x y T t_b x_a x_b h_ab

0 0 383.8 383.8 0 1 4.655495

0.13 0.261 378.2 379.404295 0.1 0.9 3.969161
0.258 0.456 373.2 375.412682 0.2 0.8 3.350846
0.411 0.632 368.2 371.785713 0.3 0.7 2.79308
0.581 0.777 363.2 368.483939 0.4 0.6 2.288689
0.78 0.9 358.2 365.467913 0.5 0.5 1.830753
1 1 353.3 362.698185 0.6 0.4 1.41257
360.135308 0.7 0.3 1.027629
Benzene 357.739834 0.8 0.2 0.669579
T H_l_ben H_v_ben 355.472314 0.9 0.1 0.33221
340 -1.9297 29.64 353.2933 1 0 0.009434
355 0.26143 30.986
370 2.5192 32.365 353.723916 0.98 0.02 0.07311
385 4.8427 33.769 382.886638 0.02 0.98 4.512417

Toluene
T H_l_tou H_v_tou
Enthalpy-C
340 -7.7511 28.003
360 -4.2882 30.342 140.00
380 -0.68946 32.77
110.00
400 3.0496 35.275
80.00

Enthalpy ()kJ/mol)
x_a H_l y_a H_v 50.00
0 0.01 0 33.243665272 20.00
0.1 -0.32 0.2025112 32.8094576251
0.2 -0.55 0.3713376 32.4536360385 -10.00
0.3 -0.69 0.5105784 32.1558531241
-40.00
0.4 -0.75 0.6243328 31.9007491436
0.5 -0.74 0.7167 31.6770302648 -70.00
0.6 -0.68 0.7917792 31.4766982625
-100.00
0.7 -0.56 0.8536696 31.2944168557
0 0.1 0.2 0
0.8 -0.40 0.9064704 31.127002644
0.9 -0.21 0.9542808 30.973030952
1 0.01 1.0012 30.8325488204

x_d H_l H_v

0.98 -0.036182421 30.8595196234

R 2.575611988
hd+(Qc/D) 110.4348602
 Overall Operating Line
mol frac enthalpy
delt_D 0.98 110.4348602
feed 0.4 -0.736965356
delt_R 0.02 -73.5734
hb 2.211241
V1 0.98 30.85951962 ht -2.70244
L1 0.955139774 -0.091204244 hf -0.73697
V2 0.962112413 30.95557743
L2 0.91679628 -0.17279792 delt_D 0.98 110.4349
V3 0.934654407 31.04521314 L1 0.452033 -0.75813
L3 0.8582338 -0.291226971
V4 0.892840464 31.17661956
L4 0.772929663 -0.446849789
V5 0.832312456 31.35667423
L5 0.663441637 -0.608793371 obj x_lef x_right
V6 0.755175449 31.57044405 -6.769E-09 0.95514 0.95514
L6 0.548709102 -0.720440987 -7.9032E-08 0.916796 0.916796
V7 0.674803008 31.7769792 7.94888E-07 0.858234 0.858233
L7 0.452033094 -0.758133158 2.64003E-07 0.77293 0.772929
V8 0.60727772 31.93976055 6.78261E-07 0.663442 0.663441
L8 0.383625263 -0.748704332 3.11999E-07 0.548709 0.548709
V9 0.54754094 32.07702398 4.71768E-07 0.452033 0.452033
L9 0.330294383 -0.718380666 5.83551E-07 0.383625 0.383625
V10 0.4706982 32.24623048 7.45375E-07 0.330294 0.330294
L10 0.269275549 -0.657000995 7.48553E-07 0.269276 0.269275
V11 0.382418361 32.43337075 9.96889E-07 0.207278 0.207277
L11 0.20727814 -0.563364918 3.2092E-07 0.1509 0.150899
V12 0.292394364 32.61994307 2.63346E-07 0.104281 0.104281
L12 0.150899794 -0.448976985 6.73213E-07 0.068507 0.068506
V13 0.210399479 32.78946097 9.2359E-08 0.042529 0.042529
L13 0.10428124 -0.332115386 8.96247E-07 0.024399 0.024398
V14 0.142559499 32.93162998 1.68624E-07 0.012081 0.012081
L14 0.068506532 -0.228122043
V15 0.090505282 33.04303752 18.348
L15 0.042528975 -0.144545467 x y
V16 0.052736973 33.12561679 big 0.014309 33.22197
L16 0.024399103 -0.082097899 small 0.007919 14.83627
V17 0.026390175 33.18427123
L17 0.012080949 -0.037703491 partial step 0.44658

