Sem.V VI

MAHARAJA KRISHNAKUMARSINHJI BHAVNAGAR UNIVERSITY
NAAC Accreditation Grade “B”

(With effect from Academic Year: 2018-19)
DETAILED CURRICULUM B. Sc. Semester – 5– CORE COURSE – CHEMISTRY
SR. PAPER TOTAL MARKS EXT. PASSING STANDARD TOTAL TEACHING

NAME OF THE PAPER CREDITS
NO. NO. +INT*= TOTAL EXT. + INT.* = TOTAL HOURS
1 CHECC -501 Inorganic Chemistry – 1 70+30=100 28+12=40 15 WEEKS X 4 HOURS = 60 04
2 CHECC -502 Organic Chemistry – 1 70+30=100 28+12=40 15 WEEKS X 4 HOURS = 60 04
3 CHECC-503 Physical & Analytical Chemistry – 1 70+30=100 28+12=40 15 WEEKS X 4 HOURS = 60 04
4 CHECC-504 Structural Chemistry – I 70+30=100 28+12=40 15 WEEKS X 4 HOURS = 60 04
5 SEC-501 Industrial Chemistry- I 70+30=100 28+12=40 15 WEEKS X 3 HOURS = 45 03
Practical Based On Paper CHECC-501 15 WEEKS X 12 HOURS

