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FIITJEE

ALL INDIA TEST SERIES


PART TEST – II

JEE (Advanced)-2018-19
PAPER –1

TEST DATE: 18-11-2018


Time Allotted: 3 Hours Maximum Marks: 183

General Instructions:

 The test consists of total 54 questions.

 Each subject (PCM) has 18 questions.

 This question paper contains Three Parts.

 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.

 Each Part is further divided into Two Sections: Section-A & Section-C.

Section-A (01– 07, 19 – 25, 37 - 43) contains 21 multiple choice questions which have one or
more than one correct answer. Each question carries +4 marks for correct answer and –2 mark
for wrong answer
Partial Marks +1 for each correct option provided no incorrect options is selected.

Section-A (08 – 13, 26 – 31, 44 - 49) contains 18 questions. Each of 2 Tables with 3 Columns and
4 Rows has three questions. Column 1 will be with 4 rows designated (I), (II), (III) and (IV).
Column 2 will be with 4 rows designated (i), (ii), (iii) and (iv). Column 3 will be with 4 rows
designated (P), (Q), (R) and (S).
Each question has only one correct answer and carries +3 marks for correct answer and –1 mark
for wrong answer.

Section-C (14 – 18, 32 – 36, 50 - 54) contains 15 Numerical based questions with answer as
numerical value from 0 to 9 and each question carries +3 marks for correct answer. There is no
negative marking.

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AITS-PT-II (Paper-1)-PCM-JEE(Advanced)/19 2

Physics PART – I
SECTION – A
(More Than One Correct Type)
This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for
its answer, out of which ONE OR MORE is/are correct.
 Z
1. 
The electric field in the space is given by E  E0 xiˆ  yjˆ  zkˆ . 
Consider a right circular cylindrical surface whose radius is ‘a’
and height ‘h’, as shown in the figure.
Now choose the correct option(s).

Y
X O

(A) The electric flux through lower circular base is zero.

(B) The electric flux through upper circular top is a2hE0

(C) The electric flux through lateral surface is 2a2hE0

(D) The total electric flux through cylindrical surface is 4a2hE0

Ans. A, B, C

Sol. Let, S1, S2 and S3 be the surface areas of the lower circular base, upper circular top and lateral
surface of the cylinder respectively.
 
1   E.dS  0 …(1)
S1
 
2   E.dS  a2hE0 …(2)
S2
   
3   E.dS  E0  r .dS …(3)
S3 S3

   xiˆ  yjˆ  x2  y 2
 
r .dS  xiˆ  yjˆ  zkˆ . 
 a   dS 
a
dS
 
Putting this value in equation (3), we have
3  aE0  dS  aE0  2ah  2a 2hE0
S3

  Total flux  1  2  3  3 a2hE0

Second Method
  
 E   3E 0     30E0
0 0
Qen  Total charge enclosed within the cylinder = a2h

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3 AITS-PT-II (Paper-1)-PCM-JEE(Advanced)/19

 3 a2h0E0
Q
Total flux = en  3a2hE0
0

2. Consider two current carrying loops in x-y plane, carrying current I1 and I2 respectively as shown
in the figure.

y
D
A C x
B I2
I1
Loop-2
Loop-1

Now consider two arbitrary elementary current elements AB & CD of lengths d 1 and d 2 on the
 
loop-1 and loop-2 respectively. Let dF12 be the force which the current carrying element I2 d 2
 
exerts on the current carrying element I1d 1 & F12 represent the net force on 1st loop by the 2nd

loop, developed due to interaction between current carrying loops. Similarly dF21 be the force
  
which the current carrying element I1 d 1 exerts on the current carrying element I2 d 2 & F21
represent the net force on 2nd loop by the 1st loop, developed due to interaction between current
carrying loops. Choose the correct option(s)
  
(A) dF12  dF21  0
  
(B) dF12  dF21  0
  
(C) F12  F21  0
  
(D) F12  F21  0

Ans. B, C

Sol. dB12  Magnetic field at any point on the elementary element AB due to current carrying element

I2d 2 .
 
 0  I2 d   r12 
dB12  
4  r12 3 

  
  
dF12  I1d 1  dB12  

 0  I1d 1  I2 d 2  r12 
 3
 4  r12
 
The force dF12 will be in the plane of loop and perpendicular to the current carrying element I1d i
(say along p̂12 ).
  

Similarly dF21 

0 I2 d 2  I1d 1  r21  [Say along p̂21 ]
3
4 r21

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AITS-PT-II (Paper-1)-PCM-JEE(Advanced)/19 4

 p̂12 is not parallel to p̂21 , in general


  
So, dF12  dF21  0
  

But F12 
 0I1I2 
d 1  d 2  r12 
4 L L 3
r12
1 2
  

F21 
 0I1I2 
d 2  d 1  r21 .
4 L L1  r 3
21
 2  
Hence, F12  F21  0

3. Consider an isolated sphere of radius ‘b’, made of a material with permittivity 0 and electrical
conductivity , whose volume charge density varies with time t and is given as
 e  t /  if 0  r  a
 0
 0 if a  r  

Where   0 and 0 < a < b. The spherical layer between radii ‘a’ and ‘b’ is neutral. Then choose

the correct option(s).

a3 0
(A) The surface charge density at outer surface of sphere is at t   n2.
8b2

(B) The total current in the region 0 < r < a increases with the radius.

