S16.1 S16.

2 S28 R8
Vapour Fraction 0 0 0 0
Temperature [C] 180 80 195.60155 180
Pressure [kPa] 3000 3000 100 100
Mass Flow [kg/h] 64116.82 64116.8194282 50423.594 1404.32479

Ethylene 3.42E+01 34.1527900312 5.37E-08 0

Oxygen 2.24E-01 0.2240475786 9.34E-13 0
Ethylene oxide 3.40E+02 339.995484416 2.20E-04 0
Cabon dioxde 2.39E+03 2389.35096323 1.58E-06 0
Water 10823.32 10823.3196424 58.553365 0
Ethylene carbonate 7.03E+02 703.030016523 703.00429 703.004292
Ethylene glycol 49125.43 49125.425984 48960.715 0
Potassium carbonate 0.00E+00 0 0 0
Potassium bicarbonate 0 0 0 0
Potassium hydoxide 701.3205 701.3205 701.3205 701.3205
Heat Flow [kJ/h] -5.4E+08 -557743432.766 -350180871 -1.02E+07
P1.1 P1.2
0 0
210 25
100 100
49019.26886 49019.269 703

0 0
0 0
0 0
0 0
58.55336517 58.553365
0 0
48960.72 48960.72
0 0
0 0
0 0
-2.97E+08-362980846
Name S1 S2 S3.1 S3.2 S3.3 S5.1
Vapour Fraction 0 0 0 1 1 1
Temperature / oC 24.9 24.9 24.9 -37.6 230.0 230.0
Pressure / kPa 100000 100000 100000 3000 3000 3000
Mass Flow / kg h-1 29892 26892 56784 56784 56784 332737
Component flow rate
Ethylene / kg h-1 29892 0 29892 29892 29892 154490
Oxygen / kg h-1 0 26892 26892 26892 26892 24559
Ethylene oxide/ kg h-1 0 0 0 0 0 41647
Carbon dioxide / kg h-1 0 0 0 0 0 43305
Water / kg h-1 0 0 0 0 0 68735
Ethylene Carbonate / kg h-1 0 0 0 0 0 0
Ethylene Glycol / kg h-1 0 0 0 0 0 0
Potassium Carbonate / kg h-1 0 0 0 0 0 0
Potassium Bicarbonate / kg h-1 0 0 0 0 0 0
Potassium Hydroxide / kg h-1 0 0 0 0 0 0
Heat Flow [kJ/h] 49726679 -3676.11 49723003 49723003 72427079 -9.6E+08

Name S9.1 R1.1 S18 PRG-3 R2 S19.1

Vapour Fraction 1 0 1 1 1 1
Temperature / oC 85.40321 99.99821 26.3551 26.3551 26.3551 26.3551
Pressure / kPa 101.325 101.325 3000 3000 3000 3000
Mass Flow / kg h-1 59622.13 91055.74 223551.4 2258.095 167663.6 55887.86
Component flow rate
Ethylene / kg h-1 159.9584 1.61E-26 152786.8 1543.301 114590.1 38196.69
Oxygen / kg h-1 23.9162 1.22E-25 24290.2 245.3555 18217.65 6072.549
Ethylene oxide/ kg h-1 36900.96 2.02E-08 4698.402 47.45861 3523.802 1174.601
Carbon dioxide / kg h-1 1253.384 2.22E-25 41631.4 420.5192 31223.55 10407.85
Water / kg h-1 21283.91 91055.74 144.6909 1.461525 108.5182 36.17273
Ethylene Carbonate / kg h-1 0 0 0 0 0 0
Ethylene Glycol / kg h-1 0 0 0 0 0 0
Potassium Carbonate / kg h-1 0 0 0 0 0 0
Potassium Bicarbonate / kg h-1 0 0 0 0 0 0
Potassium Hydroxide / kg h-1 0 0 0 0 0 0
Heat Flow [kJ/h] -3.3E+08 -1.4E+09 -9.5E+07 -956074 -7.1E+07 -2.4E+07

