications
■ Severe lost circulation
■ Support for cement plugs
Benefits
■ Internally activated
■ Rig time savings
■ No downhole mixing of fluids
Features
■ Use to 163°C [325°F]
■ Set time independent of BHT
■ Can be weighted to 2040 kg/m3 [17 lbm/gal]
■ Requires no tripping
■ Set time short and adjustable
■ Is acid-soluble when set
■ Can be mixed up to 3 weeks before use
CemNET fibers are inert and require no special handling. They can be readily
dispersed in water-base fluids such as cement. An interlocking network is formed,
allowing the cement to bridge and resume circulation.
Services 17
Applications
■ Regain circulation while cementing
■ Most cement slurry formulations
■ All temperatures
■ Any slurry density
Benefits
■ Minimizes losses during cementing
■ Raises cement tops
■ Helps prevent cement fallback
■ Reduces the need for costly remedial operations
■ Reduces excess cement requirement
■ Makes cement returns more predictable, thus decreasing disposal costs
■ Provides coverage of loss zones during cementing operations
Features
■ Fibers added directly to the slurry during mixing, without dry blending
■ No effect on cement properties
■ Compatible with most cementing systems and additives
■ Forms bridging network in the slurry
Applications
■ Mud removal in oil and gas wells, including deviated, extended-reach, horizontal and injection
wellbores
■ Oil-base mud (OBM) or water-base mud (WBM)
Benefits
■ Enhances zonal isolation
■ Eliminates production of unwanted downhole fluids
■ Reduces occurrence of sustained casing pressure
■ Minimizes casing corrosion through improved cement bonding
■ Reduces remedial operations and their associated costs
Features
■ An engineered approach using specialized tools and products
■ Ability to assess the effect of all relevant parameters on the mud removal process
■ A wide range of flexible preflush systems for all application conditions
■ Proven results in the field
■ Environmentally friendly spacers
Recognizing that effective mud removal cannot be achieved without considering the effect of
all relevant parameters, the WELLCLEAN II engineering solution utilizes innovative products
and tools to design cement placement for effective zonal isolation. These products and tools
include
■ optimized chemical wash systems
Pipe centralization
Because fluids in the annulus tend to flow more freely on the wide side, casing centralization is
critical to ensure continuous flow all around the annulus. Schlumberger engineers use the cen-
tralization module of CemCADE software to design the optimum degree of standoff to meet the
requirements for mud removal.
Services 19
Displacement regimes
Complete mud removal can be achieved using either laminar or turbulent flow regimes. The
choice between the two regimes depends on several parameters and conditions, including well
geometry and fluid properties. The design engineer must analyze all the relevant parameters to
make the right selection. The WELLCLEAN II simulator is a powerful tool for showing critical
results with the chosen fluids and flow regimes. These include such parameters as the percent-
age of cement coverage, the risk of leaving a mud film or channel at the end of the cement job,
and for turbulent flow, the contact time—all as a function of depth and time.
Fluids design
Knowledge of cement and spacer fluid properties is essential to ensure proper zonal isolation.
The effectiveness of each fluid to displace the fluid ahead of it can be checked using the
WELLCLEAN II simulator. Output will clearly predict channeling that exists between the fluids.
WELLCLEAN II simulator output guides the design engineer to improve mud displacement
through modification of spacer and cement properties and flow parameters.
WELLCLEAN II simulator
Ensuring complete zonal isolation is the ultimate goal of cementing operations. However, fre-
quently this goal is not achieved. Because incomplete mud removal is a repeated source of unex-
pected costs for operators, every effort should be made to ensure critical zonal isolation on the
primary cement job.
A two-dimensional numerical simulator, the WELLCLEAN II simulator uses computational
fluid dynamics to predict the process of cement placement. Based on well geometry and trajec-
tory, downhole fluid properties, volumes, pump rates, and casing centralization, Schlumberger
engineers predict the efficiency of mud removal and identify whether a mud channel will be left.
Using the WELLCLEAN II simulator, engineers can make the necessary design changes to opti-
mize the operation and achieve zonal isolation.
The design engineer uses visually displayed displacement patterns produced by the
WELLCLEAN II simulator as a guide to the most efficient and complete form of mud removal.
Applications
■ Mud removal and cement placement to achieve zonal isolation in vertical, extended-reach and
horizontal wells
Benefits
■ Enhanced zonal isolation
■ Reduced costs associated with mud removal through optimized job design
■ Predictable results validated by physical experiments and field performance
Features
■ Accurate rheological description of fluids (Herschel-Bulkley model)
■ Simulation of fluid placement in turbulent and laminar flow
■ Maps of fluid position and concentration in annulus
■ Maps of fluid velocity and flow regime
■ Animated view of fluid displacement process as a function of job time
■ View of potential detrimental contact between mud and cement during displacement
5000 5000
5400 5400
Depth Depth
(ft) (ft)
5800 5800
6200 6200
Wide Narrow Wide Wide Narrow Wide Wide Narrow Wide Wide Narrow Wide
Mud High
Spacer Medium
Cement Low
None
Modeling allows the engineer to analyze various mud removal scenarios and
select the best one to achieve zonal isolation.
WELLCLEAN II advisor
The WELLCLEAN II advisor design tool greatly facilitates the selection and adjustment of addi-
tive concentrations in spacer fluids for the optimal rheological properties to achieve the ultimate
goal of mud displacement and zonal isolation. This software reduces engineering and laboratory
time through recommendation of additive concentrations for the specific mud removal scenario
(flow regime, required fluid properties) at the temperature of the well.
Chemical washes
Chemical washes are used if increased density is not needed for well control and turbulent flow
is required. These fluids have a density and viscosity close to those of water or oil. When pumped
ahead of the cement slurry, they assist in mud removal by diluting, thinning, and dispersing mud
and by water-wetting the casing surface, improving the quality of the bond between the cement
and the casing and formation.
When oil-base fluid is used for drilling, base oil is often the first preflush fluid and is followed
by chemical washes containing surfactants and/or solvents.
Schlumberger offers a comprehensive line of MUDCLEAN* chemical washes for all applications.
Services 21
Applications
■ Cementing jobs where a light preflush is pumped in turbulent flow
Benefits
■ Improved bonding and hydraulic isolation
Features
■ Displace mud by thinning, turbulence and erosion
■ Preflushes for any type mud
■ Compatible with cement slurries
■ Compatible with WBM and OBM
■ Leave surfaces water-wet
■ Easy to mix in the field
Chemical washes are lightweight, thin fluids that remove mud by turbulent flow.
MUDPUSH spacers
Spacers are weighted fluids that provide a compatible buffer between the drilling fluid and the
cement slurry and offer control of rheological and flow properties. They can be designed for tur-
bulent or laminar flow regimes. Performance of the spacer is optimized using engineering tools
such as the WELLCLEAN II simulator. Their effective use results in displacement of drilling fluid
around and along the annulus for effective zonal isolation.
To provide effective mud removal, Schlumberger offers a wide range of MUDPUSH* spacer flu-
ids to suit zonal isolation criteria under all well conditions.
Schlumberger offers a comprehensive line of MUDCLEAN chemical washes for all applications.
Depending on well conditions and on the fluid properties, the spacer is designed to be pumped
MUDPUSH WHT Water (any salinity) 1560–2400 [13–20] Laminar 232 [450] WBM or OBM
in either turbulent or laminar flow. Performance of the spacer is optimized using engineering
tools such as the WELLCLEAN II simulator.
The MUDPUSH II spacer properties are specially formulated to address environmental con-
cerns. Properties include lower toxicity, better biodegradation and lower bioaccumulation to pro-
duce a minimal impact on the environment.
MUDPUSH II spacers have less retarding effect on the cement than earlier versions of spac-
ers. Any contaminated cement slurry is subject to less delay in strength development. This proves
critical, especially at tops of liners when relatively fast strength development is required.
In wells drilled with an oil-base drilling fluid, the proper surfactant and, in some instances, a
solvent, are tailored to the base oil. These surfactants and solvents are added to basic MUDPUSH
spacer to disperse the oil phase into water and provide a water-wet surface for better bonding to
the cement.
Services 23
Applications
■ All cementing operations to 232°C [450°F]
Benefits
■ Turbulent or laminar flow displacement
■ Predictable displacement along the entire cemented interval
■ Good fluid loss control over a wide density and temperature range
Features
■ Density range from 1200 to 2400 kg/m3 [10 to 20 lbm/gal] or 1560 to 2400 kg/m3 [13 to 20 lbm/gal]
for MUDPUSH WHT spacer
■ Compatible with cement
■ Excellent suspension properties
■ Compatible with fresh water, salt water or seawater
■ Compatible with all drilling fluids (water- and oil-base)
■ Stable rheological profile with increasing temperature
■ Excellent reproducibility between laboratory and field performance
■ Extremely stable
■ Easy to mix in the field
In the upper log, a conventional spacer resulted in poor isolation in the permeable section
(140-mm [51⁄2-in.] liner at inclination of 55° with 1800-kg/m3 [15-lbm/gal]) cement. The lower
log shows a 178-mm [7-in.] liner in a horizontal well cemented with lightweight cement and
using MUDPUSH II spacer for mud removal.
Applications
■ Remote data transmission
■ Remote monitoring of wellsite operations
■ Two-way communication and distribution of real-time cementing, leakoff test (LOT),
formation integrity test (FIT) and completion test information
■ Cement evaluation
■ Remote monitoring and decision-making on squeeze cementing
■ Sharing of data among selected parties
■ Supervisory control of remote assets
■ Distribution of cementing laboratory reports
Benefits
■ Secure connection to confidential data
■ Real-time worldwide access to data through the Internet or an intranet
■ Speedy communication of well data such as caliper and survey information for cementing
design
■ Simultaneous review of data from many sources for cement evaluation
■ Real-time decision-making
■ Promotion of teamwork and collaboration
■ Real-time access to Schlumberger experts
■ Time and expense of travel to wellsite saved
■ Fewer safety and environmental hazards
Services 25
Features
■ No communication infrastructure or specialized software required
■ Alarm notification services
■ Access to complete well data for use in cementing design
■ User-defined acquisition of data, either streamed or polled
■ Compatible with CemCADE cementing design and evaluation software
■ Comparison of actual job with design
■ Proprietary software for autorecovery and compression to manage network outages and expen-
sive bandwidth
■ Customizable graphics
■ Configurable levels of accessibility for partners and third parties
■ Acceptance and display of wellsite information transfer specification (WITS) or WITS markup
language (WITSML) data from any source
System requirements
■ Minimum 200-MHz personal computer
■ 32-MB random access memory
■ Windows NT® Windows® 98, ME, 2000, or XP
■ Netscape® or Microsoft® Internet Explorer browser
■ Internet connection using transmission control protocol/internet protocol (TCP/IP) over local
area networks, wide area networks, or modem-to-modem over Ethernet, telephone, cell phone
or satellite. There are no restrictions regarding types of Internet access, but a high-speed con-
nection will enhance system performance. A minimal 9600-bps link is required to upload real-
time data.
