fclmv-4 DETACHABLE

( f11 £4 '1 ｾ＠ #11 '1 (＾ｦｾ＠ I)

CHEMISTRY · (Paper I)
(11flT : rfr.:r. F:fTl?: Ｓｦｾ＠ Jiq;: 250
Time Allowed : Three Hours Maximutn Marks: 250

ｾ＠ ｾｲｩｦ＠ cnT ｾ＠ ｾ＠ ｾ＠ ¥ Mkl ｦｾ＠ f<5J <'1 mitcfi ｾｔ＠ Cfil t tl I rt lJ:4 Cfl ｾ＠ I
ｾ＠ 3TIO ＾ｲｾ＠ ｾ＠ \111 Gl"ciif -q ｦ｣ｾ＠ ｾ＠ ｃｔｾ＠ ｾ＠ 3ft\ ｾ＠ ｾ＠ "B ｾ＠ ｾ＠ I
w&n?if cn1 ｾ＠ -qf:q ＾ｲｾｮ＠ ｾ＠ ｾ＠ ｾ＠ ｾ＠ 1

＾ｲｾ＠ tiwn 1 ｾ＠ 5 ｾ＠ ｾ＠ ｡ｾ＠ ｾ＠ ＾ｲｾ＠ -B it ｾ＠ ｾｩｴ＠ Cfi11-it-Cf11i ｾ＠ ＾ｲｾＭＮＺ＠ ｾ＠ ｾ＠ mrr ＾ｲｾｮ＠

ｾ ｉ＠
ｾ＠ ＾ｦｾＢＧｬＯ＠ ｾ＠ 3i"Cfi ＧＱｾ＠ ｾ＠ ｾ＠ ｾ＠ ｾ＠ I
＾ｲ ｾ＠ ｾ＠ ｾ＠ ｾ＠ l=fTup:f -q fu& ｾ＠ ｾ＠ NI("!Ch l ｾ＠ ｾ＠ ｾ ｔ Ｍ ｾ＠ -q fcn<n 1T<n ｾＧ＠ Ｓｦｴ｜ｾ＠ l=fTup:f q;r
ｾ＠ ＠ｾ ＾ｲｾＭｴｬＢｑ＠ Ｈ｣ｲｻＮｭ ｾ ＮＩ＠ ｾ＠ ｾ＠ ｧｾｃｨ "Cf{ -Pcn<n ｾ＠ ｬ＠ ｾ＠
ｾ＠ ｾ＠ -q{ ｾ＠ 1
\3b(1 f<Sl li mm ｾ＠ fcnm l=fTm -B -fu-& ｾ＠ ｾ＠
3l R1 f<ffi 3rr<:r "CR cnW 3lcn rr@ ｾ＠ 1

ｾ＠ ＳｬＱｃｦｾ＼Ｚｪｱｩ＠ m, ｾｲｩ･ｬ［＠ ｾ＠ cnT, ＾ｦ ｾＢＧｬ＠ cnr ｾ＠ ｾ＠ ｾ＠ ｾ＠ ｾ＠ lTQ, ｾ＠ -q ｾ＠ ｾ＠ ｾ＠ I