Equilibrium stages 16.44658

Assumption: 100 moles Feed

D + B = 100
0.98D + 0.02B = 0.4(100)
D 39.58333 3.102961
B 60.41667 5.549839
 h_bt y_a y_b H_ab H_bt H_l H_v
0.009465 0 1 33.65436 33.24367 0.0094651 33.24367
-0.79938 0.202511 0.797489 33.24015 32.70009 -0.3225298 32.80946
-1.5281 0.371338 0.628662 32.86617 32.20996 -0.5523098 32.45364
-2.18547 0.510578 0.489422 32.52814 31.76747 -0.6919078 32.15585 R_min
-2.77996 0.624333 0.375667 32.22189 31.36703 -0.7525005 31.90075 R_actual
-3.31971 0.7167 0.2833 31.94337 31.00323 -0.7444779 31.67703
-3.81261 0.791779 0.208221 31.68863 30.67079 -0.6775031 31.4767 m_min
-4.26635 0.85367 0.14633 31.4538 30.36461 -0.5605638 31.29442
-4.6884 0.90647 0.09353 31.23507 30.07965 -0.4020157 31.127
-5.08607 0.954281 0.045719 31.0287 29.81102 -0.2096187 30.97303
-5.46656 1.0012 -0.0012 30.83102 29.55387 0.0094336 30.83255

-5.3915 0.991691 0.008309 30.87003 29.60461 -0.0361824 30.85952

-0.15915 0.043394 0.956606 33.56809 33.13039 -0.0657193 33.14938

Enthalpy-Concentration Graph
140.00

110.00

80.00

50.00

20.00

-10.00

-40.00

-70.00

-100.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Composition
 delt_R 0.02 -73.5734
L8 0.024399 -0.0821 0.98 110.4349
0.95514 -0.0912
0.98 110.4349
0.916796 -0.1728
0.98 110.4349
y obj x y_curve y_line 0.858234 -0.29123
0.98 -1.27E-08 0.962112 30.95558 30.955577 0.98 110.4349
0.962112 -5.71E-08 0.934654 31.04521 31.045213 0.77293 -0.44685
0.934654 -1.09E-07 0.89284 31.17662 31.176619 0.98 110.4349
0.89284 -6.6E-08 0.832312 31.35667 31.356674 0.663442 -0.60879
0.832312 -1.88E-08 0.755175 31.57044 31.570444 0.98 110.4349
0.755175 -1.8E-08 0.674803 31.77698 31.776979 0.548709 -0.72044
0.674803 -3.12E-09 0.607278 31.93976 31.939761 0.98 110.4349
0.607278 -7.28E-10 0.547541 32.07702 32.077024 0.452033 -0.75813
0.547541 -4.84E-09 0.470698 32.24623 32.24623
0.470698 -2.48E-07 0.382418 32.43337 32.43337
0.382418 -2E-07 0.292394 32.61994 32.619943
0.292394 2.82E-08 0.210399 32.78946 32.789461
0.210399 1.73E-07 0.142559 32.93163 32.93163
0.142559 1.67E-08 0.090505 33.04304 33.043038
0.090505 1.76E-09 0.052737 33.12562 33.1256168
0.052737 1.03E-09 0.02639 33.18427 33.184271
0.02639

hyp
33.22198 Min. Reflux Ratio 1.287806
14.83627 Feed condi & q-val subcooled 1.345621
No. of stages 16.44658
Reboiler duty 407.95577
Condenser duty 342.78736
Minimum Enriching line Stripping line 45-degree line
0.476122 0.69637 0.98 0.98 0.451122 0.599035 0
0.98 0.98 0.451122 0.599035 0.02 0.02 1

