Autothermal reforming:

CH4+2O2↔CO2+2H2O CH4+H2O ↔
CO+3H2 C2H6+2H2O ↔ 2CO+5H2
C3H8+3H2O ↔ 3CO+7H2
CO2+H2↔CO+H2O

ASSUME

Component Mol Weight

Carbon Dioxide, CO2 44.0095
Nitrogen, N2 28.014
Methane, CH4 16.043
C2H6 30.07
C3H8 44.1
H2S, ppmv 34.08
Mercaptans, ppmv, CH3S
47.095
Oxygen O2 31.998
Carbon Monoxide, CO 28.0101
Steam, H2O 18.0153
Water H20 18.0153
Hydrogen, H2 2.01588
Total
OUTPUT

Avg Production t/day

 55
H2 Production kg/h
2227.5
H2 Production Purity kg/h
2291.6666667
Output COx ppmv
20
 356.9553200961 kmol/hr

NATURAL FEED

Composition v% Mole fraction Mole Flow rate

2 0.02 7.1391064019
0.7 0.007 2.4986872407
90 0.9 321.259788087
5.005 0.05005 17.8656137708
2.145 0.02145 7.6566916161
0.06 0.0006 0.2141731921

0.09 0.0009 0.3212597881

0
0
0
0
0
100

kg/h
 2291.6666666667
kmol/h
1104.9764866956 22.0995297339
kmol/h 2 % recycle
1136.8070850778 22.7361417016
kg/h
4.5833333333
Recycle H2

Mole Fraction Mole flow rate

0 0
0 0
0 0
0 0
0 0
0 0

0 0
0 0
0 0
0 0
0 0
1 22.0995297339
CH3S+H2 ↔ CH4+H2S

Conversion = 0.98

Hydrogeneration

IN OUT
Mole Flowrate Mole Flowrate
7.1391064019 7.1391064019
2.4986872407 2.4986872407
321.2597880865 321.5746226788
17.8656137708 17.8656137708
7.6566916161 7.6566916161
0.2141731921 0.5290077844

0.3212597881 0.0064251958
0 0
0 0
0 0
0 0
22.0995297339 21.7846951416
379.05484983 379.05484983
 ZnO+H2S ↔ ZnS+ H2O

Conversion 0.98

Delsulfurisation

IN OUT
Mole fraction Molar Flow rate Molar Flow rate
0.0188339667 7.1391064019 7.1391064019
0.0065918883 2.4986872407 2.4986872407
0.8483590774 321.5746226788 321.5746226788
0.0471320016 17.8656137708 17.8656137708
0.0201994292 7.6566916161 7.6566916161
0.0013955969 0.5290077844 0.0105801557

1.69505699890429E-05 0.0064251958 0.0064251958

0 0 0
0 0 0
0 0 0.5184276287
0 0 0
0.0574710893 21.7846951416 21.7846951416
1 379.05484983
 Steam Feed

Mole Fraction Mole Flowrate

0.0188339667 0
0.0065918883 0
0.8483590774 0
0.0471320016 0
0.0201994292 0
2.7911938582E-05 0

1.6950569989E-05 0
0 0
0 0
0.001367685 1174.7218924176
0 0
0.0574710893 0
1

ASSUME STEAM:CH4
STEAM FEED
 Oxygen Feed

Mole Fraction Mole Flowrate Mole Fraction

0 0 0
0 0 0
0 0 0
0 0 0
0 0 0
0 0 0

0 0 0
0 128.1704567534 1
0 0 0
1 0 0
0 0 0
0 0 0

3:01
964.7238680365
CH4+1/2O2↔CO+2H2

Partial Oxidation

IN OUT
Molar Flow rate Molar Flow rate Mole Fraction
7.1391064019 7.1391064019
2.4986872407 2.4986872407
321.5746226788 65.233709172
17.8656137708 17.8656137708
7.6566916161 7.6566916161
0.0105801557 0.0105801557

