CET SUMS

1). Calculate entropy change of evaporation of dry saturated steam at 500 kPa and 425 K, Latent heat of
vaporization is 2106 KJ/Kg1.

2). A heat engine operates between 700 K and 300 K. Calculate maximum efficiency.

3). Calculate entropy change if 2 Kg of gas at 277 K is heated at constant volume to 368 K, Cv = 1.42 KJ/Kg
K.

4). Assuming air as an ideal gas calculate it’s molar volume at 3500C and 105 N/m2, R = 8.314 J/mol.K.

5). If a body of 10 kg is moving at 50 m/s calculate it’s kinetic energy.

6). If a body of 10 kg is moving at 50 m/s calculate it’s kinetic energy.

7). A closed system executes adiabatic process due to which a change in internal energy takes place. A
work of 20 kJ is done by the system on surroundings during this process. Determine change of specific
internal energy of the system if system contains mass of 0.5 kg.

8). A system contains 15 kg of a gas. During a process 9.5 kJ work is done on the system and 39.5 kJ heat
is rejected from the system. Find change of specific internal energy of the system.

9).Calculate standard heat of reaction at 250C of the following reaction

Na2CO3 (s) + Fe2O3 (s)  Na2O.Fe2O3 (s) + CO2 (g), using following data

Standard heat of formation of Na2CO3 (s) = -1130.68 kJ/mol

Standard heat of formation of Fe2O3 (s) = -817.3 kJ/mol

Standard heat of formation of Na2O.Fe2O3 (s) = -1412.2 kJ/mol

Standard heat of formation of CO2 (g)= -393.51 kJ/mol1.

10). Calculate the change in enthalpy between reactants and products if both are at 250°C and if 9 mol of
ethylene oxide is produced by following reaction

C2H4 (g) + ½ O2 (g)  C2H4O (g), using following data

Standard heat of formation of C2H4 (g) = 52.50 kJ/mol

Standard heat of formation of C2H4O (g) = -52.63 kJ/mol

11). If a Carnot engine receives heat at 900 K and rejects heat at 500 K, what is its thermal efficiency?1

12). Using Hess’s law, calculate heat of formation of Benzoic acid crystals (C7H6O2) at 250°C using
following data:
Standard heat of formation of CO2 (g) = -393.51 kJ/mol

Standard heat of formation of H2O (l) = -285.83 kJ/mol

Standard heat of combustion of C7H6O2 = -3226.95 kJ/mol2

13). 9 kg of air has volume 9.7 m3 when it is at temperature 350°C. If it is compressed at constant
pressure up to temperature 3500°C, find heat transfer, change in internal energy and work done.

Take R=0.287 kJ/kg K and Cv=0.718 kJ/kg K.

14). What is the change in entropy when 1 mol of an ideal gas at 335 K and 10 bar is expanded
irreversibly to 300 K and 1 bar? Take Cp = 29.3 J/mol K, R=8.314 J/mol K.

15). Calculate the degree of freedom for a system of pure water.

16). The potential energy of a body of 10 kg is 1.5 KJ. Calculate it’s height. 2

17). A system consisting of some fluid is stirred in a tank. The rate of work done on the system by the
stirrer is 1500 W. The heatgenerated due to stirring is dissipated to the surroundings. If the heat
transferred to the surroundings is 4000 kJ/hr., determine the change in internal energy.2

18). A heat engine operates between 850 K and 350 K. Calculate maximum efficiency.

19). What is the change in entropy when 1 mol of an ideal gas at 335 K and 10 bar is expanded
irreversibly to 300 K and 1 bar? Take Cp = 29.3 J/mol K, R=8.314 J/mol K.

20). A system contains 15 kg of a gas. During a process 30 kJ work is done on the system and 55 kJ heat is
rejected from the system. Find change of specific internal energy of the system.

21). A system consisting of some fluid is stirred in a tank. The rate of work done on the system by the
stirrer is 1600 W. The heat generated due to stirring is dissipated to the surroundings. If the heat
transferred to the surroundings is 3000 kJ/hr., determine the change in internal energy.