(C) The electric field in the region b < r <  is independent of time.

(D) The total current in the region a < r < b is independent of radius.

Ans. B, C, D

 4 3 t / 
 a 0 e  Q0 e t /  if 0ra
Sol. Q t   3
 0 if a r b
4 3
Here Q0  a 0
3
According Gauss’ Law, we can write
 Q0 r e  t / 
 3
if 0  r  a
 40 a
 t / 
Q e
E   0 2 if a  r  b
 40 r
 Q
0
 2
if b  r  
 40 r
Using conservation of charge we can write surface charge density at the outer surface of sphere
as,
Q  Q t Q0
 0
4 b 2

4b2

1  e t /  
1
If t   n2  1  e  n2  ,
2

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5 AITS-PT-II (Paper-1)-PCM-JEE(Advanced)/19

3
4 3 1 1 a 0
So,   a 0   
3 4b2 2 6b2
J = current density = E
I = current = Jr2
Hence in the region 0  r  a, the volume is source of conduction current while the region a < r <
b has no source of conduction current.

4. The variation of potential along x-axis is shown in the figure. The potential does not vary along
the y-axis or z-axis. Ignore the behaviour at the end points of interval. Now choose the correct
option(s) for given interval –3m < x < 3m.
Vx(in volt)
b
15

e
10

5 c d
X(metre)
–3 –2 –1 0 1 2 3

–5

a –10

(A) The greatest absolute value of Ex is 25 V/m.

(B) An electron is released at point (– 1m, 0), it will move along positive x-axis.

(C) A proton is released at point (1.5 m, 0), it will move along positive x-axis.

(D) An electron is released at point (– 2.5 m, 0), it will move along positive x-axis.

Ans. A, D

Sol. Ex

10/3

x
–3 –2 –1 0 1 2 3

–25

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AITS-PT-II (Paper-1)-PCM-JEE(Advanced)/19 6

5. Three point charges are kept at points A(0, 4a), O(0, 0)


and B(0, –4a) as shown in the figure. A(0, 4a) 5Q

–5Q
X
O P(3a, 0)

(0, –4a)B
+3Q

(A) Work was done on the external agent who assembled these charges in moving them
from infinity to the point.

(B) The electric field at point P is Ep  E X ˆi  E y ˆj, then Ex is negative and Ey is positive.


(C) The electric field at point P is Ep  E x ˆi  E y ˆj, then both Ex and Ey are negative.

975Q
(D) A positive charge has to be put at point P to make the potential energy of system
8
of all four point charges to be zero.

Ans. A, C

Sol. Potential energy of the system is negative so option A E3


is correct
5KQ KQ 3KQ
  53, E1  , E2  , E3  
9 5 25
5KQ KQ 3 3KQ 3 5KQ 24KQ E1 
Ex         0
9 5 5 25 5 9 125
K 4 3K 4 8K
Ey      0 E2
5 5 25 5 125
25Q2 15Q2 5xQ 5Qx 15Q2 3Qx
     0
4 8 5 3 4 5
65Q2 8Qx 5Qx  24  25  x 65Q 65  15Q
  0    x
8 5 3 15 8 8

6. In the circuit shown in figure, the switch S is closed at the moment t C R


= 0. At the moment t = RCn2, the currents through both resistors
are found to be ‘I’. Then choose the correct option(s)

L R

V
(A) I
R

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V
(B) I
2R

L
(C) R
2C

L
(D) R
C

Ans. B, D

V  
Rt
V  RCt
Sol. I1   1  e
 , and
L
I2  e
R  R
According to question at t = RCn2, we have
Rt Rt t
V  V  RCt
  
I1  I2   1  e
  L
e  1  e L
 e RC
…………..( 1)
R  R
t
 1
Given t = RCn2  e RC  e n2  , Putting this value in equation (1), we have
2
L
R
C
Rt Rt
 1  1 Rt R
1 e L   e L    n2   RCn2  n2
2 2 L L

7. A loop is formed by two fixed parallel conductors connected


by a solenoid with inductance L = 2H and a conducting rod of
mass m = 8 kg which can freely slide without friction, over the
conductors. The conductors are located in a horizontal plane v0 x
and in a uniform vertical magnetic field B =  Tesla directed
into the plane of the paper. The distance between the
conductors is  = 2 m. At the moment t = 0, the rod is
imparted an initial velocity v 0 = 2 m/s directed to the right. The
resistance of loop is negligible. Choose the correct option( s)

(A) The rod will perform periodic motion, but not SHM

(B) The rod will perform SHM

(C) The time period of oscillation of rod is 4 s

4
(D) The amplitude of oscillation of rod is metre.