Services 27
Software
Applications
■ Primary cementing on land and offshore wells
■ Centralizer selection and centralization optimization
■ Mud removal optimization
■ Gas migration risk assessment and optimization
■ Temperature simulations
■ Preparation of cement slurry testing schedules
■ Foamed cement design
■ Postjob analysis
■ Plug cementing
Features
The fluid placement simulator evaluates well control and pipe integrity by computing and com-
paring hydrostatic and dynamic pressures with the formation fracture and pore pressures, and
tubular burst and collapse ratings. This is done for all points in the well during the cementing
process.
■ Fluid test data (e.g., rheology and thickening time) are managed in a database.
■ Standoff is optimized using caliper and directional survey data and properties of the
centralizers.
■ Forces to run the casing in the hole are calculated.
■ WELLCLEAN technology and fluid-fluid displacement theory is used to predict mud removal
and help ensure zonal isolation.
■ Temperatures in the well during conditioning and cementing are determined, enabling slurry
design for specific conditions.
■ Schedules for thickening-time tests are constructed using temperature simulator.
■ Temperature schedules are generated to avoid premature setting or excessive WOC time
resulting from over-retardation.
■ Postplacement analysis aids in analysis and minimization of the risk of gas migration after
cement placement.
■ Postplacement analysis aids in selection of operational procedures and slurry properties for
minimization of risk of gas migration.
■ Surge and swab calculations check well security during running and moving casing.
■ Tables are generated to schedule and monitor foamed cement job.
■ Foamed cement job optimization.
■ Well data and cementing parameters are exported to external software, such as SoniCalc
acoustic log calculator.
■ Postjob evaluation is performed using quality assurance and quality control plots from data
recorded during the treatment.
■ Pressure signature evaluation of unanticipated events.
■ Designs for balanced plug minimize chance of contamination during placement.
■ Volumes for balanced fluids are calculated.
■ Well control and pipe integrity are checked during forward or reverse circulation following
plug cementing.
Temperature plots show a profile of the temperature in the casing and in the
annulus at selected times during the cementing process.
Software 31
Stress analysis model
Wells are exposed to many changing conditions that create mechanical stresses on the casing and
the cement sheath behind it. These stresses can come from pressure changes; fluid weight
changes during drilling and completion; pressure testing and pressure treating such as squeeze
cementing or high-pressure stimulation treatments; changes in well pressures caused by reser-
voir pressure depletion. Temperature changes, especially in upper portions of a well producing
high-temperature fluids, can also generate mechanical stresses.
FlexSTONE cement is designed to prevent cement failure caused by these mechanical
stresses. This flexible and expansive cement can survive the mechanical stresses and maintain
isolation in the wellbore, when properly designed. A proper design requires knowledge of the cur-
rent stress conditions in the well as well as the future conditions that will occur over its life.
Stress analysis model software was developed by Schlumberger to predict the stresses to be
experienced by the cement sheath throughout the life of the well. By analyzing the changing con-
ditions of the well, the mechanical stresses are determined. The software also assesses the
mechanical properties of the cement to determine if the cement will survive these stresses. If
not, the mechanical properties of the cement can be modified so that the cement will survive to
provide isolation for the life of the well.
Using
stress
analysis
model
software,
set-cement
properties
are matched
to formation
properties and
future well conditions.
Mechanical properties
of FlexSTONE cement
are adjusted through
static testing.
Benefits
■ Isolation for the life of the well
■ Cement designed for the conditions of the well
Features
■ Evaluates well stresses based on anticipated well operations
■ Evaluates cement behavior under anticipated stresses
■ Allows selection of minimum cement mechanical properties to maintain isolation
Applications
■ Pipe and cementing data lookup
■ Cementing computations
■ Typical fracturing calculations
■ Coiled tubing calculations
■ Basic materials formulation (cement, hydrochloric acid, brines)
■ Volume calculations for tanks, pits, tubing and annulus
■ Engineering calculations
■ Unit conversions in multiple standards
■ Field quality checks
Benefits
■ Faster, more consistent computations through user-friendly calculators
■ Fewer calculation errors
■ Intuitive extrapolation of computations from single-point entry
■ Faster, more accurate volume calculation for intricate geometries and hanger scenarios
■ Rapid access to database
■ Better understanding of forces through enhanced graphics and animations
■ Archiving of data and calculations for future use
Software 33
Features
■ Pipe data for both API standard and non-API tubulars
■ Exchange of data among users
■ Useful calculators to assist in multiple well operations such as drilling and workover, cement-
ing, fracturing, acid, oil and brines and coiled tubing
■ Library of predefined wellbore diagrams
■ Engineering data with source equations
■ Data from tables can be copied and pasted into other applications such as spreadsheets or
word processing software
■ View of page can be copied into other applications to use in reports or presentations
The Schlumberger i-Handbook tool retains the familiar appearance of a book, making use of
the program intuitive. A right click on the section tab displays a table of contents for the section.
Clicking on an item in the list opens that part of the book. Standard oilfield and metric units are
supported, and changing the units is as simple as clicking on the displayed unit and selecting the
alternate. Users can also save a particular units format under the custom units option, thus hav-
ing the flexibility of using multiple units systems. Tubing and casing data tables can be expanded
so that additional physical properties may be viewed. Data entered in any calculator or wellbore
configuration can be saved and sent to another user, thus facilitating quick and accurate
exchange of information.
Wellbore diagrams can be created by dragging and dropping the elements, and
the i-Handbook tool automatically calculates volumes.
Software 35
A thorough understanding of the treatment and effects of recommended actions are commu-
nicated through visual, sometimes animated, schematics. Using various input, the user can pre-
pare diagrams illustrating the various combinations of strings and sizes, thus creating multiple
realistic design options in one session. With a zoom feature, wellbore features can be examined
closely. Wellbore elements are automatically labeled, and the user can color code volumes per-
taining to different sections in the wellbore. The completed wellbore schematic can be presented
as a picture file pasted in a report by using “copy” feature.
In addition to providing views of various fluid positions during the job, the i-Handbook tool can
be used to generate configurations corresponding to hangers and wellbore geometries associated
with washouts and under-reaming.
An automated check corrects elements of the well scenario or alerts the user to an inconsis-
tency so that corrections can be made. For example, the system issues an alert if the input for
the outer diameter of a pipe is greater than the wellbore diameter.
The i-Handbook tool includes data not included in printed versions of the engineering hand-
book and each section has been updated with new content. Supplier databases have also been
updated and expanded. New offerings include the following.
Volume
■ Annulus and tubular volume calculation
■ Volume-to-depth conversions
Fracturing
■ Expanded proppant database
■ Slurry density tables and proppant fill tables
■ Calculation of gate settings for various blender types
■ Proppant settling rates in various fluid types
■ Calculation of flow of gas through chokes
■ Calculation of pressure drop across an orifice
■ Calculation of perforation friction
The i-Handbook tool makes it easy to calculate volumes for a balanced cement plug.
Software 37
Materials
Introduction
In today’s remote areas and extreme environments, exploration puts increasing demands on the
technology required for developing new reserves. No new technology is better tailored to these
demands than Advanced Cement Technology from Schlumberger. Incorporating 10 years of R&D,
Advanced Cement Technology provides a range of cement alternatives, tailored to the well, to
achieve zonal isolation for the life of the well.
CemCRETE Advanced Cement Technology decouples set-cement properties from slurry den-
sity. With CemCRETE systems, properties such as permeability and strength are superior to
those of conventional cements. Slurries can be lighter (or heavier) than ever, without compro-
mising properties of the set cement.
CemSTONE systems, the newest generation of Schlumberger Advanced Cement Technology,
offer set-cement properties that can be adjusted to meet the requirements of the well. They are
purpose-built to withstand mechanical stresses and changes in temperature and pressure that
damage conventional cements. CemSTONE systems offer control over properties never possible
with conventional oilwell cement, allowing you to meet your requirements for such set proper-
ties as flexibility, expansion and impact resistance.
Standard cement slurries require water to fill the void between particles. CemCRETE slurries
fill the interparticle void with more solids, giving superior cement properties.
0.25
0.20
0.15
Permeability
(mD)
0.10
0.05
0.00
12.0 lbm/gal 12.0 lbm/gal 15.8 lbm/gal 17.5 lbm/gal
Conventional LiteCRETE Conventional DensCRETE
cement cement cement cement
Foamed cement
LiteCRETE cement
3500
3000
2500
Compressive 2000
strength
(psi) 1500
1000
500
0
8 9 10 11 12 13
Density (lbm/gal)
0
Permeability
(log mD) –1
–2
–3
–4
8 9 10 11 12 13
Density (lbm/gal)
Materials 41
Low-density LiteCRETE slurry frequently eliminates stage cementing in long intervals. With
performance similar to higher-density slurries, you can get exceptional perforation quality with-
out reducing cement integrity. LiteCRETE systems are even strong enough for hydraulic fractur-
ing treatments or setting kickoff plugs.
In some cases, special properties may be built into CemCRETE slurry systems to meet specific
performance criteria. For instance, casing strings through permafrost zones must be cemented
with slurries having protection from freezing. For this application, Schlumberger developed
Arctic LiteCRETE cement.
Applications
■ Across weak formations where high-performance cement is required
■ Slurries with densities as low as 900 kg/m3 [7.5 lbm/gal]
■ Alternative to stage cementing or topping out
■ Alternative to foamed cement
■ Across completion intervals
■ Kickoff plugs
Benefits
■ Production-quality zonal isolation across easily fractured formations
■ Longer cement columns without losses caused by hydrostatic pressure
■ Elimination of two-stage cementing
■ Less damage to completion intervals resulting from slurry or filtrate invasion
■ Whipstock plugs at lower densities with less tendency for contamination or falling downhole
Features
■ Cement with low density but that has completion-quality properties
■ Slurry preparation without special equipment or additional personnel
■ Set-cement properties vastly superior to those of other lightweight systems at equivalent
densities
Applications
■ Placement of full columns of cement for complete coverage across weak, shallow formations
in deepwater
■ Potential shallow water or gas flows
Benefits
■ Cement circulation to surface across weak shallow formations
■ WOC time minimized in low-temperature environments
■ Control and isolation of shallow water or gas formations
■ Low-density, low-temperature cementing without complicated equipment setup or additional
personnel on the rig
Features
■ Rapid compressive strength development even at 4°C [40°F]
■ Low density with compressive strengths comparable to those of higher-density cement
■ Low density with low permeability
■ Slurry preparation without special equipment or additional personnel
■ Compatible with Schlumberger gas migration technology
Materials 43
3500
2000
Pressure
At 65°F
(psi) 1500
1000
500
0
0 5 10 15 20 25 30
Time (hr)
At low temperatures, 1500-kg/m3 [12.5-lbm/gal] Deep CRETE slurry develops strength faster than conventional
Class G cement with density of 1895 kg/m3 [15.8 lbm/gal]. WOC time is reduced, saving rig time and reducing costs.
500
350
300
Friction
pressure 250
(lbf/1000 ft)
200
150
100
50
0
1 3 5 7 9
Pump rate (bbl/min)
CemCRETE technology results in slurry formulations that have excellent flow properties. Friction
pressures are much reduced, so slurries can be placed at greater flow rates to reduce place-
ment time and enable better mud removal.
