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densitas alkohol

densitas aquadest
0.8057 0.996233
46 18.02
92.04% 7.96%
no alkohol aquadest mol alkoholmol aquadest fraksi mol alkohol
indeks bias
1 9 1 0.145087 0.087322558 0.624272192 1.351
2 8 2 0.128966 0.139047663 0.481191512 1.35
3 7 3 0.112845 0.190772768 0.371668139 1.349
4 6 4 0.096724 0.242497873 0.285135664 1.347
5 5 5 0.080604 0.294222978 0.215042443 1.3425
6 4 6 0.064483 0.345948082 0.157110222 1.341
7 3 7 0.048362 0.397673187 0.108426778 1.335
8 2 8 0.032241 0.449398292 0.066941012 1.331
9 1 9 0.016121 0.501123397 0.031166571 1.3245

fraksi mol=x indeks bias=y


hubungan indeks bias dengan fraksi mol alkohol
no x y x^2 xy y hitung %kesalahan
1 0.624272 1.351 0.389716 0.843391731 1.356276195 0.39054
2 0.481192 1.35 0.231545 0.649608541 1.350361497 0.0267776
3 0.371668 1.349 0.138137 0.50138032 1.345833998 0.2346925
4 0.285136 1.347 0.081302 0.384077739 1.342256901 0.3521232
5 0.215042 1.3425 0.046243 0.28869448 1.339359373 0.2339387
6 0.15711 1.341 0.024684 0.210684808 1.33696456 0.3009277
7 0.108427 1.335 0.011756 0.144749749 1.334952074 0.00359
8 0.066941 1.331 0.004481 0.089098486 1.333237127 0.1680786
9 0.031167 1.3245 0.000971 0.041280124 1.331758276 0.5480012
Σ 2.340955 12.071 0.928836 3.152965978 0.2509633

dengan metode least square


y= a x+ b
pakai matriks (dibalik ruasnya)
Σx n a = Σy
Σx^2 Σx b = Σxy
maka
Σx a + n b=
Σx^2 a + Σx b=
a b
12.071 = 2.340954533 9
3.152966 = 0.928836288 2.340954533
a b
28.25766 = 5.480068124 21.06859079
28.37669 = 8.359526588 21.06859079
-0.11903 = -2.87945846 0
a = 0.041338201
b = 1.330469906
persamaan garis yang didapat
y= 0.041338 x+ 1.330469906

mencari fraksi mol distilat dan residu dari persamaan


aquadest alkohol yD xD yR xR
80 110 1.35 0.472447 1.345 0.351493146
80 80 1.349 0.448256 1.342 0.278921048
110 80 1.3495 0.460351 1.339 0.206348949

mencari sifat penguapan rata-rata (αab)


dari fig. 543 GG Brown "unit operation" didapat:
suhu (°F) P° alkohol (psia) P° aquadest (psia)
no D R D R D R
1 174.2 192.2 15 20 7 10
2 174.2 197.6 15 25 7 11
3 174.2 199.4 15 30 7 13

αD P°al/P°aq
αR P°al/P°aq
αab α𝑅 ∗ α𝐷
tabel sifat penguapan
suhu (°F)
no D R αD αR αab
1 174.2 192.2 2.142857 2 2.070196678
2 174.2 197.6 2.142857 2.272727273 2.206837074
3 174.2 199.4 2.142857 2.307692308 2.22374795

menentukan Nmin dari HETP


a. Metode Mc. Cabe Thile
data fraksi mol uap cair didapat dengan rumus
α𝑎𝑏∗𝑥
y= y=fraksi mol uap 𝐻𝐸𝑇𝑃
1+ α𝑎𝑏−1 𝑥
x=fraksi mol cairan
αab= 2.070197 αab= 2.206837074
x y x y
0 0 0 0 0
0.1 0.187006 0.1 0.1 0.196918815
0.2 0.341043 0.2 0.2 0.35554938
0.3 0.470122 0.3 0.3 0.486069217
0.4 0.579855 0.4 0.4 0.595342344
0.5 0.674288 0.5 0.5 0.688166259
0.6 0.756412 0.6 0.6 0.767995198
0.7 0.828487 0.7 0.7 0.837379508
0.8 0.892251 0.8 0.8 0.898243151
0.9 0.949062 0.9 0.9 0.952064886
1 1 1 1 1
Nmin

b. Metode Fenske Underwood


𝑥𝐷 1 − 𝑥𝑅
log( ∗ )
𝑁𝑚𝑖𝑛 = 1 − 𝑥𝐷 𝑥𝑅 𝐻𝐸𝑇𝑃
log α𝑎𝑏
αab= 2.070196678 2.206837074 2.2237479
fraksi mol
xD xR log Nmin HETP
0.4724 0.3515 0.21799 0.689815653 95.67773616
0.4482 0.2789 0.322237 0.93736185 70.4103757
0.46035 0.2063 0.516133 1.487048661 44.3832147
Grafik Standar
1.36

1.355

1.35

1.345
indeks bias

2.258669385 1.34

1.335

1.33

1.325

1.32
0 0.1 0.2 0.3 0.4 0.5 0.6
Σy fraksi mol
Σxy
𝑦 − 1,330469819
𝑥=
0,04134

suhu (°C)
D R
79 89
79 92
79 93

αab=2,070197
1
𝑡𝑖𝑛𝑔𝑔𝑖 𝑘𝑜𝑙𝑜𝑚 𝑏𝑎ℎ𝑎𝑛 𝑖𝑠𝑖𝑎𝑛
𝐻𝐸𝑇𝑃 = 0.9
𝑁𝑚𝑖𝑛
0.8
αab= 2.22374795
x y 0.7
indeks bias (y)

0 0 0.6
0.1 0.198128821 0.5
0.2 0.357300451 0.4
0.3 0.487976363
0.3
0.4 0.59718004
0.5 0.689802052 0.2
0.6 0.769352583 0.1
0.7 0.838416357 0
0 0.1 0.2 0.3 0.4 0.5 0.6
0
0.8 0.898938774 0 0.1 0.2 0.3 0.4 0.5 0.6
0.9 0.952412069 fraksi mol (x)
1 1
Nmin

αab=2,22374795
1

0.9
𝑡𝑖𝑛𝑔𝑔𝑖 𝑘𝑜𝑙𝑜𝑚 𝑏𝑎ℎ𝑎𝑛 𝑖𝑠𝑖𝑎𝑛
𝐻𝐸𝑇𝑃 = 0.8
𝑁𝑚𝑖𝑛
0.7
tinggi kolom 66

indeks bias (y)


0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6
fraksi mol (x)
y = 0.0413x + 1.3305
R² = 0.7911

y hitung
y data
Linear (y data)

0.6 0.7
b=2,070197 αab=2,20683707
1
0.9
0.8
0.7
indeks bias (y)

0.6
0.5
0.4
0.3
0.2
0.1
0
0.6 0.7 0.8 0.9 1
0
0.6 0.7 0.8 0.9 1
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
fraksi mol (x)

b=2,22374795
yD xD yR xR
1.35 0.472447 1.345 0.351493
1.349 0.448256 1.342 0.278921
1.3495 0.460351 1.339 0.206349

0.6 0.7 0.8 0.9 1


fraksi mol (x)
Series1
Series2
1

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