1.287806 obj x ycurve yline

2.575612 Tb 368.4839 -5.57E-08 0.476122 0.69637 0.69637

0.5629 0.4 0.4 -1E-06 0.451122 0.599035 0.599036

0.476122 0.69637

Obj x_lef x_right y y-x Curves for B

0.98 0.98 1
1 1.67E-08 0.95514 0.95514 0.98 0.9

Mole fraction of Benzene in Vapor

0.95514 0.962087
0.8
2 -1.25E-08 0.916743 0.916743 0.962087
0.916743 0.93443 0.7
3 -6.12E-08 0.857756 0.857756 0.93443 0.6
0.857756 0.891942
0.5
4 -1.38E-07 0.771172 0.771172 0.891942
0.4
0.771172 0.829575
5 -4.86E-07 0.658913 0.658913 0.829575 0.3
0.658913 0.748715 0.2
6 1.73E-07 0.540182 0.540182 0.748715
0.1
0.540182 0.663193
7 -8.36E-07 0.439548 0.439549 0.663193 0
0 0.1 0.2 0.3 0.4
0.439549 0.583458
8 -5.91E-07 0.361647 0.361648 0.583458 Mole fraction
0.361648 0.478829
9 3.5E-07 0.275387 0.275387 0.478829
0.275387 0.362972
10 6.87E-07 0.194575 0.194574 0.362972
0.194574 0.254432
11 -5.8E-08 0.128815 0.128815 0.254432
0.128815 0.166111
12 2.26E-07 0.080666 0.080666 0.166111
0.080666 0.101442
13 5.97E-07 0.047889 0.047889 0.101442
0.047889 0.057419
14 9.29E-07 0.025796 0.025795 0.057419
0.025795 0.033905
15 3.43E-07 0.015065 0.015064 0.033905
0.015064 0.019801
 0.02 -73.5734
0.547541 32.07702
0.02 -73.5734
0.470698 32.24623
0.02 -73.5734
0.382418 32.43337
0.02 -73.5734
0.292394 32.61994
0.02 -73.5734
0.210399 32.78946
0.02 -73.5734
0.142559 32.93163
0.02 -73.5734
0.090505 33.04304
0.02 -73.5734
0.052737 33.12562
0.02 -73.5734
0.02639 33.18427
45-degree line Tf 298.15
0 Tb 368.4839
1 Hib -7.73062
Hf 32.24365
Hmb 2.32
Hit -14.258
Hf 30.07639
Hmt -2.72635
q 1.345621

y-x Curves for Benzene-Toluene

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Mole fraction of Benzene in Vapor

 0 0
1 1

0.4 0.4
0.47601 0.69637
x y T t_b x_a x_b h_ab
0 0 383.8 383.8 0 1 4.655495
0.13 0.261 378.2 379.404295 0.1 0.9 3.969161
0.258 0.456 373.2 375.412682 0.2 0.8 3.350846
0.411 0.632 368.2 371.785713 0.3 0.7 2.79308
0.581 0.777 363.2 368.483939 0.4 0.6 2.288689
0.78 0.9 358.2 365.467913 0.5 0.5 1.830753
1 1 353.3 362.698185 0.6 0.4 1.41257
360.135308 0.7 0.3 1.027629
Benzene 357.739834 0.8 0.2 0.669579
T H_l_ben H_v_ben 355.472314 0.9 0.1 0.33221
340 -1.9297 29.64 353.2933 1 0 0.009434
355 0.26143 30.986
370 2.5192 32.365 353.723916 0.98 0.02 0.07311
385 4.8427 33.769 368.483939 0.4 0.6 2.288689
382.886638 0.02 0.98 4.512417
Toluene
T H_l_tou H_v_tou
340 -7.7511 28.003
360 -4.2882 30.342 Enthalpy-Concentr
380 -0.68946 32.77
140.00
400 3.0496 35.275
110.00