Applications
■ High-pressure primary cementing
■ High-density slurries to 2880 kg/m3 [24 lbm/gal]
■ Well control plugs
■ Sidetrack and whipstock plugs
■ Grouting
Benefits
■ Easier slurry placement in narrow fracture-pressure/pore-pressure windows
■ Reduced costs and risks associated with long WOC
■ High-density cements that can be continuously mixed
Features
■ High-density cement slurry with lower viscosities
■ Greater density differentials with high-density drilling fluids
■ Shorter placement times, allowing use of slurries with shorter pumping time, and
consequently shorter WOC time
■ Stability at high temperatures without special additives
■ Easy design of high-density systems
■ Reduced additive requirements
■ Ability to increase the density at the wellsite using special additives
Materials 45
Syringe containing
the slurry to be injected
Transparent
plate
Porous plate
In this 120-micrometer [0.005-in.] slot test, well-dispersed microcement bridged immediately after
entering the slot. SqueezeCRETE slurry penetrated and filled the entire length of the slot, providing
a complete, effective seal.
Applications
■ Microannulus repair
■ Repair of leaking liner tops
■ Repair of leaking perforations
■ Squeeze of small channels
■ Plugging and sealing of old gravel packs
Benefits
■ Improved penetration into difficult-to-repair and difficult primary isolation problems
■ Superior channel-filling properties for complete isolation repair
■ Low placement pressures for improved fluid placement
■ Restoration of zonal isolation or well integrity
Features
■ Superior injectivity compared to other remedial systems, including microcements
■ Superior slurry properties, including low viscosity, low fluid loss
■ Superior set-cement properties, including high compressive strength and low permeability
Materials 47
Temperature shock that occurs
when hot produced fluids pass
through lower-temperature
surface casings causes
Microannuli are created stress cracks in conventional
by changing the fluid weight. cement. CemSTONE systems
CemSTONE systems can are very resistant to thermal
expand to reseal the well. and mechanical stresses.
Applications
■ HPHT gas wells
■ Casings subjected to changing stress loading
■ Casings isolating gas, either productive or nuisance
■ Steam injection wells
■ Areas with high tectonic stresses
Benefits
■ Zonal isolation during and after stimulation treatments
■ Extended productive life of steam injection wells
■ Long-term isolation and casing protection in dynamic stress environments
■ Long-term isolation and casing protection in corrosive environments
■ Protection from annular gas and fluid migration
■ Prevention of sustained casing pressure
■ Prevention and healing of microannuli resulting from decreases in pressure or temperature
while drilling and completing
Materials 49
12
Conventional cement
FlexSTONE system
10
Well isolation 6
properties
0
T/E ratio Bond strength Permeability
(MPa after 4 weeks’ set time) (µD)
Properties of conventional cements are not adequate for difficult well isolation.
FlexSTONE systems have higher ratios of strength to Young’s modulus (T/E) and
higher bond strength while maintaining low permeability.
Features
■ Mixed and pumped with conventional equipment
■ Flexibility adjusted to the requirements for the life of the well
■ Linear expansion two to three times greater than possible with conventional cement systems
■ Lower permeability than conventional cement—independent of slurry density
■ Resistance to corrosive fluids
Applications
■ Multilateral completions
■ Reentry wells
■ Sidetrack plugs, especially in hard formations
■ Across shoes where impacts are high during subsequent drilling
Benefits
■ Zonal isolation integrity across multilateral junctions
■ Improved security against failure of the cement sheath in high-impact areas
■ Better isolation in high-density, precision perforating
■ Improved success in setting sidetrack plugs
Features
■ Engineered mechanical properties
■ Mixed and pumped with conventional equipment
■ Increased durability
■ High resistance to impact
■ Lower permeability than conventional set cement—independent of slurry density
■ Broad density range (1200–3360 kg/m3 [10–28 lbm/gal])
■ Greater drilling resistance for faster sidetracks
Materials 51
DuraSTONE Advanced Cement Technology systems are more durable and have better
impact resistance than conventional cements, so they provide better isolation under
rugged drilling and completion conditions. The conventional cement (top right) failed
after 6 impacts while the DuraSTONE cement (bottom right) held up to more than
82 impacts.
16
15X
14
12
10
DuraSTONE
system 8
performance
6
4 3.5X
3X
2
Conventional cement
0 performance
Drilling Impact Energy for
resistance resistance flexural failure
DuraSTONE systems are tougher than conventional cement. They have better
drilling resistance and impact resistance, and significantly more energy is
required to cause flexural failure.
Lightweight Cements
Lightweight cements are used to control losses to weak or high-permeability formations. In most
cases, cement extended by the addition of water and additives to prevent water separation are
adequate to control the losses. These cements generally have low strength and high permeabil-
ity. However, when low density with either high strength or low permeability is required, special
formulations are necessary to meet those requirements.
Applications for lightweight cements include very weak, fractured, and highly permeable or
vuggy formations. Such cements can be used in primary, squeeze or plug cementing.
Low-density LiteCRETE cement or foamed cement can float on water. After a short period,
the high-porosity foamed cement sinks as a result of water absorption. LiteCRETE cement
continues to float as a result of its low porosity and permeability, which is beneficial for
preventing gas flow and damage to the cement or casing by corrosive fluids.
Materials 53
LiteCRETE cement
LiteCRETE cement is a special formulation using patented technology to produce very low
permeability and high strength. LiteCRETE cement is discussed in detail in the section on
CemCRETE cements.
Foamed cement
Cement is foamed by adding a gas (generally nitrogen) and surfactants. Foamed cement has been
very effective in controlling losses when very weak formations are cemented or where formations
are highly permeable. The thixotropic nature, in addition to the low density of the cement, makes
it highly effective in these scenarios. In addition to their low density, foamed cement slurries pro-
vide excellent strength and relatively low permeability compared with low-density cements pre-
pared by conventional means. Foamed cement has greater durability than conventional cements.
This cement can be made at virtually any density, depending on the density of the base slurry
and the amount of gas. Virtually any cement used in the oil field can be used as the base slurry.
A further advantage of foamed cement is that the density at which it is mixed can be selected
immediately prior to the job, unlike the case of preblended cements. Additionally, by merely
adjusting the gas ratio, the density can be changed during the job to provide slurries with differ-
ent properties in different parts of the well.
Materials 55
With a low rate of fluid loss and low rheology values at high salinities, the SALTBOND service
also provides controllable thickening times and high early compressive strengths. The result is
valuable protection against casing collapse.
SALTBOND slurry offers these advantages:
■ good fluid-loss control (less than 100 mL/30 min)
Materials 57
Cements for harsh environments
In some situations, cement with special resistance properties is required. This is true in wells
with soluble sulfates that can attack the cement (generally controlled by the chemistry of the
Portland cement during manufacture) or when other chemical compounds may contact the
cement. Sulfate resistance is imparted to the cement in moderate- and-high-sulfate resistant
cements during manufacture. Resistance to attack by other chemicals is controlled by selection
of the components added to the cement or by using special cements, such as synthetic cement.
Acid-resistant cement
In some situations, cement is exposed to acid. Portland cement is acid soluble, although in most
cases acid treatment does not cause failure to the cement sheath. When large volumes of acid are
pumped at high rates and expose old perforations that have been sealed with cement, the plugs
in the perforations sometimes fail. Acid-resistant cement can prevent such failures.
Acid-resistant cement is made from conventional API cement with a special formulation of
latex that reduces the permeability of the cement and imparts acid resistance. When used for
plugging perforations, this formulation has been effective in wells where acid treatments have
caused failure of the plugged perforations in other cement formulations.
When complete resistance to attack by acid or other chemicals is required, synthetic cement
can be used.
Synthetic cement
Synthetic cement is designed for completing waste-disposal wells. It is characterized by high cor-
rosion resistance and high compressive and shear-bond strength. Synthetic cement is resistant
to attack by strong acids and bases, such as 37% hydrochloric, 60% sulfuric and 50% sodium
hydroxide, at elevated temperatures. However, it is not resistant to organic solvents such as ace-
tone or chlorinated solvents. The system density can be adjusted from 1140 to 1560 kg/m3 [9.5 to
13.0 lbm/gal]. The upper temperature limit of synthetic cement is between 93 and 104°C [200
and 220°F], depending on the required pumping time.
Remedial cementing is another application for synthetic cement. Computer modeling shows
that it can enter microleaks and microannuli at low differential pressures.
Materials 59
Benefits
■ Simplified slurry design
■ Cost-effective
■ Minimized rig time
■ Fewer additives for simplified wellsite logistics
■ Low sensitivity to cement variations for reduced slurry-design time
Features
■ Universal fluid-loss and retarder additives for any condition
■ Low sensitivity to cement brands
■ Low sensitivity to temperature and concentration variations
■ Lower concentrations needed
■ Highly predictable concentration and thickening time
■ Minimized WOC time
■ Environmentally friendly chemistry
0.9
0.8
0.7
0.6
0.5
UNIFLAC L
(gal/sk) 0.4
0.3
0.2
13.0 lbm/gal
0.1 16.2 lbm/gal
0.0 18.5 lbm/gal
50 150 250 350 450
Temperature (°F)
Benefits
■ Economical
■ Savings from less WOC time
■ Simplified slurry design
■ Simplified logistics—few additives required
Features
■ Low sensitivity to cement brands
■ Low sensitivity to temperature
■ All densities
■ Fresh to salt-saturated mix water
■ Compatible with all additives, including calcium chloride accelerator and silicate extenders
■ Synergy with Schlumberger UNISET retarders
■ Low concentration requirements
■ Excellent slurry rheology
12
10
D177
4
2
0.00 0.05 0.10 0.15 0.20 0.25
Concentration (gal/sk)
Materials 61
Excessive retardation by conventional retarders impairs strength development, extending WOC
time and making the cement vulnerable to invasion by well fluids or mechanical damage from
changing stresses in the well. In extreme cases, some cementing treatments must be done in
several stages to avoid excessively long setting times. This complicates and increases the overall cost
of the operation.
UNISET HT additive retards to provide sufficient time to place the cement, yet promotes early and
rapid strength development to minimize WOC time. UNISET HT additive is also much less sensitive
to temperature variations than other cement retarders. It is the preferred retarder for the most
challenging situations when temperature is not well defined or if there is a large difference between
temperature at the top of the liner and the bottom of the cement.
Applications
■ All cementing operations
Benefits
■ Simplified slurry design
■ Much reduced risk of problems from inherent temperature errors
■ Cost benefits from simplified logistics, reduced additive usage and shorter WOC time
■ Lower concentrations required due to synergy with UNIFLAC additives
Features
■ Full range of temperature
■ All densities
■ Fresh water and seawater
■ Highly reliable and predictable concentration and thickening time response
■ Only two additives needed for entire temperature range
■ Synergistic with UNIFLAC fluid-loss additives
■ Rapid setting and compressive-strength development
7
16-lbm/gal slurry
5
D121/D28
Ratio of time to reach 4
50 psi at 320°F (hr)
to thickening time
at 350°F (hr) 3
D121/D28
2
1
2 4 6 8 10 12
Thickening time at 350°F (hr)
1.0
0.8
0.6
Concentration
(gal/sk)
0.4
0.2
0.0
180 200 220 240 260 280 300 320
Pump rate (bbl/min)
Cementing additives
The following paragraphs and tables describe the performance of cementing additives by func-
tional group. Some materials are discussed in more detail in sections on specific functional
systems. The Cementing Additive Quick Guide and Cementing Additive List provide descriptions
of additives listed by functional group and by code, respectively. The list gives general application
conditions for each additive. These application conditions reflect those tested during product
development. In many cases, the products can be used outside the quoted conditions with testing
appropriate to specific applications.