Name PureEOTo S13.2 S13.3 S27 PRG-2 S14.1

Vapour Fraction 1 1 1 1 1 0
Temperature / oC 3.84408 292.624 181.724 180 180 180
Pressure / kPa 70 5066 5066 5066 2026.25 2026.25
Mass Flow / kg h-1 36714.15 36714.15 36714.15 74.28635 1237.335 75194.39
Component flow rate
Ethylene / kg h-1 19.80039 19.80039 19.80039 0 334.1424 388.4715
Oxygen / kg h-1 2.120673 2.120673 2.120673 0 37.54722 10.1861
Ethylene oxide/ kg h-1 35832.27 35832.27 35832.27 0 119.3271 1023.361
Carbon dioxide / kg h-1 708.868 708.868 708.868 74.28635 689.4253 600.0341
Water / kg h-1 151.0857 151.0857 151.0857 0 37.40819 2130.266
Ethylene Carbonate / kg h-1 0 0 0 0 18.97378 70531.37
Ethylene Glycol / kg h-1 0 0 0 0 0.510566 510.698
Potassium Carbonate / kg h-1 0 0 0 0 0 0
Potassium Bicarbonate / kg h-1 0 0 0 0 0 0
Potassium Hydroxide / kg h-1 0 0 0 0 0 0
Heat Flow [kJ/h] -5.2E+07 -3.6E+07 -4.3E+07 -653603 -6059118 -4.8E+08

Name WaterRecoS28 S21 S20 S19.2 S22

Vapour Fraction 1 0 0 0 1 0
Temperature / oC 102.2914 195.6015 95 95 95 400
Pressure / kPa 100 100 3000 3000 3000 3000
Mass Flow / kg h-1 13693.19 50423.8 566643.8 73862.65 55887.58 588025.9
Component flow rate
Ethylene / kg h-1 34.1579 5.37E-08 0 0 38196.63 589.3072
Oxygen / kg h-1 0.224106 9.34E-13 0 0 6072.322 40.61944
Ethylene oxide/ kg h-1 340.011 2.20E-04 0 0 1174.578 53.52996
Carbon dioxide / kg h-1 2389.347 1.58E-06 0 0 10407.87 0
Water / kg h-1 10764.72 58.55361 0 73862.65 36.17309 6030.328
Ethylene Carbonate / kg h-1 2.57E-02 703.0073 0 0 0 0
Ethylene Glycol / kg h-1 164.7099 48960.92 0 0 0 0
Potassium Carbonate / kg h-1 0 0 566643.8 0 0 533959.5
Potassium Bicarbonate / kg h-1 0 0 0 0 0 47352.58
Potassium Hydroxide / kg h-1 0 701.3205 0 0 0 0
Heat Flow [kJ/h] -1.7E+08 -3.5E+08 -8.5E+07 -1.1E+09 -1.8E+07 -2.5E+07

Name R3.1 CompVap2R4.1 R1.2 R4.3 S4

Vapour Fraction 1 0.717018 1 0 1 1
Temperature / oC 400 400 201.0439 5 230 229.4047
Pressure / kPa 3000 3000 3000 101.325 3000 3000
Mass Flow / kg h-1 108368.1 108367.8 276031.4 91055.74 275953.5 332737.3
Component flow rate
Ethylene / kg h-1 37607.33 37607.38 152197.4 1.61E-26 151860.8 181753
Oxygen / kg h-1 6031.702 6031.928 24249.58 1.22E-25 24308.38 51200
Ethylene oxide/ kg h-1 1121.048 1121.07 4644.871 2.02E-08 4942.593 4942.593
Carbon dioxide / kg h-1 0 31223.55 2.22E-25 31101.87 31101.87
Water / kg h-1 63608.06 63607.43 63715.95 91055.74 63739.85 63739.85
Ethylene Carbonate / kg h-1 0 0 0 0 0 0
Ethylene Glycol / kg h-1 0 0 0 0 0 0
Potassium Carbonate / kg h-1 2.85E-75 0 0 0 0 0
Potassium Bicarbonate / kg h-1 2.53E-76 0 0 0 0 0
Potassium Hydroxide / kg h-1 0 0 0 0 0 0
Heat Flow [kJ/h] -7E+08 -7E+08 -7.8E+08 -1.4E+09 -7.6E+08 -6.9E+08