6 CHECC-505 200 80 12
To CHECC-504 =180
*INTERNAL MARKS : 30
Time duration of theory examination will be 02.30 Hours
Time duration of practical examination will be 12.00 Hours (4 Sessions of Three Hours)
1
Paper No: CHECC -501
Title of the Paper: Inorganic Chemistry – I Credits: 04
Marks: Semester End Examination: 70Marks
Continues Internal Evaluation: 30 Marks
Teaching Marks/
Unit Detailed Syllabus
Hours Weight
1 Operators and Wave mechanics : 12 14
Operator. Concept, Linear operator, Commutator operator,
Vector operator, Laplacian operator, Hamiltonian operator,
Hermition operator, Unitary operator, Construction of
Hamilatonian operator for He, He2+, H2, H2+, Li, Be, B, N and C.
Particle in a one-dimensional box and in a three dimensional
box.
2 Molecular Orbital Theory: Introduction. Molecular orbital 12 14
energy level diagram of homo-nuclear diatomic and hetero-
nuclear diatomic molecules like B2, N2, O2, NO, CO and their
ions with stability concept and magnetic properties of
molecules and ions.
3 Organometalic compounds :Introduction, Structure of 12 14
Beryllium dimethyl [Be(CH3)3], Aluminum trimethyl
[Al(CH3)3], Platinum tetramethyl [Pt(CH3)4], Zeiss salt
K[PtCl3(C2H4)], Ferrocene [(C5H5)2Fe], Dibenzene chromium
[Cr(C6H6)2]
Non-aqueous solvents
Non-aqueous solvents and importance of study in non-
aqueous media, Classification of solvents, Characteristics of
solvents pertaining to water and study of the following
systems (i) Protonic solvent, Liq. NH3, HF (ii) Non-Protonic
liq. SO2
4 Metal carbonyl compounds :Classification of metal 12 14
carbonyls, General methods for preparation of metal
carbonyls, Explanation of bonding in metal carbonyls,
Effective atomic number rule(EAN) in metal carbonyls,
explanation for structure of metal carbonyls of
Molybdenum(Mo),Tungsten(W), Iron(Fe), Manganese(Mn),
Cobalt(Co), Nickel(Ni) and Ruthenium(Ru) with their I.R
spectra.
5 Sidgwick-Powel Rules :Six Rules of Sidgwick & Powel, Its 12 14
extension by Nyholm and Gillespie by proper illustrations
such as BeH2, BeCl2, BH3, CH4, NH3, H2O, CIF3, PCl5, SF6 and IF7
2
:: REFERENCE BOOKS::
1. Basic Inorganic Chemistry; 3rd edition, F. A. Cotton, G. Wilkinson and P. L. Gaus; John Wiley &
Sons.
2. Inorganic Chemistry; 3rd edition, Gary L. Miessler and Donald A. Tarr; Pearson Education
International.
3. Inorganic Chemistry; Gray Wulfsberg, University Science Books, U.S.
4. A Text Book of Inorganic Chemistry; 11th edition, P. L. Soni; S. Chand & Sons.
5. Principles of Inorganic Chemistry; Puri, Kalia and Sharma ; Milestone Publishers &
Distributors.
6. Vogel’s Inorganic qualitative analysis,; 7th edition, G. Svehla; Pearson Education International.
7. Advanced Inorganic Chemistry; 3rd edition, F. A. cotton & G. Wilkinson; Interscience
Publishers
8. Valency and Molecular Structure, E.Cartmell and G.W.A. Fowles; Butterworths Scientific
Publications
9. Theoretical Inorganic Chemistry, 2nd edition, M. C. Day & J. Selbin; Reinhold Publishing
Corporation, New York
10. Concise inorganic chemistry; 5th edition, J. D. Lee; Blackwell Science Ltd, France
3
Title of the Paper: Organic Chemistry - 1 Credits: 04
Continues Internal Evaluation 30 Marks
Teaching Marks/
Hours Weight
1 (A)Polypeptides and proteins : 12 14
Introduction and classification of peptides,
General methods for synthesis of Polypeptides by Fischer's &
Bergmann's method, Determination of amino acid sequence in
Polypeptides and Proteins by Senger, Edman, Schlack and Kumpf's
methods.
(B)Alkaloids:
Brief introduction of alkaloids, constitution and synthesis of Hygrine
and coniine.
2 (A)Vitamins, steroids and hormones : 12 14
Introduction, synthesis and analytical evidence for the constitution of
vitamin-A (Retinol), its relation with β-carotine, Vitamin-C (L-ascorbic
acid), introduction to steroids, only structural formula of adrenaline.
(B) Terpinoids:
Brief account on terpinoids, isoprene rule. Classification of terpinoids,
constitution and synthesis of citral and menthol.
3 Stereochemistry : 12 14
Introduction, concept of chirality (only introduction), racemisation,
theory of racemisation, methods for the resolution of racemates.
methods for asymmetric synthesis. Walden inversion, molecular
asymmetry and optical activity of allenes, spiranes and diphenyl
derivatives, geometrical isomerism of the compounds containing
>C=C< and >C=N− Beckmann re-arrangement, methods for determining
configuration of cis-trans isomers.
4 Reactions : 12 14
Principle, mechanism and synthetic applications of the following
reactions:
(i) Ardent-Eistert reaction
(ii) Bischler-Napieralski reaction
(iii) Claisen-Schmidt condensation reaction
(iv) Deickmann reaction
(v) Mannich reaction
(vi) Pechmann reaction
5 Nucleic acids : 12 14
Introduction, classification, degradation of nucleic acids, synthesis and
analytical evidence for the structure of Adenosine, Guanosine, Cytidine,
Uridine, Thymidine. Structure of Nucleotides and Nucleic acids.
Function of Nucleic acid in Protein synthesis. Differences between the
structural features of RNA and DNA.
4
1. Organic reaction mechanism: An Introduction, Ronald Breslow; Benzamin
2. Reaction and reagents; O. P. Agrawal; Goel Publishing House, Meerut
3. Organic Chemistry, 7th edition, Morrison and Boyd; Pearson Education Inc.
4. Medicinal Chemistry; Vol.1, A. Burger; Wiley Interscience
5. Organic Chemistry; Vol. I , II & III, S. M. Mukherji, S. P. Singh and R. P. Kapoor, New Age
International Publishers
6. A Text Book of Organic Chemistry; R.K.Bansal; New Age International Publishers
7. Text Book of Organic Chemistry; P.L.Soni; S. Chand & Sons
8. Organic Chemistry Natural Products; Vol. I & II, O. P. Agarwal; Goel Publishing House, Meerut
5
Title of the Paper: Physical & Analytical Chemistry – 1
Credits: 04
Teaching Marks/
Hours Weight
1 Thermodynamics: Equilibrium between the phases of one 12 14
component. Clapeyrone equation, equilibrium between two
crystalline forms, liquid vapour equilibria, Clausious-Clapeyrone
equation. solid vapour equilibria, variation of equilibrium, latent
heat on total pressure condition of equilibrium for the system of
more than one component.
Nernst’s heat theorem: Third law of thermodynamics and its
limitations, application of third law of thermodynamics,
determination of absolute entropy of solids, calculation of free
energy changes of reactions, calculation of equilibrium constants,
partition function. Types of partition functions without derivation.
2 Adsoption: Introduction, Frundlich adsoption isotherm and its 12 14
limitations, Langmuir adsoption isotherm, Derivation of B.E.T.
equation, Gibbs adsorption equation, direct and indirect method
for the verification of Gibbs adsoption equation
3 Study of Gaseous substances: Postulates of kinetic theory of 12 14
gases, determination of kinetic equation for gases. Derivation of
gaseous law from kinetic equation, derivation of PV isotherm of
real gases, van der Waals equation. Critical temperature, critical
pressure and critical volume, critical phenomenon and Andrew's
experiment. Van der Waals equation and critical state. Molecular
velocity, root mean square, average and most probable velocities,
numerical.
4 Phase rule: Phase rule for three component system, graphical 12 14
representation, partially miscible three liquid system-three types.
System composed of two solids and a liquid- four types.
5 Chromatography: Introduction and classification of 12 14
chromatography. Partition chromatography, column
chromatography, paper chromatography, thin layer
chromatography, Ion exchange chromatography, Gas-liquid
chromatography, Gas-solid chromatography.
6
:: REFERENCE BOOKS ::
1. Physical Chemistry ; 9th edition, Atkin P.W. & J. D. Poula; Oxford University Press, Oxford.
2. Comprehensive Physical Chemistry; B.K.Vermani and S.Kiran Vermani ; Laxmi Publications
3. An Introduction to Electro Chemistry; 10th edition, Samuel Glasstone ; Affiliated East –West
Press pvt. Ltd. New Delhi
4. Physical Chemistry; 5th edition; G. M. Barrow, McGraw-Hill, New York.
5. The Elements of Physical Chemistry; 9th edition, Atkin P.W. & J. D. Poula; Oxford University
Press, Oxford.
6. Physical Chemistry through problems; 2nd edition; S.K.Dogra and S.Dogra; New Age
International Publishers.
7. University General Chemistry; C.N.R. Rao ; McMillan Publishers
8. Textbook of Physical Chemistry; P.L.Soni , O.P.Dharmarha and U. N. Dash; Sultan Chand &
Sons.
9. Basic concepts of analytical chemistry,3rd edition ;S.M.Khopkar; New Age publishers.
10. Analytical chemistry; Dharuba charan das; PHI Pearning P.L.
11. Advanced Physical Chemistry; 18th edition; J. N. Gurtu and A. Gurtu; Pragati Prakashan.
7