Accelerators
Accelerators are materials that cause cement to hydrate and develop strength earlier and faster.
They are commonly used to provide improved strength at low temperatures and to counteract the
retarding effects of other additives. Accelerators also shorten the thickening time.
Antigelation agents
In some cases gelation is caused by the chemical makeup of the cement. Many times this gela-
tion can be controlled by dispersants, but special materials may be required.
Materials 63
DeepCEM additives
DeepCEM liquid cementing additives were created for short transition time and early compres-
sive-strength development. Such properties are necessary for isolation and early casing release
to ensure successful cementation in the unconsolidated, low-temperature environment of the
surface and conductor casings in deepwater wells. They are also useful in other low-temperature
situations. DeepCEM additives are discussed in detail on page 56.
Dispersants
Dispersants act to reduce the viscosity of cement by breaking up aggregates of the fine cement
particles. This reduction in viscosity allows mixing at lower water/cement ratios for higher
density, improved fluid-loss control and pumping at reduced pressures.
Expanding additives
Expanding additives react chemically after hydration (setting) to produce an increase in the bulk
volume of the cement. This reaction provides benefits in zonal isolation and protection of the cas-
ing. When used across soft formations, flexible systems may be required to prevent microannulus
formation.
Extenders
Extenders allow the production of a greater volume of slurry from the powdered cement. This fea-
ture can result in reduced cost and, where the extenders are lightweight (or they allow additional
water to be used), lower density. The advantage of reduced cost is obvious. Reduced density is
important where weak formations are to be cemented. Such weak formations could part and
allow loss of the slurry during the cementing operation. A variety of extenders are available to pro-
vide for different requirements of lower density, lower cost and other performance parameters.
Retarders
Retarders are used to lengthen the time that a cement slurry can be pumped or remains fluid so
that other operations (such as pulling pipe after spotting a cement plug) can be performed. They
are required at elevated temperatures or when large volumes of slurry require a long time to
pump at lower temperatures.
Special additives
There are a number of additives that do not fit neatly into functional groupings. Fibers are used
for controlling lost circulation (see section on CemNET advanced fiber cement). Special types of
fibers also improve the impact resistance and tensile strength of cement (see section on
DuraSTONE cement).
The flexibility of cement can be improved by the use of special additives. This increase in flex-
ibility provides increased resistance to failure by mechanical stresses imposed on the cement
during well operation. (See section on FlexSTONE cement.)
Granular salt (sodium chloride) and potassium chloride are used primarily to change the ionic
nature of the water in the slurry, which helps to minimize adverse formation interactions. In
cases where the formation is salt, high concentrations of salt, up to saturation, are commonly
used to prevent leaching salt from the borehole wall.
Silica is used to combat strength retrogression. Strength retrogression is a change in the
hydration products that are formed when cement is exposed to high temperatures (>110°C
[230°F]). Silica is available in coarse or fine grades for cementing.
Thixotropic additives
Thixotropic additives produce an intentional gelation of the cement to aid in placement of the
cement. Thixotropic cement is discussed as RFC cement on page 56.
UniSLURRY additives
UniSLURRY additives have unique and synergistic properties. These additives have been pur-
pose built to perform their function and have properties that distinguish them from other fluid-
loss or set-control (retarder) additives. UniSLURRY additives, UNIFLAC fluid-loss additive,
UNISET LT retarder and UNISET HT retarder are discussed on pages 59–63.
Weighting agents
Weighting agents are used to increase the density of the cement when needed for well control.
Spacers
Spacers are generally thickened, weighted fluids used to aid in mud removal and to separate the
mud from the cement to prevent any compatibility problems.
Chemical washes
Chemical washes are generally thin fluids with surfactants to aid in mud removal and to separate
the mud from the cement to prevent any compatibility problems.
The following tables list additives by functional category (Cementing Additive Quick Guide)
and by additive code (Cementing Additive List).
Materials 65
Cementing Additive Quick-Guide
Code Form, Liquid (L) Material and/or Application Temperature Range
or Solid (S) Application (BHCT except where noted)
Accelerators
D044 S Sodium chloride No limit
D077 L Calcium chloride Below 55°C [130°F]
D186 L Set enhancer 7–55°C [45–130°F]
S001 S Calcium chloride Below 55°C [130°F]
S002 S Calcium chloride Below 55°C [130°F]
Antifoam Agents
D046 S Foam preventer No limit
D047 L Foam preventer No limit
D144 L Defoamer No limit
D175 L Defoamer No limit
M045 L Defoamer No limit
Chemical Washes
D122A L Chemical wash concentrate No Limit
D191 L Surfactant for washes and spacers Maximum 250°C [482°F]
D192 L Chemical wash concentrate No Limit
DeepCEM Additives
D185 L Low temperatures; nonretarding Maximum 57°C [135°F]
D186 L Set enhancer 7–55°C [45–130°F]
Dispersants
D065 S Freshwater systems Maximum 121°C [250°F]
D065A S SALTBOND additive for high-salinity systems Maximum 121°C [250°F]
D080 L Liquid equivalent to D065 Maximum 121°C [250°F]
D080A L SALTBOND additive for high-salinity systems Maximum 121°C [250°F]
D121 S Dispersant, retarder, fluid-loss additive 121–274°C [250–525°F]
D145A L Low temperature Maximum 85°C [185°F]
D185 L Low temperature; nonretarding Maximum 57°C [135°F]
D604AM L SALTBOND additive for high-salinity systems Maximum 121°C [250°F]
D604M L Easy-to-disperse cement Maximum 121°C [250°F]
Expanding Additives
D053 S Additive for RFC and SELFSTRESS systems Maximum 85°C [185°F]
D174 S Low to moderate temperatures Maximum 110°C [230°F] BHST
D176 S High temperatures 80–204°C [176–400°F] BHST
Extenders
D020 S Bentonite Maximum 232°C [450°F] BHST
D035 S Class F fly ash Maximum 232°C [450°F] BHST
D048 S Class F fly ash Maximum 232°C [450°F] BHST
D056 S Diatomaceous earth No limit
D072 S Expanded perlite Maximum 232°C [450°F] BHST
D075 L Sodium silicate Limited by ability to retard
D079 S Sodium metasilicate Limited by ability to retard
D124 S LITEFIL* ceramic microspheres Maximum 232°C [450°F] BHST
D125 S Expanded perlite Maximum 232°C [450°F] BHST
D128 S Attapulgite Maximum 232°C [450°F] BHST
D132 S Class C fly ash Maximum 232°C [450°F] BHST
Fluid-Loss Additives
D008 S Fluid loss control 85–232°C [185–450°F]
D059 S High-salinity systems 38–93°C [100–200°F]
D065A S SALTBOND additive for high-salinity systems About 121°C [250°F]
D080A L SALTBOND additive for high-salinity systems About 121°C [250°F]
D112 S Low-density systems 4–93°C [ 40–200°F]
D167 S UNIFLAC additive 0–204°C [32–400°F]
D168 L UNIFLAC additive 0–204°C [32–400°F]
D300 L Low to moderate temperatures, nonretarding Maximum 121°C [250°F]
D604AM L SALTBOND additive for high-salinity systems About 121°C [250°F]
Gas-Control Agents
D500 L GASBLOK LT additive for low temperatures Maximum 71°C [160°F]
D600G L Latex GASBLOK MT additive for 66–121°C [150–250°F]
moderate temperatures
D700 L Latex GASBLOK HT additive for high temperatures 121–191°C [250–375°F]
D701 L GASBLOK stabilizer for high temperatures Maximum 191°C [375°F]
Retarders
D008 S Moderate temperature; also controls fluid loss; 54–104°C [130–220°F]
used mostly with high-salinity systems
D013 S Low temperatures Maximum 85°C [185°F]
D028 S High temperatures 104–149°C [220–300°F]
204°C [400°F] (with aid D121)
D081 L Low temperatures Maximum 85°C [185°F]
D093 S Retarder aid; high temperatures 149–204°C [300–400°F]
D110 L High temperatures 79–149°C [175–300°F]
191°C [375°F] (with aid D121)
D121 S Retarder aid; high temperatures 110–177°C [230–350°F]
D150 L High temperatures 104–149°C [220–300°F]
204°C [400°F] (with aid D121)
D161 L UNISET additive for high temperatures 85–232°C [185–450°F]
D177 L UNISET additive for moderate temperatures 60–121°C [140–250°F]
D800 S Moderate temperatures 52–121°C [125–250°F]
154°C [310°F] (with aid D121)
D801 L Moderate temperatures 52–121°C [125–250°F]
154°C [310°F] (with aid D121)
Materials 67
Cementing Additive Quick-Guide (continued)
Code Form, Liquid (L) Material and/or Application Temperature Range
or Solid (S) Application (BHCT except where noted)
Spacers
D182 S Additive for MUDPUSH II spacer Maximum 149°C [300°F]
D190 S MUDPUSH WHT additive Maximum 232°C (450°F)
Special Additives
D030 S Coarse silica; strength retrogression control No limit
D044 S Salt No limit
D053 S Additive for RFC and SELFSTRESS cements Maximum 85°C [185°F]
D066 S Silica flour; strength retrogression control No limit
D111 L Additive for RFC cement Maximum 85°C [185°F]
D140 S Activator for PERMABLOK plug Maximum 80°C [176°F]
107°C [225°F]
D606 S Gelation suppressant No limit
J120 S Polymer for polymer plug 200°F
M117 S Potassium chloride No limit
Surfactants
D139 L Stabilizer for foamed cement Maximum 232°C [450°F]
D607 L Wash or spacer for OBM removal Maximum 232°C [450°F]
F040 L Aid in OBM removal Maximum 232°C [450°F]
F057 L Aid in OBM removal Maximum 232°C [450°F]
F078 L Foaming agent for foamed cement Maximum 232°C [450°F]
F103 L Aid in OBM removal Maximum 232°C [450°F]
F104 L Foaming agent for foamed cement Maximum 232°C [450°F]
U066 L Solvent for OBM removal Maximum 232°C [450°F]
U100 L Solvent for OBM removal Maximum 232°C [450°F]
Suspending Agents
D153 S Antisettling agent Maximum 149°C [300°F]
D162 L Antisettling agent Maximum 149°C [300°F]
Thixotropic Agents
D053 S Additive for RFC and SELFSTRESS cements Maximum 85°C [185°F]
D111 L Additive for RFC cement Maximum 85°C [185°F]
Weighting Agents
D018 S Ilmenite No limit
D031 S Barite No limit
D076 S Hematite No limit
D151 S Calcium carbonate No limit
D157 S Micromax Maximum 232°C [450°F]
D165 S Additive for DensCRETE slurries No limit
D166 S Additive for DensCRETE slurries No limit
D013 Retarder Low to moderate Brown powder 1.23 Temperature: to 60°C [140°F] when used
temperatures alone and 85°C [185°F] with a dispersant.
Concentration: 0.1–0.5% BWOC. Can be
used in fresh water and seawater.
D018 Ilmenite High-density slurries Black granules 3.50–4.50 High-density slurries and spacers to
2300 kg/m3 [19 Ibm/gal].
