JP XII Physical&Inorganic Chemistry (7) - Prev Class XI Chap B S - Solution & Colligative Properties - Solid State-1

PHY./INO.
CHEMISTRY
TARGET : JEE (Main + Advanced) 2016

Course : VIJETA (JP) Date : 11-05-2015 NO. 10 & 11
TEST INFORMATION
DATE : 17.05.2015 PART TEST (PT) - 01 (ADVANCED)
Syllabus : Solution & Colligative Properties, Solid State, Thermodynamics, Ionic equilibrium, s-Block
Element. (All ChemInfos and Handouts till date)
This DPP is to be discussed in the week (11-05-2015 to 16-05-2015)

DPP No. # 10 (JEE-ADVANCED)
Total Marks : 79 Max. Time : 49 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.3 (3 marks, 2 min.) [09, 06]
Multiple choice objective ('–1' negative marking) Q.4 to Q.8 (4 marks, 2 min.) [20, 10]
Integer type Questions ('–1' negative marking) Q.9 to Q.12 (4 marks 3 min.) [16, 12]
Match the Following (no negative marking) Q.13 (8 marks, 6 min.) [08, 06]
ChemINFO : 4 Questions ('–1' negative marking) Q.14 to Q.17 (4 marks, 2 min.) [16, 08]
1. The density of KBr is 2.75 gm/cc length of the unit cell is 654 pm. K = 38, Br = 80, then what is true
about the predicted nature of the solid.
KBr dk ?kuRo 2.75 gm/cc rFkk bdkbZ dks "Bhdk dh dks j yEckbZ 654 pm gSA K = 38, Br = 80, rc Bks l dh iz d`fr
ds lanHkZ esa dkSulk dFku lR; gS &
(A*) Solid has F.C.C. structure with co-ordination number = 6
Bksl ] leUo; la[;k = 6 ds lkFk F.C.C. lajpuk j[krk gSA
(B) Solid has simple cubic structure with co-ordination number = 4
Bksl ] leUo; la[ ;k = 4 ds lkFk ljy ?kuh; lajpuk j[krk gSA
(C) Solid has F.C.C. structure with co-ordination numbers-1
Bksl ] leUo; la[ ;k = 1 ds lkFk F.C.C. lajpuk j[krk gS
(D) None of these dksbZ ugha
Z  118
Sol. 2.75 = 8 3  Z = 4 (fcc with NaCl type structure)
( 6.54  10 )  6.023  10 23
2. A crystal is made of particle X, Y & Z. X forms FCC packing, Y occupies all octahedral voids of X and Z
occupies all tetrahedral voids of X, if all the particles along one body diagonal are removed then the formula
of the crystal would be -
,d fØLVy X, Y vkSj Z d.kksa ls cuk gSA X , FCC ladqy cukrk gS] X dh lHkh v"VQydh; fjfDr;k¡ Y }kjk Hkjh tkrh gSa
vkSj X dh lHkh prq"Qydh; fjfDr;k¡ Z }kjk Hkjh tkrh gaAS ;fn ,d dk; fod.kZ ds lkis{k lHkh d.kksa dks gVk fn;k tk;s rc
fØLVy dk lw=k gksxk -
(A) XYZ2 (B) X2YZ2 (C) X8Y4Z5 (D*) X5Y4Z8
Sol. When all particle along one body diagonal are removed, these 2 X particles from corner are removed, one Y
particle removed & 2 Z particle removed.
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PAGE NO.- 1
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1 1 15
Hence new arrangement, X particle = 6 6  ; Y particle = 3 ; Z particle = 6
8 2 4
Hence formula = X15 / 4 Y3 Z 6  X 5 / 4 YZ 2 = X5Y4Z8
gy tc dk; fod.kZ ds lkis{k lHkh d.k gVkrs gaS rks dksuksa ij ls 2 X d.k] ,d Y d.k vkSj 2 Z d.k gVasxsA
1 1 15
blfy;s ubZ O;oLFkk] X d.k = 6  6  ; Y d.k = 3 ; Z d.k = 6
8 2 4
blfy;s lw=k = X15 / 4 Y3 Z 6  X 5 / 4 YZ 2 = X5Y4Z8
3. A crystal is made of particles A and B. A forms FCC packing and B occupies all
the octahedral voids. If all the particles along the plane as shown in figure are
removed, then, the formula of the crystal would be :
(A*) AB (B) A5B7
(C) A7B5 (D) None of these.
,d fØLVy A rFkk B d.kksa ls cuk gSA A Qyd dsUnzh; (FCC) ladqyu djrk gS ,oa B
lHkh v"VQydh; fjfDr;ksa esa jgrk gSA ;fn fp=k esa fn[kk;s x;s ry ds lHkh d.k gVk
fy;s tk;as rc fØLVy dk lw=k gksxkA
(A*) AB (B) A5B7
(C) A7B5 (D) buesa ls dksbZ ugha
1 1  1 1  5
Sol. In new arrangement, A particles =   8   6  –   4   2  =
8 2  8 2  2
1   1  5
& B particles =   12  1 –  1   2  =
4   4  2
So, formula is AB
1 1  1 1  5
u;h O;oLFkk esa A d.k =  8  8  2  6  –  8  4  2  2  =
    2
1   1 5 
&B d.k =  4  12  1 – 1  4  2  =
    2
vr% lw=k AB gSA
4. Select the correct statement(s) related to hexagonal close packing of identical spheres in three dimensions:
(A) In one unit cell there are 12 octahedral voids and all are completely inside the unit cell
(B*) In one unit cell there are six octahedral voids and all are completely inside the unit cell.
(C) In one unit cell there are six octahedral void and out of which three are completely inside the unit cell and
other three are from contributions of octahedral voids which are partially inside the unit cell
(D*) Co-ordination number of every sphere is 12 in hcp lattice.
f=kfoe esa xksydksa dh "kV~dks.kh; fufoM+ foU;kl (hcp) ls lEcfU/kr lgh dFku ;k dFkuksa dk p;u dhft,A
(A) ,dd dksf"Bdk esa 12 v"VQydh; fNnz gksrs gSa vkSj ;s lHkh iw.kZr% ,dd dksf"Bdk ds vUnj gksrs gSaA
(B*) ,dd dksf"Bdk esa N% v"VQydh; fNnz gksrs gSa vkSj ;s lHkh iw.kZr% ,dd dksf"Bdk ds vUnj gksrs gSaA
(C) ,dd dksf"Bdk esa N% v"VQydh; fNnz gksrs gSa ftues ls rhu iw.kZr% ,dd dksf"Bdk ds vUnj gksrs gS vkSj 'ks"k rhu mu
v"VQydh; fNnzksa ds ;ksxnku ls curs gS tks vkaf'kd :i ls ,dd dksf"Bdk ds vUnj gksrs gSaA
(D*) hcp tkyd esa izR;sd xksyd dh leUo; la[;k 12 gSA
PAGE NO.- 2
Sol.
hcp = AB AB AB ...............pattern repeat