Ans. B, C, D

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AITS-PT-II (Paper-1)-PCM-JEE(Advanced)/19 8

Sol. Suppose that at any instant of time, velocity of the rod is v i d


a
towards right.
The current in the circuit is i. In the figure,
Va  Vb  Vd  Vc
Fm v0 x
i.e. Ldi  Bldx
Integrating, we get Li  Blx
Magnetic force on the rod at this instant is
b c
B2  2
Fm  iB  x … (i)
L

Since, this force is in opposite direction of v , so from Newton’s second law we can write,
 d2 x  B2l2
m 2    x
 dt  L
Comparing this with equation of SHM, i.e.
d2 x
 2 x  0  x  A sin t  v  A cos t … ( ii)
dt 2
Bl
We have,  
mL
2 mL 82
So T  2  2  4s
 Bl  2
v 4
At t = 0, v  v 0  v 0  A  A  0  m
 

(Matching Type)
(Matching type - Single Correct Option)
This section contains SIX questions of matching type. The section contains TWO tables (each having 3
columns and 4 rows). Based on each table, there are THREE questions. Each question has FOUR
options (A), (B), (C), and (D). ONLY ONE of these four options is correct.

Answer 8, 9 and 10 by appropriately matching the information given in the three columns
of the following table.

Two moles of an ideal mono-atomic gas is V


taken through a cyclic process ABCA as C
shown in the V-T diagram. In the process 8V0
BC, TV2 = constant. Answer the questions
by referring to the data in the table.
(Take n  2   0.7 )
4V0 B

V0
A

T0 = 300K 4T0 = 1200K T

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Column –1 shows the processes. Column –2 shows the work done in that process and Column
–3 shows the energy supplied in that process.
Column – 1 Column – 2 Column – 3

(I) AB (i) 1800 R (P) –1800 R

(II) BC (ii) –1260 R (Q) – 3060 R

(III) CA (iii) 900 R (R) 4500 R

(IV) BCAB (iv) 1440 R (S) 1440 R

8. Pick a combination in which work done is maximum

(A) (I) (i) (R)

(B) (II) (i) (P)

(C) (III) (iv) (S)

(D) (III) (ii) (R)

Ans. A

9. Pick a combination in which thermal energy supplied is maximum

(A) (II) (iii) (P)

(B) (IV) (iii) (S)

(C) (I) (i) (R)

(D) (I) (ii) (Q)

Ans. C

10. Pick a correct combination

(A) (I) (ii) (P)

(B) (I) (ii) (Q)

(C) (IV) (iv) (S)

(D) (II) (i) (Q)

Ans. C

Sol.8-10. The equation of the process BC is


TV 2  cons tan t
PV 3  cons tan t
Molar heat capacity of the gas in the process BC is

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AITS-PT-II (Paper-1)-PCM-JEE(Advanced)/19 10

R
 C  CV 
1 x
3R R
  R
2 2
The work done by the gas during the process BC is
nRT 2R  900 
 WBC    900R
1 x 1 3
5R
Q AB  nCpT  2  1200  300   4500R
2
QBC  nCT  2  R 300  1200   1800R
 V 
QCA  WCA  nRT0 ln  0   2R300  3n2   1800R  0.7  1260R
 8V0 
 Wcycle  Qcycle  Q AB  QBC  QCA  4500R  1800R  1260R = 1440 R
Wcycle 1440R
 Efficiency,    100   100  32%
Qsup plied 4500R

Answer 11, 12 and 13 by appropriately matching the information given in the three
columns of the following table.

R2 i2
Vb R1

C qi
ib i1 K

qi is the initial charge on the capacitor. The key K is closed at t = 0


Column – 1 Column – 2 Column – 3
Battery Resistance Capacitance & Initial
charge
R1 = R2 = 5  C = 5 F
(I) Vb = 0 V (i) (P)
R = 10  qi = 0
R1 = 5 
(II) Vb = 30 V (ii) (Q) C = 20 F
R2 = 10 
qi = 0
R = 10 
R1 = 10 
C = 5 F
(III) Vb = –30 V (iii) R2 = 5  (R)
qi = 100 C
R = 10 
C = 20 F
(IV) Vb = 60 V (iv) R1 = R2 = R = 10  (S)
qi = 100 C

11. In which of the following cases, will the current i1 = 5/3 A, initially?

(A) (I) (i) (P)

(B) (II) (iv) (R)

(C) (II) (iv) (P)

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11 AITS-PT-II (Paper-1)-PCM-JEE(Advanced)/19

(D) (I) (iii) (Q)

Ans. B

12. In which of the following cases will the net charge flowing through the capacitor be equal to 300
C?

(A) (II) (i) (S)

(B) (I) (ii) (R)

(C) (IV) (i) (S)

(D) (III) (iii) (P)

Ans. C

13. In which case will the current through R decay exponentially to zero with a time constant of 0.2
ms?

(A) (IV) (ii) (Q)

(B) (I) (iii) (S)

(C) (II) (i) (R)

(D) (I) (iii) (Q)

Ans. B

Sol.11-13. Vb  ibR  i1R1  0


i2R2  q / C  i1R1  0
dq
With i2 
dt
Substituting the given values, we get the result.