D020 Bentonite Cement extender Light tan to 2.65 API untreated bentonite. To 25% BWOC when
gray powder dry blended. About one-fourth as much is
required when prehydrated. Minimum density:
1380 kg/m3 [11.5 Ibm/gal]. Attapulgite (D128)
is used in salt water.
D024 Gilsonite Lost circulation Black granules 1.07 LCM. Concentration: 10.6–106 kg/t [1–10 lbm/sk].
control Temperature to 149°C [300°F].
D028 Retarder High temperatures Dark brownish 1.25 Temperature: 104–149°C [220-300°F];
Can be used to 204°C [400°F] with a retarder aid.
Concentration: 0.05–1.0% BWOC. Can be used
in fresh water and in high-salinity systems.
D029 Cellophane Lost circulation Clear thin flakes 1.45 LCM. Concentration: 1.3–5.3 kg/t
flake control [0.125–0.5 Ibm/sk].
D030 Silica Strength White to tan granules 2.65 100-mesh silica sand. Prevents strength
retrogression retrogression at temperatures above
control 110°C [230°F]. Concentration: 35-50%
BWOC. D030 is preferred to D066 (silica flour)
in dense, low-water-ratio slurries.
D031 Barite Weighting agent Grey or tan powder 4.33 High-density slurries and spacers
(to 2300 kg/m3 [19 Ibm/gal]).
D035 LITEPOZ 3 Cement extender Tan to gray powder 2.48 Class F fly ash. Normally substituted for a
extender portion of the cement on an absolute volume
basis (e.g., in USA, 35:65) or blended on a
bulk volume basis (e.g., in Canada, 1:1).
D042 KOLITE lost Lost circulation Black angular 1.30 LCM. Granular material of controlled
circulation control granules particle size distribution.
additive Concentration: 10.6–106 kg/t [1–10 lbm/sk].
D044 Granulated Accelerator; White granules 2.16 Sodium chloride. Used where formations are
salt inhibit clay swelling; sensitive to fresh water. Accelerates cement
facilitate bonding in set when used at concentrations to 15%
salt formations BWOW (by weight of water). At 18% BWOW,
its effect is essentially neutral and thickening
times are similar to those obtained with fresh
water. Above 18% BWOW, D044 retards setting
of cement. Used above 18% to minimize
leaching of salt formations.
D046 Antifoam Control foaming of Tan solid 1.50 General purpose solid foam preventer.
cement slurries Typical concentration: 2 kg/t [0.2 Ibm/sk].
Materials 69
Cementing Additive List (continued)
Code Name Application Description SG Primary Purpose
D047 Antifoam Control foaming of Colorless liquid 1.00 General purpose liquid foam preventer.
cement slurries Typical concentration: 4.5 L/t [0.05 gal/sk]
for cement slurries and 6 L/m3 [0.25 gal/bbl]
for spacers.
D048 LITEPOZ 6 Cement extender Gray to tan powder 2.01 Class F fly ash. Normally substituted for a
extender portion of the cement on an absolute volume
basis (e.g., in USA; 35:65) or blended on a bulk
volume basis (e.g., in Canada, 1:1).
D053 Cement agent Thixotropy and White powder 2.70 Additive for RFC cement and SELFSTRESS
expansion cement. Thixotropic slurries (RFC cement)
are used for lost circulation control and their
expansive properties. SELFSTRESS cement
is used for its expansion. Effective up to
85°C [185°F].
D056 Extender Cement extender Light gray granules 2.10 Diatomaceous earth.
D059 FLAC* fluid- Salt cement slurries White powder 1.36 Fluid-loss control additive for salt slurries.
loss additive Can be used in fresh slurries with dispersant.
Temperature range: 38–93°C [100–200°F].
Typical concentration: 0.5 to 1% BWOC.
Retards at low temperatures.
D065 TIC* Freshwater or low Light brown powder 1.43 Powerful cement dispersant. Concentration:
dispersant salinity slurries 0.1–1.5% BWOC. Can be used with seawater.
Temperature to 121°C [250°F].
D065A SALTBOND Fluid-loss control for Light brown powder 1.43 Dispersant and fluid-loss additive for high-
additive high salinity slurries salinity slurries when “difficult-to-disperse
in salt” cement is used. Temperature to
121°C [250°F].
D066 Silica flour Strength White to tan granules 2.65 Fine silica flour (finer than 200 mesh). Prevents
retrogression strength retrogression at temperatures above
control 110°C [230°F]. Concentration: 35–50% BWOC.
Preferred over D030 in lightweight slurries and
at very high temperatures.
D072 Perlite Cement extender White, fluffy powder 2.40 Expanded volcanic glass. Used in shallow wells;
collapses at high pressure (significant at
20.7 MPa [3000 psi]).
D075 Sodium silicate Cement extender Colorless liquid 1.38 Silicate-based liquid extender. Preferred for
seawater applications. When used with fresh
water, requires calcium chloride addition
to the mix water. Typical concentration:
18–54 L/t [0.2–0.6 gal/sk]. Minimum density:
1380 kg/m3 [11.5 Ibm/gal]. Accelerates set.
D076 Hematite Weighting agent Reddish brown powder 4.95 High-density slurries and spacers to
2300 kg/m3 [19 Ibm/gal].
D077 Liquid calcium Cement slurry Clear to straw 1.38 Liquid form of calcium chloride. Used in fresh
chloride accelerator colored liquid water or seawater. Maximum concentration
of 35.5 L/t (0.4 gal/sk).
D079 Sodium Cement extender White solid 2.40 Sodium metasilicate extender. Most applicable
metasilicate for low bulk-storage requirements, such
as remote locations and offshore.
Typical concentration: 0.25–3% BWOC.
Minimum density: 1380 kg/m3 [11.5 Ibm/gal].
Accelerates set.
D080A SALTBOND Fluid-loss control Dark brown liquid 1.24 Dispersant and fluid-loss additive for high-salinity
additive for salt slurries slurries when “difficult-to-disperse in salt”
cement is used. Temperature: to 121°C [250°F].
Concentration: 27–81 L/t [0.3–0.9 gal/sk].
D081 Liquid retarder Low to moderate Brown liquid 1.26 Liquid equivalent to D013. Temperature range:
temperatures to about 60°C [140°F] when used alone and
about 85°C [185°F] with a dispersant.
Concentration: 2–9 L/t [0.02–0.1 gal/sk].
Can be used in fresh water and seawater.
D093 Retarder aid Increase White powder 1.73 Synergistic effect with all retarders, increasing
performance range their effective range. Most useful above
of retarders 149°C [300°F]. Detrimental effect on most
fluid-loss control additives.
D095 CemNET fiber Lost circulation Fibers 2.55 Controlling and preventing lost circulation.
control Maximum temperature: 150°C [302°F].
Concentration: to 7 kg/m3 [2.5 lb/bbl].
D096 CemNET fiber Lost circulation Fibers 1.27 Controlling and preventing lost circulation.
control Maximum temperature: 232°C [450°F].
Concentration: to 6 kg/m3 [2.1 lb/bbl].
D110 Retarder High temperatures Brown liquid 1.13 Temperature: 79-149°C [175–300°F];
to 190°C [375°F] with D093.
Concentration: 2–45 L/t [0.05-0.5 gal/sk].
D111 RFC additive Liquid additive for Light green liquid 1.26 Concentration: to 72 L/t [0.8 gal/sk].
thixotropic cement
slurries
D112 FLAC fluid-loss Low-density slurries Tan powder 1.15 Control fluid loss, primarily in lightweight
additive slurries. Temperature: to 93°C [200°F].
Concentration: 0.5–3.0% BWOC. Can be used
in fresh water and seawater. Strong viscosifier.
D121 TIC III Dispersant, retarder Dark brown powder 1.38 Temperature: to 177°C [350°F]. Concentration:
tri-functional and aid for fluid-loss 0.5–2.0% BWOC. Effective in fresh water and
additive control high-salinity systems.
D122A Chemical Mud thinning, Brown liquid 1.03 Typical concentration: 12 L/m3 [0.5 gal in 41.5 gal]
wash dispersing and in water.
concentrate removal
D124 LITEFIL Ultralightweight Gray powder 0.65- 0.85 Hollow ceramic microspheres allowing slurry
extender cementing additive density as low as 1080 kg/m3 [9 Ibm/gal].
Temperature: to 232°C [450°F]. Pressure limit
owing to crushing of spheres: about 35 MPa
[5000 psi].Application ranges may be extended
with testing.
D125 Perlite Extender Off-white, fluffy powder 2.40 Expanded volcanic glass used in shallow wells;
collapses at high pressure (significant at
20.7 MPa [3000 psi]).
D128 Attapulgite Extender for salt Light tan to 2.65 Clay extender for saline waters
cement slurries gray powder (including seawater).
D130 Polyester flake Lost circulation Clear thin flakes 1.06 LCM. Concentration: 1.3–5.3 kg/t [0.125–0.5 Ibm/sk].
control
Materials 71
Cementing Additive List (continued)
Code Name Application Description SG Primary Purpose
D132 Cement Carbon dioxide- Tan to gray powder 2.67 Class C fly ash; component of carbon
agent resistant cement dioxide-resistant cement.
D139 Foamed Foamed cement Clear to hazy 1.07 Used to maintain downhole stability of
cement yellow liquid foamed cement.
stabilizer Usual concentration: 9 L/t [0.1 gal/sk].
D140 Hardener Hardener for Yellow liquid 1.24 Hardener for PERMABLOK rigid gel system.
PERMABLOK lost Temperature: to 80°C [176°F]. May be extended
circulation plug through laboratory testing to 107°C [225°F].
Concentration: 5–20% by volume of solution,
depending on temperature, required gel time
and rigidity.
D144 Antifoam High-salinity slurries White liquid 1.00 General purpose liquid foam preventer
additive and spacers and defoamer. Added to the mix water. Typical
(efficient in any fluid) concentration: 1–5 L/t [0.01–0.05 gal/sk] for
cement slurries and 2.4 L/m3 [0.1 gal/bbl]
for spacers.
D145A Liquid Low temperatures Viscous liquid 1.24 Dispersant, much less retarding than D080.
dispersant Temperature: to 85°C [185°F] in freshwater
systems. Usual concentration: 4 to
27 L/t [0.05 to 0.3 gal/sk].
D150 Retarder High temperatures Dark brown liquid 1.11 Liquid equivalent to D028. Temperature:
104–149°C [220–300°F]; to 204°C [400°F]
with a retarder aid. Concentration:
2–36 L/t [0.02–0.4 gal/sk].
D151 Calcium Weighting agent White powder 2.70 Graded calcium carbonate. Weighting material
carbonate for spacers for spacers, especially where acid solubility
is required.
D152 Premium Extender Light tan to 2.65 Premium grade of bentonite having better
bentonite gray powder fluid-loss control properties when used at
high concentrations (>12%).
D153 Antisettling Suspending additive White to gray powder 2.53 Maintains slurry stability at downhole
additive temperature conditions. For all densities.
Temperature: to 149°C [300°F].
Concentration: 0.1–1.5% BWOC.
D154 Extender Low temperatures Gray powder 2.20 Microsilica. Improves performance of most set
cement formulations; better strength and lower
permeability. Useful for lightweight systems to
1320 kg/m3 [11 Ibm/gal], especially at low
temperatures (to 85°C [185°F]).