\ifGf CTCf1 \3 ?<1 fuJ (1 ｾ＠ m , ｾ＠ ｡ｾ＠ ｾ＠ ｇｾ＠ 1qct1 wqfBclliA'Cfi :wn -B ｾ＠ ｾ＠ 1
ｾ＠ Ｓｦ｝ｃｾ＠ -m, -m \3q9)ffi ｾ＠ cnr ｾ＠ chlMC!> ＨＱｾ＠ ｾ＠ -pnzy cfilRrtl!> 1
＾ｦｾ＠ ｾ＠ ｾ＠ ｾ＠ ｾ＠ Tfit ｾｔｇ＠ "ffism ｾ＠ 3f.Tffi\ ｾ＠ ｾ＠ I
＾ｬｾ＠ ｾ＠ ｾ＠ cRt l"J1TRT ｾｬｩ＠ ｬ ｪｭｾ＠ cfiT ｾ＠ 1 ｾ＠ CfiTCT ｾ＠ m, en ＾ｦ ｾ Ｂ［ｦ＠ ｾ＠ ｾ＠ cRt T[1TRl cRt ｾ＠ ｾ＠ ｾ＠
ｾ＠ ＳｦｾｭＺ＠ ｾ＠ 1T<n mI ｾ＠ gffil Cfl l "B ｾ＠ ｾ＠ ｾＳｄ＠ ｾ＠ 'IT ｾ＠ Ｓｦｾ ｔ Ｎ＠ cnT ｾ＠ <§'q' it CfiTCT \1fRT ｾ＠ I
QUESTION PAPER SPECIFIC lNSTRUCTIONS
Please read each of the following instructions carefully before attempting questions.
T here are EIGHT questio ns divideJ in Two Sections and p1inted both in HINDI and in ENGLISH.
Candidate has to attem pt FfVE questions in a ll.
Question Nos. 1 and 5 arc compulsory and out of the remaining, THREE are to be attempted choosing
at least ONE questio n from each Section ..
The number.of marks ca n·ied by a questio n/ part is indicated against it.
Answers must b e w ritten in the medium authorized in the Admission Certificate w hich must be stated
clearly on the cover of this Question-cum-Answer (QCA) Booklet in the space provided. No marks will
be given for answers w ritten in m edium other than the authorized one.
Coordinate d iagrams, w herever required, sha ll be drawn in the space provided for answering the
question itself.
Unl ess o therw ise mentioned, symbo ls and notati o ns carry their usua l standard m eanings.
Assume suitabl e data , i [ considered necessary, and indicate the same c learly.
Word lim it in ｱｵ
w herever specified, sho uld be adhered to. ･ｳ ｴｾ ｯ ｮ ｳＬ＠
Attempts of questio ns shall be counted in sequential o rder. Unl ess struc k ofC attempt of a ques tion
sha ll be counted even i r attempted part ly. Any page o r po rtio n of th e page left bla nk in the
Q ucstion-cun1 -Answct Booklet must be <::!early s truck o ff'.

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 Values of fundamental phys(cal constants

Planck's constant h - 6·6262 X 1o- 34 Js

mass of electron m - 9·109 1 X 10-?1 kg ·.
charge on electron e - 1·60210 x 1o- 19 c
velocity of light in a vacuum c - 2·997925 x 108 ms- 1
Avogadro constant NA - 6·022045 x 1023 . mol- 1
Boltzmann constant kB = · 1·3805 X 10- 23 JK- l
Faraday constant F - 96500 C mol- 1
Gas constant R = 8·3 14 JK- 1 mol- 1
rc - 3·14

&O:S 'A' SECTION 'A'

l.(a) ｾ＠ ｾ＠ ? ＠ｾ ｾ＠ ｾｮｩｴ＠
Cf2:fT ｾ＠ ｾ＠ fi<"iH13fi" ｾ＠ ｾ＠ ｾ＠ ＠ｾ ｾ＠ mｾ＠ ｾ＠ ?
co;- 3W1<1 ｾ＠ ｜Ｓｾ Ｑ ｴｩＧＨ ｏｉ＠ "« ｾ＠ o/ ｾ＠ chlMQ\ I
What is resonance energy ｾ＠ What are the conditions which permit structures to
have ｲ･ｳｯｮ｡ｾ＠ ? Discuss resonance taking the example of ion. 10 co;-

ｾＬ＠
dNc = ｾ＠ ｾ＠ c "« (c + de) ｾ＠ ｾＳｉｔ＠ cfiT ｾ＠ ｾ＠
N = ｾＳｉｔ＠ cfiT ¥ ｾ＠ ｾ＠ I
.m = 3l lfik1Cfl ﾷ ｾ＠ ｾ＠ I
T = ｃｨｾＧｩ＠ ｾ＠ ｾ＠ crrq ｾ＠
ｾ Ｎ＠ itm HCfl P"'l cfiT ＾ｉｾ＠ Cf)d w ｾ＠ ｾ＠ fu-o: ｾ｜ｩｪ＠ Cf) ｾ＠ Olj, q ?I ch1 MQ\· I
For an ideal. gas, the distribution 1'!-w of molecular speed is,

• r

· where, .
dNc = Number molecules within the speed range c and (c + de).
N = Total number of molecules. .
m =Molecular mass.
T = Temperature in Kelv.in scale.
Derive the expression of most probable speed of this gaseous system. 10