Title of the Paper: Structural Chemistry – I
Credits: 04
Teaching Marks/
Hours Weight
1 Mass spectroscopy: 12 14
Introduction and principle of mass spectroscopy,
working of mass spectrometer,
Various types of ions produced in mass spectrum, Interpretation of
mass spectrum,
Nitrogen rule, Unsaturated site,
Mass spectrum of paraffin hydrocarbons, olefins, alcohols,
aldehydes, carboxylic acids, amines, applications of mass
spectroscopy.
2 Microwave spectroscopy: 12 14
Origin of Microwave spectroscopy,
Classification of molecules, linear molecule, spherical top
molecules, symmetrical top molecules, prolase and oblase
symmetric top molecules, asymmetric top molecules,
Rigid rotator model of di-atomic molecules, selection rules,
Derivation of rotation frequency equation,
Applications of rotational spectra.
3 Magnetic susceptibility: 12 14
Definition of magnetic susceptibility,
Types of magnetism such as: diamagnetism, paramagnetism,
ferromagnetism, antiferro magnetism. Determination of magnetic
susceptibility,
Guy's method to determine magnetic susceptibility,
Derivation of only spin magnetic moment formula,
Use of magnetic moment in structure determination of inorganic
compounds.
4 Dipole moment: 12 14
Introduction, definition of dipole moment,
Types of polarisation, induced polarisation, orientation
polarisation and molar polarisation,
Determination of dipole moment by various methods such as
vapour temperature method, refraction method, dilution method.
Dipole moment of benzene, mono substituted benzene compounds
and disubstituted benzene compounds and numerical.
Applications of dipole moment to find out the molecular structure.
8
5 Conformation: 12 14
Introduction, fundamental postulates of tetrahedral theory,
Conformational analysis of alkanes, substituted alkanes,
cyclohexane, monosubstituted cyclohexanes and disubstituted
cyclohexanes,
Factors affecting stability of conformation
ESR spectroscopy:
Introduction, principle,
Hyperfine splitting,
ESR spectra of H1, H2, methyl free radical, C6H5+, C6H5 (phenyl) free
radical,
Simple applications of ESR.
1. Instrumental methods of chemical analysis; 5th edition, Ewing G. W.; McGraw Hill Higher
Education.
2. Instrumental analysis; 2nd edition, Chritian G.D. and O’Reilly J.E.; Allyn & Bacon, USA
3. Introduction to Spectroscopy; 4th edition, Pavia, Lampman, Kriz & Vyvyan; Cengage Learning,
USA
4. Spectrometric identification of organic compounds; 7th edition, Silverstrein, Webster &
Kiemle; John Wiley & Sons, INC
5. Elementary organic Spectroscopy; Revised edition, Y. R. Sharma; S. Chand & Company Pvt.
Ltd.
6. Spectroscopy of organic compounds; 6th edition, P. S. Kalsi; New Age International Publishers
7. Spectroscopy, 12th edition, B K Sharma; Goel Publishing House, Meerut
9
Paper No: SEC -501
Title of the Paper: Industrial Chemistry - 1
Credits: 03
Teaching Marks/
Hours Weight
1 Unit Process, Unit Operation and Industrial Equipments 12 14
Unit Process: Introduction, Study of following Unit Processes with
reactions involve in it: Nitration, Sulphonation, Halogination,
Reduction. Unit Operations: Introduction, Study of following Unit
Operations: Filtration, Drying, Distillation, Crystallization.
Industrial Equipments: Introduction, Study of following Industrial
Equipments: Valves, Heat Exchangers, Pressure Vessels, Boilers.
2 Synthetic Dyes and Food Colors Dyes: Introduction, 12 14
Classification of Dyes with suitable examples, Preparation and uses
of following dyes: Alizarine, Congo Red, Methyl Orange,
Phenolphthaline. Food Color: Introduction, Purpose of Food
Coloring, Natural and Artificial Food Color with their regulations,
Preparation and uses of following Food Color: Anthocyanin, beta-
carotene, Allura Red AC, Quinoline Yellow WS.
3 Polymer, Resin & Rubber: 12 14
Introduction, Types of Polymarization, Types of Resin, Types of
Rubber, Preparation and Uses of following : Teflon, Saran, Orlon,
Vinyone, Urea formaldehyde, Melamine resin, Epoxy resin, Buna-S
rubber, Buna-N rubber, Neoprene and examples based on Weight
average molecular mass and number average molecular mass of
polymers.
4 Marine Chemicals and Silica Products: 12 14
Marine Chemicals: Introduction, Types of Sea Water (Bitterns),
Production of MgCl2, MgSO4, Mg(OH)2, MgCO3, KCl & Br2 from Sea
Water with diagram and reactions.
Silica Products: Introduction, Manufacture of different types of
Precipitated silica, Properties and uses of different types of
precipitated silica.
5 Industrial Waste and Treatment: 12 14
Introduction, Characteristics of Industrial waste, Types of
Industrial waste, Principles of Industrial waste treatment,
Treatment of disposal of Industrial waste, The nature and
treatment of some Industrial waste.
10
1. Industrial Chemistry; 16th edition, B. K. Sharma; Goel Publication House, Meerut
2. Rogers’ Industrial Chemistry; 6th edition, C. C. Furnas & Allen Rogers; D. Van Nostrand
Company Inc.
3. Industrial Chemistry ; William Thornton; John Wiley & Sons
4. Shreve’s Chemical Process Industry; R. Norris Shreve & J. A. Brink; McGraw Hill Higher
Education.
5. Production Technology Manufacturing Processes; Vol. 1, O. P. Khanna; Dhanpat Rai
Publication
6. A Text Book of Polymer & Products; M. S. Bhatnagar; S. Chand & Company Pvt. Ltd.
11
Paper: CHECC -505