Concentration: 5–20% BWOC.
D155 Extender Low temperatures Gray liquid 1.40 Suspension of microsilica in water. Improves
performance of set cement; usually gives better
strength and lower permeability. Useful for light-
weight systems to 1320 kg/m3 [11 Ibm/gal].
Concentration: 90–360 L/t [1–4 gal/sk].
D157 Weighting High-density slurries Red brown powder 4.80 Compatible with freshwater and high-
agent salinity slurries to 232°C [450°F]. Applicable
1920–2640 kg/m3 [16–22 lbm/gal]. Very small
particle size (5 micrometers) enables addition
directly to mix water, allowing last-minute
density increases.
D162 Liquid Sedimentation control Off-white liquid 0.84 Compatible with freshwater and high-
antisettling salinity slurries. For all densities.
additive Temperature: to 149°C [300°F].
Concentration: 0.45–2.3 L/t [0.005–0.025 gal/sk].
D165 CemHD DensCRETE slurries Reddish powder 4.95 Special grade of hematite for DensCRETE slurries.
D166 CemD DensCRETE slurries White powder 2.65 Special grade of silica for DensCRETE slurries.
D167 UNIFLAC S Fluid-loss control White powder 1.32 Compatible with freshwater and high-salinity
additive slurries. Temperature: to 204°C [400°F].
All densities. Typical concentration:
0.1 to 0.8% BWOC.
D168 UNIFLAC L Fluid-loss control Colorless to yellow 1.08 Liquid version of D167. Compatible with
additive liquid freshwater and high-salinity slurries.
Temperature: to 204°C [400°F]. All densities.
Typical concentration: 9–81 L/t [0.1–0.9 gal/sk].
D174 Expanding Low to moderate Tan powder 3.22 Temperature: 27–110°C [80–230°F].
cement temperatures Typical concentration: 3–5% BWOC.
additive
D175 Antifoam High-salinity slurries White liquid 0.99 General purpose liquid foam preventer and
additive and spacers (efficient defoamer. Added to the mix water. Typical
in any fluid) concentration: 1–5 L/t [0.01–0.05 gal/sk] for
cement slurries and 2.5 L/ m3 [0.1 gal/bbl]
for spacers.
D176 Expanding High temperatures Tan powder 3.54 Temperature: 80–204°C [176–400°F].
cement Typical concentration: 1–5% BWOC.
additive
D177 UNISET LT Low to moderate Light green liquid 1.10 Can be used with fresh water or seawater.
additive temperatures Concentration: to 26 L/t [0.3 gal/sk].
Low sensitivity of thickening time to
changes in temperature or concentration.
Maximum temperature: 121°C [250°F] if
used in combination with UNIFLAC additive
(D167 or D168).
D182 MUDPUSH II Low to moderate Red brown powder 1.32 Concentrate for preparing MUDPUSH II spacer;
spacer temperatures used with freshwater, seawater, or high-salinity
additive spacers. MUDPUSH II spacer density can be
designed to 2400 kg/m3 [20 lb/gal].
Temperature: to 149°C [300°F].
D185 Dispersant Low temperatures Colorless liquid 1.04 DeepCEM additive for cold environment of
deepwater. Nonretarding. Temperature: to
57°C [135°F]. Rheology is not affected by salt
(D044) or calcium chloride (S001).
Materials 73
Cementing Additive List (continued)
Code Name Application Description SG Primary Purpose
D186 Set enhancer Low temperatures Green liquid 1.35 DeepCEM additive for cold environment of
deepwater. Enhances the set profile of
cement; accelerates cement hydration
resulting in early compressive strength
development. It is especially effective with
GASBLOK LT additive (D500) and D185
dispersant. D186 can be used with
DeepCRETE systems. Preferred temperature:
7–55°C [45–130°F]. Compatible with fresh
water or seawater.
Concentration: to17.8 L/t [0.2 gal/sk].
D190 MUDPUSH High temperatures Colorless powder 1.23 Viscosifies to suspend weighting agents
WHT additive and control fluid loss in MUDPUSH WHT
high-temperature spacer, which has a
temperature limit of 232°C (450°F).
Density: to 2400 kg/m3 [20 lb/gal].
D191 Surfactant For spacers and Clear opalescent liquid 0.98 Environmentally friendly surfactant used in
washes for removal washes and MUDPUSH spacers for removal
of OBM of OBM, low-toxicity OBM or synthetic OBM.
Temperature: to 250°C [482°F].
Typical concentration: 48 L/m3 [2 gal/bbl].
D192 Chemical Mud thinning, Dark brown liquid 1.18 Environmentally friendly surfactant used
wash dispersing and in washes. No limit on temperature.
concentrate removal
D300 Fluid-loss Low to moderate Green liquid 1.00 Nonretarding. Compatible with calcium chloride.
additive temperatures Compatible with salinity to 10% BWOW.
Temperature: 27–120°C [80–250°F].
Concentration: 32–117 L/t [0.35–1.3 gal/sk].
Only dispersants D145A and D185 can be
used with D300 fluid-loss additive.
D500 GASBLOK LT Gas migration Yellow liquid 1.01 Nonretarding liquid additive.
additive control at low Temperature: to 71°C [160°F].
temperatures Density: 1260–1970 kg/m3 [10.5–16.4 lbm/gal].
Compatible with fresh water and seawater.
Typical concentration: 45–180 L/t [0.5–2.0 gal/sk].
D600G GASBLOK MT Gas migration White liquid 1.02 Latex additive. Temperature: 66–121°C [150–250°F].
additive control additive Concentration: 130–260 L/t [1.5–3.5 gal/sk] in
GASBLOK slurries; 90–180 L/t [1–2 gal/sk] as
WELBOND cement. Lower concentration is
required when used for fluid-loss control only.
D602 Diatomaceous Cement extender White to gray powder 2.10 Naturally occurring material used as extender.
earth
D604AM SALTBOND Fluid-loss control for Dark brown liquid 1.21 Salt system dispersant and fluid-loss additive.
additive high salinity slurries Temperature: to 121°C [250°F].
Concentration: 27–81 L/t [0.3-0.9 gal/sk].
D604M Dispersant “Easy-to-disperse” Dark brown liquid 1.21 Formulated to minimize overdispersion.
cements Temperature: 121°C [250°F].
Concentration: 0.9–9 L/t [0.01–0.1 gal/sk].
D606 Gel- Antigelling additive White crystals 2.68 Eliminates primary gelling tendency of cement
suppressing with improperly balanced sulfate. Typical
additive concentration: 0.5–1.0% BWOC.
D700 GASBLOK HT Gas-migration-control White liquid 1.02 Latex additive. Typical temperature:
additive additive for high 121–191°C (250–375°F). Concentration:
temperatures 177–310 L/t [2–3.5 gal/sk]. The addition of
D701 (high-temperature latex stabilizer)
may be required.
D701 GASBLOK Stabilizer for Clear yellow 1.05 Used to stabilize D700 GASBLOK slurry;
stabilizer GASBLOK slurries viscous liquid necessary. Typical concentration: 5% by
volume of D700.
D800 Retarder Low to moderate Dark brown powder 1.26 Lignosulfonate retarder with reduced tendency
temperatures for gelation. Temperature: 52–121°C [125–250°F]
BHCT; can be extended to 154°C [310°F] when
used with a retarder aid. Compatible with fresh
water or salt water (to saturation).
Concentration: 0.25–2% BWOC.
D801 Retarder Low to moderate Dark brown liquid 1.18 Liquid version of D800. Temperature:
temperatures 52–121°C [125–250°F] BHCT; can be extended
to 154°C [310°F] when used with a retarder
aid. Compatible with fresh water or salt
water (to saturation). Concentration:
4.5-36 L/t [0.05-0.4 gal/sk].
F040 EZEFLO* For spacers and Clear liquid 1.04 Typical concentration: 2–10% by volume.
surfactant washes for removal
of OBM
F057 Surfactant For spacers and Yellow liquid 1.07 Typical concentration: 2–10% by volume.
washes for removal
of OBM
F078 EZEFLO For spacers and Clear amber liquid 0.89 Typical concentration: 2–10% by volume.
surfactant washes for removal Also used for foaming cement slurries
of OBM with nitrogen or air.
Typical concentration: 19–18 L/t [0.1–0.2 gal/sk].
F103 EZEFLO For spacers and Clear colorless liquid 0.94 Typical concentration: 2–10% by volume.
surfactant washes for removal
of OBM
F104 Foaming Foamed cement Clear amber liquid 1.01 For foaming cement slurries with nitrogen or air.
additive Also used in washes and in MUDPUSH spacers
for removal of OBM.
Typical concentration: 2–10% by volume.
Typical concentration: 9–18 L/t [0.1–0.2 gal/sk].
J120 Polymer Polymer Plug White powder 1.00 Polymer for use in Polymer Plug lost circulation
lost circulation system control system.
J237A Fluid-loss Fluid-loss control in Creamy liquid 1.06 Typical concentration: 6 L/ m3 [0.25 gal/bbl].
additive chemical washes
M045 Antifoam Washes and spacers White liquid 1.00 General purpose liquid foam preventer and
additive defoamer. Added to the mix water. Typical
concentration: 5 L/t [0.05 gal/sk] for cement
slurries and 2.5 L/m3 [0.1 gal/bbl] for spacers.
Materials 75
Cementing Additive List (continued)
Code Name Application Description SG Primary Purpose
M117 Potassium Clay stabilizer White to gray 1.98 Used in washes and spacers as a clay
chloride crystals stabilizer. Typical concentration: 3% BWOW.
Sometimes used in cement slurry to control
swelling shales.
S001 Calcium Accelerator White solid 1.75 Calcium chloride 77%. Typical concentration:
chloride 1 to 2% BWOC. Increases temperature of slurry
when dissolved.
S002 Calcium Accelerator White solid 1.75 Calcium chloride 95%. Typical concentration:
chloride 1 to 2% BWOC. Increases temperature of slurry
when dissolved.
U066 Mutual For spacers and Colorless to 0.90 Used in washes and in MUDPUSH spacers for
solvent washes for removal white liquid removal of OBM and particularly environmen-
of environmentally tally safe OBM. Typical concentration: 2–10%
safe OBM by volume.
U100 Mutual For spacers and Colorless to 0.90 Used in washes and in MUDPUSH spacers for
solvent washes for removal white liquid removal of OBM and particularly environmen-
of environmentally tally safe OBM. Typical concentration: 2–10%
safe OBM by volume.
Note: Temperatures, concentrations and other conditions of application are typical. Testing may allow extension of ranges.
Introduction
Cementing requires specially designed equipment. Equipment may be high-powered like the
CPF-376 double-pump cement trailer or CPT-372 double-pump cement truck or highly versatile
to accomplish numerous cementing operations each day, like the CemSTREAK cementing unit.
Even more specialized equipment is required for use offshore, with the skids designed to deliver
high power with high reliability. In many cases, offshore cementing is done using liquid additives
and LAS* liquid additive systems are used for precise delivery of the additives to the mixing sys-
tem. When subsea heads are used, the DeepSea EXPRESS plug launching system is used for reli-
able wiper plug launching. Monitoring and recording of the cementing operation is done using
the CemCAT computer-aided treatment software and a portable computer. Innovative mixing
control is accomplished using the SFM* Solids Fraction Monitor.
