A B Psat zi R Ki V

n-pentano -6405 17.062 #DIV/0! 20.76 1.987 #DIV/0! 0.355

n-hexano -7092.3 17.076 44.64
n-heptano -8412.9 18.051 34.6

T
P 44.1 lb/pulg2
2280.6346 mmHg
Yi
#DIV/0!
T 100 oC V 0.1818 0.2 20
373.15 K L 0.8182

zi Psat
componentes fi(moles) Ai Bi Pb
(mmHg)
Etano 10 0.05 817.08 7.277361 122371.016 21635.2854
Propano 20 0.1 1051.38 7.392262 37556.2255
n-Butano 80 0.4 1267.56 7.492753 12469.0932
2Metil- propano 90 0.45 1183.44 7.349085 15052.1661
TOTAL 200 1

V 0.1818 1818
L 0.8182
 0.1818

Pr P Ki yi xi zt

15373.5902 18504.4378 6.6131 0.1637 0.0247 0.0500

2.0296 0.1710 0.0842 0.1000
0.6738 0.2865 0.4252 0.4000
0.8134 0.3789 0.4658 0.4500
TOTAL 1.0000 1.0000
 A B C Psat
acetona 14.3145 2756.22 228.06 81.6285
metanol 16.5785 3638.27 239.5 55.2061
90

a) T 50

x1 x2 Y1 Y2 P y1 y2
0 1 1.8965 1.0000 55.2061 0.0000 1.0000 80
0.1 0.9 1.6793 1.0064 63.7127 0.2152 0.7848
0.2 0.8 1.5062 1.0259 69.9001 0.3518 0.6482
0.3 0.7 1.3683 1.0593 74.4443 0.4501 0.5499
0.4 0.6 1.2591 1.1078 77.8068 0.5284 0.4716 70
0.5 0.5 1.1735 1.1735 80.2885 0.5965 0.4035
0.6 0.4 1.1078 1.2591 82.0622 0.6612 0.3388
0.7 0.3 1.0593 1.3683 83.1901 0.7276 0.2724
0.8 0.2 1.0259 1.5062 83.6266 0.8011 0.1989 60
0.9 0.1 1.0064 1.6793 83.2083 0.8886 0.1114
1 0 1.0000 1.8965 81.6285 1.0000 0.0000

b) P 75
50
Tsat
0.0 0.2 0.4
1) 47.6444
2) 57.2349

x1 x2 Tsupuesta P1sat P2sat alfa Y1 Y2

1 0 47.6444 75.0000 49.7980 1.5061 1.0064 1.6793
47.4680 74.5215 49.41169 1.5082 1.0064 1.6793
47.4680 74.5215 49.41169 1.5082 1.0064 1.6793
47.4680 74.5215 49.41169 1.5082 1.0064 1.6793
47.4680 74.5215 49.41169 1.5082 1.0064 1.6793
47.4680 74.5215 49.41169 1.5082 1.0064 1.6793
47.4680 74.5215 49.41169 1.5082 1.0064 1.6793
47.4680 74.5215 49.41169 1.5082 1.0064 1.6793
47.4680 74.5215 49.41169 1.5082 1.0064 1.6793
47.4680 74.5215 49.41169 1.5082 1.0064 1.6793

x1 y1 t/c
0 0 57.2349
0.1 0.2101 53.9595
0.2 0.3487 51.7411
0.3 0.4498 50.1864
0.4 0.5302 49.0684
0.5 0.5998 48.2532
0.6 0.6653 47.6675
0.7 0.7318 47.2808 60.0000
 60.0000
0.8 0.8047 47.1018
0.9 0.8907 47.1836
1 1 47.6444

55.0000

50.0000

45.0000
0 0.2
90

80

70

60

50
0.0 0.2 0.4 0.6 0.8 1.0

Pjsat Tcalc y1 y2
74.5215 47.4680 1.0000 0.0000
74.5215 47.4680
74.5215 47.4680
74.5215 47.4680
74.5215 47.4680
74.5215 47.4680
74.5215 47.4680
74.5215 47.4680
74.5215 47.4680
74.5215 47.4680

60.0000
60.0000

55.0000

50.0000

45.0000
0 0.2 0.4 0.6 0.8 1
 x1 0.0500 y1 0.05 alfa 12 x=0 5.0948
x2 0.9500 y2 0.95 alfa 12 x=1 0.7620
P1sat 79.8 kPa P1sat 79.8 kPa P2sat/P1sat 0.5075
P2sat 40.5 kPa P2sat 40.5 kPa ln P2/P1 -0.6782
Y1 2.3570 Y1 1.0000 x1az=y1az 0.8570
Y2 1.0024 Y2 1.0000 x2az=y2az 0.1430
T 343.15 K T 343.15 K Y1az 1.0196
Pburbuja 47.9708 kPa Procio 41.5224513 kPa Paz 81.3663
y1 0.1960 x1 0.0110
y2 0.8040 x2 0.9890
Procio calc 42.1914
x1 cal 0.0104
x2 cal 0.9896
Y1 2.5352
Y2 1.0001