Name R6.1 S24.2 S26 PRG-5 R8 P1.1

Vapour Fraction 1 1 1 1 0 0
Temperature / oC 180 180 180 180 180 210
Pressure / kPa 2800 2800 3000 3000 100 100
Mass Flow / kg h-1 39642.06 8106.222 31535.83 5464.35 -1E+07 -3E+08
Component flow rate
Ethylene / kg h-1 703.497 401.5099 301.987 52.3266 0 0
Oxygen / kg h-1 45.61743 37.12667 8.490767 1.471232 0 0
Ethylene oxide/ kg h-1 601.8129 19.38354 582.4294 100.9201 0 0
Carbon dioxide / kg h-1 35761.55 7544.274 28217.28 4889.33 0 0
Water / kg h-1 2016.42 103.9277 1912.493 331.3859 0 58.55337
Ethylene Carbonate / kg h-1 1.943891 0 1.943891 0.336826 703.0043 0
Ethylene Glycol / kg h-1 0 511.2136 88.58019 0 88.58
Potassium Carbonate / kg h-1 0 0 0 0 0 0
Potassium Bicarbonate / kg h-1 0 0 0 0 0 0
Potassium Hydroxide / kg h-1 1.13E-11 0 1.13E-11 1.96E-12 701.3205 0
Heat Flow [kJ/h] -3.4E+08 -6.7E+07 -2.8E+08 -4.8E+07 -1.02E+07 -2.97E+08
NA S5.2 S6 S17 S7.1 S7.2
0 1 0 1 0 0
230.0 20.0 5.0 26.4 20.5 130.0
3000 3000 101 3000 3000 3000
0 332737 21354 225810 128281 128281

0 154490 0 154330 160 160

0 24559 0 24536 24 24
0 41647 0 4746 36901 36901
0 43305 0 42052 1253 1253
0 68735 21354 146 89943 89943
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 -1.3E+09 -3.4E+08 -9.6E+07 -1.5E+09 -1.4E+09

S9.2 S10 PRG-1 S11 S13.1 S12

0.293654 0 1 0 1 0
15 200 205.6997 128.8855 3.84408 219.7903
101.325 2600 2600 2600 70 2600
59622.13 22428.8 1382.445 80668.49 36714.83 43953.66

159.9584 0 140.1579 19.80042 19.80042 1.20E-06

23.9162 0 21.79545 2.120753 2.120753 2.01E-08
36900.96 0 8.479184 36892.48 35832.96 1059.525
1253.384 0 544.5083 708.8757 708.8664 9.36E-03
21283.91 22428.8 667.5038 43045.21 151.0842 42894.13
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
-4E+08 -3.4E+08 -1.3E+07 -7.2E+08 -5.2E+07 -6.4E+08

S15 S25 S16.1 ToCO2RecoS8 S16.2

0 1 0 0.998959 1 0
30 180 180 26.3551 100 80
 3000 3000 3000 3000 101.325 3000
25221.39 37000.18 64117 55887.58 22396.37 64117

0 354.3136 34.1579 38196.63 0 34.1579

0 9.961999 0.224106 6072.322 0 0.224106
0 683.3495 340.0112 1174.578 0 340.0112
0 33106.61 2389.347 10407.87 0 2389.347
25221.39 2243.878 10823.27 36.17309 22396.37 10823.27
0 2.280718 703.033 0 0 703.033
0 599.7938 49125.63 0 0 49125.63
0 0 0 0 0 0
0 0 0 0 0 0
0 1.33E-11 701.3205 0 0 701.3205
-4E+08 -3.2E+08 -5.4E+08 -2.3E+07 -3E+08 -5.6E+08

R5.1 S23.1 S23.2 S24.1 PRG-4 R3.2

0 1 0.257305 1 0 1
560.9555 560.9555 100 100 100 400
3000 3000 3000 2800 3000 3000
568301.4 19726.27 19726.27 8106.222 11620.05 108368.1

32.08027 557.2269 557.2269 401.5099 155.7169 37607.33

1.241929 39.37751 39.37751 37.12667 2.250847 6031.702
6.014959 47.515 47.515 19.38354 28.13146 1121.048
315.0293 10092.84 10092.84 7544.274 2548.57 0
1303.272 8989.309 8989.309 103.9277 8885.381 63608.06
0 0 0 0 0 0
0 0 0 0 0 0
566643.8 5.01E-76 5.01E-76 0 0 2.85E-75
0 0 0 0 0 2.53E-76
0 0 0 0 0 0
1.29E+08 -1.9E+08 -2.3E+08 -6.8E+07 -1.6E+08 -7E+08