Applications
■ Cementing services
■ Low- and intermediate-range pumping services
■ Remedial cementing operations requiring very low pump rates
■ Low-range pressure testing
Benefits
■ Ability to reach difficult locations
■ Savings in rig time through rapid rig-up and rig-down
■ Minimal environmental impact
■ Weight compliant with various road ban rules
■ Crew of only two operators for improved logistics, reduced risks and costs
■ Downtime probability reduced or eliminated by reliability of equipment
■ Ability to mix all slurry types
Features
■ Four-wheel drive
■ 127-kW [170-hhp] triplex pump
■ Rating of 20.7-MPa [3000-psi] working pressure
■ 38 m [125 ft] of 50.8-mm [2-in.] hose rated to 20.7-MPa [3000-psi] working pressure
■ Powered reel for hose storage, deployment and retrieval
■ 1.11-m3/min [7-bbl/min] pump rate
■ Nonradioactive densitometer
■ SLURRY CHIEF Mark III cement mixer
■ Oilfield or metric gauges
■ Integrated data-acquisition system
■ Two 1.1-m3 [6.9-bbl] displacement tanks
■ CemCAT real-time monitoring
■ Four separate systems for pressure relief
■ Self-sufficient unit, including cement head and extra treating iron
The CPF-376 double-pump cement truck delivers high reliability in high-pressure pumping operations.
0.95-m3 [6-bbl] mixing tub and a 2.2-m3 [14-bbl] averaging tank. This arrangement produces
superior density control and separates the critical mixing stage from downhole pumping. It also
provides the ability to mix 3.2 m3 [20 bbl] of cement in batch mode for squeeze and plug operations.
The CemCAT system is used to monitor and record treatment parameters and to provide a job
report.
Applications
■ Cementing services
■ High-power pumping services
■ Remedial cementing operations
Benefits
■ Full redundancy ensures ability to complete job
■ Downtime reduced or eliminated by reliability of equipment
■ Ability to mix all slurry types
Equipment 79
Features
■ 194-kW [260-hhp] power per triplex pump, for a total of 388 kW [520 hhp]
■ 2.7-m3/min [17-bbl/min] pump rate
■ Working pressure rating to 137.9 MPa [20,000 psi]
■ Fully redundant for high reliability
■ SLURRY CHIEF Mark III cement mixer
■ Automatic density control system
■ Two nonradioactive densitometers
■ Oilfield or metric gauges
■ Underdrive for pumping at low rates
■ Direct drive centrifugal pumps for reliability
■ Integrated data-acquisition system
■ CemCAT real-time monitoring
■ Self-sufficient unit, including treating iron
Applications
■ Cementing services
■ High-power pumping services
■ Remedial cementing operations
Benefits
■ Full redundancy ensures ability to complete job
■ Downtime reduced or eliminated by reliability of equipment
■ Ability to mix all slurry types
Features
■ Power to 388 kW [520 hhp]
■ Pump rate to 2.7 m3/min [14 bbl/min]
■ Working pressure rating of 68.95 MPa [10,000 psi]
■ Fully redundant for high reliability
■ SLURRY CHIEF Mark III cement mixer
■ Nonradioactive densitometer
■ Oilfield or metric gauges
■ Integrated data-acquisition system
■ CemCAT real-time monitoring
■ Self-sufficient unit, including treating iron
Equipment 81
CPS cement pumping skids are available in a number of configurations to fit any requirement.
Offshore cementing skids are fitted with all sensors necessary for direct connection to the
CemCAT data-acquisition and monitoring system. The CemCAT system monitors and records
the critical job parameters including rate, pressure and slurry density.
Batch mixers, such as the CBS-961 twin 50-bbl mixer, are available for mixing of cement
slurries or other fluids. The CBS-961 unit features two centrifugal pumps for picking up fluids
from remote tanks, recirculating for mixing and for delivering fluid to high-pressure pumps.
Standard equipment
■ SLURRY CHIEF cement mixer
■ Nonradioactive densitometer
■ Two triplex pumps
■ Stainless-steel displacement tanks
■ Slurry pump
■ Recirculation pump
■ Two mixing water pumps
■ Full selection of fluid ends
Optional equipment
■ SFM package
■ Automatic density control
■ Zone II-certified engine package
■ Remote control package
■ Split skid with bulkhead
■ Optional loose equipment skid
■ Marine cool kit
■ Liquid additive metering system
■ Soundproof enclosure (for CPS-601 and CPS-665 units)
Width (mm [in.]) 2,578 [102] 3,011 [119] 2,898 [114] 3,007 [118] 3,150 [124] 3,841 [151]
Height (mm [in.]) 3,043 [120] 3,467 [136] 3,333 [131] 3,339 [132] 3,323 [131] 3,267 [129]
Operating weight (kg [lbm]) 20,658 [45,550] 32,180 [70,960] 33,840 [74,600] 37,360 [82,380] 38,010 [83,810] 46,795 [103,180]
Max. rate at 1.6 [10] 3.1 [19.7] 2.9 [18.3] 2.9 [18.3] 2.9 [18.3] 3.8 [24.0]
41.4 MPa [6000 psi] at 46.9 MPa
(m3/min [bbl/min]) [6800 psi]
Applications
■ Offshore cementing operations
■ Operations in remote areas
Benefits
■ Allows use of neat (unblended) cement for all operations
■ Provides high versatility in slurry designs
■ Simplifies logistics
■ Enables last-minute design without regard to time of transport from base
■ Eliminates waste of unused blended cement
■ Enables decisions on treatment volumes at time of job
Equipment 83
Features
■ Meters up to four different additives into mixer
■ Stainless-steel construction for durability
■ Remote control of additive addition
■ Certified for Zone II operations
■ Electromagnetic flow meters
Applications
■ Primary and remedial cementing operations
■ Miscellaneous high-pressure pumping services for testing blowout preventers or for leakoff or
formation integrity tests
■ Matrix acidizing and coiled tubing services
Benefits
■ Superior QC during all treatment phases
■ Precise treatments that follow job design
■ Immediate data for job-critical decisions, thus reducing risk
■ Exceptional flexibility, performance and reliability
Features
■ Complete integration with CemCADE design and evaluation software
■ Clear, customizable digital displays and plots of job data
■ Real-time data transmission from wellsite to any location worldwide
■ Detailed postjob plots including QA and QC plots and reports
■ Archive of job data for future use
Equipment 85
Slurry density
Slurry rate
Solid fraction
100 10
90 9
80 8
70 7
60 6 Slurry density
Solid
50 5 (lbm/gal)
fraction
40 4 Slurry rate
(%)
(bbl/min)
30 3
20 2
10 1
0 0
0 5 10 15 20 25 30 35 40 45
Time (min)
100
90 88% of volume ± 2% of the solid-fraction target
99% of volume ± 0.2 lbm/gal
80
70
60
Volume 50
(%)
40
30
20
10
0
0 10 20 30 40 50 60 70 80 90 100
Solid fraction (%)
The SFM-C system controls the solids fraction, which in turn controls the density.
The SFM-C system is a complementary technology, designed to provide QC for very low density
LiteCRETE slurry systems. Although SFM-C technology was developed specifically for light-
weight-cement operations, it is effective for slurries of any density.
This new SFM-C technology allows cementing crews to maintain slurry properties while con-
tinuously mixing and pumping large slurry volumes. The system requires a slurry flow meter, such
as the nonradioactive densitometer already available on cementing units, a residence tank sen-
sor, a water flow meter and process-controlled valves. These retrofits can be added easily to land
or offshore mixing equipment.
User-friendly software helps cementing crews monitor and easily switch between automatic
and manual control.
Applications
■ All cementing operations
■ Slurries with very low densities (less than 1320 kg/m3 [11 lbm/gal])
Features
■ Continuous-mixing control of all slurries, even at densities equal to or lower than that of water
■ More sensitive method for controlling cement mixing than by density measurement
■ Independent of specific gravity of components
■ Automatic control of slurry quality
■ Real-time monitoring
■ Complete compatibility with all data-acquisition systems
■ Easy installation on conventional mixing equipment
Nonradioactive densitometer
Density measurement and control in the oil industry have traditionally been accomplished by
using radioactive densitometers, mainly because they are nonintrusive, durable and easy to use.
Unfortunately, the radioactive technique has several major drawbacks; the radioactive source
presents safety and environmental concerns, and the required accuracy (12 kg/m3 [0.1 lbm/gal])
is difficult to attain.
Because of the deficiencies of radioactive densitometers, Schlumberger uses a nonradioactive
densitometer that employs a proven method; poses no health, safety, or environmental hazard;
and provides direct density measurements with an accuracy of better than 12 kg/m3 [0.1 lbm/gal].
The nonradioactive densitometer is extremely reliable, easy to use and requires no on-site cal-
ibration. Additionally, it measures flow rate with an accuracy of ±0.5% of reading and can be used
as a flow-measurement instrument for acidizing service. The vibrating tube principle governs the
density measurement in the nonradioactive densitometer.
Equipment 87
Applications
■ Cementing operations with slurry density over 1200 kg/m3 [10 lbm/gal]
■ Land and offshore (including Zone II)
■ Process controlled operations
■ Can be used for acidizing service
Benefits
■ Accurate density measurement
■ Reliability, requires no on-site calibration
■ Minimal environmental and safety concerns
Features
■ No radioactive source
■ Superior accuracy and field-proven reliability for measuring density and flow rate
■ Accuracy greater than 12.0 kg/m3 [0.1 lbm/gal]
■ Virtually maintenance-free
■ Easy configuration; easily drained and cleaned in place
■ Output (density, rate) independent of changes in temperature, pressure, flow profile
or viscosity
■ Fast response time
Introduction
Cement evaluation plays an important role in the cementing process. By cement evaluation, the
quality of zonal isolation is confirmed. In cases where zonal isolation is not achieved, the evalu-
ation helps diagnose the problems that led to the poor zonal isolation. Consequently, methods
and slurry design used for the primary cementing are reviewed and improved for the next well.
Results also help in deciding whether remedial work is required. Cement evaluation and QC are
processes completed during and after every step of primary cementing.
During the design, using Schlumberger CemCADE design software, the design engineer uses
well data and cementing parameters to predict the results with selected cement systems, select-
ing the one providing the desired zonal isolation. During execution, the operation is monitored
and analyzed. Finally, in the evaluation, cement evaluation logs are acquired for final confirmation
of hydraulic zonal isolation.
Thus, cement evaluation is a continuous process beginning with the design and continuing
with execution analysis, post-treatment analysis and analysis of cement evaluation logs to deter-
mine zonal isolation.
Design
In the design the well data are entered into CemCADE software to ensure optimum WELLCLEAN
mud removal, pipe centralization, cement slurry for downhole conditions, flow rate, etc. The
execution, as designed, is simulated and theoretical mud removal and zonal isolation are
assessed. If results are not satisfactory, the design is revised and the simulation is rerun.
See page 29 for more information on CemCADE software and WELLCLEAN mud removal.
Execution analysis
The purpose of primary cementing is to achieve zonal isolation. The slurry composition and the
execution procedure are designed to provide complete zonal isolation. The properties of the
cement sheath are optimized to isolate all productive zones, as well as those containing water
and nuisance gas.