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l.(c) ¥ C: lt=ltH ｾ＠ (1-l.Jr) cfiT ｾ ｉ＠ ｓｉｾ＠ 'B ｾ＠ ｾ＠ Cf[ff ｾ＿＠ ｾ＠ fcn
1-lJT = -_I_(()1-JJ Cp ()p T , 11
I

Define Joule-Thomson coefficient (1-l.JT ) . What is its unit in SI system? Show that

1-l.JT = __1 (()J-JJ . 10

Cp ()p T, 11

l.(d) (1) "'tfR ｾ＠ Cf)f ｾ＠ ACh iLI Ｈｾ＠ ｾ＠ 'B ) ｾ＠ ｾ＠ I OLI IMI chlMQ) I
( i i) irff ｾ＠ ｾ＠ "t1f?f 'B lTlf ｾ＠ "CR fq 'tl C1 Jl ｾ＠ ｾ＠ irff 31 tll\s') 'i COT o;-t:cfq Ict 'i mm
ｾ＠ I OLI IMI cNMQ) I
(i) Four-phase sulphur system (in equilibrium) is impossible. Explain. 5
(ii) In open container, on heating, solid sulphur melts, but solid iodine sublimes.
Explain. 5

I.( e) ｾ＠ ｾ＠ ｴｦｬ］ｾ ｴ ＧＢｦｬ＠ tilflCh(Ot Ch1 ｾ＠ ｾｊＡｃｨＱ＠ cRt ｭｾＳｄ＠ "ct"m ｾ｣ｦＱｗＭｩｴ＠ ｭｾ＠ ｾ＠ R<ifGQ) 1

0·1 M NaCl Ｈｾ Ｉ＠ MC1Ll'i Ｎ ｾ＠ ｾ＠ 25°C "CR l=fl'c<:f 311LIACh flRhllct l ｾ＠ cnr 4RChC1'i
cf\l!Vic( I ｾ＠ ｾ＠ Allct iCh ＨａＩｾＧ＠ 0·51 mol- 112 L 112 1
Write down the Debye-Hi.ickel limiting equation with symbolic significances and
their units. Calculate mean ionic activity co-efficient of 0· 1 M NaC I (aq) solution
at 25°C. The value of Debye-Hi.ickel constant (A) is 0·5 1 mol- 112 L 112 . 10
'
2.(a) (i) ｾｬ ｬ Ｇｩ｣ｴ ｬ＠ ｾ＠ ｾ＠ tffif Cf[ff m-a ｾ＠ ? ｾ＠ SI ｾ＠ ｾｯｴｊｬ＠ -B ｾ＠ Cf[ff ｾ＠ ? ｾｦ＠
iTfr ｾ＠ ｾｌｬＧｩ｣ｴ＠ ｾ＠ "CR ｾ＠ m
Cf)f flCh i( I, JO!Ch mm ｾ＠ I OLI IM I chlMQ) I
(ii) ｩｨＺ Ｍ Ｓｬｇｾｦ＠ iTfr ｾ＠ ｾＧ＠ GfrlfC1" m cfiT ｾ＠ ｾｬｍｑＩ＠ 1 cths(cll('fl iTfr ｾ＠ ｾ＠ ｾ＠
ｾ＠ ACh iR<iQ) I
( i) What is the dimension of viscosity co-efficient? What is its unit in Sl system?
T he temperature effect on viscosity co-efficient of ideal gas is positive.
Explain. I0
.(ii) Define Boyle temperature of non-idea l gas. Obtain its expression for
van der Waals' gas. 15

2.(b) 2 flr.flr. O!ffi1 ｾ＠ ｾ＠ flclflt=J J"l(Cf)(l ｾｲＵＩｃｦｬ＠ Cf1T "Q)Cfi ｾ＠ -B flt=JCt (cf)Lj ｾ＠ ｾ＠ "C1\
ｾ＠ ｾ＠ (fm -:0\l"tf -B ｱｦ＼Ｚ｣ｴｊｾ＠ ｾ＠ cfiliVIQ) 1 ｾ＠ ｾ ［＠ w:Wr ｾ＠ m "CR ｴ］ｾ＼ｃｨｄ＠ cnr ｾ＠ m
490 dyne c m- 1 ｾ＠ I
Find the change in surface area and energy when two identical mercury droplets of
diameter 2 mm merged isothermally to one drop. Given th at surface tension of
mercury is 490 dyne cm- 1 at ･ｸ ｰ ･ ｲｩｭ ･ ｾｴ｡ ｬ＠ temperature. l0