R4.2 S14.2 R6.2 R6.3 R6.4 R7

1 0 1 0.988676 0.988675 0.98873
230 180.5465 250.5077 180 180 179.9691
3000 3000 5066 5066 5066 5066
276031.4 75194.39 39642.06 39642.06 39643.29 39717.58

152197.4 388.4715 703.497 703.497 702.8135 702.8135

24249.58 10.1861 45.61743 45.61743 45.61265 45.61265
4644.871 1023.361 601.8129 601.8129 601.9852 601.9852
31223.55 600.0341 35761.55 35761.55 35763.14 35837.42
63715.95 2130.266 2016.42 2016.42 2016.588 2016.588
0 70531.37 1.943891 1.943891 1.943884 1.943884
0 510.698 511.2136 511.2136 511.2085 511.2085
0 0 0 0 0 0
0 0 0 0 0 0
0 0 1.13E-11 1.13E-11 1.13E-11 1.13E-11
-7.6E+08 -4.8E+08 -3.4E+08 -3.4E+08 -3.4E+08 -3.4E+08

P1.2
0
25
100
-3.6E+08

0
0
0
0
58.55337
0
88.58
0
0
0
-3.6E+08
 Oxidati
Stream S1 S2 S3.1
Vapour Fraction 0 0 0
Temperature / oC 25 25 25
Pressure / kPa 100000 100000 100000
Mass Flow / kg h-1 29892 26892 56784
Component flow rate
Ethylene / kg h-1 29892 0 29892
Oxygen / kg h-1 0 26892 26892
Ethylene oxide/ kg h-1 0 0 0
Carbon dioxide / kg h-1 0 0 0
Water / kg h-1 0 0 0
Ethylene Carbonate / kg h-1 0 0 0
Ethylene Glycol / kg h-1 0 0 0
Potassium Carbonate / kg h-1 0 0 0
Potassium Bicarbonate / kg h-1 0 0 0
Potassium Hydroxide / kg h-1 0 0 0
Heat Flow / kJ h-1 4.97E+07 -3.68E+03 4.97E+07

Recovery o
Stream S5.2 S17 S18
Vapour Fraction 1 1 1
Temperature / oC 20 26 26
Pressure / kPa 3000 3000 3000
Mass Flow / kg h-1 332737 225810 223551
Component flow rate
Ethylene / kg h-1 154490 154330 152787
Oxygen / kg h-1 24559 24536 24290
Ethylene oxide/ kg h-1 41647 4746 4698
Carbon dioxide / kg h-1 43305 42052 41631
Water / kg h-1 68735 146 145
Ethylene Carbonate / kg h-1 0 0 0
Ethylene Glycol / kg h-1 0 0 0
Potassium Carbonate / kg h-1 0 0 0
Potassium Bicarbonate / kg h-1 0 0 0
Potassium Hydroxide / kg h-1 0 0 0
Heat Flow / kJ h-1 -1.26E+09 -9.56E+07 -9.47E+07

Recovery of CO2
Stream S9.1 S9.2 PRG-1
Vapour Fraction 1 0 1
Temperature / oC 85 15 206
Pressure / kPa 101 101 2600
Mass Flow / kg h-1 59622 59622 1382
Component flow rate
Ethylene / kg h-1 160 160 140
Oxygen / kg h-1 24 24 22
Ethylene oxide/ kg h-1 36901 36901 8
Carbon dioxide / kg h-1 1253 1253 545
Water / kg h-1 21284 21284 668
Ethylene Carbonate / kg h-1 0 0 0
Ethylene Glycol / kg h-1 0 0 0
Potassium Carbonate / kg h-1 0 0 0
Potassium Bicarbonate / kg h-1 0 0 0
Potassium Hydroxide / kg h-1 0 0 0
Heat Flow / kJ h-1 -3.35E+08 -4.00E+08 -1.32E+07

