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Soal Teknik Reaktor
Soal Teknik Reaktor
Species (mol%)
O2 13.0
N2 79.0
SO2 8.0
Thus,
[NO3]SS = k1[N2O5]
k2[NO2] + k3[NO2] + k4[NO] (H)
Cis kf trans
kr
r = k(O3)2∕3(N2O5)2∕3
NO2 + NO3
NO3 + O3
k5 − − → NO2 + 2O2
NO2 + O3
k6 − − → O2 + NO
where N2O5
∗ is an excited nitrogen pentoxide molecule and
M is any molecule. NO3 should be treated as an active intermediate.
Show whether or not this mechanism is consistent
with the experimentally observed rate expression.
Note that the stoichiometry of this reaction is given by
2O3 → 3O