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2.(c) 298 K -q"\, 3H:P:lljqkFi ｾ＠ 2Cu+ (aq) ｾ＠ Cu(s) + Cu 2+ (aq) ｾ＠ ｾ＠ ｴｩｕｬｃｉｾ＠
ｾ＠ cnr qf.zCfi('i'i chlMQ\ I W %298 K "W1 -q"\

Ecou+;cu = +0·52 V (1'2TI Ecou 2+;cu+ = +0·16

.
V I

Calculate the equilibrium constant for the disproportion reaction :

2Cu-+: (aq) ｾ＠ Cu(s) + Cu 2 + (aq) at 298 K. Given : ｅｾｵ Ｋ＠ !Cu = +0·52 V and

ｅｾｵ Ｒ Ｋ＠ leu+ = +0·16 V at 298 K. 15

3 .(a) ( i) 1:%' Cfitf ｾ＠ 7l1f ｾ＠ cfiT ｾ＠ m?fT cnr, ｦｾＭ ｾ＠ -q"\, m tcrcf: t:rG CR 'Cfio/ ｾ＠ "W1

tR 3lT ｾ＠ ｾ＠ ｉｾ＠ (I) ｾｈＨｦＲｔｉ＠ (II) ｾｇ＠ ｾ＠ ffl. Cfln ｾ＠ ? ｾ｜Ｓｭ＠

"ffl1*r ｾ＠ 'Cfi'RUT ｾ＠ I

(ii) 1:%' ｾ＠ <lfl lltACfi ｾ＠ ｾ＠ ｾ＠ ｾｇ＠ (J mol- 1) cnr ｾ＠ T (K) ｾ＠ tmT ｾ＠

- .
%, ｾｇ］｡Ｋ｢ｔ Ｋ｣ ｔ Ｒ
ｾ＠ a,b (1'2TI ｣ｾ＠ ｾＳｔｨＺ＠ ｔｾ＠ ｾｉ＠

(I) a, b ＨｾＧ＠ c cfiT ｾｃｦｩ＠ Iｾｬｴ＠ i CflfT ｾ＠ ?

(II) ｌ｜ｓＨｦｾ＠ L\H ｾ＠ ｾＧ＠ T ｾ＠ ｾ＠ ﾷ ｾ＠ ｾ＠ ｾＧ＠ ai\JiCfi ｾ＠ chlMQ\ I

(i) At constant pressure, the te'mperature of a fixed amount of hot tea in a cup
.decreases spontaneously to room temperature. What will be the sign of (I) L\H
and (II) L\ G of this process? Give reason(s) in support of your answer. 10

(ii) L\G (J rnol- 1) for an electrochemica l reaction, as a function of temperature,

T (K) is given by L\G = a + bT + ｣ｔ Ｒ
ｾ＠ where a, b ｡ｾ､＠ c are constants and
independent ofT.

(I) What are the units of a, b and c ? and

(II) Find the expressions of L\S and L\H as a function of T. 15

3.(b) ｾｔｃｉＩ＠ -mw ｾ＠ lJffi ｾ＠ cf.T ｾ＠ ｾ＠ ｉｾ＠ SI ｾ＠ ｾｏｉ｣ｴｬ＠ 'B ｾＧｃｦｺｮ＠ ｾ＿＠
Cflt1 ｾ＠ 1:%' m?fT ＠ｾ ｬｊｕｔｾ＠ ｾ＠ ? Cl ｣ｨｾ＠ ｾ ｉ＠ Cl \3'm ｾ＠ I ｾ＠ l1R 'CfiT mrrfcrcr cffi crrB
Cf)RCI1 cnt.=r -B ｾ＠ ?
Define partial molar Gibbs free energy. What is its unit in SI system? Is it intensive
property? Answer with justification. What factors influence its val ue? 10