Purification
Stream S19.1 S19.2 S20
Vapour Fraction 1 1 0
Temperature / oC 26 95 95
Pressure / kPa 3000 3000 3000
Mass Flow / kg h-1 55888 55888 73863
Component flow rate
Ethylene / kg h-1 38197 38197 0
Oxygen / kg h-1 6073 6072 0
Ethylene oxide/ kg h-1 1175 1175 0
Carbon dioxide / kg h-1 10408 10408 0
Water / kg h-1 36 36 73863
Ethylene Carbonate / kg h-1 0 0 0
Ethylene Glycol / kg h-1 0 0 0
Potassium Carbonate / kg h-1 0 0 0
Potassium Bicarbonate / kg h-1 0 0 0
Potassium Hydroxide / kg h-1 0 0 0
Heat Flow / kJ h-1 -2.37E+07 -1.79E+07 -1.15E+09

C
Stream S13.1 S13.2 S13.3
Vapour Fraction 1 1 1
Temperature / oC 4 293 182
Pressure / kPa 70 5066 5066
Mass Flow / kg h-1 36715 36714 36714
Component flow rate
Ethylene / kg h-1 20 20 20
Oxygen / kg h-1 2 2 2
Ethylene oxide/ kg h-1 35833 35832 35832
Carbon dioxide / kg h-1 709 709 709
Water / kg h-1 151 151 151
Ethylene Carbonate / kg h-1 0 0 0
Ethylene Glycol / kg h-1 0 0 0
Potassium Carbonate / kg h-1 0 0 0
Potassium Bicarbonate / kg h-1 0 0 0
Potassium Hydroxide / kg h-1 0 0 0
Heat Flow / kJ h-1 -5.20E+07 -3.64E+07 -4.34E+07

Hydrolysis reaction
Stream S14.1 S14.2 S15
Vapour Fraction 0 0 0
Temperature / oC 180 181 30
Pressure / kPa 2026 3000 3000
Mass Flow / kg h-1 75194 75194 25221
Component flow rate
Ethylene / kg h-1 388 388 0
Oxygen / kg h-1 10 10 0
Ethylene oxide/ kg h-1 1023 1023 0
Carbon dioxide / kg h-1 600 600 0
Water / kg h-1 2130 2130 25221
Ethylene Carbonate / kg h-1 70531 70531 0
Ethylene Glycol / kg h-1 511 511 0
Potassium Carbonate / kg h-1 0 0 0
Potassium Bicarbonate / kg h-1 0 0 0
Potassium Hydroxide / kg h-1 0 0 0
Heat Flow / kJ h-1 -4.78E+08 -4.78E+08 -4.00E+08

Purification of EG
Stream S16.2 PRG-4 S28
Vapour Fraction 0 0 0
Temperature / oC 80 100 196
Pressure / kPa 3000 3000 100
Mass Flow / kg h-1 64117 11620 50424
Component flow rate
Ethylene / kg h-1 34 156 0
Oxygen / kg h-1 0 2 0
Ethylene oxide/ kg h-1 340 28 0
Carbon dioxide / kg h-1 2389 2549 0
Water / kg h-1 10823 8885 59
Ethylene Carbonate / kg h-1 703 0 703
Ethylene Glycol / kg h-1 49126 0 48961
Potassium Carbonate / kg h-1 0 0 0
Potassium Bicarbonate / kg h-1 0 0 0
Potassium Hydroxide / kg h-1 701 0 701
Heat Flow / kJ h-1 -5.58E+08 -1.60E+08 -3.50E+08
 Oxidation of Ethylene
S3.2 S3.3 S4 R3.2 R2 R4.1 R4.2 R4.3 S4
1 1 1 1 1 1 1 1 1
-38 230 229 400 26 201 230 230 229
3000 3000 3000 3000 3000 3000 3000 3000 3000
56784 56784 332737 108368 167664 276031 276031 275953 332737

29892 29892 181753 37607 114590 152197 152197 151861 181753

26892 26892 51200 6032 18218 24250 24250 24308 51200
0 0 4943 1121 3524 4645 4645 4943 4943
0 0 31102 0 31224 31224 31224 31102 31102
0 0 63740 63608 109 63716 63716 63740 63740
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
4.97E+07 7.24E+07 -6.88E+08 -7.05E+08 -7.10E+07 -7.75E+08 -7.60E+08 -7.60E+08 -6.88E+08