SECTION – C
(Single digit integer type)
This section contains FIVE questions. The answer to each question is a single Digit integer ranging from
0 to 9, both inclusive.

14. Inner surface of a cylindrical shell of length  and of material of T1 T2


thermal conductivity k is kept at constant temperature T1 and outer
surface of the cylinder is kept at constant temperature T2 such that
 T1  T2 as shown in figure. Heat flows from inner surface to outer
surface radially outward. Inner and outer radii of the shell are R and
2R respectively. Due to lack of space this cylinder has to be
 R
2R
R

replaced by a smaller cylinder of length , inner and outer radii
2 4
and R respectively and thermal conductivity of material nk. If rate
of radial outward heat flow remains same for same temperatures of
inner and outer surface i.e. T1 and T2, then find the value of n.

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AITS-PT-II (Paper-1)-PCM-JEE(Advanced)/19 12

Ans. 4

Sol. Since rate of heat flow remains same in both the cases, so
2R R
dx dx
R k2 x   R  nk  4k  n = 4

4
nk  2  x  2

15. If the reading of the ideal ammeter connected 10 V 4V 8V 6V


 13 
in the given circuit is n   ampere, find the
 20 
value of n. Assume that the cells have 10  8 A
4 2
negligible internal resistance.

Ans. 3

8 2 2 6 8V 6V
Sol. I = I1 + I2 + I3 + I4 =   8V 10 V 4V
10 8 4 2 O
32  10  20  120 78
 Amp
40 40 10  I1 8  I2 4  I3 2  I4 A
I

O O O
O

16. To disperse all the mass of the Earth to infinity against its own gravitational field would require
2.4  1032J of energy. Mass of the earth is 6  1024 kg and radius of earth is 6400 km. Since earth
is mostly iron, therefore, its specific heat capacity is about 500J kg1 K1. Assuming that the earth
was formed by very cold objects falling from a great distance away, if its maximum possible
temperature soon after its formation is   104 K. Find the value of 

Ans. 8

Sol. 2.4  1032  6  1024  500  T


.4  108 4  105
 T   8  104 K
500 5

17. A conducting sphere of radius a is in side a hollow


conducting sphere of radii 2a and 3a as shown in the 3a
figure. The inner sphere is earthed. The capacitance of
system of sphere and hollow sphere is 5k0a. Find the 2a
value of k.
a A

Ans. 4

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Sol. C1  120 a C1
4 0  b  a 
C2   8 0 a
ba
A B
C eq  C1  C2  200 a
C2

18. A current I = 20 ampere flows through a wire shaped in the form of an infinite parabola of latus

rectum 4a (a = 1 mm). If the magnetic field at the focus of the parabola is   10 tesla, where
 and  are the positive integer, less than 9. Find the value of    .

Ans. 6

Sol. The magnetic field at the focus P of the parabola is d


given by the Biot-Savart law: 

 0 Id   r
B , rd
4  r 3
d r
 
Where r and d l0 are as shown in figure. The
 P
direction of B is perpendicular to the plane of the
parabola and out of it. We note that
 
d  r r d sin  r d d
3
  2  .
r r3 r r
2
Therefore, B   0I / 4    d / r  . The equation of the parabola is r 1  cos    2a, so that
0

0I 2 1  cos   0I 4    107  20


B d     2  103 tesla
4 0 2a 4a 4  103

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Chemistry PART – II
SECTION – A
(More Than One Correct Type)
This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for
its answer, out of which ONE OR MORE is/are correct.

19. Which of the following statement(s) is/are incorrect?

(A) Major part of energy needed for the heterolysis of C – X bond in SN1 reaction mechanism
-
is obtained by the solvation of X by polar protic solvent.

(B) Greater solvation of attacking nucleophile and poor solvation of transition state promotes
the reaction by SN2 mechanism.

(C) Increase in the number of phenyl ring at C of C – X causes a shift in mechanism from SN1
to SN2.

(D) Allyl and benzyl halides shows both SN1 and SN2 reaction.

Ans. B, C

20. Select the correct statements:

(A) NH2 – NH2 does not give Lassaigne’s test for detection of nitrogen.

(B) HCOOH gives (+ve) HgCl2 test.