Procio x1 x2 Y1 Y2
41.5224513 0.0110 0.9890 2.5323 1.0001
42.1914204 0.0104 0.9896 2.5352 1.0001
42.1914057 0.0104 0.9896 2.5352 1.0001
Prociocal
42.1914
42.1914
42.1914
 A B C
14.3916 2795.82 230
16.5938 3644.3 239.76

x1 0.175
x2 0.825
A 0.64
P1sat 111.8862
P2sat 81.1026 a) T
T 59 59 59
z1 0.25
z2 0.75 b) Tsup
Y1 1.5459 55.1155 55.1155
Y2 1.0198 1.9722E-05
P 101.3300
Pcalc 98.5026
y1 0.2987
y2 0.7013 0.572 57.2
V 0.572
L 0.428
z1 0.2458
z2 0.7542
1.0000
V L
0.572 0.428

P1 P2 ln(P2/P1) x1 x2 Y1 Y2 Paz
98.0698 69.0634 -0.3507 0.7739 0.2261 1.0332 1.4672 101.3300
P
101.3300
Punto de Burbuja P 100 P 200 P
T Especies xi Ki Ki*xi Ki Ki*xi Ki
140 Etano 0.1 6.8 0.68 3.8 0.38 3.65
Propano 0.2 2.7 0.54 1.49 0.298 1.42
Isobutano 0.3 1.31 0.393 0.73 0.219 0.71
Isopentano 0.4 0.42 0.168 0.25 0.1 0.25
1 1.781 0.997

Punto de Rocio P 100 P 150 P

T Especies yi Ki yi/Ki Ki yi/Ki Ki
140 Etano 0.48 6.8 0.07058824 4.82 0.09958506 3.8
Propano 0.25 2.7 0.09259259 1.9 0.13157895 1.49
Isobutano 0.15 1.31 0.11450382 0.91 0.16483516 0.715
Isopentano 0.12 0.425 0.28235294 0.32 0.375 0.25
1 0.56003759 0.77099917

Etano
 210 P 195 P 220
Ki*xi Ki Ki*xi P 203 Ki Ki*xi
0.365 4.1 0.41 3.6 0.36
0.284 1.55 0.31 1.41 0.282
0.213 0.75 0.225 0.695 0.2085
0.1 0.22 0.088 0.241 0.0964
0.962 1.033 0.947

200 P 210 P 215 P 220 P

yi/Ki Ki yi/Ki Ki yi/Ki Ki yi/Ki Ki
0.12631579 3.65 0.13150685 3.61 0.13296399 3.6 0.13333333 3.25
0.16778523 1.42 0.17605634 1.42 0.17605634 1.41 0.17730496 1.3
0.20979021 0.71 0.21126761 0.704 0.21306818 0.7 0.21428571 0.615
0.48 0.25 0.48 0.245 0.48979592 0.24 0.5 0.225
0.984 0.999 1.012 1.025

P 215
P 180
Ki Ki*xi
4.21 0.421
1.65 0.33
0.8 0.24
0.279 0.1116
1.103

250
yi/Ki
0.14769231
0.19230769
0.24390244
0.53333333
1.11723577
Bc 1 kg Vapor
componentes %peso peso PM moles f yi
etano 1.02 0.0102 30 0.0003 0.0193 0.110
propano 3.75 0.0375 44 0.0009 0.0484 0.107
isobutano 42.51 0.4251 58 0.0073 0.4162 0.412
n-butano 52.72 0.5272 58 0.0091 0.5161 0.372
TOTAL 100 1 0.0176 1 1.001

Presion 110.8 psia

Temperatura 130 oF
T burbuja 124 oF
T rocio 136 oF
T 100 T 120 T
xi Ki Ki*xi=yi Ki Ki*xi Ki
1 0.0193 4.8 0.0927 5.6 0.1081 5.82
2 0.0484 1.62 0.0784 2.1 0.1016 2.25
3 0.4162 0.72 0.2996 0.95 0.3954 1.09
4 0.5161 0.56 0.2890 0.7 0.3613 0.765
0.7597 0.9664

T 120 T 130 T
yi Ki yi/Ki=xi Ki yi/Ki Ki
1 0.0193 5.6 0.0034 5.82 0.0033 6.01
2 0.0484 2.1 0.0230 2.25 0.0215 2.35
3 0.4162 0.95 0.4381 1.09 0.3818 1.12
4 0.5161 0.7 0.7373 0.765 0.6747 0.81
1.2019 1.0813
 Liquido Vapor Liquido
%mol xi %mol yi %mol xi %mol
11.0236 0.0031 0.3119 0.1101 11.0065 0.0031 0.3115
10.6950 0.0202 2.0164 0.1026 10.2643 0.0202 2.0164
41.2011 0.3497 34.9725 0.4157 41.5715 0.3473 34.7302
37.1612 0.6294 62.9425 0.3716 37.1612 0.6294 62.9425
100.0809 1.0024 100.2432 1.0000 100.0034 1.0000 100.0006