Recovery of EO
S19.1 PRG-3 S6 S7.1 S7.2 S8 S9.1 R1.1 R1.2
1 1 0 0 0 1 1 0 0
26 26 5 20 130 100 85 100 5
3000 3000 101 3000 3000 101 101 101 101
55888 2258 21354 128281 128281 22396 59622 91056 91056

38197 1543 0 160 160 0 160 0 0

6073 245 0 24 24 0 24 0 0
1175 47 0 36901 36901 0 36901 0 0
10408 421 0 1253 1253 0 1253 0 0
36 1 21354 89943 89943 22396 21284 91056 91056
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
-2.37E+07 -9.56E+05 -3.39E+08 -1.50E+09 -1.45E+09 -2.97E+08 -3.35E+08 -1.41E+09 -1.45E+09

ry of CO2
S10 S11 S12 S13.1
0 0 0 1
200 129 220 4
 2600 2600 2600 70
22429 80668 43954 36715

0 20 0 20
0 2 0 2
0 36892 1060 35833
0 709 0 709
22429 43045 42894 151
0 0 0 0
0 0 0 0
0 0 0 0
0 0 0 0
0 0 0 0
-3.38E+08 -7.24E+08 -6.44E+08 -5.20E+07

Purification of EO
S21 R3.1 R3.2 S22 S23.1 R5.1 S23.2 S24.1 PRG-4
0 1 1 0 1 0 0 1 0
95 400 400 400 561 561 100 100 100
3000 3000 3000 3000 3000 3000 3000 2800 3000
566644 108368 108368 588026 19726 568301 19726 8106 11620

0 37607 37607 589 557 32 557 402 156

0 6032 6032 41 39 1 39 37 2
0 1121 1121 54 48 6 48 19 28
0 0 0 10093 315 10093 7544 2549
0 63608 63608 6030 8989 1303 8989 104 8885
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
566644 0 0 533960 0 566644 0 0 0
0 0 0 47353 0 0 0 0 0
0 0 0 0 0 0 0 0 0
-8.48E+07 -7.05E+08 -7.05E+08 -2.50E+07 -1.94E+08 1.29E+08 -2.28E+08 -6.76E+07 -1.60E+08

Carbonation reaction
S24.1 S24.2 S26 R6.1 R6.2 R6.3 R6.4 S27 R7
1 1 1 1 1 1 1 1 1
100 180 180 180 251 180 180 180 180
2800 2800 3000 2800 5066 5066 5066 5066 5066
8106 8106 31536 39642 39642 39642 39643 74 39718

402 402 302 703 703 703 703 0 703

37 37 8 46 46 46 46 0 46
 19 19 582 602 602 602 602 0 602
7544 7544 28217 35762 35762 35762 35763 74 35837
104 104 1912 2016 2016 2016 2017 0 2017
0 0 2 2 2 2 2 0 2
0 0 511 511 511 511 0 511
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
-6.76E+07 -6.69E+07 -2.76E+08 -3.43E+08 -3.40E+08 -3.44E+08 -3.44E+08 -6.54E+05 -3.44E+08

Hydrolysis reaction
R8 S27 S25 S26 PRG-5 S16.1
0 1 1 1 1 0
180 180 180 180 180 180
100 5066 3000 3000 3000 3000
1404 74 37000 31536 5464 64117

0 0 354 302 52 34
0 0 10 8 1 0
0 0 683 582 101 340
0 74 33107 28217 4889 2389
0 0 2244 1912 331 10823
703 0 2 2 0 703
0 0 600 511 89 49126
0 0 0 0 0 0
0 0 0 0 0 0
701 0 0 0 0 701
-1.02E+07 -6.54E+05 -3.24E+08 -2.76E+08 -4.79E+07 -5.38E+08

EG
P1.1 P1.2 R8
0 0 0
210 25 180
100 100 100
49019 49019 -10175512

0 0 0
0 0 0
0 0 0
0 0 0
59 59 0
 0 0 703
0 0 0
0 0 0
0 0 0
0 0 701
-2.97E+08 -3.63E+08 -1.02E+07
S5.1
1
230
3000
332737

154490
24559
41647
43305
68735
0
0
0
0
0
-9.59E+08
PRG-2 S14.1
1 0
180 180
2026 2026
1237 75194

334 388
38 10
 119 1023
689 600
37 2130
19 70531
1 511
0 0
0 0
0 0
-6.06E+06 -4.78E+08
 S4 S5.1
1 1
229 230
3000 3000
332737 332737