(C) -D-glucopyranosyl--D-fructofuranose shows muta rotation.

O O
|| ||
(D) NH2  C NH  C NH2 gives Biuret test.

Ans. A, B, D


Sol. HgCl2  HCOOH   Hg  CO2  2HCl
Grey deposit 

21. CH3

Na O
Liq.NH   A  
 Zn  Product
3
3

Which of the following product can be obtained as major product(s) in above reaction?

(A) O O
H C CH2 C H

(B) O O
H3C C CH2 C H

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(C) CHO
H3C HC
CHO

(D) O O
H3C C CH2 C CH3

Ans. A, B

Sol. CH3 CH3


O O
Na O3
   H C
Zn  3
C CH2 C H
Liq.NH3
O O
H C CH2 C H

22. The major product A and B in the following reaction sequence are:
O
 i NaBH
Dimer    ii TsOH  
4
  A  B
(A) O

(B) O

(C) O

(D)
C

Ans. B, D

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Sol. O

O


 4  2 cycloaddition 
O O

NaBH4
OH
H OH
C H
TsOH
CH3 
O O
+
O
O

23. Which of the followings will give cyclic product upon heating?

(A) COOH
H3C CH2 CH2 CH2 HC
OH

(B) OH
H3C CH CH2 CH2 CH2 COOH

(C) OH
H3C CH2 CH CH2 CH2 COOH

(D) OH

H3C CH2 CH2 HC CH2 COOH

Ans. A, B, C

Sol. A will form lactide


O
C O
H9 C4 HC CH C 4H 9
O C

O
B, C form lactone

H3C O O H 5C 2 O O

24. Which of the following are correct statements?

(A) In carboxylate, nucleophile prefer to attack on acyl carbon while in sulfonates nucleophile
prefer to attack on alkyl carbon.

(B) Carboxylate anion is stronger base than sulfonate anion.

(C) Sulfonate anion is a better leaving group than carboxylate anion.

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(D) Carboxylate anion is a better leaving group than sulfonate anion.

Ans. A, B, C

Sol. O O

Nu
R C OR   R C Nu  R  O

O O
Nu 
R S OR 
 R S O  R  Nu
O O
Sulfonoic acid is stronger acid than carboxylic acid.

25. Which of the following statement(s) is/are correct?

(A) Sucrose has a pyranose and a furanose ring hold together by glycosidic linkage.

(B) Maltose has one glycosidic linkage and free hemiaccetal form

(C) Glucose, fructose and galactose forms same osazone

(D) 

Go for reaction,   D  Glucose 
   D  Glucose, is positive .

Ans. A, B



  D  Glucose 
   D  Glucose
Sol.
36% 64%
64% 16
K eq    1.77
36% 9
Go  2.303RT logk eq   ve

(Matching Type)
(Matching type - Single Correct Option)
This section contains SIX questions of matching type. The section contains TWO tables (each having 3
columns and 4 rows). Based on each table, there are THREE questions. Each question has FOUR
options (A), (B), (C), and (D). ONLY ONE of these four options is correct.

Answer Q. 26, Q. 27 and Q. 28 by appropriately matching the information given in the three
columns of the following table.

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Column 1 Column 2 Column 3


(I) (i) NH2 (P) Give ppt. when
 3i CH  CH CH  Cl/Anhyd. AlCl treated with Br2/H2O

2 2
 ii O2 /h
3

 iii H

(II) (ii) O (Q) In presence of strong


i  BuLi base self

O C H
|| disproportionation
 ii  H C H/H
 iii PCC reaction takes place

(III) (iii) OH (R) Form foul smelling


i  BuLi compound with

O
|| CHCl3/NaOH
 ii  H C H/H
 iii PCl5
 iv  NH3

(IV) (iv) H2 C NH2 (S) Form acetyl


 i  CH3Cl/AlCl3 derivative with
  ii  Cl2 , h 
 iii  NaNH2 O
||
R  C Cl / Pyridine

26. Which of the following combination is CORRECT for I ?

(A) (I) (ii) (R)

(B) (I) (iii) (P)

(C) (I) (ii) (P)

(D) (I) (iii) (Q)

Ans. B

27. Which of the following combination is CORRECT?

(A) (II) (ii) (Q)

(B) (II) (ii) (R)

(C) (III) (ii) (R)

(D) (IV) (i) (Q)

Ans. A

28. Which of the following combination is CORRECT for IV ?

(A) (IV) (i) (P)

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(B) (IV) (iv) (R)

(C) (IV) (i) (R)

(D) (IV) (i) (Q)

Ans. B

Answer Q. 29, Q. 30 and Q. 31 by appropriately matching the information given in the three
columns of the following table.