For calculating voids between two layers A and B.
Octahedral voids = 3 = represented by (•).
So total octahedral voids = 6 = All are completely inside.
hcp = AB AB AB ...............izdkj dh iqujko`fÙk gksrh gSA

A rFkk B ijrksa ds e/; fjfDrdkvksa dh x.kuk ds fy;s
v"VQydh; fjfDrdk;sa 3 ftUgs (•) ds }kjk fu:fir fd;k tkrk gSA
vr% dqy v"VQydh; fjfDrdk;sa 6 gS tks fd iw.kZr% vUnj dh vksj gSA
5. In an isothermal expansion of an ideal gas sample, the correct relation is : (consider all relations with respect
to magnitude only)
[The reversible and irreversible processes are carried out between same initial and final states.]
(A*) W rev > W irrev (B) W irrev > W rev (C) qrev < qirrev (D*) Erev = Eirrev
,d xSlh; uewus ds ,d lerkih; izlkj esa] lgh lEcU/k gS % ¼lHkh laca/kksa dks dsoy ifjek.k ds vk/kkj ij ekurs gq,½ leku
[izkjfEHkd rFkk vfUre voLFkk ds e/; mRØe.kh; rFkk vuqRØe.kh; izØe lEiUu fd;s tkrs gSaA ]
(A*) W rev > W irrev (B) W irrev > W rev (C) qrev < qirrev (D*) Erev = Eirrev
6. An ideal gas undergoes an adiabatic expansion against constant external pressure. Which of the following
are correct :
(A) Internal energy of the gas remains unchanged.
(B*) Temperature of the system decreases.
(C*) E + Pext.V = 0
(D*) Internal energy of the gas decreases.
,d vkn'kZ xSl] fu;r ckg~; nkc ds fo:)] :)ks"eh; izlkj n'kkZrh gSA fuEu esa ls dkSuls dFku lgh gSa %
(A) xSl dh vkUrfjd ÅtkZ vifjofrZr jgrh gSA (B*) ra=k ds rki esa deh gksrh gSA
(C*) E + Pext.V = 0 (D*) xSl dh vkUrfjd ÅtkZ esa deh gksrh gSA
Sol. In adiabatic expansion q = 0 so E = –Pext V or E + V = 0.
g y- :)ks"eh; çlkj esa] q = 0 blfy, E = –Pext V ;k E + V = 0.
7. W hich of the following statement (s) are correct about Boyle temperature :
(A) Temperature at which 1 st virial cofficient becomes Zero
(B*) Temperature at which 2 nd virial cofficient becomes Zero
a
(C*) According to Vander waal's equation, value of T B =
Rb
(D*) T B of a gas depends upon the nature of gas
fuEu esa ls dkSulk@dkSuls dFku ckW;y rki ds lanHkZ esa lR; gS %
(A) rki ftl ij izFke fofj;y xq.kkad 'kwU; gksrk gSA
(B*) rki ftl ij f}rh; fofj;y xq.kkad 'kwU; gksrk gSA
a
(C*) ok.Mj okWy lehdj.k ds vuqlkj T B dk eku = gksrk gSA
Rb
(D*) xSl dk T B, xSl dh izd`fr ij fuHkZj djrk gSA
PAGE NO.- 3
 3 
 
8. In the fluorite structure if the radius ratio is  2 – 1 , how many ions does each cation touch ?
 
(A) 4 anions (B*) 12 cations (C*) 8 anions (D) No cations
 3 
 – 1 ,
¶yqvksjkbV dh lajpuk ftlesa ;fn f=kT;k dk vuqikr  2  gks rks fdrus vk;u izR;sd /kuk;u dks Li'kZ djrs gSa ?
 
(A) 4 _.kk;u (B*) 12 /kuk;u (C*) 8 _.kk;u (D) ,d Hkh /kuk;u ugha
Sol. In flourite structure, cations form the lattice & anions occupy each of tetrahedral voids.
¶yqvksjkbV dh lajpuk esa /kuk;u tkyd esa rFkk _.kk;u izR;sd prq"Qydh; fNnzksa esa Hkjs tkrs gSaA
9. Two mole of an ideal diatomic gas undergoes expansion along a straight line on PV curve from initial state A
(3L, 8 atm) to final state B (7.5L, 2 atm). Calculate the magnitude of q for the above process in L atm.
,d vkn'kZ f}ijek.kfod xSl ds nkss eksy] PV oØ esa ,d ljy js[kk ds vuqfn'k izkjfEHkd voLFkk A (3L, 8 atm) ls vafre
voLFkk B (7.5L, 2 atm) rd izlkfjr gksrs gaSA mijksDr izØe esa q ds ifjek.k dh x.kuk L atm esa djksA
Ans. 0
Sol.
W AB = – Area under curve oØ ds vUrxZr {ks=kQy