Title of the Paper: Practical [Based on paper CHECC – 501 to 504] Credits: 12
Marks: Semester End Examination: 200 Marks
DETAILED CURRICULUM FOR PRACTICAL

Students have to prepare their Practical journals of Chemistry for Laboratory work
and they have to submit certified journals in the University practical exams. Students
are not allowed in the laboratory without certified journals in the University
practical examination. Time duration of Practical examination is 12.00 Hours (4
Sessions of Three Hours).
Teaching
Detailed Syllabus for Chemistry Practical
Hours
Organic separation solid and liquid mixtures (two component system), (Minimum 12 180
mixtures) (solid+solid, solid+liquid, liquid+liquid)
Gravimetric analysis With interfering as cu2+ & Fe3+ ions: Ni as Ni(DMG)2 and Ba as BaSO4
Organic Estimation Estimation of the following functional groups/Compounds:

Amide, Amine, Phenol and Glucose (by bromination method)
Physical exercises Exercise based on analytical instruments :

1. Determination of cell constant, and determination of
dissociation constant of weak acid (acetic acid) by
conductometry.
2. Determination of solubility and solubility-product of given
sparingly soluble salt by conductometry.
3. Determination of degree of hydrolysis of given salt (ammonium
chloride) from its given standard solution by
pH-metry.
4. Determination of viscosity of pure liquids A and B, and their
different percentage compositions and determination of
composition of unknown mixture of A and B.
5. Study of inversion of sucrose in presence of 1N HCl and
determination of the order of the reaction by polarimeter.
6. Determination of amount of Ni+2 ion in given solution by
colorimeter.
7. Determination of strength of FeSO4 (NH4)2SO4 6H2O solution
using standard K2Cr2O7 solution by potentiometric method.
8. Chromatographic separation of metal ions – Cu2+ , Ni2+ and Co2+
etc.
12
DETAILED CURRICULUM B. Sc. Semester – 6 – CORE COURSE – CHEMISTRY

---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
PAPER TOTAL MARKS EXT. PASSING STANDARD TOTAL TEACHING

SR. NAME OF THE PAPER CREDITS
NO. +INT*= TOTAL EXT. + INT.* = TOTAL HOURS
NO.
1 CHECC -601 Inorganic Chemistry – 2 70+30=100 28+12=40 15 WEEKS X 4 HOURS =60 04
2 CHECC -602 Organic Chemistry – 2 70+30=100 28+12=40 15 WEEKS X 4 HOURS =60 04
3 CHECC-603 Physical & Analytical Chemistry – 2 70+30=100 28+12=40 15 WEEKS X 4 HOURS =60 04
4 CHECC-604 Structural Chemistry – 2 70+30=100 28+12=40 15 WEEKS X 4 HOURS =60 04
5 SEC-601 Industrial Chemistry – 2 70+30=100 28+12=40 15 WEEKS X 3 HOURS =45 03
Practical Based On Paper CHECC-601 15 WEEKS X 12HOURS