Column 1 Column 2 Column 3


(I) Novolac (i) OH (P) Cross linked

 HCHO

(II) Bakelite (ii) O (Q) Linear chain


H2 C CH CH2
O 
OH OH OH

(III) Dacron (iii) COOH (R) Branched


chain
H2C CH2

OH OH

COOH

(IV) Glyptal (iv) NH2 (S) Fibre

 Formaldehyde

29. Which of the following combination is CORRECT for Glyptal?

(A) (IV) (ii) (P)

(B) (IV) (ii) (Q)

(C) (IV) (iv) (P)

(D) (IV) (i) (P)

Ans. A

30. Which of the following combination is CORRECT for Bakelite?

(A) (II) (i) (Q)

(B) (II) (i) (P)

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(C) (II) (iv) (R)

(D) (II) (iv) (P)

Ans. B

31. Which of the following combination is CORRECT?

(A) (IV) (iii) (P)

(B) (I) (iv) (P)

(C) (III) (iii) (S)

(D) (II) (iii) (S)

Ans. C
SECTION – C
Single Integer Answer Type

This section contains 5 questions. Each question, when worked out will result in one integer from 0 to 9
(both inclusive).

32.
KOH

EtOH
Br 
A B C
1.99 gram of A on above reaction produces 1.062 gram mixture of B and C ratio of 2 : 1. if
percentage of B formed will be x % then find the value of x/10.

Ans. 6

118  1.99
Sol. The theoretical yield will be   1.18 gram
199
1.062
Hence percentage yield will be   100%  90%
1.18
2
Hence, B formed will be  90%   60%
3
x = 6.

33.
NH2
NaNO2
HCl,   A
 B

COOH
What is the double bond equivalent of B.

Ans. 6

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Sol.
NH2

COOH

34. How many of given below compounds will form red colour with HNO2 and followed by addition of
NaOH?
(CH3)2CHNO2, CH3CH2-NO2, (CH3)3NO2,

H
C NO 2
NO 2 ,
,
H3C HC NO 2

Ans. 1

Sol. HNO2
CH3  CH2  NO 2  NaOH
 CH3  C  NO 2   CH3  C  NO2
+
N OH N ONa
Nitrolic acid Red colour

35. Find the number of nucleophile whose nucleophilicity is greater than pyridine in SN2 reaction
RS  , ArS  ,I ,CN ,OH ,F ,NO3

Ans. 5

Sol. RS , ArS ,I ,CN ,OH

36. i Ph P CHCOOEt


Ph  CHO  3
ii LiAlH ,Et O 78o C
 A 
4 2

 i TsOH
ii A  B 

O
How many oxygen atoms are there in B.

Ans. 2

Sol. O

Ph  P CHCOOEt C
Ph  CHO 
3
 Ph LiAlH4
OEt Ph OH
A
O
 i TsOH
  ii  A  Ph O
O

B

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Mathematics PART – III

SECTION – A

(More Than One Correct Type)


This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for
its answer, out of which ONE OR MORE is/are correct.

tanb     
37. If obtuse angle bisectors of the lines tan2 bx + 4y + 7 = 0 and x  y2 0;  b    ,   is
4   2 2 
 tanb 
 x  y  2
tan2 bx  4y  7 4
   , then b can lie in the interval
tan4 b  16 2
tan b
1
16

   
(A)   4 ,  12 
 

  
(B)  4, 0
 

   
(C)   12 ,  18 
 

  
(D)  12 , 4 
 

Ans. A, B, C

Sol. a1a2 + b1b2 < 0


 tan2 b + tan b < 0

 b0
4

38. The global minimum value of


|cot x – 1| + |cot x – 2| + |cot x – 31| + |cot x – 32| + |cot x – 24| + |cot x – 5| + |cot x – 6|
+ |cot x – 17| + |cot x – 8| + |cot x – 9| + |cot x – 10| + |cot x – 11| + |cot x – 12|

occurs at x  sec 1   , then INCORRECT statements is/are (where [.] denotes the greatest

integer function)

(A)     31

(B) [ + ] = 18


(C)    2
 

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 2 
(D)    11
  

Ans. A, B, C, D

Sol. Minimum sum occurs at cot x = 10


 101 
 x = sec 1 
 10 
 

 4x 
39. If f  x   sin1   , then
 4  x2 

(A) f  
8  2    2 tan1  2 1 
2
(B) f  12  3   3

 3  1  3 
(C) f     2 tan  
 8 2  8 2


(D) f       2 tan1  
 2

Ans. A, B, C, D

 1  x 
   2 tan   ; x  2
  2
 4x   x
Sol. sin1  2 
  2 tan1   ; 2  x  2
 4  x   2
 x
   2 tan1   ; x2
  2

40. Minimum value of 2x 2  2x  1  2x 2  10x  13 is  , then

(A)  is an even number

(B) sum of digits of  is 2

(C) number of prime factors of  is 2

(D) number of prime factors is 3

Ans. A, B, C

Sol.    12     2  2 2     2 2     2  5 2
Line is y = x + 2 and P(,  + 2) is any point on this line and A  (2, 5) and B(–1, 2)