1
=–  ( 8+2)  (7.5 – 3)
2
= – 22.5 L atm
5R
UAB = nCVT = 1  [TB – TA]
2
5R  2  7.5  8  3 
=1  = – 22.5 L atm
2  1 R 1 R 
 qAB = U – W = – 22.5 + 22.5 = 0.
10. If ice at 0ºC and water at 52ºC are mixed in 1 : 2 mass ratio, then find the final temperature of mixture (in ºC)
after considerable time.
Given : Latent heat of fusion of ice = 80 cal/g and specific heat capacity of water = 1 cal/g/ºC.
;fn 0ºC ij cQZ rFkk 52ºC ij ty ¼ikuh½ dks nzO;eku vuqikr 1 : 2 esa feyk;k tkrk gS] rc dqN le; i'pkr~ feJ.k
dk vfUre rki (ºC esa) Kkr dhft;sA
fn;k gS : cQZ ds xyu dh xqIr Å"ek = 80 cal/g ty dh fof'k"V Å"ek /kkfjrk = 1 cal/g/ºC.
Ans. 8
Sol. Let final temperature of mixture be TºC.
Heat gained by ice = Heat lost by water
mLƒ + m × 1 × (T – 0) = 2m × 5 × (52 – T)
 80 + 1 (T) = 2 × 1 × (52 – T)
 3T = 104 – 80 = 24
 T = 8ºC
Sol. ekuk fd feJ.k dk vfUre rki TºC.
cQZ }kjk xzg.k Å"ek = ty }kjk eqDr Å"ek
mLƒ + m × 1 × (T – 0) = 2m × 5 × (52 – T)
 80 + 1 (T) = 2 × 1 × (52 – T)
 3T = 104 – 80 = 24
 T = 8ºC
PAGE NO.- 4
11. A metallic element has cubic lattice. Each edge of the unit cell is 3.0Å. The density of the metal is 8.5 g/cc.
How many unit cells will be present in 50 g of the metal?
,d /kkfRod rRo] ?kuh; tkyd j[krk gSA bldh bdkbZ dks"Bhdk dh izR;sd dksj yEckbZ 3.0Å gSA /kkrq dk ?kuRo 8.5
g/cc. gS A /kkrq ds 50 g es a fdruh bdkbZ dks" Bhdk mifLFkr gks xh ?
Ans. 2.178 × 1023
Sol. mass of one unit cell = d  V = 8.5  (3 10–8)3 = 8.5  27  10–24 gm
50
no. of cells in 50 g = = 2.178  1023
8.5  27  10 24
12. Classify the following as intensive properties and extensive properties :

Density, Temperature, Total heat capacity, Boiling point, Molarity, Enthalpy, Volume, Pressure, Entropy.
fuEufyf[kr jkf'k;ksa dks vek=kkRed xq.k/keZ ,oe~ ek=kkRed xq.k/keZ ds vk/kkj ij oxhZd`r dhft, %
?kuRo] rkieku] dqy Å"ek /kkfjrk] DoFkukad fcUnq] eksyjrk] ,UFkSYih] vk;ru] nkc] ,UVªksih
Sol. Only Density, Temperature, Boiling point, Molarity and Pressure are intensive properties (independent of the
size of the system). Rest all are extensive properties.
gy . dsoy ?kuRo] rkieku] DoFkukad fcUnq] eksyjrk rFkk nkc gh vek=kkRed xq.k/keZ n'kkZrs gSa ¼D;ksafd ;g ra=k ds vkdkj @ nzO;eku
ij fuHkZj ugha gSA½ 'ks"k lHkh ek=kkRed xq.k/keZ n'kkZrs gSaA
13. Match the column I with II

Column I Column II
(A) C2H5OH + H2O (p) Raoult’s law is not obeyed
O
(B) || (q) Raoult’s law is obeyed
CHCl3  CH3  C  CH3
(C) n-Hexane + n-Heptane (r) Smixing > O
(s) Hmixing < O
(t) can form minimum boiling azeotropic mixture
LrEHk-I dks LrEHk-II ds lkFk lwesfyr fdft, &

LrEHk I LrEHk II
(A) C2H5OH + H2O (p) jkmYV fu;e dk ikyu ugha djrk gSA
O
(B) || (q) jkmYV fu;e dk ikyu djrk gSA
CHCl3  CH3  C  CH3
(C) n-Hexane + n-Heptane (r) Smixing < O
(s) Hmixing < O
(t) U;wure fLFkjDok/kh feJ.k cuk ldrk gSA
Ans. A  p, t B  p, r, s C  q
Sol. (A) C2H5OH + H2O show positive deviation
O
(B) CHCl3 + || show negative deviation
CH3  C  CH3
(C) n-Hexane + n-Heptane form ideal solution
(A) C2H5OH + H2O _.kkRed foy;u n’kkZrk gSA
O
(B) CHCl3 + || _.kkRed fopyu n'kkZrk gSA
CH3  C  CH3
(C) n-gsDlsu + n-gsIVsu vkn’kZ foy;u cukrk gSA
PAGE NO.- 5
ChemINFO-1.7 Solid State
Daily Self-Study Dosage for mastering Chemistry Crystal defects
Any deviation from the perfectly ordered arragement constitutes a defects or imperfection. Imperfection can be
because of the impurities and temperature. Point defects is defects will be only at certain lattice positions.
Point defects :
1. Stoichiometric : The formula of component remains same after presence of these defects.
2. Impurity defect : In molten containing a little amount of SrCl2 is crystallised some of the sites of Na+ ions are
occupied by Sr2+. Each Sr2+ replaces two Na+ ions.
3. Non-stoichiometric : The formula of compound will get modified because of the presence of these defects.
Non Stoichiometric defects.
1. Metal excess defect :
(a) Metal excess : A compound may have excess metal ion if a negative ion is absent
from its lattice site leaving a vacancy which is occupied by electron to maintain
electrical neutrality.
(b) Metal excess defects due to interstitial cation :

If the extra positive ion is present in an interstitial site. Electrically neutrality is maintained
by the presence of an electron in interstitial site.
2. Metal deficiency Defect : There are many solids which are difficult to prepare in the stoichiometric composition
and contain less amount of the metal as compared to the stoichiometric proportion. A typical example of this type
is FeO which is mostly found with a composition of Fe 0.95O.
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
14. In a crystal some ions are missing from normal
sites. This is an example of 17.
(A) F-centre (B) Interstitial defect
(C) Frenkel defect (D*) Schottky defect
15. When an ion leaves its correct lattice site and – –
occupies interstitial sites in its crystal lathice , it