80.00

Enthalpy ()kJ/mol)
x_a H_l y_a H_v
50.00
0 0.01 0 33.243665272
0.1 -0.32 0.2025112 32.8094576251 20.00
0.2 -0.55 0.3713376 32.4536360385 -10.00
0.3 -0.69 0.5105784 32.1558531241
-40.00
0.4 -0.75 0.6243328 31.9007491436
0.5 -0.74 0.7167 31.6770302648 -70.00
0.6 -0.68 0.7917792 31.4766982625 -100.00
0.7 -0.56 0.8536696 31.2944168557 0 0.1 0.2 0.3 0.4
0.8 -0.40 0.9064704 31.127002644
Compo
0.9 -0.21 0.9542808 30.973030952
1 0.01 1.0012 30.8325488204

x_d H_l H_v

0.98 -0.036182421 30.8595196234

R 3.170630817
hd+(Qc/D) 128.8183846
 Overall Operating Line
mol frac enthalpy
delt_D 0.98 128.8183846
feed 0.4 -0.752500486
delt_R 0.02 -85.644

V1 0.98 30.85951962
L1 0.955139774 -0.091204244
V2 0.961113691 30.95888584
L2 0.914652788 -0.177272204 delt_D 0.98 128.8184
V3 0.930475536 31.05861791 L1 0.494919 -0.74839
L3 0.849438733 -0.308268805
V4 0.881307493 31.2118268
L4 0.750680519 -0.483525153
V5 0.807285393 31.42785764 L
L5 0.623390328 -0.655217505 obj x_lef x_right
V6 0.712457982 31.6820997 -6.769E-09 0.95514 0.95514
L6 0.494919107 -0.748385097 -6.9113E-08 0.914653 0.914653
V7 0.617208442 31.91636428 1.05278E-07 0.849439 0.849439
L7 0.39309153 -0.751928547 2.27264E-07 0.750681 0.75068
V8 0.537464341 32.09964184 3.54528E-07 0.62339 0.62339
L8 0.321847495 -0.711625052 1.99088E-07 0.494919 0.494919
V9 0.439212748 32.31368856 1.67475E-07 0.393092 0.393091
L9 0.24628391 -0.626071318 1.03873E-07 0.321847 0.321847
V10 0.334542277 32.53287937 1.0785E-07 0.246284 0.246284
L10 0.17654247 -0.504571554 1.38351E-07 0.176542 0.176542
V11 0.237655981 32.73295804 5.86887E-08 0.119336 0.119336
L11 0.119336482 -0.372125217 1.52639E-08 0.076496 0.076496
V12 0.158093248 32.89882447 4.74734E-09 0.046446 0.046446
L12 0.07649621 -0.252451137 2.02643E-09 0.026292 0.026292
V13 0.098508595 33.02574178 4.71665E-09 0.013168 0.013168
L13 0.046445991 -0.15758965
V14 0.056738372 33.11678775
L14 0.026292096 -0.088778587
V15 0.028739355 33.17900324
L15 0.013168452 -0.041687384
14.533
x y
big 0.015571 33.22069
small 0.02 18.646

partial step 0.561277

Equilibrium stages 14.56128

Assumption: 100 moles Feed
D + B = 100
0.98D + 0.02B = 0.4(100)
D 39.58333 3.102961
B 60.41667 5.549839
 h_bt y_a y_b H_ab H_bt H_l H_v
0.009465 0 1 33.65436 33.24367 0.00946514 33.24367
-0.79938 0.202511 0.797489 33.24015 32.70009 -0.32252979 32.80946
-1.5281 0.371338 0.628662 32.86617 32.20996 -0.55230984 32.45364
-2.18547 0.510578 0.489422 32.52814 31.76747 -0.69190779 32.15585
-2.77996 0.624333 0.375667 32.22189 31.36703 -0.75250049 31.90075
-3.31971 0.7167 0.2833 31.94337 31.00323 -0.74447792 31.67703
-3.81261 0.791779 0.208221 31.68863 30.67079 -0.67750315 31.4767
-4.26635 0.85367 0.14633 31.4538 30.36461 -0.56056382 31.29442
-4.6884 0.90647 0.09353 31.23507 30.07965 -0.40201568 31.127
-5.08607 0.954281 0.045719 31.0287 29.81102 -0.20961871 30.97303
-5.46656 1.0012 -0.0012 30.83102 29.55387 0.00943359 30.83255