Ethylene / 181753 154490

Oxygen / kg h-1 51200 24559
Ethylene oxide/ kg h-1 4943 41647
Carbon dioxide / kg h-1 31102 43305
Water / kg h-1 63740 68735
Ethylene Carbonate / kg h-1 0 0
Ethylene Glycol / kg h-1 0 0
Potassium Carbonate / kg h-1 0 0
Potassium Bicarbonate / kg h-1 0 0
Potassium Hydroxide / kg h-1 0 0
-6.88E+08 -9.59E+08

332737 332737

Unit

Stream

S13.3 R7 PRG-2 S14.1

1 1 1 0 S13.3
182 180 180 180
5066 5066 2026 2026
36714 39718 1237 75194

Ethylene / 20 703 334 388

R7
Oxygen / kg h-1 2 46 38 10
Ethylene oxide/ kg h-1 35832 602 119 1023 R7
Carbon dioxide / kg h-1 709 35837 689 600
Water / kg h-1 151 2017 37 2130
Ethylene Carbonate / kg h-1 0 2 19 70531
Ethylene Glycol / kg h-1 0 511 1 511
Potassium Carbonate / kg h-1 0 0 0 0
Potassium Bicarbonate / kg h-1 0 0 0 0
Potassium Hydroxide / kg h-1 0 0 0 0
-4.34E+07 -3.44E+08 -6.06E+06 -4.78E+08

S14.2 S15 R8 S25

Ethylene / 388 0 0 354
Oxygen / kg h-1 10 0 0 10
Ethylene oxide/ kg h-1 1023 0 0 683
Carbon dioxide / kg h-1 600 0 0 33107
Water / kg h-1 2130 25221 0 2244
Ethylene Carbonate / kg h-1 70531 0 703 2
Ethylene Glycol / kg h-1 511 0 0 600
Potassium Hydroxide / kg h-1 0 0 701 0

S27
1
180
5066
74

0
0
0
74
0
0
0
0
0
0
-6.54E+05
 Unit React-1 (Oxidation reactor)
Inlet
Stream Component Mass flow / kg h-1 Total flow / kg h-1
Ethylene 181753
Oxygen 51200
S4 Ethylene oxide 4943 332737
Carbon dioxide 31102
Water 63740

React-1 (Oxidation reactor)

Inlet Outlet
Component Mass flow / kg h-1 Total flow / kg h -1
Stream Component Mass flow / kg h-1
Ethylene 20 Ethylene 334
Oxygen 2 Oxygen 38
Ethylene oxide 35832 Ethylene oxide 119
Carbon dioxide 709 PRG-2 Carbon dioxide 689
Water 151 Water 37
Ethylene Carbonate 0 Ethylene Carbonate 19
Ethylene Glycol 0 Ethylene Glycol 1
Ethylene 703 76432 Ethylene 388
Oxygen 46 Oxygen 10

S14.1
 76432

Ethylene oxide 602 Ethylene oxide 1023

Carbon dioxide 35837 S14.1 Carbon dioxide 600
Water 2017 Water 2130
Ethylene Carbonate 2 Ethylene Carbonate 70531
Ethylene Glycol 511 Ethylene Glycol 511

S16.1 Unit
34 Inlet
0 Stream Component Mass flow / kg h-1
340 Ethylene 388
2389 Oxygen 10
10823 Ethylene oxide 1023
703 S14.2 Carbon dioxide 600
49126 Water 2130
701 Ethylene Carbonate 70531
Ethylene Glycol 511
Potassium hydroxide 0
Ethylene 0
Oxygen 0
Ethylene oxide 0
Carbon dioxide 0
S15
Water 25221
Ethylene Carbonate 0
Ethylene Glycol 0
Potassium hydroxide 0
Ethylene 0
Oxygen 0
Ethylene oxide 0
Carbon dioxide 0
R8
Water 0
Ethylene Carbonate 703
Ethylene Glycol 0
Potassium hydroxide 701
Ethylene 0
Oxygen 0
Ethylene oxide 0
S29
 Carbon dioxide
S29
Water 0
Ethylene Carbonate 0
Ethylene Glycol 0
Potassium hydroxide
React-1 (Oxidation reactor)
Outlet
Stream Component Mass flow / kg h-1 Total flow / kg h-1
Ethylene 154490
Oxygen 24559
S5.1 Ethylene oxide 41647 332737
Carbon dioxide 43305
Water 68735