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41. Let ABC be a triangle and D be the mid-point of side BC. Suppose DAB = BCA and DAC =
15º, then

(A) ADC is obtuse

(B) ADC is acute

(C) if O is the circumcentre of ADC, then AOD is equilateral

(D) if O is the circumcentre of ADC, then triangle AOD is isosceles

Ans. A, C

AD BD CD AD
Sol.  , 
sinB sin  sin 15º  sin 
Finally, we get ADC is obtuse

42. A hexagon inscribed in a circle has three consecutive sides of length 3 and three consecutive
sides of length 5, and then the radius of the circle is

7
(A)
3

5
(B)
2

(C) 2 3

(D) 4

Ans. A

Sol. Let the hexagon be ABCDEF with AB = BC = CD = 3 and DE = EF = FA = 5


So, AOB = BOC = COD =  and DOE = EOF = FOA = 
So,  +  = 120º
 
Now, 3  2r sin   and 5  2r sin  
2  2
 120º     9  3 7
5  2r sin   ; 5  r  3 1  2    ; r 
 2    4r  2r  3

20 20

43. If S    tan1   , then S is equal to
1  1 

(A) 100 

(B) 300 

(C) 400 

(D) 225 

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Ans. A

20 20
   
Sol. S    tan1   =  20     190  100
1  1   4 2

(Matching Type)
(Matching type - Single Correct Option)
This section contains SIX questions of matching type. The section contains TWO tables (each having 3
columns and 4 rows). Based on each table, there are THREE questions. Each question has FOUR
options (A), (B), (C), and (D). ONLY ONE of these four options is correct.

Answer Q. 44, Q. 45 and Q. 46 by appropriately matching the information given in the three
columns of the following table.

Column-1: contains the curve; Column-2: number of irrational points on the curve; Column-3: number of
integral points on the curve (irrational points means both coordinates are irrational and integral points
means both coordinates are integer)

Column-1 Column-2 Column-3


x2 y2
(I)  1 (i) infinite (P) 2
9 4
x2
(II)  y2  1 (ii) 800 (Q) 4
35
(III) x2 – y2 = (200)2 (iii) 200 (R) 30
(IV) x4 – y4 = 2401 (iv) 16 (S) 100

44. Which of the following combination is CORRECT?

(A) (IV) (i) (P)

(B) (IV) (i) (R)

(C) (III) (i) (Q)

(D) (IV) (ii) (S)

Ans. A

45. Which of the following combination is CORRECT?

(A) (III) (i) (Q)

(B) (III) (ii) (R)

(C) (III) (i) (R)

(D) (I) (i) (P)

Ans. C

46. Which of the following combination is INCORRECT?

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AITS-PT-II (Paper-1)-PCM-JEE(Advanced)/19 26

(A) (IV) (i) (P)

(B) (III) (i) (Q)

(C) (II) (i) (P)

(D) (IV) (ii) (S)

Ans. D

x2
Sol. (II) For
35
 y2  1 ,  35 cos , sin  
 35 k 35 
Let tan   k 35   , 2 
 
 1  35k 1  35k 
2

1  35k 2 1
Let  k  , k 2  k 2 
35 35
1
 k   k k   k   infinite possible ways
35
(III) For x2 – y2 = (200)2, (x – y)(x + y) = 24  54
Let (x > 0, y > 0) assign one 2 to each (x + y) and (x – y)
35 1
Now, number of ways = 7
2
So, total integral points = 30
(IV) Number of integral points on x4 – y4 = 2401 is 2

Answer Q.47, Q.48 and Q.49 by appropriately matching the information given in the three columns
of the following table.

Column-1: contains conics; Column-2: number of common tangents; Column-3: number of common
normals

Column-1 Column-2 Column-3


(I) 2y2 = 2x – 1 and 2x2 = 2y – 1 (i) 0 (P) 0
2 4  3
(II)  y  1   x   and
3 4 
2 (ii) 1 (Q) 1
 3
 x   2
 4   y  1
 1
9 3
2 2
(III) x = y – 2 and y + x – 2x + 3 = 0 (iii) 2 (R) 2
2 2
(IV) y = –4x and x = –4y (iv) 3 (S) 3

47. Which of the following options is the only CORRECT combination?

(A) (I) (iv) (Q)

(B) (I) (iv) (S)

(C) (II) (i) (S)

(D) (II) (ii) (S)

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27 AITS-PT-II (Paper-1)-PCM-JEE(Advanced)/19

Ans. A

48. Which of the following options is the only CORRECT combination?

(A) (IV) (i) (Q)

(B) (IV) (i) (P)

(C) (IV) (ii) (Q)

(D) (I) (iv) (P)

Ans. C

49. Which of the following options is the only INCORRECT combination?

(A) (III) (iii) (Q)

(B) (II) (i) (S)