– –
is called
(A) Crystal defect (B*) Frenkel defect
(C) Schottky defect (D) None of these Which of the following is correct
(A) The defect is known as schottky defect.
16. AgCl is crystallized from molten AgCl containing
(B) The defect is known as Frenkel defect .
a little CdCl2. The solid obtained will have (C) Density of compound in the defect increases.
(A*) cationic vacancies equal to number of Cd2+ (D*) Stoichiometry of compound will change
ions incorporated slightly.
(B) cationic vacancies equal to double the number
of Cd2+ ions
(C) anionic vacancies
(D) neither cationic nor anionic vacancies
PAGE NO.- 6
Daily Self-Study Dosage for mastering Chemistry Crystal defects
iw.kZ :i ls O;ofLFkr Øe ls dksbZ fopyu ,d =kqfV ;k viw.kZrk crkrh gSA viw.kZrk v'kqf);ksa o rkieku gks ldrh gSA fuf'pr tkyd
fLFkfr ij dsoy fcUnq =kqfV gksxhA
fcUnq =kqfV %
1. jl lehdj.kferh – bl =kqfV ds mifLFkr gksus ds i'pkr~ ;kSfxd dk lw=k leku jgrk gSA
2. v'kq) =kqfV : SrCl2 dh FkksMh ek=kk ;qDr xfyr esa Na+ vk;uksa ds dqN LFkyksa dk fØLVydj.k fd;k tkrk gS ftls Sr2+}kjk
?ksjk tkrk gSA çR;sd Sr2+ dks nks Na+ vk;uksa }kjk ?ksjk tkrk gSA
3. v&jl&lehdj.kferh – bl =kqfV dh mifLFkfr ds dkj.k ;kSfxd dk lw=k la'kksf/kr gksxkA
v&jl&lehdj.kferh =kqf V
1. /kkrq vkf/kD; =kqfV –
(a) /kkrq vkf/kD; =kqfV – ,d ;kSfxd /kkrq vkf/kD; vk;u gksrk gS ;fn ,d _.kkRed vk;u ,d
fjfDr;k¡ NksMdj bl ds tkyd LFky ls vuqifLFkr gks tkrk gS ftls oS/kqr mnklhurk cuk;s
j[kus ds fy , e– }kjk xzg.k fd;k tkrk gSA
(b) vUrjkdk'kh /kuk;u ds dkj.k /kkrq vkf/kD; =kqfV : ;fn ,d vUrjkdk'kh LFky esa vfrfjDr /kukRed vk;u
– –
mifLFkr gks rks vUrjkdk'kh LFky esa ,d bysDVªkWu dh mifLFkfr }kjk oS/kqr mnklhurk cuk;s j[kh tkrh gS A
– –
– –
– –
2. /kkrq
viq.kZrk =kqfV % ;gk¡ cgqr ls Bksl gS ftUgs jllehdj.kferh laxBu esa cukuk eqf'dy gS o jl lehdj.kferh lekuqikr
dh rqyuk esa de ek=kk esa /kkrq j[krs gSA bl çdkj dk ,d tfVy mnkgj.k FeO gS tks Fe 0.95O ds laxBu ds lkFk çkIr gksrk gSA
14. ,d fØLVy esa dqN vk;u lkekU; LFky ls vuqifLFkr 17.

jgrs gSA ;g fuEu dk ,d mnkgj.k gSA
(A) F-dsUnz (B) vUrjkdk'kh =kqfV
(C) ÝsUdy =kqfV (D*) 'kkWVdh =kqfV
15. tc ,d vk;u blds lgh tkyd LFky dks NksMrk gS o
blds fØLVy tkyd esa vUrjkdk'kh LFkyksa dks ?ksjrk gS]
rks ;g dgykrk gSA
(A) fØLVy =kqfV (B*) ÝsUdy =kqfV fuEu esa ls dkSulk lR; gSA
(C) 'kkWVdh =kqfV (D) dksbZ ugha (A) =kqfV dks 'kkWVdh =kqfV ds :i esa tkuk tkrk gSA
16. AgCl dks xfyr AgCl ls fØLVyhÑr fd;k tkrk gSa (B) =kqfV dks ÝsUdy dh =kqfV ds :i esa tkuk tkrk gSA
tks FkksMk CdCl2 j[krk gSA çkIr Bksl j[krk gSA (C) =kqfV esa ;kSfxd ds ?kuRo esa o`f) gksrh gSA
(D*) ;kSfxd ds fy, jllehdj.kferh esa FkksMk ifjorZu gksrk
(A*) Cd2+ vk;u dh la[;k /kuk;fud la;kstdrk ds gSA
cjkcjA
(B) Cd2+ vk;u dh nqxuh la[;k ds cjkcj /kuk;fud
la;kstdrkA
(C) _.kk;fud la;kstdrkA
(D) u rks /kuk;fud vksj uk gh _.kk;fudA
PAGE NO.- 7
DPP No. # 11 (JEE-ADVANCED)
Total Marks : 76 Max. Time : 47 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.4 (3 marks, 2 min.) [12, 08]
Multiple choice objective ('–1' negative marking) Q.5 to Q.9 (4 marks, 2 min.) [20, 10]
Integer type Questions ('–1' negative marking) Q.10 to Q.14 (4 marks 3 min.) [20, 15]
Match the Following (no negative marking) Q.15 (8 marks, 6 min.) [08, 06]
ChemINFO : 4 Questions ('–1' negative marking) Q.16 to Q.19 (4 marks, 2 min.) [16, 08]
1. Which of the following is incorrect