-5.3915 0.991691 0.008309 30.87003 29.60461 -0.03618242 30.85952

-2.77996 0.624333 0.375667 32.22189 31.36703 -0.75250049 31.90075
-0.15915 0.043394 0.956606 33.56809 33.13039 -0.06571932 33.14938

Enthalpy-Concentration Graph
0

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Composition
 delt_R 0.02 -85.644
L7 0.026292 -0.08878 0.98 128.8184
0.95514 -0.0912
0.98 128.8184
0.914653 -0.17727
V 0.98 128.8184
y obj x y_curve y_line 0.849439 -0.30827
0.98 4.54E-05 0.961114 30.95889 30.95893128 0.98 128.8184
0.961114 9.03E-05 0.930476 31.05862 31.0587082 0.750681 -0.48353
0.930476 9.68E-05 0.881307 31.21183 31.2119236 0.98 128.8184
0.881307 1.1E-05 0.807285 31.42786 31.4278686 0.62339 -0.65522
0.807285 1.99E-05 0.712458 31.6821 31.6821196 0.98 128.8184
0.712458 1.05E-05 0.617208 31.91636 31.91637477 0.494919 -0.74839
0.617208 -5.73E-06 0.537464 32.09964 32.0996361
0.537464 -5.44E-06 0.439213 32.31369 32.3136831
0.439213 -3E-07 0.334542 32.53288 32.5328791
0.334542 8.4E-08 0.237656 32.73296 32.7329581
0.237656 2.07E-07 0.158093 32.89882 32.8988247
0.158093 1.57E-08 0.098509 33.02574 33.0257418
0.098509 8.69E-09 0.056738 33.11679 33.1167878
0.056738 2.54E-09 0.028739 33.179 33.17900324
0.028739

hyp Min. Reflux Ratio 1.58531541

33.22069 Feed condi & q-val Sat'd liquid 1
18.64601 No. of stages 14.5612771
Reboiler duty 474.945658
Condenser duty 399.830728
Minimum Enriching line Stripping line 45-degree line
0.4 0.624333 0.98 0.98 0.4 0.539068 0
0.98 0.98 0.4 0.539068 0.02 0.02 1

R_min 1.585315 q 1 x_int 0.4

R_actual 3.170631 Tb 368.4839 y_int 0.624333
m_min 0.6132

Obj x_lef x_right y

y-x Curves for B
0.98 0.98
1 1.67E-08 0.95514 0.95514 0.98 1

Mole fraction of Benzene in Vapor

0.95514 0.961097 0.9
2 -5.08E-09 0.914618 0.914618 0.961097 0.8
0.914618 0.930293 0.7
3 -4.75E-10 0.849054 0.849054 0.930293 0.6
0.849054 0.880451 0.5
4 -1.51E-08 0.749053 0.749053 0.880451 0.4
0.749053 0.80443 0.3
5 -5.81E-08 0.619002 0.619003 0.80443 0.2
0.619003 0.705566 0.1
6 -3.94E-08 0.486776 0.486776 0.705566
0
0.486776 0.605047 0 0.1 0.2 0.3 0
7 1.5E-07 0.381523 0.381523 0.605047
0.381523 0.51386 Mole fraction
8 -5.18E-08 0.302615 0.302615 0.51386
0.302615 0.406073
9 -2.17E-07 0.223162 0.223163 0.406073
0.223163 0.29754
10 -1.11E-07 0.153964 0.153964 0.29754
0.153964 0.203015
11 1.86E-07 0.100273 0.100273 0.203015
0.100273 0.129672
12 -1.69E-07 0.061962 0.061962 0.129672
0.061962 0.07734
13 2.43E-07 0.036144 0.036144 0.07734
0.036144 0.042072
14 -1.58E-07 0.01938 0.019381 0.042072
0.019381 0.019174
 0.02 -85.644
0.537464 32.09964
0.02 -85.644
0.439213 32.31369
0.02 -85.644
0.334542 32.53288
0.02 -85.644
0.237656 32.73296
0.02 -85.644
0.158093 32.89882
0.02 -85.644
0.098509 33.02574
0.02 -85.644
0.056738 33.11679
0.02 -85.644
0.028739 33.179
 45-degree line q-line
0 0.4 0.4
1 0.4 0.624333

y-x Curves for Benzene-Toluene

1
Mole fraction of Benzene in Vapor

0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Mole fraction of Benzene in Vapor