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3.(c) ｾｒ＼Ｚｭ＠ Cf1T ｾ＠ {iljGI4 it ｦｾｃＺ｣ｴｬＱ＼ｕ ｉ＠ Q1m ｾ＠ 1 0·154 nm ｾ＠ ｾ＠ cfiT X-Rhozon cir
＾ｲｾ＠ coW: Cf1T ｾ＠ ＴＧｚ ｉ ｃｬｊｾ＠ ｳｩｮ･ｾ＠ TfFit 0·225, 0·3 16 ＨＱｾ＠ 0·388 11<:, (100); (110) ＨＱｾ＠
(111) ｾ＠ "B- ｾｔＺ＠ ｾ＠ ｾ＠ I ｾ＠ Rtifc<:'i Cf1T Cl1f (SC or BCC or FCC) ､ｾ＠ ｾ＠ "ffi;r
cfiT m\ C'1 kj I{ Cf)T ｒｾ＠ chl MQ) I

Polonium crystallizes in the cubic ｳｹｾｴ･ｭＮ＠ Using X-ray of wavelength 0·154 nm,
first order Bragg reflections occur at sinG values 0·225, 0·316 and 0·388 from
(100), (1 10) and (111) planes respectively. Determine the class (SC or BCC or
FCC) of the cubic crystal and edge length (a) of unit cell. 15

4.(a) (i) C'ikl 1{ a ｾ＠ "Q,CI1 fcp:fm ｾｩｴ＠ "Q,CI1 CfiUT ｾ＠ ｾ＠ ｾ＠ ､ｾ＠ a/2 ｾ＠ llt"4" ｾ＠ ｾ＠ cfiT
Sll ｾ＠ Cf1 ct I Cf)T q P.zCf1 C'1 '1 chl Ml!\ I

(ii) 1s 31 1f4c:C'1 ｾ＠ ｾ＠ ｾ＠ ｾ＠ ｾ＠ fuf&l!\ 3fR ｾ＠ ｾ＠ O?j)C"Cf?l ch'IMC!\ 1

(i) For a particle in one-dimensional box of length a calculate the probability of its
locating between zero and a/2 . · 15
(ii) Write the complete wave function for ls-orbital and deduce its shape. 10

4.(b) ｎｏｾ＠ 31j1klCf1c-Cl efT, ｾ＠ 31 1fl?c1Cf1 31 1f4c:C'1 311W ｾ＠ ｭｾＬ＠ 04 1<94 1 chlMC!\ I
Explain the paramagnetism of NO with its molecular orbital diagram. 10

4.(c) ｾｌｩ ｬ ｜ｊＱｃｦ｣ｴ ｬ＠ ｾｴＺｲ＠ mJ;:I.-C1 Cf1T ｜ＳＴＱｾ Ｑ＠ ｾ＠ ｾ＠ XeF4 it "G) t:;Cf11chl ｾｃｦｩ［ｈ＠ ｾ＠ cnT ｾ＠
ＶｾＧｚ ｉ ｾｃＡ｜＠ I

·Using valence bond theory justify the presence of two lone electron· pairs in
XeF4 . 15

@O:S 'B' SECTION 'B'

S.(a) ｾ＠ cnTfl cfiT ｭｾ＠ ｾ＠ ｾＧ＠ 3fltA3ffi ｾｬＢｩｃｦＱＧｚｏ ｉ Ｌ＠ ｾ＠ SldlChl ｾ＠ "'1111 ､ｾ＠ SI l1f?lCfi

SJO II &A it ｾ＠ ｾｃｦＱ Ｑ ｾＴＱ＠ f(qfu!cz 1 ｾ＠ P14ct ict1 CfiT ｾ＠ ｾ＠ 11<: ｾｮｊｩ＠ ict l1R "CflfT ｾ＠ ｾ＠ ?
For zero-order reaction, wTite down the Arrhenius equation, indicating n an1e of the
syn1bols and their units in SI systen1. What is high temperature limiting value of
rate constant ? 10

s.(b) . Ｓｾ＠ cfiT J=dMC1 ｾ＠ Ｓｗｾ＠ ｾ＠ ｾ＠ ISC (JRr: HCf11l! ﾢｨ ｬ ｭ ｾｬＩ＠ "CflfT ﾷ ｾ＠ ? ｊｉｃｓｾ｣ｩｬ＼ＫｨＧ＠ ｾ＠
CfiT ｜ＳＴＧＱ ｾ Ｑ＠ Cfi\ ｾ＠ ｾ＠ I
W_hat is ISC (Inter System Crossing) for an excited molecu le in singlet state ?
Answer using Jab lonski diagram. 10