fuEu esa ls dkSulk dFku lgh ugha gSA
(A) The defect is known as schottky defect
iznf'kZr =kqfV 'kkWVdh =kqVh dgykrh gSA
(B) Density of compound in the defect decreases
bl =kqfV esa ;kSfxd ds ?kuRo esa deh vkrh gSA
(C) NaCl(s) is example which generally shows this defect
NaCl(s) og mnkgj.k gS] tks lkekU;r% ;g =kqfV n'kkZrk gSA
(D*) Stoichoimetry of compound will change slightly.
;kSfxd dh jllehdj.kfefr FkksM+h lh ifjofrZr gks tkrh gSA
2. In a hypothetical solid C atoms form CCP lattice with A atoms occupying all the
Tetrahedral Voids and B atoms occupying all the octahedral voids.A and B atoms
are of the appropriate size such that there is no distortion in the CCP lattice.Now if
a plane is cut(as shown) then the cross section would like.
,d dkYifud Bksl esa dkcZu ijek.kq CCP tkyd cukrs gSa ftleas A ijek.kq lHkh prq"Qydh;
fjfDrdkvksa ls f?kjs jgrs gS rFkk B ijek.kq lHkh v"VQydh; fjfDrdkvksa ls f?kjk jgrk gSA A rFkk
B ijek.kqvksa dk vkdkj bl izdkj dk gksrk gS fd CCP tkyd esa fdlh Hkh izdkj dh fod`fr
ugha gksrh gSA vc ;fn ,d lery dks foHkkftr fd;k tkrk gS ¼tSlk fd n'kkZ;k x;k gS½ rks
vuqizLFk dkV bl izdkj dk gksuk pkfg,A
(A) (B) (C*) (D)
Sol. Octahedral void, at edge center & body center..
 Tetrahedral voids on body diagonal.
g y- dksj dsUnz o dk; dsUnz ij v"VQydh; fjfDrdkA
 dk; fod.kZ ij prq"Qydh; fjfDrdkA
3. A hypothetical ionic compound AB (mol. wt. = 240 g/mole), having co-ordination number of anion equal to 6,
has a closest anion-anion distance of 4 2 Å. Determine the density of ionic compound AB in gm/cc.
,d dkYifud vk;fud inkFkZ AB (v.kqHkkj = 240 xzke@eksy), ftlesa _.kk;u dh leUo; la[;k (co-ordination number)
6 gS] esa _.kk;u&_.kk;u dh fudVre nwjh 4 2 Å gSA vk;fud inkFkZ AB ds ?kuRo dk eku gm/cc esa Kkr dhft,A
(A) 6.24 (B*) 3.12 (C) 1.56 (D) 0.78
PAGE NO.- 8
ZM 4  240
Sol. d= = = 3.12
NA a 3 6.02  10 23  8 3  10 – 24
4. The correct relationship between critical temperature (T C) and Boyle's temperature (T B) for CO2 gas is :
CO2 xSl ds fy, ØkfUrd rki (TC) o ckW;y rki (TB) ds e/; lgh lEcU/k gSA
(A*) TB > TC (B) TB < TC (C) TB = TC (D) Nothing can be predicted.
vuqeku ugh yxk ldrs gSaA
a 8  a 
Sol. TB = , TC =   T >T
bR 27  bR  B C
5.* The values of PC and TC for two real gases X and Y (both gaseous have same molar mass) are given below.
Gases TC PC
X 100 K 20 atm
Y 200 K 100 atm
Which of the following statements is/are correct for gases X and Y, where symbols have their usual meanings:
nks okLrfod xSlksa X rFkk Y (nksuksa xSlksa dk eksyj nzO;eku leku gS) ds fy, PC rFkk TC ds eku fn;s x;s gSaA
xSlsa TC PC
X 100 K 20 atm
Y 200 K 100 atm
xSlsa X rFkk Y, ds fy, fuEu esa ls dkSulk@dkSuls dFku lR; gS] tgk¡ ladsr viuk lkekU; vFkZ j[krs gSa %
(A*) Gas X has a higher value of vanderwaal constant 'a'
(B*) Gas Y has a lower value of vanderwaal constant 'b'
(C*) Gas X has a lower value of critical density.
(D*) Gas Y shows larger deviation from ideal behaviour than gas X.
(A*) xSl X ds okW.MjokYl fLFkjkad 'a' dk eku vf/kd gSA
(B*) xSl Y ds okW.MjokYl fLFkjkad 'b' dk eku de gSA
(C*) xSl X ds ØkfUrd ?kuRo dk eku de gSA
(D*) xSl X dh rqyuk esa xSl Y vkn'kZ O;ogkj ls vf/kd fopyu n'kkZrh gSA
 2
27R 2  Tc  R  Tc



Sol.  rFkk b = P 
64  Pc  8  c 
T 2  
TC 
 C 
a   P  rFkk b   P 
 C   C
Also, greater value of TC implies it is easier to liquify it. Thus, it will show larger deviation from ideal behaviour.
TC dk eku ftruk vf/kd gksxk nzohdj.k mruk gh vklku gksxk vr% ;g vkn'kZ O;ogkj ls vf/kd fopyu iznf'kZr djsxhA
6.* The correct statement(s) regarding defects solids is (are)