6 CHECC-605 200 80 12
To CHECC-604 =180
*INTERNAL MARKS : 30
Time duration of Theory examination is 02.30 Hours
Time duration of Practical examination is 12.00 Hours 4 Sessions of Three Hours)
13
Paper CHECC: 601
Title of the Paper: Inorganic Chemistry – II Credits: 04
Continous Internal Evaluation: 30 Marks
Teaching Marks/
Hours Weight
1 Molecular symmetry: Explanation of symmetry elements and 09 14
symmetry operations with proper illustrations such as identity, axis
of rotation, plane of symmetry, point of inversion and improper axis
of rotation, multiplication of symmetry operation. Multiplication
table for C2v and C3v point groups.
Complex metric Titrations: Brief introduction, types of Complex
metric titrations, masking agents and demasking agents, back
titration, application of complex metric titrations. 03
2 Lanthanides and Actinides series: 12 14
Different nomenclature, symbol, atomic number, electronic
configuration given to lanthanide series elements, their position in
periodic table. Different methods for lanthanides elements
separation. Effect of electronic configuration on physical and
chemical properties, lanthanide contraction and its post effect and
their properties. General outlines for actinides, their nomenclature
given up to element no. 103 .
3 Hydrides and electron deficient compounds : 12 14
Brief Introduction and classification of hydrides, preparation,
properties and application of different types of hydrides such as (i)
salt like saline or ionic hydride (ii) molecular or co-valent hydride
(iii) mefllic interstitial hydride (iv) boron hydrides(electron
deficient molecule), explanation of two electron three centre(2e-
3c)bonding in B2H6 and structure of B2H6 and B5H9
4 Zero group elements: Nomenclature, atomic number, symbol, 12 14
electronic configuration and effect of electronic configuration on
their properties. Preparation and chemical reactions of XeF2, XeF4,
XeF6, XeO3, XeOF4. Explanation for bonding and structure of XeF2,
XeF4, XeF6, XeO3, XeOF4.
5 (A)Solvent extraction method: Introduction to solvent extraction 09 14
separation methods and their importance in chemistry, continuous
and counter current methods of solvent extraction, solvent
extraction systems for inorganic species, important analytical
industrial applications.
(B)Concept of qualitative analysis: sparingly soluble salt,
Common ion effects with proper illustrations. Solubility product, 03
relation between solubility product and solubility, applications of
solubility product.
14
:: REFERNCE BOOKS::
1. Basic Inorganic Chemistry; 3rd edition, F. A. Cotton, G. Wilkinson and P. L. Gaus; John Wiley &
Sons.
2. Inorganic Chemistry; 3rd edition, Gary L. Miessler and Donald A. Tarr; Pearson Education
International.
3. Inorganic Chemistry; Gray Wulfsberg, University Science Books, U.S.
4. A Text Book of Inorganic Chemistry; 11th edition, P. L. Soni; S. Chand & Sons.
5. Principles of Inorganic Chemistry; Puri, Kalia and Sharma ; Milestone Publishers &
Distributors.
6. Vogel’s Inorganic qualitative analysis,; 7th edition, G. Svehla; Pearson Education International.
7. Advanced Inorganic Chemistry; 3rd edition, F. A. cotton & G. Wilkinson; Interscience
Publishers
8. Valency and Molecular Structure, E.Cartmell and G.W.A. Fowles; Butterworths Scientific
Publications
9. Theoretical Inorganic Chemistry, 2nd edition, M. C. Day & J. Selbin; Reinhold Publishing
Corporation, New York
10. Concise inorganic chemistry; 5th edition, J. D. Lee; Blackwell Science Ltd, France
15
Paper CHECC: 602
Title of the Paper: Organic Chemistry - 2 Credits: 04
Continous Internal Evalation: 30 Marks
Teaching Marks/
Hours Weight
1 Carbohydrates and Glycosides : 12 14
introduction, methylation of carbohydrates, introduction of D and
L– configurations, mutarotation, Hudson's lactones rule,
determination of ring structure of glucose and fructose,
determination of the constitution of sucrose, synthesis and
analytical evidences for the structure of salicin and indican.
2 Terpinoids (Isoprenoids) : 12 14
Introduction, isoprene rule and classification of terpinoids.
Isolation of essential oils and terpinoids. General method of
determining structure of terpinoids. Synthesis and analytical
evidences for the structure of α-terpiniol and camphor.
3 Heterocycles : 12 14
Introduction, synthesis and chemistry of following Azoles:
Pyrazole, Imidazole, Isooxazole, Thiazole.
Synthesis and chemistry of following
Azines : Pyridazine, Pyrimidine, Pyrazine.
4 Alkaloids : 12 14
Introduction, classification, isolation and properties of alkaloids.
General methods of determination of structure of alkaloids.
Synthesis and analytical evidences for the structure of Nicotine,
Papaverine and Atropine.
5 Plant pigments: 12 14
Introduction and classification, synthesis and analytical evidence
for the structure of cyanin chloride.
Synthesis, analytical evidences and structure of flavone , flavanol,
isoflavone, crysine, quercetin and genistiein, structure of analytical
evidence for the structure of β-carotine.
:: REFERNCE BOOKS::
1. Organic reaction mechanism: An Introduction, Ronald Breslow; Benzamin
2. Reaction and reagents; O. P. Agrawal; Goel Publishing House, Meerut
3. Organic Chemistry, 7th edition, Morrison and Boyd; Pearson Education Inc.
4. Medicinal Chemistry; Vol.1, A. Burger; Wiley Interscience
5. Organic Chemistry; Vol. I , II & III, S. M. Mukherji, S. P. Singh and R. P. Kapoor, New Age
International Publishers
6. A Text Book of Organic Chemistry; R.K.Bansal; New Age International Publishers
7. Text Book of Organic Chemistry; P.L.Soni; S. Chand & Sons
8. Organic Chemistry Natural Products; Vol. I & II, O. P. Agarwal; Goel Publishing House, Meerut
16
Paper CHECC: 603
Title of the Paper: Physical & Analytical Chemistry – 2 Credits: 04
Teaching Marks/
Hours Weight
1 EMF: Polarization, cause of polarization, explanation of 12 14
polarization, remedy of polarization, decomposition voltage,
measurement of decomposition potential, reversible potential and
over voltage, polarography, hydrogen over voltage, influence of
current density, pH, temperature, electrode surface, impurity on
over voltage, measurement of over voltage, theories of over voltage.
2 Study of Solid substances: 12 14
The study of crystals, space lattice, crystal systems, lattice plane and
dimensions, Miller's indices, Bragg equation for x-ray diffraction,
the determination of crystal structure by Bragg's X-ray
spectrometer and powder method of P. Debye, P. Scherrer.
Determination of NaCl, KCl structure, determination of Avogadro
number, heat capacity of solids.
Einstein theory and Debye theory of atomic heat capacity of solids.
3 Chemical kinetics: Experimental method to study reaction 12 14
kinetics, Kinetics of simultaneous reactions, side reactions,
opposing reactions, consecutive reactions. Absolute or transition
state theory, comparison of collision and absolute rate theories.
Primary and secondary salt effects, kinetics of heterogeneous
reaction and retardation reaction, numerical.
4 Conductometry: Basic principle of conductometry, acid-base 12 14
titration, dissociation constant of mono-basic acid,
Potentiometry: Introductory information about Nernst equation,
electrodes and pH scale, applications of potentiometry to acid-base
and redox titrations,
Colourimetry: Basic principle of colorimetry. (Beer-Lambert’s
law), applications of colorimetry in determining unknown