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 I

5.( c) f8n: ｾ＠ -a-qr ffi11 ｾ＠ ｾ＠ lffi CfiT im' ｾ＠ ｾ＠ Ｓｬｦｴｲｾｗｳｵ＠ fcra: -8 \ifffi1 t I W SlltffctCh
ｾ＠ ｾ＠ ｾ＠ (i) ｾＺｊＮｇＬ＠ (ii) b.S -a-qr (iii) b.H ｾ＠ ｾ＠ Cf<:fT ｾ＠ ? 31tR \3m ｾ＠ ｴｭｾ＠
ｾ＠ ｾ＠ cmur ｾ＠ ｣ｨＩｦ｜＾Ｑｾ＠ I
At constant pressure and temperature, adsorption of a gas on solid surface occurs
spontaneous ly. For this natural process, what will be the signs of (i) b. G, (ii) b.S and
(iii) b.H · ? Give reason(s) in support of your answer. 10

5. cd) q.; <\h•n '"' ｾ＠ PI s:'"' R1 ful d :run cRt Oll l &:I I ch1 R>-1 ｾ＠ =

( i) Cp crw:r Cf)l t1 {C1 d I ｾ＠ ｾＨＺＩ＠ ｇｦｾ＠ 1'1 ａｾＧＩ＠ ｾ＠

(ii) ｾ＠ ｾ ｬ ＼ｩｬ ｬ Ｂ｣ｬｦＧｩ＠ eRr ｾ＠ ｾ＠ ｾ＠ 3:iiGffflCf){OI

Explain the following propet1ies of Ferrocene : 10

(i) Easy electrophili c substitution of its Cp ring.

(ii) Oxidation is difficult in comparison to that of cobaltocene .

5.(e) Ｂｷｾ＠ crrr) 3lTlRT CfiT "'!J>klchlL! ｾ＠ >rm: M-rr 31CW<nm ｾ＠ mtrR <R ｾ＠
11R ｾ＠ ftr;;r men t i" Oll l M I ch) f'>i ｾ＠ I
"Magnetic moment of Lanthanide (III) ions is generally different from the value
predicted by spin state." Exp lain. 10

6.(a) (i) ｜ＳＬｾｺｯ ｬ＠ ｾ＠ ｾ Ｎ＠ ｾ＠ c=rm ｾ＠ ｜ＳＬｾｺ ｯ ｬ＠ ｾ＠ ｦ｣ｾ＠ ｾ＠ ｾ＠ 3iRc114' ｾＦｬｕｔ＠ Cf<:fT ｾ＠ ?

. .

(ii) <:lfl li:IRCh ｾ＠ cRt ｦｬｾｌｉｏ ｉ＠ ｾＧ＠ En cfiT mmm ｾ＠ I ｾ＠ ｾ＠ ｾｱｲ＠

ｾ＠ 27°Co/ ＳＰｾ＠ ｾ＠ 25% ｾ＠ ｾ＠ t 3fu: 37°C ｾ＠ ｾ＠ ｾ＠ 10i1=Rc -q
-mm ｾ＠ I E a CfiT 11R SI l1f?fCn >l oIIctl ｾ＠ mer cfi1 f\>1 ｾ＠ I

(i) What are the characteristi cs, essential for catalysis with specific reference to
surface catalysis ? 10

(i i) Define activation energy, £ 0 of a chemical reaction. A gas-phase reaction

completes 25% in 30 min at 27°C and in 10 min at 37°C. Determine the Ea in SI
unit. 15

6.(b) fcR:ft ｾ＠ ｾ＠ ｾ＠ ｾ＠ ＾ｲ｣ｦｬｾｔ＠ CfiT ｜Ｓｙｾｬ ｾｬ＠ cnB o/ ｾ＠ ＧＱｇｬｾ＠ Ｈｾ＠ ｾ＠ 294 g mo l- 1 ) Cfi1

fcl&lL!'i 3i lqfct d ＾ｦｃｩｔｾ＠ ｾ＠ 80% CfiT ｱ ｬ ｻｾ ｬＢＧｩ＠ Cfl{ ｾ＠ t I fCI&lL!'i "ch1- mol L- 1 ｾ＠ fll ...ｾ､ ｬ＠ mer
ｾ＠ I ｾ＠ ｾ Ｌ＠ Ｈ］ｱｇｦｾｬｨ｣ＱｳＺｺ＠ ｾ＠ "ch1- ＾ｦｃｩｔｾｴｭＢ＠ Ｂｙｾ＠ &lkl l{ 1·0 em t 3fu: ＧＱｇｬｾ＠ "ch1-