(A*) Schottky defect is usually favoured by small difference in the sizes of cation and anion.
(B*) Schottky defect lowers the density of solids.
(C) Compounds having F-centres are diamagnetic.
(D*) Frenkel defect is a dislocation defect.
Bkslks esa =kqfV;ksa ds lanHkZ esa dkSulk@dkSuls dFku lgh gS@ gSaA
(A*) lkekU;r% 'kkSVdh =kqfV] /kuk;u rFkk _.kk;uksa ds vkdkj esa cgqr de vUrj ds dkj.k gksrh gSA
(B*) 'kkSVdh =kqfV ds dkj.k Bkslksa ds ?kuRo esa deh vkrh gSA
(C) ;kSfxd ftuesa F-dsUnz mifLFkr gksrs gSa] og izfrpqEcdh; gksrs gaSA
(D*) Ýsady =kqfV ,d izdkj dh LFkku ifjorZu (dislocation) =kqfV gSA
PAGE NO.- 9
7.* Which of the following is/are incorrect for Rock salt crystal :
(A*) If all Na+ ions occupied at body centre are removed according to schottky defect then formula of resulting
ionic compound would be Na3Cl4.
(B*) If Na+ ions would be present in alternate tetrahedral voids then formula would be Na 2Cl.
(C) If some Cl– get displaced from the lattice in the presence of Na vapours then colour of compound will
change.
(D) If interionic distance in crystal is 4.2 Å then edge length of unit cell becomes equal to 8.4 Å.
jkWd lkYV fØLVy ds fy,] fuEu esa ls dkSulk@dkSuls dFku lgh ugha gS@ gSaA
(A*) ;fn 'kkWVdh =kqfV }kjk lHkh dk; dsUnzhr Na+ vk;uksa dks i`Fkd dj fn;k tk;s rc] ;kSfxd dk lw=k Na3Cl4 gksxkA
(B*) ;fn ,dkUrfjr prq"Qydh; fjfDr;ksa esa] Na+ vk;u mifLFkr gks rc] ;kSfxd dk lw=k Na2Cl gksxkA
(C) ;fn lksfM;e ok"i dh mifLFkfr esa] tkyd ls dqN Cl– vk;uksa dks foLFkkfir dj fn;k tk;s rc] ;kSfxd dk jax ifjofrZr
gks tk;sxkA
(D) ;fn fØLVy esa vUrjvk;fud nwjh 4.2 Å gS] rc bdkbZ dksf"Bdk dh dksj yEckbZ 8.4 Å ds cjkcj gksxhA
Sol. In schottky defect equal no. of cation and anion removes and formula would remain same.
If Na+ would present in tetrahedral void then as NaCl formula must remain same.
Due to F-centre colour of compound changes
a = 2 (r+ + r–) = 2 × inter ionic distance = 8.4 Å
Sol. 'kkWVdh =kqfV esa] leku la[;k esa] /kuk;u rFkk _.kk;u i`Fkd gksrs gS rFkk lw=k leku cuk jgrk gSA
;fn Na+ vk;u prq"Qydh; fjfDr;ksa esa mifLFkr gS] rc NaCl lw=k leku cuk jgrk gSA
F-dsUnzksa ds dkj.k ;kSfxd dk jax ifjofrZr gksrk gSA
a = 2 (r+ + r–) = 2 × vUrj vkf.od nwjh = 8.4 Å
8.* Choose the correct options.

(A*) In H2O2, the O–O, bond length is greater than expected value.
(B*) In trisilyl amine (SiH3)3 N, the Si–N bond length is lesser than expected value.
(C*) The bond angle in OF2 is lesser than OCl2.
(D*) The Be atom in BeCl2(s) is sp3 hybridised.
lgh fodYi dks pqfu;sA
(A*) H2O2 esa O–O, ca/k yEckbZ izR;kf'kr eku ls vf/kd gksrh gSA
(B*) VªkbZflykbZy,ehu (SiH3)3 N esa Si–N ca/k yEckbZ ekus x, eku ls de gksrh gSA
(C*) OF2 esa ca/k yEckbZ OCl2 dh rqyuk esa de gksrh gSA
(D*) BeCl2(s) esa Be ijek.kq sp3 ladfjr gksrk gSA
Sol. (B) Has partial double bond character due to p-d delocalisation.
(C) OF2=103º (approximate) and OCl2 = 112º (approximate).
(D) Exist in polymeric structure as in solid state.
Sol. (B) p-d foLFkk;hdj.k ds dkj.k vkaf'kd f}ca/k y{k.k j[krk gSA
(C) OF2=103º (yxHkx) rFkk OCl2 = 112º (yxHkx).
(D) Bksl voLFkk esa cgqyhdj.k lajpuk esa ik;h tkrh gSA
9.* Which is(are) true about VSEPR theory ?