concentration of the homogeneous colored solution.
5 Nuclear chemistry: Tracer technique, nuclear fusion, nuclear 12 14
fission, nuclear chain reaction reactor. Uses of nuclear energy,
thermonuclear reactions on sun and stars. Detection and
measurement of radio activity: Such as, scintillation counter,
proportional counter, Geiger- Muller counter. Accelerators:
Cyclotron, Linear accelerator and examples
17
1. Physical Chemistry ; 9th edition, Atkin P.W. & J. D. Poula; Oxford University Press, Oxford.
2. Comprehensive Physical Chemistry; B.K.Vermani and S.Kiran Vermani ; Laxmi Publications
3. An Introduction to Electro Chemistry; 10th edition, Samuel Glasstone ; Affiliated East –West
Press pvt. Ltd. New Delhi
4. Physical Chemistry; 5th edition; G. M. Barrow, McGraw-Hill, New York.
5. The Elements of Physical Chemistry; 9th edition, Atkin P.W. & J. D. Poula; Oxford University
Press, Oxford.
6. Physical Chemistry through problems; 2nd edition; S.K.Dogra and S.Dogra; New Age
International Publishers.
7. University General Chemistry; C.N.R. Rao ; McMillan Publishers
8. Textbook of Physical Chemistry; P.L.Soni , O.P.Dharmarha and U. N. Dash; Sultan Chand &
Sons.
9. Basic concepts of analytical chemistry,3rd edition ;S.M.Khopkar; New Age publishers.
10. Analytical chemistry; Dharuba charan das; PHI Pearning P.L.
11. Advanced Physical Chemistry; 18th edition; J. N. Gurtu and A. Gurtu; Pragati Prakashan.
18
Paper CHECC: 604
Title of the Paper: Structural Chemistry – 2 Credits: 04
Teaching Marks/
Hours Weight
1 General introduction to spectroscopy: 12 14
Spectroscopy, spectrometry and spectrum.
Electromagnetic radiation, wavelength, wave numbers and
frequvancy, electromagnetic spectrum.
Regions of electromagnetic spectrum and types of molecular
spectrums.
Types o molecular energies- translational, rotational, vibrational
and electronic.
Types of molecular spectroscopy IR, microwave, UV, visible, NMR,
ESR and mass.
2 Ultraviolet spectroscopy : 12 14
Various spectral regions of electromagnetic spectrum in terms of
frequency and wave number,
Morse potential energy curve,
Frank Condon principle,
Electronic excitation,
Simple chromophoric groups, oxochromic groups, Conjugated
systems, systems of extended conjugation, aromatic systems,
Red and blue shifts, Hyperchromic and Hypsochromic effects,
Woodward, Fieser Scott rules for pre-designing of organic
functional groups viz conjugated dienes, unsaturated carbonyl
compounds, aromatic compounds.
3 Visible spectroscopy : 12 14
Visible spectra of transition metal complexes,
Selection rules and intensities of the transitions,
spectrum for d1 and d9 (Ti3+ and Cu2+) systems,
Orgel diagram, hole formation, derivation of Russell-Sounder's
terms (spectral terms) with example.
4 Infra Red spectroscopy : 12 14
Introduction, theory of IR,
Number of fundamental vibrations,
Types of molecular vibrations,
Principle of IR spectroscopy,
Double beam infrared spectrometer,
Selection rules (active and forbidden vibrations),
Factor influencing vibrational frequencies: Electronic effects,
hydrogen bonding, bond angles,
Sampling techniques: solids, liquids and gases,
Finger print region,
Applications of IR spectroscopy.
19
5 NMR spectroscopy : 12 14
Introduction, principle and instrumentation,
Number of signals, equivalent protons,
Enantiomeric protons and diasteriomeric protons with proper
illustrations,
Position of signals, shielding and de-shielding protons, Chemical
shift, τ(Tau )and δ(Delta) scales,
Factors affecting chemical shift,
Intensity of signals-peak area and proton counting,
Splitting of signals, spin-spin coupling and coupling constant,
Deuterium labeling,
Applications for aromaticity, H-bonding and conformation, Use of
NMR spectroscopy and limitations of NMR spectroscopy,
Problems for determination of structures of organic molecules.
:: REFERNCE BOOKS ::
1. Instrumental methods of chemical analysis; 5th edition, Ewing G. W.; McGraw Hill Higher
Education.
2. Instrumental analysis; 2nd edition, Chritian G.D. and O’Reilly J.E.; Allyn & Bacon, USA
3. Introduction to Spectroscopy; 4th edition, Pavia, Lampman, Kriz & Vyvyan; Cengage Learning,
USA
4. Spectrometric identification of organic compounds; 7th edition, Silverstrein, Webster &
Kiemle; John Wiley & Sons, INC
5. Elementary organic Spectroscopy; Revised edition, Y. R. Sharma; S. Chand & Company Pvt.
Ltd.
6. Spectroscopy of organic compounds; 6th edition, P. S. Kalsi; New Age International Publishers
7. Spectroscopy, 12th edition, B K Sharma; Goel Publishing House, Meerut
20
Paper SEC: 601
Title of the Paper: Industrial Chemistry – 2 Credits: 03
Continous Internal Evalation: 30 Marks
Teaching Marks/
Hours Weight
1 Petroleum & Petrochemicals: 12 14
Introduction, Importance of Petroleum on Economy, Methods to
search Petroleum, Refining of Petroleum, Chemical obtained from
C1, C2, C3, C4 & Aromatic hydrocarbons, Cracking and Reforming
process with suitable examples, Types of refineries in India,
Companies involved in refining and distribution of petroleum
products.
2 Paper-Pulp, Sugar & Fermentation Industries: 12 14
Introduction, manufacture of pulp and paper (Craft Process), Types
of papers, sugar : Introduction, manufacture of sugar, natural and
artificial sweetening agents, preparation and uses of saccharin,
sucaryl sodium, dulcin.
Fermentation: Introduction, Uses and adverse effects of
fermentation products, manufacture of acetic acid, alcohol &
penicillin by fermentation process.
3 Natural and Synthetic Drugs: 12 14
Introduction, Therapy and its types, Natural drugs and their
usefulness, Classification of Drugs according to diseases with
minimum one example, Concept of Dose setting and Lethal Dose,
Preparation, uses and adverse effects of following drugs : Analgine,
Chloramphenicol, Paracetamol, Ibuprofen, Avil, Diclofenic Sodium,
Chlorpromazine, Vioform, Phenobarbitone. Introduction of
Pharmacopia.
4 Qualitative and Quantitative Analysis: 12 14
Introduction, Basic chemicals used in laboratory and their MSDS,
Preparation and Standardization of different Molar solutions,
Normal solutions, % solutions with the examples of NaOH, HCl,
H2SO4 & KMnO4, Numerical based on this, General Error and its
solution, GLP Introduction, Fundamental points of GLP like
Characterization, Rules, Results and Q.A. in brief, Idea about
National and International Government Organizations like Food &
Drug Department, Pollution Control Board, WHO, ICH etc.
5 Industrial Safety: 12 14
Definitions, Purpose of Safety in Industry, Occupational Health and
Hazards, Safety at Workplace, Accident prevention techniques,
Safety management system, In plant training and visits, Fire
Hazards, Brief introduction about PPA (personal protective
application) like Helmets, Goggles, Hand Glows, Shoes, Mask.
21
1. th
Industrial Chemistry; 16 edition, B. K. Sharma; Goel Publication House, Meerut
2. Rogers’ Industrial Chemistry; 6th edition, C. C. Furnas & Allen Rogers; D. Van Nostrand
Company Inc.
3. Industrial Chemistry ; William Thornton; John Wiley & Sons
4. Shreve’s Chemical Process Industry; R. Norris Shreve & J. A. Brink; McGraw Hill Higher
Education.
5. Production Technology Manufacturing Processes; Vol. 1, O. P. Khanna; Dhanpat Rai
Publication
6. A Text Book of Polymer & Products; M. S. Bhatnagar; S. Chand & Company Pvt. Ltd.
22
Paper No: CHECC - 605
Title of the Paper: Practical [Based on paper CHECC -601 to 604 ] Credits: 06
DETAILED CURRICULUM FOR PRACTICAL