Outlet
Mass flow / kg h-1 Total flow / kg h-1
334
38
119
689
37
19
1
388 76432
10
 76432

1023
600
2130
70531
511

React-2 (Hydrolysis reactor)

Inlet Outlet
Mass flow / kg h-1 Total flow / kg h -1
Stream Component Mass flow / kg h-1 Total flow / kg h-1
388 Ethylene 354
10 Oxygen 10
1023 Ethylene oxide 683
600 S25 Carbon dioxide 33107
2130 Water 2244
70531 Ethylene Carbonate 2
511 Ethylene Glycol 600
0 Potassium hydroxide 0 100416
0 Ethylene 34
0 Oxygen 0
0 Ethylene oxide 340
0 Carbon dioxide 2389
S16.1
25221 Water 10823
0 Ethylene Carbonate 703
0 Ethylene Glycol 49126
0 101820 Potassium hydroxide
0
0
0
0
0
703
0
701
0
0
0
0
0
0
37000

63416
 Inlet Outlet
Stream Component Mass flow / kg h-1 Total flow / kg h -1
Stream Component
Ethylene 388 Ethylene
Oxygen 10 Oxygen
Ethylene oxide 1023 Ethylene oxide
Carbon dioxide 600 Carbon dioxide
S14.2 S25
Water 2130 Water
Ethylene Carbonate 70531 Ethylene Carbonate
Ethylene Glycol 511 Ethylene Glycol
Potassium hydroxide 0 Potassium hydroxide
Ethylene 0 Ethylene
Oxygen 0 Oxygen
Ethylene oxide 0 Ethylene oxide
Carbon dioxide 0 Carbon dioxide
S15 101820 S16.1
Water 25221 Water
Ethylene Carbonate 0 Ethylene Carbonate
Ethylene Glycol 0 Ethylene Glycol
Potassium hydroxide 0 Potassium hydroxide
Ethylene 0
Oxygen 0
Ethylene oxide 0
Carbon dioxide 0
R8
Water 0
Ethylene Carbonate 703
Ethylene Glycol 0
Potassium hydroxide 701
Outlet
Mass flow / kg h-1 Total flow / kg h-1
388
6
1023
71000
101
0
0
0
101820
0
4
0
122
172
712
27589
701
Stream S29 S14.2 S15 R8 S25
Vapour Fraction 0 0 0 0 1
Temperature / oC 80 181 30 180 180
Pressure / kPa 3000 3000 3000 100 3000
Mass Flow / kg h-1 701 75194 25221 1404 37933
Component flow rate
Ethylene / kg h-1 0 388 0 0 144
Oxygen / kg h-1 0 10 0 0 4
Ethylene oxide/ kg h-1 0 1023 0 0 379
Carbon dioxide / kg h-1 0 600 0 0 26315
Water / kg h-1 0 2130 25221 0 101
Ethylene Carbonate / kg h-1 0 70531 0 703 264
Ethylene Glycol / kg h-1 0 511 0 0 10208
Potassium Carbonate / kg h-1 701 0 0 0 519
Potassium Bicarbonate / kg h-1 0 0 0 0 144
Potassium Hydroxide / kg h-1 0 0 0 701 4

Stream S25 S16.1

Vapour Fraction 1 0
Temperature / oC 180 180
Pressure / kPa 3000 3000
Mass Flow / kg h-1 37933 64558
Component flow rate
Ethylene / kg h-1 144 245
Oxygen / kg h-1 4 6
Ethylene oxide/ kg h-1 379 645
Carbon dioxide / kg h-1 26315 44807
Water / kg h-1 101 172
Ethylene Carbonate / kg h-1 264 449
Ethylene Glycol / kg h-1 10208 17381
Potassium Carbonate / kg h-1 519 884
Potassium Bicarbonate / kg h-1 144 245
Potassium Hydroxide / kg h-1 4 6
S16.1
0
180
3000
64558

245
6
645
44807
172
449
17381
884
245
6