ORGANIC CHEMISTRY

TARGET : JEE (Main + Advanced) 2016

Course : VIJETA (JP) NO. 34

This DPP is to be discussed in the week (26-10-2015 to 31-10-2015)

DPP No. # 34 (JEE-ADVANCED)
Total Marks : 42 Max. Time : 28 min.
One or more than one choice Objective Q.1 to Q.4 (3 marks, 2 min.) [12, 08]
Comprehension Type(One Option Correct) ('–1' negative marking) Q.5 to Q.7 (3 marks, 2 min.) [09, 06]
Matching List Type (One Option Correct) ('–1' negative marking) Q.8 (3 marks 2 min.) [03, 02]
Single Integer Type Questions Q.9 to Q.10 (3 marks 2 min.) [06, 04]
ChemINFO : 4 Questions ('–1' negative marking) Q.11 to Q.14 (3 marks, 2 min.) [12, 08]

ANSWER KEY
DPP No. # 34 (JEE-ADVANCED)
1. (ACD) 2. (ABC) 3. (D) 4. (ABCD) 5. (C) 6. (B) 7. (C)

8. (A) 9. 6 10. 4 11. (A) 12. (B) 13. (A) 14. (C)

1. Which of the following reagents are involved in the following transformation :

fuEu vUr%ifjorZu esa dkSuls vfHkdeZdksa dk iz;ksx gqvk gS %

 + CH3CH2OH

(A*) LiAlH4 (B) Acetone ,lhVksu (C*) Ethylene glycol ,fFkyhu Xykbdksy (D*) H3O

CH2 – CH2 LiAlH / THF

| | 4 
Sol. +
OH OH
 H3O

CH3CH2OH

2. Correct statement about A, B and C is/are

A, B rFkk C ds fy, lgh dFku gS@gSa&

P2 O 5
LiAH4    A
C   
NH2

Br2/KOH

B
(A*) A can be hydrolysed in basic medium
(B*) B can form alcohol on treatment with aqueous NaNO 2 / HCl
(C*) C produces foul smell on treatment with chloroform in presence of base
(D) Compound A, B and C have same number of C.

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 (A*) A {kkjh; ek/;e esa gkbMªkstuhÑr gks ldrk gSA
(B*) B, tyh; NaNO2 / HCl ds lkFk mipkfjr djkus ij ,YdksgkWy cukrk gSA
(C*) C, {kkj dh mifLFkfr esa DyksjksQkWeZ ds lkFk mipkfjr djkus ij cncqnkj xa/k nsrk gSA
(D) ;kSfxd A, B rFkk C leku dkcZu la[;k j[krs gSA
O

LiAH
CN
Sol. NH2 
4
 P2 O5
 
NH2

(C) (A)

NH2

(B)

3. Which of the following will not react with acetyl chloride ?

buesa esa ls dkSulk ;kSfxd ,flVkby DyksjkbM ds lkFk vfHkfØ;k ugha djsxk ?

(A) H2O (B) (C) (D*)

Sol. Tertiary amine do not react with acetyl chloride.

gy r`rh;d ,ehu ,flVkby DyksjkbM ds lkFk vfHkfØ;k ugha nsrk gSA
4. In which of the following reactions correct major product is mentioned ?
fuEu esa ls dkSulh vfHkfØ;k esa lgh eq[; mRikn n'kkZ;k x;k gS \

(A*) +

H SO4 H SO
(B*) + 2   2
4
fast

(,Lijhu)

1. OH
(C*)  +
2. H

(D*) + H2 SO 4
 

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Comprehension #
Observe the following sequence of reaction

Q R S T

(U)
vuqPNsn #
fuEufyf[kr vfHkfØ;k vuqØe ij fopkj dhft,s %

Q R S T

(U)

5. The product U is :
mRikn U gS %

(A) (B)

(C*) (D)

6. W hich of the following will not be the products when S on reaction with Cl 2 / NaOH or on reaction with
Cl2/NaOH followed by acidification.
Cl2 / NaOH ds lkFk ;kSfxd S dh vfHkfØ;k djkus ij vFkok Cl2/NaOH ds lkFk vfHkfØ;k djkus ds i'pkr vEyhdj.k
djus ij fuEu esa ls dkSulk mRikn izkIr ugha gksxk %

(A) (B*) (C) CHCl3 (D)

7. T on reaction with NaNO 2/ HCl followed by reaction with H 3PO2 will give :
;kSfxd T , NaNO2/ HCl ds lkFk vfHkfØ;k djus ds ckn H3PO 2 ls vfHkd`r gksdj nsxk %

(A) (B) (C*) (D)

Sol.