 0 0
1 1

0.4 0.4
0.47601 0.624333
x y T t_b x_a x_b h_ab
0 0 383.8 383.8 0 1 4.655495
0.13 0.261 378.2 379.404295 0.1 0.9 3.969161
0.258 0.456 373.2 375.412682 0.2 0.8 3.350846
0.411 0.632 368.2 371.785713 0.3 0.7 2.79308
0.581 0.777 363.2 368.483939 0.4 0.6 2.288689
0.78 0.9 358.2 365.467913 0.5 0.5 1.830753
1 1 353.3 362.698185 0.6 0.4 1.41257
360.135308 0.7 0.3 1.027629
Benzene 357.739834 0.8 0.2 0.669579
T H_l_ben H_v_ben 355.472314 0.9 0.1 0.33221
340 -1.9297 29.64 353.2933 1 0 0.009434
355 0.26143 30.986
370 2.5192 32.365 353.723916 0.98 0.02 0.07311
385 4.8427 33.769 368.483939 0.4 0.6 2.288689
373.15 0.4 0.6 3.00243
Toluene 382.886638 0.02 0.98 4.512417
T H_l_tou H_v_tou
340 -7.7511 28.003
360 -4.2882 30.342
380 -0.68946 32.77 Enthalpy-Con
400 3.0496 35.275
140.00

x_a H_l y_a H_v 110.00

0 0.01 0 33.243665272
80.00
0.1 -0.32 0.2025112 32.8094576251
Enthalpy ()kJ/mol)

0.2 -0.55 0.3713376 32.4536360385 50.00

0.3 -0.69 0.5105784 32.1558531241
0.4 -0.75 0.6243328 31.9007491436 20.00
0.5 -0.74 0.7167 31.6770302648
-10.00
0.6 -0.68 0.7917792 31.4766982625
0.7 -0.56 0.8536696 31.2944168557 -40.00
0.8 -0.40 0.9064704 31.127002644
0.9 -0.21 0.9542808 30.973030952 -70.00
1 0.01 1.0012 30.8325488204
-100.00
0 0.1 0.2 0.3

C
x_d H_l H_v
0.98 -0.036182421 30.8595196234

R 3.954153022
hd+(Qc/D) 153.0258532
 Overall Operating Line
mol frac enthalpy
delt_D 0.98 153.0258532
feed 0.4 10.06292683
delt_R 0.02 -83.6022

V1 0.98 30.85951962
L1 0.955139774 -0.091204244
V2 0.96018282 30.96196616
L2 0.912655185 -0.181433118 delt_D 0.98 153.0259
V3 0.926361244 31.07175546 L1 0.444585 -0.75863
L3 0.8408291 -0.324745291
V4 0.869468726 31.24751765
L4 0.728507237 -0.518264281
V5 0.780945823 31.50084825
L5 0.584267631 -0.693022845 obj x_lef x_right
V6 0.667912729 31.7940056 -6.769E-09 0.95514 0.95514
L6 0.444585106 -0.758631925 -5.8129E-08 0.912655 0.912655
V7 0.558810508 32.05155562 3.72075E-08 0.840829 0.840829
L7 0.339915547 -0.72541303 1.1214E-07 0.728507 0.728507
V8 0.467215053 32.25373961 3.18363E-07 0.584268 0.584267
L8 0.266678626 -0.653726673 3.38942E-08 0.444585 0.444585
V9 0.36518261 32.46930455 2.42294E-07 0.339916 0.339915
L9 0.196001849 -0.542772519 4.01789E-08 0.266679 0.266679
V10 0.266389669 32.67359508 5.38797E-08 0.196002 0.196002
L10 0.135673533 -0.413079435 3.65849E-08 0.135674 0.135673
V11 0.181924734 32.8488105 2.10213E-08 0.088982 0.088982
L11 0.088982354 -0.289194772 1.40883E-08 0.055372 0.055372
V12 0.116541364 32.987005 4.14014E-09 0.032367 0.032367
L12 0.055372362 -0.186726717 1.1898E-08 0.017148 0.017148
V13 0.069484689 33.08879379
L13 0.032367124 -0.109965058
V14 0.037296126 33.1598793
L14 0.017147612 -0.05615761