(A*) Lone pair-lone pair repulsion is maximum.
(B*) Lone pair and double bond occupy equatorial position in trigonal bipyramidal structure.
(C*) More electronegative atoms occupies axial position in trigonal bipyramidal structure.
(D) Bigger atoms occupy axial positions in trigonal bipyramidal structure.
VSEPR fl)kUr ds fy, dkSulk lR; gS \
(A*) ,dkdh ;qXeµ,dkadh ;qXe izfrd"kZ.k vf/kdre gSA
(B*) f=kdks.kh; f}fijkehfM;y lajpuk esa ,dkdh ;qXe rFkk f}ca/k fo"kqorh; fLFkfr xzg.k djrs gSA
(C*) f=ksdks.kh; f}fijkehfM;y lajpuk esa vf/kd fo|qr_.kh ijek.kq v{kh; fLFkfr xzg.k djrk gSA
(D) f=kdks.kh; f}fijkehfM;y lajpuk esa cM+k ijek.kq v{kh; fLFkfr xzg.k djrk gSA
PAGE NO.- 10
Sol. (A), (B) and (C) are correct statements according to the VSEPR theory but (D) is false. Bigger atoms occupy
equatorial position to minimize the repulsions.
VSEPR fl)kUr ds vuqlkj (A), (B) vkSj (C) lgh okD; gS] ijUrq (D) xyr gSA cMs+ vkdkj ds ijek.kq çfrd"kZ.k dks U;wure
djus ds fy, fo"kqorh; fLFkfr dks ?ksjrs gSaA
10. Lithium forms a b.c.c lattice. If the lattice constant is 3.50 × 10–10 m and the experimental density is 5.30×102
kg m–3 and, calculate the percentage occupancy of Li metal. (Li = 7)
fyfFk;e b.c.c tkyd cukrk gSA ;fn tkyd fu;rkad 3.50 × 10–10 m gS rFkk izk;ksfxd ?kuRo 5.30×102 kg m –3 gSA rc
Li /kkrq }kjk ?ksjk x;k izfr'kr ?kuRo (percentage occupancy) D;k gSA (Li = 7)
Ans. 97.78 %.
zM zM
Sol. We have theoretical density = =
NV N(a 3 )
For a b.c.c lattice: z = 2 and given that a = 3.50 × 10–10 and M = 7× 10–3 kg / mole
2  (7  10 –3 )
dcal = = 5.42 × 102 kg m–3
6.022  10 23  (3.50  10 –10 )3
 exp 5.30  10 2
 percentage occupancy = = × 100 = 97.78 %.
 cal 5.42  10 2
11. In a cubic lattice, the closed packed structure of mixed oxides of the lattice is made up of oxide ions ; one
eighth of the tetrahedral voides are occupied by divalent ions (A2+) while one half of the octahedral voids are
occupied by trivalent ions (B3+). What is the formula of the oxides ?
,d fefJr vkWDlkbM ds ?kuh; tkyd esa fufcM ladqy lajpuk] vkWDlkbM vk;uksa ls cuh gS rFkk leprq"Qydh; fjfDr;ksa
dk 1/8 Hkkx f}la;ksth /kuk;u (A+2) }kjk rFkk v"VQydh; fjfDr;ksa dk vk/kk Hkkx f=kla;ksth /kuk;u (B+3) }kjk ?ksjk tkrk
gSA vkWDlkbM dk lw=k Kkr dhft;sA
Ans. AB2O4
Sol. Let there be 80 O 2– in the crystal.
 Octahedral voids = 80 ; Tetrahedral voids = 160
1
A2+ ions = × 60 = 20
8
1
B3+ ions = × 80 = 40
2
A2+ : B3+ : O2– = 20 : 40 : 80 = 1 : 2 : 4
 Formula is AB2O4.
12. The difference in the number of  and  bonds in trimer of SO3 i.e. S3O9 is : (consider no co-ordinate bond to
be present)
SO3 ds f=kyd (S3O9) esa  rFkk  ca/kksa dh la[;k esa vUrj gS : (blesa milgla;ksth ca/k dks mifLFkr ugha ekurs gq, )
Ans. 6
Sol.  = 12 and  = 6  difference (vUrj) = 12 – 6 = 6
13. In SiO2, each silicon atom is covalently bonded in a tetrahedral manner to four oxygen atoms and each
oxygen atom in turn is covalently bonded to another two silicon atoms giving a three dimensional network
solid. The total number of atoms comprising each ring forming the three dimensional network solid is :
SiO2 esa] izR;sd flfydu ijek.kq pkj vkWDlhtu ijek.kqvksa ls prq"Qydh; :i ls lgla;kstd ca/k }kjk tqM+k gks rk gS rFkk
blh izdkj ls izR;sd vkWDlhtu ijek.kq Hkh vU; nks flfydu ijek.kqvksa ls lgla;kstd ca/k }kjk tqM+k gks rk gS] ftlls ,d
f=kfoeh; tkyd Bksl curk gSA vr% izR;sd oy; ¼ring½ esa fdrus ijek.kq mifLFkr gksrs gSa \
Ans. 8
PAGE NO.- 11
Sol.
14. 2 moles of an ideal gas A (CP = 4R) and 4 moles of an ideal gas B (C V = 3R/2) are taken together in a
container and allowed to expand reversibly and adiabatically from 49 L to 64 L, starting from an initial
temperature of 47ºC. Find the final temperature of gas in ºC.
,d ik=k esa ,d vkn'kZ xSl A (CP = 4R) ds 1 eksy rFkk ,d vU; vkn'kZ xSl B (CV = 3R/2) ds 4 eksy dks ,d lkFk fy;k
x;k gS rFkk nksuks dks] :)ks"eh; rFkk mRØe.kh; :i ls 49 L ls 64 L, rd izlkfjr gksus fn;k tkrk gS ;fn izkjfEHkd rki
47ºC gks] rc xSl dk vfUre rki ºC esa Kkr dhft;s \
Ans. 7
n A C PA  nB CPB 2  4R  4  (5R / 2) 18 R
Sol. min = n C = = 12 R = 1.5
A VA  nB C VB 2  3R  4  (3R / 2)
Now, T1V1 – 1 = T2V2 – 1
 320 (49)0.5 = T2 (64)0.5
320  7
 T2 = = 280 K = 7ºC
8
15. Column - I Column - II

(A) 74% occupancy of space (p) Coordination No. of cation in fluorite structure
(B) Coordination No -8 (q) Cubic close packing
(C) Ca2+ ion in CaF2 (r) Hexagonal close packing
(D) Coordination No. – 12 (s) body centred cubic packing.
dkWye - I dkW y e - II
(A) 74% ladqy {kerk ¼izfr'kr ?kuRo½ (p) ¶yksjkbV lajpuk esa /kuk;u dh leUo; la[;k
(B) leUo; la[;k -8 (q) ?kuh; fufcM ladqyu
(C) CaF2 esa Ca2+ vk;u (r) "kV~dks.kh; fufcM ladqyu
(D) leUo; la[;k – 12 (s) dk; dsUnzh; ?kuh; ladqyu
Ans. (A)  q,r (B)  p,s (C)  q (D)  q,r
PAGE NO.- 12
Daily Self-Study Dosage for mastering Chemistry Magnetic properties
Based on the behaviour of substances when placed in the magnetic field, they are classified into five classes.
Properties Description Alighment Examples Application
Diamagnetic Replled by the All paired e– TiO2, V2O5. Insulator
magnetic field. They
contains paired
electron and
unpaired electrons
are absent. Non
metallic elements
(excepts O2,S).
Paramagnetic At least unpaired O2, Cu 2+, Fe 3+, VO2, Electronic
Attracted by the
electron. CuO appliances
magnetic field due to
th e presence of
permanent magnetic
dipoles
Ferromagnetic P e r m a n e n t Dipoles are aligned in Fe, Ni, CO, CrO

2 CrO2 is used in audio
magnetism even in the same direction
and video tapes
th e absence of
magnetic field.
Antiferromagnetic This arises when the MnO, MnO 2, Mn 2O, –

dipole alignment is FeO, FeO 2 ; NiO,
zero due to equal and Cr2O3, CoO, CO3O4
opposite alignment.
This arises when FeO 3 O4 (Magnetite), –

Ferrimagnetic there is net dipole ferrites like MgFe2O4,
moment. ZnFe2O4
16. Which of the following is correct option 18. Which of the following is correct option.
(A) O2 is show diamagnetic properties. (A) Diamagnetic properties showing material
(B) S is show diamagnetic properties. repelled by magnetic field.
(C*) TiO2 show diamagnetic properties. (B) Paramagnetic showing properties material
(D) VO2 show diamagnetic properties. used for making T.V and washing machine
(C*) Both are correct.
17. Which is the following is correctly match (D) None of these
(A) Diamagnetic  19. Which of the following statement is not true