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(5 to 7)

(P) (Q) (R)

(S) (T)

(U)

8. Match list I with II and then select the correct answer from the codes given below the lists-
List I (Reactants) List II (Product)
(P) Benzaldehyde + NaBH4 (1) Benzoic acid
(Q) Benzoyl chloride + H2 + Pd + BaSO4 +  (2) Benzyl amine
(R) Benzyl alcohol + H2CrO4 (3) Benzyl acohol
(S) Benzamide + LiAlH4 (4) Benzaldehyde

lwph I dks lwph II ds lkFk lqesfyr dhft, rFkk uhps fn;s x;s dwVksa ds vk/kkj ij dkSulk mÙkj lgh gS %
lwph I lwph II
(P) csUtSfYMgkbM + NaBH4 (1) csUtksbd vEy
(Q) csUtkW;y DyksjkbM + H2 + Pd + BaSO4 +  (2) csfUty ,ehu
(R) csfUty ,YdksgkWy + H2CrO4 (3) csfUty ,YdksgkWy
(S) csUtkekbM + LiAlH4 (4) csUtSfYMgkbM
Codes dksM :
P Q R S P Q R S
(A*) 3 4 1 2 (B) 2 3 1 4
(C) 3 4 2 1 (D) 3 1 4 2

9. How many monocarboxylic acids (Including stereo) would give Methylcyclopropane on sodalime
decarboxylation.
fdrus eksuksdkcksZfDlfyd vEy ¼f=kfoe leko;oh lfgr½ lksMkykbe }kjk fodkcksfZ Dlyhdj.k djus ij esfFkylkbDyksikz sius nsrs gSaA
Ans. 6

Sol.

10. Two stereoisomers (cis and trans) of 3, 4-Dibromocyclopentane-1, 1-dicarboxylic acid undergo decarboxylation,
find out the total number of product formed.
3, 4-MkbczksekslkbDyksisUVsu-1, 1-MkbdkcksZfDlfyd vEy ds nks f=kfoe leko;oh (lei{k rFkk foi{k) ds fodkcksZfDlfydj.k ls
dqy fdrus mRikn izkIr gksrs gSA
Ans. 4

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Sol. + opti-

cal active ¼izdkf'kd lfØ;½ optical active ¼izdkf'kd lfØ;½ optical inactive ¼izdkf'kd vlfØ;½

ChemINFO-2.8 Chemistry in Every day life

Daily Self-Study Dosage for mastering Chemistry Antifertility

Antifertility drugs :
Chemical substances which are used to check pregnancy in women are called anti-fertility drugs or birth control
pills or oral contraceptives. It is known that estrogens control the menstrual cycle while progesterone supersses
ovulation.
Birth control pills essentially contain a mixture of sythetic estrogen and progesteron derivatives. Both these
compounds are harmones.
Northindrone is an example of synthetic progestrone derivative which is more potent than progestrone and used in
combination with ethynyl estradiol (novestrol) an estrogen derivative.

Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.

11. The chemical substance which are used to check pregnancy in women are called :
(A*) Antifertility drugs (B) Antimalerial drugs (C) Antihistamines (D) Antiseptics

12. The harmone that supresses ovulation is :

(A) Estrogen (B*) Progestrone (C) Dihydrotestosterone (D) Testostrone

13. Which of the following is an antifertility drug :

(A*) Norethindrone (B) Soframycine (C) Detol (D) Tetracyclin

14. Norethidrone and ethynylestradiol combination is used as :

(A) Analgesic drug (B) Tranquilizers (C*) Antifertility drug (D) Antihistamines

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 ChemINFO-2.8 Chemistry in Every day life
Daily Self-Study Dosage for mastering Chemistry Antifertility

izf rtuu vks"kfèk;k¡ :

,sls jklk;fud inkFkZ tks efgykvksa esa xHkkZoLFkk ds ifj{k.k ds fy, iz;qDr gksrh gS izfrtuu vkS"kfèk;k¡ ;k tUe fujksèkd fiYl ;k vksjy
xHkZfujksèkd dgykrs gSA ;g Kkr gS fd ,LVªkWtu ekfld pØ dks fu;af=kr djrk gS] tcfd izkstsfLVjkWu v.MksRltZu de djrk gSA
tUe fujksèkd fiYl esa la'ysf"kr ,LVªkstu rFkk izkstsfLVªjkWu O;qRiUuksa dk feJ.k gksrk gSA ;s nksuks ;kSfxd gkeksZu gSA ukWjbZfFkuMªkWu
la'ysf"kr izkstsfLVjkWu O;qRiUuksa dk ,d mnkgj.k gS tks izkstsfLVksjkWu ls vfèkd izHkkoh gksrk gS rFkk ,d ,LVªkWtu O;qRiUu ,fFkukby
,LVªkMkbvkWy ¼ukWosLVªkWy½ ds lkFk la;kstu esa iz;qDr gksrk gSA

Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.

11. og jklk;fud inkFkZ tks efgykvksa eas xHkkZoLFkk ds ifj{k.k ds fy, iz;qDr gksrk gS] dgykrk gS&
(A*) izfrtuu vkS"kfèk;k¡ (B) izfreysfj;k vkS"kfèk;k¡ (C) izfrfgLVkfeUl (D) iwfrjksèkh

12. og gkeksZu tks v.MksRltZu dks ?kVk nsrk gSA

(A) bLVªkstu (B*) izkstsfLVjkWu (C) MkbgkbMªksVsLjsfLVjkWu (D) VsLVsfLVjkWu

13. fuEu esa ls dkSulh ,d izfrtuu vkS"kèkh gSA

(A*) ukWjbZfFkuMªkWu (B) lksQjkek;flu (C) MsVkWy (D) VsVªklkbfDyu

14. ukWj,fFkMªkWu rFkk ,fFkfuybLVªkMkbvkWy dk l;kstu fdl :i esa iz;qDr gksrk gSA
(A) fiMkgkjh vkS"kèkh (B) iz'kkUrd (C*) izfrtuu vkS"kèkh (D) izfrfgLVkfeUl

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