IV-1

BAB IV
NERACA PANAS

Sebagai Basis Perhitungan

Kapasitas Produksi = 10.000 ton/tahun
Hari Kerja = 330 hari
Jumlah Produksi = 1262,6263 kg/jam
Basis Waktu = 1 jam
Satuan Massa = Kg
SatuanPanas = kJ
Satuan Cp = kJ/kmol
Suhu Referensi = 25oC (298,15 K)

4.1 Heater-1 (E-112)

Steam in
T = 160oC

Q1 Q4
Heater 1
T = 30oC T = 100oC

Steam out
T = 160oC
 IV-2

Tabel 4.1 Neraca Panas Heater 1

Input (kj) Output (Kj)

Komponen
Q1 Q4
C5H11Cl 14178.1077 221317.1691
C5H10Cl2 12191.1924 3883.1980
steam - -198831.0670
total 26369.3001 26369.3001

4.2 Heater-2 (E-122)

Steam in
T = 160oC

Q2 Q5
Heater 2
T = 30oC T = 100oC

Steam out
T = 160oC

Tabel 4.2 Neraca Panas Heater 2

Input (kJ) Output (kJ)

Komponen
Q2 Q5
C18H33NaO2 1,8156 28,0329
C18H31NaO2 0,2031 3,1354
steam - -29,1497
total 2,0186 2,0186
 IV-3

4.3 Heater-3 (E-132)

Steam in
T = 160oC

Q3 Q6
Heater 3
T = 30oC T = 100oC

Steam out
T = 160oC

Tabel 4.3 Neraca Panas Heater 3

Input (kJ) Output (kJ)

Komponen
Q3 Q6
C5H11Cl 6577.1908 98536.6511
C5H10Cl2 1250199.5415 283766.0773
Steam - 874474.0039
Total 1256776.7323 1256776.7323

4.4 Reaktor (R-210)

Q6 Air pendingin
Q5 Tin = 5oC
Q4
T = 100oC
Q7
Reaktor T = 100oC

Air pendingin
Tout = 30oC
 IV-4

Tabel 4.4 Neraca Panas Reaktor

Input Output
Komponen
Q4 (kJ) Q6 (kJ) Q5 (kJ) Q7
C5H11Cl 221317.1691 - - 553.2929
C5H10Cl2 3883.1980 - - 3883.1980
NaOH - 98536.6511 - 4926.8326
H2O - 283766.0773 - 283766.0773
C18H33NaO2 - - 28.0329 28.0329
C18H33NaO2 - - 3.1354 3.1354
C5H11OH - - - 231717.9321
NaCl - - - 91346.1557
C5H10 - - - 8919.3508
Sub total 607534.2638 625144.0077
Panas Reaksi -17609.7439 -
Beban pemanas - -35219.4878
Total 589924.5199 589924.5199

4.5 Mixer (M-220)

Q8
T= 30 ℃

Q7 Q9
Mixer
T=100 ℃ T = 76.18 ℃
 IV-5

Tabel 4.5 Neraca Panas Mixer

Input (kJ) Output (kJ)
Komponen
Q7 Q8 Q9
C5H11Cl 553.2929 - 372.0353
C5H10Cl2 3883.1980 - 2620.4348
NaOH 4926.8326 - 3363.2027
H2O 283766.0773 27548.0292 474430.4202
C18H33NaO2 28.0329 - 5.7642
C18H33NaO2 3.1354 - 0.4886
C5H11OH 231717.9321 - 83652.5417
NaCl 91346.1557 - 62577.9006
C5H10 8919.3508 - 25669.2488
Total 652692.0369 652692.0369

4.6 Dekanter (H-310_

Q10
T = 76.18 ℃
Q9
T = 76.18 ℃
Dekanter

Q11
T= 76.18 ℃
 IV-6

Tabel 4.6 Neraca Panas Dekanter

Input (kJ) Output (kJ)

Komponen
Q9 Q10 Q11
C5H11Cl 372.0353 - 372.0353
C5H10Cl2 2620.4348 - 2620.4348
NaOH 3363.2027 3363.2027 -
H2O 474430.4202 474430.4202 -
C18H33NaO2 5.7642 5.7642 -
C18H33NaO2 0.4886 0.4886 -
C5H11OH 83652.5417 2497.5760 81154.9658
NaCl 62577.9006 62577.9006 -
C5H10 25669.2488 - 25669.2488
Subtotal 652692.0369 542875.3522 109816.6847
Total 652692.0369 652692.0369

4.7 Heater 4 (E-312)

Steam in
T = 160oC

Q11 Q12
Heater 4
T = 76.18 oC T = 119.96 oC

Steam out
T = 160oC
 IV-7

Tabel 4.7 Neraca Panas Heater 4

Input (kJ) Output (kJ)

Komponen
Q11 Q12
C5H11Cl 372.0353 710.0131
C5H10Cl2 2620.4348 4965.2460
C5H11OH 81154.9658 114947.3100
C5H10 25669.2488 5133.6865
Steam - -15939.5708
Total 109816.6847 109816.6847

4.8 Vaporizer (V-320)

Q13
T = 42.54 ℃
Q12
T = 119.96 ℃
Vaporizer

Q14
T = 134.2 ℃

Tabel 4.8 Neraca Panas Vaporizer

Qin (kJ/jam) Qout (kJ/jam)

Komponen Q
Q12 Hsteam Q13 Q14 Hsteam
penguapan

C5H11Cl 709.483 - 824.2002

C5H10Cl2 4961.535 376.878 5747.0937
1014976 248709 751756.15
C5H11OH 114861.4 - 132042.73
C5H10 5129.850 - 1182.1596
Subtotal 125662.3 1014976 376.878 139796.18 248709 751756.15
Total 1140638.2824 1140638.2824
 IV-8

4.8 Cooler 1 (E-322)

Steam in
T = 5oC

Q13
Cooler 1 Q15
T = 42,54oC
T = 30oC

Steam out
T = 30oC

Tabel 4.8 Neraca Panas Cooler 1

Komponen Q13 Q15

C5H10 376.8784 107.6289
beban pemanas - 269.2495
Total 376.8784 376.8784

4.9 Cooler 2 (E-325)

Steam in
T = 5oC

Q14
Cooler 2 Q16
T = 134.2oC
T = 30oC

Steam out
T = 30oC
 IV-9

Tabel 4.10 Neraca Panas Cooler 2

Komponen Q14 Q16
C5H11Cl 824.2002 35.4188
C5H10Cl2 5747.0937 250.6900
C5H11OH 132042.7256 6057.2476
C5H10 1182.1596 54.1099
beban pemanas - 133398.7128
Total 139796.1790 139796.1790