0.0064251958 0.0064251958
128.1704567534 0
0 256.3409135068
1175.2403200463 1175.2403200463
0 0
21.7846951416 534.4665221553
6
CH4+H2O ↔ CO+3H2
C2H6+2H2O ↔ 2CO+5H2
C3H8+3H2O ↔ 3CO+7H2

Conversion = 1

Reforming

IN OUT
Molar Flow rate Molar Flow rate
7.1391064019 7.1391064019
2.4986872407 2.4986872407
65.233709172 22.5102235875
17.8656137708 0
7.6566916161 0
0.0105801557 0.0105801557

0.0064251958 0.0064251958
0 0
256.3409135068 357.7657014811
1175.2403200463 1073.815532072
0 0
534.4665221553 805.5618890752
2269.3081452099
0.3549812707
 Steam H2O addded

Mole Ftaction Mola Flow rate Mole Fraction

0 0
0 0
0 0
0 0
0 0
0 0

0 0
0 0
0 0
1073.2971044434 1
0 0
0 0

ASSUME WATER:CO 3:01

STEAM NEEDED 1073.2971044434
Steam ADDED -0.5184276287
CO+H2O↔CO2+H2

Conversion = 0.6

HWGS

IN OUT
Molar Flow rate Molar Flow rate
7.1391064019 221.7985272906
2.4986872407 2.4986872407
22.5102235875 22.5102235875
0 0
0 0
0.0105801557 0.0105801557

0.0064251958 0.0064251958
0 0
357.7657014811 143.1062805924
1073.2971044434 858.6376835547
0 0
805.5618890752 1020.2213099638
 CO+H2O↔CO2+H2

Conversion 0.75

LWGS

IN OUT
Mole Fraction Molar Flow rate Molar Flow rate
221.7985272906 329.1282377349
2.4986872407 2.4986872407
22.5102235875 22.5102235875
0 0
0 0
0.0105801557 0.0105801557

0.0064251958 0.0064251958
0 0
143.1062805924 35.7765701481
858.6376835547 751.3079731103
0 0
1020.2213099638 1127.5510204082
Seperator

IN OUT
Mole Fraction Mole Fraction
329.1282377349 329.1282377349
2.4986872407 2.4986872407
22.5102235875 22.5102235875
0 0
0 0
0.0105801557 0.0105801557

0.0064251958 0.0064251958
0 0
35.7765701481 35.7765701481
751.3079731103 0
0 751.3079731103
1127.551020408 1127.5510204082
Conversion = 0

Co2 Removal PSA

IN OUT IN
Molar Flow rate Molar Flow rate Molar Flow rate
329.1282377349 329.1282377349 329.1282377349
2.4986872407 2.4986872407 2.4986872407
22.5102235875 22.5102235875 22.5102235875
0 0 0
0 0 0
0.0105801557 0.0105801557 0.0105801557

0.0064251958 0.0064251958 0.0064251958

0 0 0
35.7765701481 35.7765701481 35.7765701481
0 0 0
751.3079731103 751.3079731103 751.3079731103
1127.5510204082 1127.5510204082 1127.5510204082
Final Flowrate
OUT
Molar Flow rate

1105
364.9048079
0.000364905
 Ho298.15
Component Mol Weight kJ/mol A B C
Carbon Dioxide, CO2 44.010 -393.52 24.99735 55.18696 -33.69137
Carbon Monoxide, CO 28.011 -110.53 25.56759 6.09613 4.054656
Steam, H2O 18.015 -241.83 30.092 6.832514 6.793435
Nitrogen, N2 28.013 191.61 28.98641 1.853978 -9.647459
Hydrogen, H2 2.016 130.68 33.066178 -11.363417 11.432816
Methane, CH4 16.043 -74.87 -0.703029 108.4773 -42.52157
Total
 D E F G H
7.948387 -0.136638 -403.6075 228.2431 -393.5224
-2.671301 0.131021 -118.0089 227.3665 -110.5271
-2.53448 0.082139 -250.881 223.3967 -241.8264
16.63537 0.000117 -8.671914 226.4168 0
-2.772874 -0.158558 -9.980797 172.707974 0
5.862788 0.678565 -76.84376 158.7163 -74.8731