22). A heat engine operates between 980 K and 300 K. Calculate maximum efficiency.

23). What is the change in entropy when 1 mol of an ideal gas at 340 K and 12 bar is expanded
irreversibly to 300 K and 1 bar? Take Cp = 29.3 J/mol K, R=8.314 J/mol K.

24). Calculate standard heat of reaction at 250C of the following reaction

Na2CO3 Fe2O3 (s) =  Na2O.Fe2O3 (s) + CO2 (g), using following data

Standard heat of formation of Na2CO3 (s) = -1130.68 kJ/mol

Standard heat of formation of Fe2O3 (s) = -817.3 kJ/mol

Standard heat of formation of Na2O.Fe2O3 (s) = -1412.2 kJ/mol

Standard heat of formation of CO2 (g)= -393.51 kJ/mol

25). Calculate the change in enthalpy between reactants and products if both are at 250C and if 5 mol of
ethylene oxide is produced by following reaction. C2H4 (g) + ½ O2 (g) = C2H4O (g), using following data
Standard heat of formation of C2H4 (g) = 52.50 kJ/mol. Standard heat of formation of C2H4O (g) = -52.63
kJ/mol.

26). If an engine receives 10000 kJ heat and rejects 6000 kJ heat, what is its thermal efficiency?

27). If a system expands from 500 lit to 1500 lit volume at constant pressure of 9 x 105 N/m², find
boundary work during the process.3

28). Using Hess’s law, calculate heat of formation of Benzoic acid crystals (C7H6O2) at 250C using
following data: Standard heat of formation of CO2 (g) = -393.51 kJ/mol

Standard heat of formation of H2O (l) = -285.83 kJ/mol

Standard heat of combustion of C7H6O2 = -3226.95 kJ/mol.

29). A gas is enclosed in a closed vessel of volume 0.4 m3 has absolute pressure 3 bar and temperature
40 0C. If it is compressed at constant volume upto 6 bar, find its mass and change in internal energy. Take
Cv=0.72 kJ/kg K and R = 0.29 kJ/kg K.

30). What is the change in entropy when 2 kg of an ideal gas at 277 K is heated at constant volume to a
temperature of 368 K? Take Cv = 1.42 kJ/kg K.

331). Calculate the degree of freedom for system of liquid water, vapor and ice are in equilibrium.3

32). A closed system executes adiabatic process due to which a change in internal energy takes place. A
work of 10 kJ is done by the system on surroundings during this process. Determine change of specific
internal energy of the system if system contains mass of 0.2 kg.

33). A system contains 10 kg of a gas. During a process 15 kJ work is done on the system and 35 kJ heat is
rejected from the system. Find change of specific internal energy of the system3.

34). Calculate standard heat of reaction at 250C of the following reaction Na2CO3 (s) + Fe2O3 (s) =
Na2O.Fe2O3 (s) + CO2 (g), using following data3

Standard heat of formation of Na2CO3 (s) = -1130.68 kJ/mol

Standard heat of formation of Fe2O3 (s) = -817.3 kJ/mol

Standard heat of formation of Na2O.Fe2O3 (s) = -1412.2 kJ/mol

Standard heat of formation of CO2 (g)= -393.51 kJ/mol

35). Calculate the change in enthalpy between reactants and products if both are at 250C and if 5 mol of
ethylene oxide is produced by following reaction
C2H4 (g) + ½ O2 (g)  C2H4O (g), using following data

Standard heat of formation of C2H4 (g) = 52.50 kJ/mol

Standard heat of formation of C2H4O (g) = -52.63 kJ/mol4.

36). Using Hess’s law, calculate heat of formation of Benzoic acid crystals (C7H6O2) at 250C using
following data: Standard heat of formation of CO2 (g) = -393.51 kJ/mol

Standard heat of formation of H2O (l) = -285.83 kJ/mol

Standard heat of combustion of C7H6O2 = -3226.95 kJ/mol4.