ＳＱ｣ｦｾｬＡｓｃｨ､ ｬ＠ 2·0 L g- 1 cm- 1 ｾ＠ I

Us ing a particular waveleng th of li g bt, a solution of a substance (molar mass
294 g mol- 1) tran smits 80% of incid ent light. Determine the concentratio n of the
solution in mo l L- 1• Given that optical path length of the ·spect rophotomete r tube
1 1 l0
IS 1·0 em and absorptivi ty of the substance is 2·0 L g- em .

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6.(c) ｾ＠ ·fct<'14<"1 -q NH; 3fi?:R" cfiT 298 K 1R ｬｦｵｾ＠ lo-8 m 2 s- 1 v- 1 ｾ＠ 1 qf\Cfl<"'<i
7·62 x
chlMC!\ ｾ＠ (i) ｾ＠ 'i:l i<'1CflC11 (ii) 25·0 ･ｭｾ＠ 1R fBm ｾＰＱｃｦｬＺｳ＠ ｾ＠ l=ft£1" lTfu <:fR ｾ＠ 1R
15·0 V Cf1f fcrl:rcr wn ｾ＠ \1fT4" I CH COONH ＨｾＩ＠ -q 3ITlAT ｾ＠ ＳｬｒＺ ｴｾｬＱ＼＠ ict1l Cf1f qRCfl<"'<i
3 4
ch1MC( ｾ＠ ｾ ﾷ＠ ｾ＠ -q CH3coo- 3m:Rl cfiT Ｂｩｦｵｾｒ［ｲｭ＠ 4·24 X Io- 8 m 2 s- 1 y - l ｾ＠ I
In aqueous solution, at 298 K, the. mobility of NH; ion is 7·62 x l 8 m 2 s- 1 1. o- v-
Calculate its (i) molar conductivity; (ii) velocity if 15·0 V is applied across
the electrodes of 25·0 em apart. Calculate the transport numbers of the ions in
CH3 COONH4 (aq) solution if the mobility of CH Coo- ion is 4·24 x 1o- 8 m 2 s- 1 v - 1
3
under same condition. 15
7.(a) (i) CllflCfll ｾ＠ ｜ＳＧｾ＼ｃｦｬ＠ cn1 ｦｩ＼］ｴＺｾＢｬ＠ ｾ＠ fuf<51C!\ 3ffi ｾ＠ HCl Ｍ｡ｾ＠ 3i1Cftn\i1<"1 ｾ＠ ｭｾ＠
｜Ｓｱ］ｴＺｾ ｬＴＱ＠ tiCfl<"'<i cnl Ｂｇｾ＠ I
(ii) K4 [Fe(CN)6] -CflT mfi54l1 ＼ｩｬ ｾ＼［ｬｧＩｦ ｩ ｾＺｓ＠ -q ｾ＠ qf{qRfCi ｾ＠ ｾ＠ ? ｓ Ｒ Ｍ ｭｾ＠ ｾ＠ mfi54l"l
<"1, ｾ＼ｩｬ＠ ｧ［ｦｬｾＺｳ＠ cfiT m Rh41 Fc1 f<SI C!\ 1