Students have to prepare their Practical journals of Chemistry for Laboratory work and they have to
submit certified journals in the University practical exams. Students are not allowed in the
laboratory without certified journals in the University practical examination. Time duration of
Practical examination is 12.00 Hours (4 Sessions of Three Hours).
Teaching
Detailed Syllabus for Chemistry Practical
Hours
Inorganic qualitative Inorganic qualitative analysis of mixture containing six radicals. 180
analysis (simple mixture + PO43- Soluble & insoluble) BO33-,CrO42-,Cr2O72-
(Min. 12 mixtures)
Gravimetric analysis With interfering ions: Fe as Fe2O3 and Al as Al2O3 .
Volumetric Analysis Estimation of Bi3+, Cu2+, Mg2+ and Fe3+ by EDTA method.
Physical exercises Exercise based on analytical instruments :
1. Determination of cell constant, and determination of
dissociation constant of weak acid (acetic acid) by
conductometry.
2. Determination of solubility and solubility-product of given
sparingly soluble salt by conductometry.
3. Determination of degree of hydrolysis of given salt (ammonium
chloride) from its given standard solution by
pH-metry.
4. Determination of viscosity of pure liquids A and B, and their
different percentage compositions and determination of
composition of unknown mixture of A and B.
5. Study of inversion of sucrose in presence of 1N HCl and
determination of the order of the reaction by polarimeter.
6. Determination of amount of Ni+2 ion in given solution by
colorimeter.
7. Determination of strength of FeSO4 (NH4)2SO4 6H2O solution
using standard K2Cr2O7 solution by potentiometric method.
8. Chromatographic separation of the following metal ions:
Cu2+ , Ni2+ and Co2+ etc.
23