437). 5 kg of air has volume 7.5 m3 when it is at temperature 350C. If it is compressed at constant
pressure up to temperature 2500C, find heat transfer, change in internal energy and work done. Take
R=0.287 kJ/kg K and Cv=0.718 kJ/kg K.

38). What is the change in entropy when 1 mol of an ideal gas at 335 K and 10 bar is expanded
irreversibly to 300 K and 1 bar? Take Cp = 29.3 J/mol K, R=8.314 J/mol K4

39). A system consisting of some fluid is stirred in a tank. The rate of work done on the system by the
stirrer is 2.25 hp . The heat generated due to stirring is dissipated to the surroundings. If the heat
transferred to the surroundings is 3400 KJ/h , determine the change in internal energy.4

40). Heat is transferred to 10 kg of air which is initially at 100 kPa and 300 K until its temperature reaches
600 K. Determine the change in internal energy and change in enthalpy for constant volume process.
Assume air is an ideal gas. Cv=20.785 kJ/kmol and molecular wt. of air = 29.

41). Assuming air as an ideal gas calculate it’s molar volume at 3500C and 105 N/m2, R = 8.314 J/mol°K.

42). One kilomol CO2 occupies a volume of 0.381 m3 at 313 K. Calculate the pressures by Ideal gas
equation and Vander Waals equation. Take contant a = 0.365 Nm4/mol2 and b = 4.28 x 10 -5 m3/mol.

43). Using Hess’s law, calculate heat of formation of liquid ethyl acetate at 298 K using following data:

Standard heat of formation of CO2 (g) = -393.51 kJ/mol

Standard heat of formation of H2O (l) = -285.83 kJ/mol

Standard heat of combustion of liquid ethyl acetate C4H8O2 = -2230.91 kJ/mol.

44). Calculate entropy change if 2 Kg of gas at 287 K is heated at constant volume to 378 K, Cv = 1.42
KJ/Kg K.

45). Calculate degree of freedom for binary distillation. 4

46). A system contains 10 kg of a gas. During a process 15 kJ work is done on the system and 35 kJ heat is
rejected from the system. Find change of specific internal energy of the system.
47). A closed system executes adiabatic process due to which a change in internal energy takes place. A
work of 15 kJ is done by the system on surroundings during this process. Determine change of specific
internal energy of the systemif system contains mass of 0.5 kg.5

48). What is the change in entropy when 2 kg of an ideal gas at 277 K is heated at constant volume to a
temperature of 368 K? Take Cv = 1.42 kJ/kg K5.

49). If a system expands from 500 lit to 1500 lit volume at constant pressure of 9 x 105 N/m2, find
boundary work during the process.5

50). Calculate standard heat of reaction at 250C of the following reaction Na2CO3 (s) + Fe2O3 (s) =
Na2O.Fe2O3 (s) + CO2 (g), using following data Standard heat of formation of Na2CO3 (s) = -1130.68
kJ/mol

Standard heat of formation of Fe2O3 (s) = -817.3 kJ/mol

Standard heat of formation of Na2O.Fe2O3 (s) = -1412.2 kJ/mol

Standard heat of formation of CO2 (g)= -393.51 kJ/mol5.

51). If a Carnot engine receives heat at 600 K and rejects heat at 400 K, what is its thermal efficiency?

52). What is the change in entropy when 1 mol of an ideal gas at 335 K and 10 bar is expanded
irreversibly to 300 K and 1 bar? Take Cp = 29.3 J/mol K, R=8.314 J/mol K.

53). Calculate entropy change of evaporation of dry saturated steam at 500 kPa and 425 K, Latent heat of
vaporization is 2106 KJ/Kg.

54). Using Hess’s law, calculate heat of formation of Benzoic acid crystals (C7H6O2) at 250C using
following data:

Standard heat of formation of CO2 (g) = -393.51 kJ/mol5

Standard heat of formation of H2O (l) = -285.83 kJ/mol5

5
6