The first QC step and evaluation during the execution determines if the materials were mixed
according to the design and if the displacement process followed the prescribed procedure. This
evaluation is made using plots of the slurry density, solids fraction, flow rate and pumping
pressure during the execution.
See page 84 for more information on CemCAT monitoring software.
Postcementing analysis
If the execution analysis indicated abnormal values of any monitored parameters, a thorough
analysis is performed after the operation. The data acquired during the cementing operation are
loaded into CemCADE cementing design and evaluation software and the execution data can be
overlaid and compared with the simulation run during the design. The simulation can also be
rerun using density and volumes of fluid mixed and pumped to determine if mud removal para-
meters were met.
Sonic services
CBLs, with amplitude and/or attenuation and Variable Density waveform data, have been the pri-
mary method for cement quality evaluation for many years. The principle of the cement bond
measurement is to record the transit time and amplitude (or attenuation) of a 20-kHz acoustic
wave after propagation through the well fluid and the pipe wall.
The measurement is the amplitude in millivolts of the tubular first arrival (E1) at a receiver
with 0.91-m [3-ft] or shorter spacing. The amplitude of the signal is a function of the attenuation
by the shear coupling of the cement sheath to the pipe. The attenuation rate depends on the
cement acoustic impedance, cement thickness, pipe diameter, pipe thickness and percentage of
bonded circumference.
A receiver with 1.52-m [5-ft] spacing is used to record the Variable Density waveform for bet-
ter discrimination between sonic waves traveling through pipe and those through formation. This
measurement is generally used to qualitatively assess the cement-to-formation bond.
SlimAccess tool
The SlimAccess* wireline logging tool is designed for slim, complex-geometry boreholes. It gen-
erates, records and digitizes acoustic waves and provides CBL amplitude, Variable Density mea-
surement and attenuation measurement for cement bond evaluation. It is also used for openhole
applications such as seismic correlation, porosity measurement and evaluation of lithology. It has
a short-spacing 0.30-m [1-ft] transmitter-receiver for cement evaluation in fast formations.
Besides the primary transmitter-receivers used for CBL and Variable Density measurement, the
SlimAccess tool also uses a second set of transmitter-receivers for backup. It is a monopole sonic
tool with a diameter of 6.35 cm [21⁄2 in.], which enables it to be run in 14-cm [51⁄2-in.] casing.
Applications
■ Determine quality of pipe to cement bond
■ Determine quality of formation-to-cement bond
■ Identify cement top
■ HPHT wells (SlimXtreme tool)
Benefits
■ Logging in pipe as small as 14 cm [51⁄2 in.]
■ Log quality minimally affected by environmental conditions
Features
■ 0.30-m [1-ft] receiver for cement evaluation in fast formation
■ 6.35-cm [21⁄2-in.] diameter
■ Low sensitivity to environmental conditions
■ Combinable with ultrasonic imaging tool for enhanced interpretation
Applications
■ Determination of quality of pipe-to-cement bond
■ Qualitative evaluation of cement-to-formation bond
■ Identification of cement top
Benefits
■ Tubing does not have to be removed from well (no rig required).
■ Interpretation is valid, even in fast formations.
■ Time is saved when the tool is run in combination with other tools.
Features
■ Combinable with PS Platform suite or RST tool for well, reservoir and cement integrity
evaluation in the same run
■ Combinable with PipeView* multifinger caliper tool for PS Platform tool string, for cement
and pipe integrity evaluation in the same run giving complete well integrity diagnosis
■ 4.29-cm [111⁄16-in.] diameter
■ 8-segment receiver for bond variation mapping
■ 0.61-m [2-ft] receiver
Evaluation 91
A SCMT log showing possible channel and its position aids in decision to squeeze and
in design of the squeeze cementing treatment.
Ultrasonic services
USI UltraSonic Imager
The USI UltraSonic Imager provides an accurate and reliable high-resolution, comprehensive,
real-time answer product revealing pipe-to-cement bond quality and downhole pipe condition.
Using ultrasonic technology, the USI tool sends ultrasonic pulses between 200 kHz and 700 kHz
that travel through the well fluid and strike the casing, providing 360º azimuthal coverage using
a single rotating transducer. The transducer receives reflected signals that have undergone mul-
tiple reflections between the casing internal and external interfaces. The signal decays at a rate
dependent on the acoustic impedance of the material in the annulus.
USI log maps of the acoustic impedance of the material in the annulus are generated using
very advanced processing techniques. From the acoustic impedance values, the material in the
annulus is identified and maps are prepared showing the nature (gas, liquid, solid) of the mate-
rial in the annulus. High-resolution maps of pipe wall thickness, internal radius and inner wall
rugosity are provided for accurate evaluation of the pipe condition. The results are displayed in
real time as quantitative, self-explanatory interpreted cement and pipe integrity maps.
The combination of the USI tool with CBL and Variable Density tools provides enhanced
assessment of cement-to-pipe and cement-to-formation bond quality.
Applications
Cement integrity
■ Hydraulic zonal isolation evaluation
■ Remedial work decision-making and assessment of effectiveness
■ Primary cementing process improvement
■ Identification of gas invasion
■ Determination of casing support before sidetrack
■ Cement top identification and free pipe identification for pipe retrieval
Benefits
■ Detailed channel identification and location
■ Remedial cementing optimization
■ Microannulus identification
■ Accurate, effective real-time answers
■ Rig time saving by acquiring cement and pipe integrity data in one run
■ Continuous improvement of cementing process
Features
■ Cement map showing cement quality and presence of channels
■ Pipe integrity data
■ Wellsite product for enhanced three-dimensional (3D) visualization
■ 100% azimuthal coverage by a single, rotating transducer
■ 5º radial and 3.81-cm [11⁄2-in.] vertical resolution in high-resolution mode
■ Combinable with inclinometry tools to aid image orientation in deviated wells
■ Combinable with CBL tools for enhanced evaluation
A USI log with optional Variable Density data provides the best identification of uncemented
channels and aids in decisions to squeeze and in design of the squeeze cementing treatment.
Evaluation 93
The USI log provides several presentations reflecting different applications. The easily read-
able, color-coded images make cement coverage in the annulus easy to interpret. Problems such
as channels in cement and tubular damage can be seen directly on the images, thus revealing
the status of zonal isolation for decisions about remedial work. Enhanced field products allow
visualization of the cement distribution and quality, as well as a 3D view of pipe condition to further
facilitate remedial work decisions. QC log presentations are used for data validation.
Cement integrity evaluation is essential, not only for zonal isolation confirmation and help in
the remedial work decision and design, but also for the determination of the causes of poor
cementing procedures. All acoustic logs are sensitive to cement-to-pipe bond. Some measure-
ment methods are affected by downhole conditions more than others and in different ways. For
this reason, a USI log and CBL combination is advisable to help diagnose zonal isolation problems
at the cement/pipe interface and the cement/formation interface. A full analysis of the cement
evaluation logs will assist in diagnosing the problem and provide information to improve the
cementing.
Thus, USI logs and CBLs with Variable Density data should be acquired together because their
responses area complementary, especially in the presence of
■ microannulus (liquid or gas)
■ fast formation
■ high-attenuation mud
■ lightweight cement.
The table shows the USI log and the CBL response under the different conditions.
Well-bonded cement Cement (high acoustic impedance) Low amplitude or high attenuation;
characteristic Variable Density log
Contaminated cement Shown as solid with low acoustic impedance if set Complicates interpretation
Casing condition Very sensitive: Corrosion, wear and deformed casing Slightly affected: No indication on log of quality
can be quantified in alternate acquisition mode
■ identifies microdebonding
The processed USI log and CBL with Variable Density data can be displayed side by side for
complete visual cement evaluation in real time at the wellsite. This feature helps the completion
engineer make sound decisions on remedial actions. The combination also helps cementing
companies in the continuous improvement and enhancement of their cementing systems and
methods for best hydraulic isolation and cement integrity results.
Nonstandard environment
The evaluation of ultralightweight cement systems or logging in heavy mud or nonstandard casing
sizes may require advanced interpretation.
For further information about cement evaluation services, please refer to www.slb.com/oilfield.
Evaluation 95
Glossary
Absolute Volume. Volume a solid occupies or displaces Bond Log. See Cement Bond Log.
when added to water divided by its weight: the volume
Bottomhole Circulating Temperature (BHCT). The
per unit mass. Units are gallons per pound or cubic
temperature that occurs at the bottom of a well while
meters per kilogram.
fluid is being circulated. The temperature used for most
American Petroleum Institute (API). Organization tests of cement slurry in a liquid state (thickening time,
which standardizes materials and procedures for use in fluid loss, etc.). In most cases, is lower than the BHST,
oilfield. but in some cases, such as in deepwater or in the arctic,
may be higher than BHST.
API Cement. One of several classes of cement manufac-
tured to the specifications of API Specification 10A. Bottomhole Static Temperature (BHST). The undis-
Classes of API cement are A, B, C, D, E, F, G and H. turbed temperature at the bottom of a well. After circu-
lation and the well is shut in, this temperature will be
API Recommended Practice 10B. Recommended
approached after about 24–36 hr, depending on condi-
Practice for Testing Well Cements. The standard which
tions. The temperature used in most tests in which the
gives guidelines for testing methods for cements and
cement slurry is required to set or is set.
cement formulations for use in well cementing.
Procedures are intended to be modified to conditions of Bulk Volume. The volume per unit mass of a dry mater-
the well. ial plus the volume of the air between its particles.
API Specification 10A. Specification for Cements and BWOB. See By Weight of Blend.
Materials for Well Cementing. The standard which spec-
BWOC. See By Weight of Cement.
ifies requirements for API well cements and specifica-
tion testing methods. BWOW. See By Weight of Water.
API Water. The amount of mixing water specified in API By Weight of Blend (BWOB). Used to define the
Specification 10A for specification testing of cement to amount (in percent) of a material added to cement
meet API requirements. This amount in not intended to when the material is added based on the total amount of
be a guide for mix water requirements in field applica- a specific blend.
tions.
By Weight of Cement (BWOC). Used to define the
Base Slurry. Conventional cement slurry used as the amount (in percent) of a material added to cement. The
cementitious component of a foamed cement slurry. method used for most additives in the dry form.
Bc. See Bearden Units of Consistency. By Weight of Water (BWOW). Used to define the
amount (in percent) of a material added to a cement
Bearden Units of Consistency (Bc). The pumpability or
slurry based on the weight of water used to mix the
consistency of a slurry is measured in Bearden units of
slurry. Normally used only for salt.
consistency (Bc), a dimensionless quantity with no
direct conversion factor to more common units of vis- Cement Bond Log (CBL). An acoustic log used to mea-
cosity. sure the attenuation rate of a sound wave propagating
along the casing. Can be used as an indication of the
BHCT. See Bottomhole Circulating Temperature.
quality of cement in the annulus.
BHST. See Bottomhole Static Temperature.
Consistometer. Laboratory apparatus used to determine
Blaine Fineness. The particle size or fineness of a the thickening time of a cement slurry as described in
cement in cm2/g or m2/kg as determined from air per- API Specification 10A and API Recommended Practice
meability tests using a Blaine permeameter. 10B.
Mark Identifier
ARCTICSET cement system for use through permafrost
EZEFLO surfactant
SlimAccess wireline logging tool for slim and complex geometry boreholes