(i) Write Vaska's catalyst with structure and show its oxidative addition with
HCl and oxygen. 15
(ii) How is K4 [Fe(CN)6] is converted into sodium nitroprusside? Write reaction of
s2
- ion with sodium nitroprusside. .10
7.(b) ｦｬｾ｣ｊＤｨＢ＠ -q ｾ＠ ｾ＠ cfiT ｱｦｻｾＱ＠ ch1MC!\ 1 :it ｾＱｭ ｾＦｩｬｦ｣＼Ｑ＠ ｾ＠ ｾ＠ fu?r ｾ＠ ｾ＠ ? ｾ＠
lJ&l ｾ＠ Cf4T ｾ＠ ?
Define prosthetic group in cytocb.romes. How do they differ from haemoglobin ?
What is their main function ? 10
7.(c) mfuct1l<1 Cfln ｾ＠ ? ｾ＾ｔｉ＠ ｾ＠ ｾ＠ ? Cflt;mR>tCfl<i ｣ｳｴｾ＼Ｑｬ＠ ｾ＠ li'QC"Cltof ｾｴｲｬ］ｉｔ＠ mr
Ｍ｡ｾ＠ ｩＧｪｗｬｾｮ＠Ｓ Cflf crufrr ch1 f'i1 C!\ 1
What are silicones? How are they obtained? Discuss the i1.nportant properties and
applications of organosilicon po lymers. 15
8.(a) (i) ｾ＠ -q WJffi EAN ｾ＠ Cf1f wl Cfln ｾ＠ ? Hklfc1fulC1 ｾ＠ ｾ＠ [Fe(CN) ]4- Ｍ｡ｾ＠ 6
[Fe(CN)6] 3- ｾ＠ EAN ｾ＠ cfiT fiq;c-q<i l ciT "ffi1l chlMC!\ 3ft\ ｾ＠ ｾ＠ cfiT ｾｴｒｮ＠ ｾ＠
ｾ＠ -q m ｈｉｓｃｦｬｾ＠ HCfltfuC!\ 1
(ii) fShte:<"' ｾ＠ ｭｾｉＧＢｃｩ＠ cfiT ｾ Ｑｍ＠ I chlMC!\ ｉｾ＠ ti4l\i1CflC11 3Tf<SFtr ｭｾｴＧＢｃｩ＠ ｾ＠ ｾ＠ ft:r?r ｾ＠ ?
·[CoF6 ] 3- 3i'j1klchl4 ｾ＠ 3ffi [Co(NH) 6 ] 3+ ｾｒｲｫｴ｣ｨｬＴ＠ \ilcstfCh ｾ＠ 3iiSC:lf1<'1chl4 ｾＧ＠
ｾ＠ ｾＲＺﾣＱＧ＠ cnl ｾ＠ ｭＮｾ ｬｲ ｃｩ＠ ｾ＠ ｾ＠ ｾ＠ ｾ＠ ?
(i) What is meant by EAN rule applied to the complexes? Apply the concept of
EAN rule on the fo llowing two complexes [Fe(CN) ]4- and [Fe(CN) ] 3- and
6 6
draw your conclusion about the validity of the rule. 10
(i i) Explain crystal field theory. How does it differ from valence bond theory ?
How does this theory account for the fact that [CoF ] 3- is paramagnetic whi le
6
[Co(NH3 ) 6 ] 3+ is diamagnetic though both are octahedral. 15

7 s th-p-chn1.
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 .
s.(b) ＢｷｾＧｬ＼Ｚｩｳ＠ cfiT ｾＦｮ＠ ｾ＠ ｾｆ･ｴ｣Ｚ Ｇｩｬｴ＠ .q ｾ＠ 311CfttlCf){OI ｾ＠ ｾ＠ ｾ＠ ｾ＠ ｾ＠
3Pl Q\FefC:'"ll<:i"'l cfiT ｾＦｮ＠ ｾｍｭ＠ Ｈｦｾ＠ '"fliSIR14s:t cfiT +2 311CftflCfi{OI ｾＲＱ＠ ｾ＠ ｾ＠
ｾ＠ ｾ＠ 1" 041€41 chlMC( I
"High oxidation states are more common in early actinides than lanthanides but the
. oxidation state for americium
+2 . and nobelium are. more stable relative to those of
other actinides." Explain. 10

S.(c) CR1!f Ｈｦｾ＠ ｾ＠ >fCI1lU i)) ｾｩｴ＠ ｭｾ＾Ｚｲ＠ 'hTti%'!11'1 c:Rtorftmm ｾＧｬ Ｂｃｩ Ｑ ｾ＠ ., ｾｬ＼Ｚｩ｣ｴＱ＠ ':hTtihil'"l ｾ＠
ｾ＠ G1 ｾ＠ ｾＳｉｔ＠ ｾ＠ ｜Ｓｾ Ｑ ｾ＼Ｐ Ｑ＠ ｲｾｦｵＡｃＨ＠ 1

Defme phosphazenes with formulae for ring and chain types. Write two examples
of substitution reactions of cyclophosphazenes. 15

sth-p-chtn 8
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