(C) (II) (iii) (S)

(D) (IV) (ii) (Q)

Ans. B

Sol. (I) 2y2 = 2x – 1 and 2x2 = 2y – 1


 1 1
Equation of tangents are y  m  x   
 2  4m
2
1 m
and y   mx  respectively
2 4
m 1 1 m2
So,     ; m3 – 2m2 – 2m + 1 = 0
2 4m 2 4
This equation has 3 real and distinct roots i.e., 3 common tangents
For common normals they are symmetric about y = x
So, only one common normal
4 x2 y2
(II) After shifting at origin, we get y 2  x and  1
3 9 3

Equation of normals are y  mx 


2
m
1 3
m and y  mx 

m a2  b2 
3 3 2 2 2
a b m
2 1 3 6m
So, m m  ; m = 0, 1. Hence, 3 common normals
3 3 9  3m2
m2
(III) y = x2 and y = –(x – 1)2 equation of tangents are y = mx –
4
m2
and y  m  x  1  respectively
4
So, we get m = 0, 2; 2 common tangents
1 1 1 1
Common normals: equation are y  mx   and y  mx  m  
2 4m2 4m2 2
3 2
So, we get 2m + 2m + 1 = 0 only one real root is 1 common normals

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AITS-PT-II (Paper-1)-PCM-JEE(Advanced)/19 28

(IV) y2 = –4x and x2 = –4y


Number of common tangents will be same
2 2
For y = 4x and x = 4y only one common tangents
3 1
Common normals: 2m + m = 2  2
m
f(m) = m5 + 2m3 + 2m2 + 1 only one root negative
So, only one common normals

SECTION – C
(One Integer Value Correct Type)

This section contains 5 questions. Each question, when worked out will result in one integer from 0 to 9
(both inclusive).

3x  2
50. If a chord AB of the curve y  is a normal to the curve at a point A, subtending an angle 
x2
sin    PAB 
at the point P(2, 3). Then the value of is equal to _____
sin    PAB 

Ans. 3

Sol. Shift the curve so that centre is origin, xy = 4  c


1 1 1 1  t4 A  ct1, 
 t 2  3 ; m  OA   2 , m  OB   2  t16 ; tan   2 1  t1 
t1 t1 t2 t1
1 0(0, 0)
t12  B
t12 t14  1
Also, tan  OAB     c
1 1 2t12  ct 2 , 
 t 2 
tan 
  2
tan  OAB 
sin    A 
So, 3
sin    A 

51. Assuming that no three circles passing through same points and every two circles intersects in
two distinct points. If the number of regions that points are created by 7 mutually non over-lapping
circles in a plane is 11k, then k is _____

Ans. 4

Sol. Tn = Tn – 1 + 2(n – 1): n  2


Tn = n2 – n + 2
T7 = 72 – 7 + 2 = 44
2 2
52. The combined equation of the principal axes of the hyperbola 2x + 12xy – 7y – 16x + 2y – 5 = 0
is ax2 + 2hxy + by2 – x + 7y + c = 0, then |a + b – 2h + c| is equal to _____

Ans. 6

Sol. c  (1, 1); The axes are the bisectors of the angle between the asymptotes

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29 AITS-PT-II (Paper-1)-PCM-JEE(Advanced)/19

 x  12   y  12 2   7 
So, 
 x  1 y  1 6
2 2
2x – 3xy – 2y – x + 7y – 3 = 0

x2 y2
53. From the point (1, 1) normals are drawn to the ellipse   1 , then locus of conormal points
9 4
2 2
is 1xy + 2x + 3y + 4x + 5y + 6 = 0, then 1 + 2 + 3 – 4 – 5 – 6 is equal to _____

Ans. 0

x  x1 y  y1 Q(x2, y2) P(x1, y1)


Sol. Equation of normal at P(x1, y1); 
x1 y1
2
a b2
2 2 2 2 A(h, k)
 (a – b )x1y1 + b yx1 – a xy1 = 0
Point (h, k) lies on it
So; (a2 – b2)x1y1 + b2kx1 – a2hy1 = 0
h(x3, y3) s(x4, y4)
Similarly, for points Q, R and S are
2 2 2 2
(a – b )x2y2 + b kx2 – a hy2 = 0
(a2 – b2)x3y3 + b2kx3 – a2hy3 = 0 and (a2 – b2)x4y4 + b2kx4 – a2hy4 = 0
Thus, P, Q, R, S lie on the curve (a2 – b2)xy + b2kx – a2hy = 0 i.e., 5xy + 4x – 9y = 0

54. Three circles C1, C2 and C3 with radii 2, r, 8 respectively are given. They are placed such that C2
lies to the right of C1 and touches it externally, C3 lies to the right of C2 and touches it externally.
Further, there exist two straight lines each of which is a direct common tangent simultaneously to
all three circles, then r is _____

Ans. 4

Sol. r  28

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