0.4 350 0.26126146 373.15 n_vap/n_liq

0.4 373.15 0.46276747 373.15 0.452416

Isobaric V
385
obj x_lef x_right y
Isobaric V
8.4803E-08 0.261261457 0.2612613719 373.15
1.94673E-07 0.462767468 0.4627672729 373.15 385

380

375

Temperature (K)
370

365

360

355

350
0 0.1 0.2

4.647
x y
big 0.020149 33.21604
small 0.02 28.51288

partial step 0.858407

Equilibrium stages 13.85841

Assumption: 100 moles Feed

D + B = 100
0.98D + 0.02B = 0.4(100)
D 39.58333 3.102961
B 60.41667 5.549839
 h_bt y_a y_b H_ab H_bt H_l H_v
0.009465 0 1 33.65436 33.24367 0.009465144 33.24367
-0.79938 0.202511 0.797489 33.24015 32.70009 -0.322529793 32.80946
-1.5281 0.371338 0.628662 32.86617 32.20996 -0.552309843 32.45364
-2.18547 0.510578 0.489422 32.52814 31.76747 -0.691907787 32.15585 R_min
-2.77996 0.624333 0.375667 32.22189 31.36703 -0.752500486 31.90075 R_actual
-3.31971 0.7167 0.2833 31.94337 31.00323 -0.744477915 31.67703 m_min
-3.81261 0.791779 0.208221 31.68863 30.67079 -0.677503146 31.4767
-4.26635 0.85367 0.14633 31.4538 30.36461 -0.560563821 31.29442
-4.6884 0.90647 0.09353 31.23507 30.07965 -0.402015683 31.127
-5.08607 0.954281 0.045719 31.0287 29.81102 -0.209618709 30.97303
-5.46656 1.0012 -0.0012 30.83102 29.55387 0.009433593 30.83255

-5.3915 0.991691 0.008309 30.87003 29.60461 -0.036182421 30.85952

-2.77996 0.624333 0.375667 32.22189 31.36703 -0.752500486 31.90075
-1.93873 0.624333 0.375667 32.65509 31.93359 0.037731214 32.38405
-0.15915 0.043394 0.956606 33.56809 33.13039 -0.065719325 33.14938

Enthalpy-Concentration Graph

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Composition
 delt_R 0.02 -83.6022
L7 0.032367 -0.10997 0.98 153.0259
0.95514 -0.0912
0.98 153.0259
0.912655 -0.18143
0.98 153.0259
y obj x y_curve y_line 0.840829 -0.32475
0.98 3.78E-05 0.960183 30.96197 30.96200396 0.98 153.0259
0.960183 7.49E-05 0.926361 31.07176 31.071830358 0.728507 -0.51826
0.926361 7.11E-05 0.869469 31.24752 31.24758879 0.98 153.0259
0.869469 5.13E-06 0.780946 31.50085 31.50085338 0.584268 -0.69302
0.780946 1.5E-05 0.667913 31.79401 31.794020568 0.98 153.0259
0.667913 -1.62E-06 0.558811 32.05156 32.051554 0.444585 -0.75863
0.558811 -8.1E-06 0.467215 32.25374 32.25373151
0.467215 -2.77E-07 0.365183 32.4693 32.46930427
0.365183 1.73E-05 0.26639 32.6736 32.67361242
0.26639 1.67E-07 0.181925 32.84881 32.84881067
0.181925 8.16E-08 0.116541 32.987 32.98700508
0.116541 2.03E-08 0.069485 33.08879 33.08879381
0.069485 4.65E-09 0.037296 33.15988 33.1598793
0.037296