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MAHARAJA KRISHNAKUMARSINHJI BHAVNAGAR UNIVERSITY

NAAC Accreditation Grade “B”

DETAILED CURRICULUM B. Sc. Semester – 5– CORE COURSE – CHEMISTRY

SR. PAPER TOTAL MARKS EXT. PASSING STANDARD TOTAL TEACHING

1 CHECC -501 Inorganic Chemistry – 1 70+30=100 28+12=40 15 WEEKS X 4 HOURS = 60 04

2 CHECC -502 Organic Chemistry – 1 70+30=100 28+12=40 15 WEEKS X 4 HOURS = 60 04

3 CHECC-503 Physical & Analytical Chemistry – 1 70+30=100 28+12=40 15 WEEKS X 4 HOURS = 60 04

4 CHECC-504 Structural Chemistry – I 70+30=100 28+12=40 15 WEEKS X 4 HOURS = 60 04

5 SEC-501 Industrial Chemistry- I 70+30=100 28+12=40 15 WEEKS X 3 HOURS = 45 03

Practical Based On Paper CHECC-501 15 WEEKS X 12 HOURS

Paper No: CHECC -504

Paper: CHECC -505

DETAILED CURRICULUM FOR PRACTICAL

Organic Estimation Estimation of the following functional groups/Compounds:

Physical exercises Exercise based on analytical instruments :

DETAILED CURRICULUM B. Sc. Semester – 6 – CORE COURSE – CHEMISTRY

PAPER TOTAL MARKS EXT. PASSING STANDARD TOTAL TEACHING

1 CHECC -601 Inorganic Chemistry – 2 70+30=100 28+12=40 15 WEEKS X 4 HOURS =60 04

2 CHECC -602 Organic Chemistry – 2 70+30=100 28+12=40 15 WEEKS X 4 HOURS =60 04

4 CHECC-604 Structural Chemistry – 2 70+30=100 28+12=40 15 WEEKS X 4 HOURS =60 04

5 SEC-601 Industrial Chemistry – 2 70+30=100 28+12=40 15 WEEKS X 3 HOURS =45 03

Practical Based On Paper CHECC-601 15 WEEKS X 12HOURS

DETAILED CURRICULUM FOR PRACTICAL

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