(A) In ferromagnetic the dipoles are aligned in
(B*) Paramagnetic  same direction.
(B*) In the ferrimagnetic the net dipole moment
(C) Ferromagnetic  is zero
(C) Ferromagnetic properties showing material
used for making audio & video tapes.
(D) Antiferromagnetic 
(D) Antiferromagnetic arises when dipole moment
is zero.
PAGE NO.- 13
Daily Self-Study Dosage for mastering Chemistry Magnetic properties
Based on the behaviour of substances when placed in the magnetic field, they are classified into five classes.
Properties Description Alighment Examples Application
çfrpqEcdh; pq E cdh; {ks = k + } kjk lHkh ;qfXer e– gksA TiO2, V2O5. dqpkyd
fu"df"kZrA os ;qfXer e–
j[krk gS o v;qfXer e–
vuq i fLFkr gks r s gS A
v /k k f R o d rRo
¼flok;sO2,S½
2+ 3+
v uq
pqEcd h; LFkk;h pqEcdh; vk?kq.kZ de ls de v;qfXer e– O2, Cu , Fe , VO2, bySDVªkWfud vuqç ;ksx
CuO
dh mifLFkfr ds gks A
dkj.k pqEcdh; {ks=k
)kjk vkd"kZ.k
y kS
gpq
Ecd h; pqEcdh; {ks=k dh leku fn'kk esa f)/kzqo Fe, Ni, CO, CrO2 JO; o n`'; nksuksa esa
vuqifLFkfr esa Hkh laj sf[kr gksrs gSA CrO2 ç;qDr gksr k gS A
LFkk;h pqEcdRo
çfr y kS
gpq
Ecd h; ;g gksrk gS tc leku –
MnO, MnO 2, Mn 2O,
o foijhr laj s[ k.k ds FeO, FeO 2 ; NiO,
dkj.k tc f}/kzqo vk?kw.kZ Cr2O3, CoO, CO3O4
'kwU; gksrk gSA
FeO 3 O4 (Magnetite), –
y ?kq
y kS
gpq
Ecd h; ;g gksrk gS tc ifj.kkeh
ferrites like MgFe2O4,
f}/kzqo vk?kw.kZ gksA ZnFe2O4
16. fuEu esa ls dkSulk fodYi lgh gS (A) çfrpqEcdh; xq.k/keZ pqEcdh; {ks=k }kjk çfrdf"kZr
(A) O2 çfrpqEcdh; xq.k/keZ n'kkZr k gS A inkFkZ dks n'kkZrk gSA
(B) S çfrpqEcdh; xq.k/keZ n'kkZ rk gS A (B) vuqpq Ecdrk T.V o /kks us dh e'khu dks cukus ds
(C*) TiO2 çfrpq Ecdh; xq.k/keZ n'kkZr k gS A fy, ç;qDr inkFkZ ds xq.k/keZ dks n'kkZrk gSA
(D) VO2 çfrpq Ecdh; xq.k/keZ n'kkZ rk gSA (C*) nks uks a lgh gS
(D) dksb Z ugha
17. fuEu esa ls fdldk lgh feyku gksrk gS \
19. fuEu esa ls dkSu lk lgh ugha gS
(A) çfrpq Ecdh;  (A) ykSg pqEcdh; esa f}/kz qo leku fn'kk esa la js f[kr
gksrs gSaA
(B*) vuq pqEcdh;  (B*) y?kqykSg pq Ecdh; es a ifj.kkeh f}/kzq o vk/kw.kZ 'kwU;
gksrk gSA
(C) ykSg pqEcdh;  (C) ykS g pq E cdh; xq . k/keZ JO; o n` ' ; dks
cukus ds fy, ç;q D r inkFkZ dks n'kkZ r k
(D) çfrykS gpqEcdh; 
gSA
18. fuEu esa ls dkSulk fodYi lgh gS (D) çfrykS gpq Ecdh; çkIr gks rk gS tc f}/kzq o vk?kw.kZ
'kwU; gksrk gSA
PAGE NO.- 14

JP XII Physical&Inorganic Chemistry (7) - Prev Class XI Chap B S - Solution & Colligative Properties - Solid State-1

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PHY./INO.

TARGET : JEE (Main + Advanced) 2016

DATE : 17.05.2015 PART TEST (PT) - 01 (ADVANCED)

This DPP is to be discussed in the week (11-05-2015 to 16-05-2015)

hcp = AB AB AB ...............pattern repeat

hcp = AB AB AB ...............izdkj dh iqujko`fÙk gksrh gSA

W AB = – Area under curve oØ ds vUrxZr {ks=kQy

12. Classify the following as intensive properties and extensive properties :

13. Match the column I with II

LrEHk-I dks LrEHk-II ds lkFk lwesfyr fdft, &

(b) Metal excess defects due to interstitial cation :

15. When an ion leaves its correct lattice site and – –

occupies interstitial sites in its crystal lathice , it

14. ,d fØLVy esa dqN vk;u lkekU; LFky ls vuqifLFkr 17.

1. Which of the following is incorrect

(A) (B) (C*) (D)

Sol. Octahedral void, at edge center & body center..

 Tetrahedral voids on body diagonal.

g y- dksj dsUnz o dk; dsUnz ij v"VQydh; fjfDrdkA

 dk; fod.kZ ij prq"Qydh; fjfDrdkA

6.* The correct statement(s) regarding defects solids is (are)

8.* Choose the correct options.

(D) Exist in polymeric structure as in solid state.

9.* Which is(are) true about VSEPR theory ?

Sol.  = 12 and  = 6  difference (vUrj) = 12 – 6 = 6

15. Column - I Column - II

Ferromagnetic P e r m a n e n t Dipoles are aligned in Fe, Ni, CO, CrO

Antiferromagnetic This arises when the MnO, MnO 2, Mn 2O, –

This arises when FeO 3 O4 (Magnetite), –

(A) Diamagnetic  19. Which of the following statement is not true

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