n_vap/n_liq %vap %liq

0.311492 0.688508

Isobaric Vapor-Liquid Equilibrium Curve

385
 Isobaric Vapor-Liquid Equilibrium Curve
385

380

375

370

365

360

355

350
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Mole Fraction Benzene

hyp Min. Reflux Ratio 1.977076511

33.21604 Feed condi & q-val sat'd mixture 0.688508
28.51289 No. of stages 13.85840707
Reboiler duty 463.6139975
Condenser duty 474.9455654
Minimum Enriching line Stripping line 45-degree line
0.332221 0.549817 0.98 0.98 0.361086 0.486014 0
0.98 0.98 0.361086 0.486014 0.02 0.02 1

1.977077 q 0.688508 obj x ycurve yline

3.954153 2.62E-07 0.332221 0.549817 0.549816
0.6641
-2.71E-07 0.361086 0.486014 0.486014

y-x Curves for Benzen

Obj x_lef
x_right y
0.98 0.98 1
1 1.67E-08 0.95514 0.95514 0.98 0.9
0.95514 0.960097

Mole fraction of Benzene in Vapor

0.8
2 -3E-09 0.912472 0.912472 0.960097
0.912472 0.926044 0.7
3 -1.9E-09 0.840166 0.840166 0.926044 0.6
0.840166 0.868337
0.5
4 2.01E-08 0.726423 0.726423 0.868337
0.726423 0.777558 0.4
5 5.78E-08 0.579445 0.579445 0.777558 0.3
0.579445 0.660255
0.2
6 1.29E-07 0.436443 0.436443 0.660255
0.436443 0.546125 0.1
7 -1.84E-07 0.329097 0.329097 0.546125 0
0.329097 0.442346 0 0.1 0.2 0.3 0.4 0.5
8 1.22E-07 0.248525 0.248525 0.442346
Mole fraction of Ben
0.248525 0.33226
9 -1E-08 0.175121 0.175121 0.33226
0.175121 0.231968
10 2.18E-07 0.11616 0.11616 0.231968
0.11616 0.15141
11 2.7E-07 0.073045 0.073044 0.15141
0.073044 0.0925
12 1.65E-07 0.043503 0.043503 0.0925
0.043503 0.052138
13 3.86E-07 0.024116 0.024115 0.052138
0.024115 0.025649
14 4.27E-07 0.011738 0.011738 0.025649
0.011738 0.008737
 0.02 -83.6022
0.467215 32.25374
0.02 -83.6022
0.365183 32.4693
0.02 -83.6022
0.26639 32.6736
0.02 -83.6022
0.181925 32.84881
0.02 -83.6022
0.116541 32.987
0.02 -83.6022
0.069485 33.08879
0.02 -83.6022
0.037296 33.15988
45-degree line q-line
0 0.332221 0.549817
1 0.4 0.4

y-x Curves for Benzene-Toluene

0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Mole fraction of Benzene in Vapor

 0 0
1 1

0.4 0.4
0.47601 0.549817
= -0.908x3 + 0.7744x2 - 2.2831x + 33.244 H_v
= -1.5648x3 + 5.3629x2 - 3.798x + 0.0074 hl
0.5629x + 0.4284 min = 0.6132x + 0.379
= 0.7203x + 0.2741 en = 0.7602x + 0.235
1.3431x - 0.0069 strip = 1.366x - 0.0073
0.6832x3 - 1.8892x2 + 2.2072x equil curve
-6.5747x3 + 22.177x2 - 46.109x + 383.8 T_b graph = -11.518x3 + 3.1097x2 - 22.051x + 383.83
0.0001471*x^2 + 0.04387*x - 33.85 h_l ben graph
0.00006444*x^2 + 0.04505*x + 6.872 H_v ben graph
0.0001726*x^2 + 0.05228*x - 45.48 h_l tol graph
0.0001038*x^2 + 0.04444*x + 0.8976 H_v tol graph
 0.0032 0.111
= 0.6641x + 0.3292 0.0049 0.148
y = 0.7981x + 0.1978 0.0062 0.143
= 1.3663x - 0.0073 0.008 0.166
0.0095 0.2
7x2 - 22.051x + 383.83