130 T 124 T 125 T 123 T interp

Ki*xi Ki Ki*xi Ki Ki*xi Ki Ki*xi Ki
0.1124 5.71 0.1102 5.79 0.1118 5.7 0.1100 5.7011
0.1089 2.21 0.1070 2.18 0.1055 2.11 0.1021 2.121
0.4536 0.99 0.4120 1.1 0.4578 1 0.4162 0.9989
0.3948 0.72 0.3716 0.724 0.3737 0.72 0.3716 0.72
1.0697 1.0008 1.0487 0.9999

135 T 136 T interp 136.8276 T 137 T

yi/Ki Ki yi/Ki Ki yi/Ki Ki yi/Ki Ki
0.0032 6.19 0.0031 6.1983 0.0031 6.2 0.0031 6.2
0.0206 2.4 0.0202 2.4 0.0202 2.4 0.0202 2.45
0.3716 1.19 0.3497 1.1983 0.3473 1.2 0.3468 1.2
0.6372 0.82 0.6294 0.82 0.6294 0.82 0.6294 0.825
1.0326 1.0024 1.0000 0.9995
 123.11
Ki*xi
0.1101
0.1026
0.4157
0.3716
1.0000

138 T 140 T 150

yi/Ki Ki yi/Ki Ki yi/Ki
0.0031 6.25 0.0031 6.61 0.0029
0.0198 2.49 0.0194 2.7 0.0179
0.3468 1.21 0.3439 1.35 0.3083
0.6256 0.865 0.5967 0.952 0.5422
0.9953 0.9631 0.8713
 T
Componentes % peso Peso PM moles f Ki
metano 12.5 0.125 16 0.0078 0.3000 9
etano 7.81 0.0781 30 0.0026 0.1000 0.9
Propano 34.38 0.3438 44 0.0078 0.3000 0.165
n-butano 45.31 0.4531 58 0.0078 0.3000 0.0315
100 0.0260 1.0000

Presion 150 psia

V 0.3007 3007 30070
L 0.6993
 -30 T -29 T -28
yi xi=yi/ki Ki yi xi=yi/ki Ki yi xi=yi/ki
0.79281574 0.08809064 9 0.79281574 0.08809064 9 0.79281574 0.08809064
0.09276096 0.10306774 0.92 0.094238 0.10243261 0.92 0.094238 0.10243261
0.06610551 0.40063947 0.169 0.0675995 0.39999706 0.17 0.06797225 0.39983677
0.01333225 0.42324598 0.033 0.01395823 0.42297681 0.034 0.01437512 0.42279755
0.9650 1.0150 0.9686 1.0135 0.9694 1.0132
T -27 T -26 T -24
Ki yi xi=yi/ki Ki yi xi=yi/ki Ki yi
9.1 0.79460874 0.08731964 9.2 0.79637064 0.08656203 9.25 0.7972401664
0.94 0.09569695 0.10180526 0.96 0.09713813 0.10118555 0.98 0.0985618727
0.175 0.06983152 0.39903728 0.18 0.07168338 0.39824098 0.19 0.0753649975
0.034 0.01437512 0.42279755 0.0355 0.01499978 0.42252894 0.037 0.0156236451
0.9745 1.0110 0.9802 1.0085 0.9868

T -20
Ki yi
9.4 0.80
1.01 0.10
0.21 0.08
0.04 0.02
1.0000
xi=yi/ki
0.0861881261
0.1005733394
0.3966578814
0.4222606789
1.0057

xi=yi/ki
0.09
0.10
0.39
0.42
1.0000
Burbuja T T 70 T 50 T
Componentes f = xi Ki yi = Ki*xi Ki yi = Ki*xi Ki
n-butano 0.25 0.8 0.2 0.56 0.14 2.1
n-pentano 0.75 0.24 0.18 0.16 0.12 0.74
1 0.38 0.26

P 40 psia
V 0.4 4000 40000
L 0.6 T 100 T 120
Componentes f = yi Ki yi xi=yi/Ki Ki yi
n-butano 0.495 1.2 0.5500 0.4583 1.65 0.6482
n-pentano 0.51 0.39 0.2631 0.6746 0.56 0.3466
SUMA 0.8131 1.1329 SUMA 0.9948
 140 T 135 T 134 T 133 T
yi = Ki*xi Ki yi = Ki*xi Ki yi = Ki*xi Ki yi = Ki*xi Ki
0.525 1.98 0.495 1.98 0.495 1.81 0.4525 1.8
0.555 0.69 0.5175 0.68 0.51 0.67 0.5025 0.67
1.08 1.0125 1.0050 0.9550

T 122 T 121
xi=yi/Ki Ki yi xi=yi/Ki Ki yi xi=yi/Ki
0.3929 1.67 0.6519 0.3904 1.65 0.6482 0.3929
0.6189 0.57 0.3511 0.6159 0.59 0.3599 0.6100
1.0118 SUMA 1.0030 1.0063 SUMA 1.0081 1.0029
 132
yi = Ki*xi
0.45
0.5025
0.9525