Neraca Massa Proses Pembuatan Etanol dari Molase

MO1 101 Komponen M01 M12 M11

abu 5.05 4.55 0.51
molase 95.95 0.45 95.50
C6H12O6 0 0 0
Etanol 0 0 0
air 0 0 0
yeast 0 0 0
H2SO4 0 0 0
NH2SO4 0 0 0
Vinase 0 0 0
Total 101.00 5.00 96.00

M11= 101.00 M21=

1. Tangki Filter Press

Neraca massa total
M11 M01 = M11 + M12
abu
M01 molase Neraca massa komponen
abu M12
molase abu M01: abu = 0,05*M01
molase molase = 0,95*M01

M11: abu = 0,9*M01

molase = 0,1*abu(M11)

M12: abu = abu(M01)-abu(M11)

molase = molase(MO1)-mola

2. Tangki Berpengaduk (RATB)

M02 Neraca massa total
Air M11 = M02 + M12

M11 M21 Neraca massa komponen

abu abu
molase molase M21: abu = abu(M12)
C6H12O6 molase = 0,02*molase(M12)
 C6H12O6 = 2*0,98*molase(

M02: air = 0,98*molase(M12)/342

3. Heat Exchanger
Neraca massa total
M31 = M21
M21 M31
abu abu Neraca massa komponen
molase molase M31: abu = abu(M21)
C6H12O6 C6H12O6 molase = molase(M21)
C6H12O6 = C6H12O6(M21

4. Heat Exchanger
Neraca massa total
M41 = M31
M31 M41
abu abu Neraca massa komponen
molase molase M41: abu = abu(M31)
C6H12O6 C6H12O6 molase = molase(M31)
C6H12O6 = C6H12O6(M31
Molase
M21 M02 M31 M41 M03 M51 M04 M05 M06
0.51 0 0.51 0.51 0 0.51 0 0 0
1.91 0 1.91 1.91 0 1.91 0 0 0
98.51 0 98.51 98.51 0 98.51 0 0 0
0 0 0 0 0 0 0 0 0
0 4.93 0 0 492.56 492.56 0 0 0
0 0 0 0 0 0 0 0 0.99
0 0 0 0 0 0 0 0.49 0
0 0 0 0 0 0 0.10 0 0
0 0 0 0 0 0 0 0 0
100.93 4.93 100.93 100.93 492.56 593.48 0.10 0.49 0.99

100.93 M51= 593.48 M61=

5. Tangki Pencampuran
M03
air

komponen
M41 M51
abu = 0,05*M01 abu abu
molase = 0,95*M01 molase molase
C6H12O6 C6H12O6
abu = 0,9*M01 air
molase = 0,1*abu(M11)

abu = abu(M01)-abu(M11)
molase = molase(MO1)-molase(M11) 6. Tangki Fermentor
M05
M04 H2SO4 M06
NH2SO4 yeast
M61
abu
komponen molase
M51 etanol
abu = abu(M12) abu air
molase = 0,02*molase(M12)/342*342 molase yeast
C6H12O6 = 2*0,98*molase(M12)/342*180 C6H12O6 C6H12O6
air
air = 0,98*molase(M12)/342*18

7. Tangki Evaporator
M71 Neraca massa total
etanol M61 = M71 + M07
air
komponen M61 Neraca massa kompone
abu = abu(M21) abu
molase = molase(M21) molase M71:
C6H12O6 = C6H12O6(M21) etanol
air
yeast M72:
C6H12O6 M72
abu
molase
komponen yeast
abu = abu(M31) air
molase = molase(M31) etanol
C6H12O6 = C6H12O6(M31) C6H12O6
 M61 M71 M72 M81 M82
0.51 0 0 0 0
1.91 0 0 0 0
1.97 0 0 0 0
96.54 91.71 4.83 89.60 2.11
492.56 214.00 278.56 4.72 209.28
1.58 0 0 0 0
0 0 0 0 0
0 0 0 0 0
0 0 5.96 0 0
595.06 305.71 289.35 94.32 211.40
595.06 94.32 211.40
595.06 305.71 595.06

8. Destilasi Fraksional
Neraca massa total Neraca massa total
M51 = M41 + M03 M71 = M81 + M82

Neraca massa komponen M71 M81 Neraca massa komponen

etanol etanol
M03: air = 5*C6H12O6(M14) air air M81:
M82
M51: abu = abu(M41) etanol
molase = molase(M41) air
C6H12O6 = C6H12O6(M41) M82:
air = air(M03)

Neraca massa total

M61 = M51+M04+M05+M06

Neraca massa komponen

M61: abu = abu(M51)

molase = molase(M51)
etanol = 0,98*C6H12O6(M51)
air = air(M51)
 yeast = NH2SO4(M04)+H2SO4(M05)+yeast(M06)
C6H12O6 = 0,02*C6H12O6(M51)
Konsentrasi etanol = etanol/M61

Neraca massa total

M61 = M71 + M07

Neraca massa komponen

etanol = 0,95*0,3*etanol(M61)
air = 0,95*0,7*etanol(M61)

abu = abu(M61)
molase = molase(M61)
yeast = yeast(M61)
etanol = etanol(M61)-etanol(M71)
air = air(M61)-air(M71)
C6H12O6 = C6H12O6(M61)
Neraca massa total
M71 = M81 + M82

Neraca massa komponen

D = (xf-xb)*M71/(xd-xb)
etanol = 0,95*D
air = 0,05*D

E = (xd-xf)*M71/(xd-xb)
etanol = 0,01*E
air = 0,99*E
 M01 1 M11 M2
Abu 5% 2
Tetes 95% 1% Abu
99% Tetes

M12
2% Tetes
98% Abu

1. Filter pres 4. Heat Exchanger

Untuk menyaring abu yang terkandung dalam molases Tempat terjadinya pendingi
NM TOTAL : M01 = M12 NM TOTAL : M31 = M41

2. Reaktor Berpengaduk 5. Mixer

Tempat terjadinya reaksi Tempat terjadinya pencamp
NM TOTAL : M12 + M02 = M21 NM TOTAL : M41 + M03

6. Fermentor

3. Heat Exchanger 7. Evaporator

Tempat terjadinya sterilisasi dengan suhu 110˚C Tempat terjadinya evaporas
NM TOTAL : M21 = M31 NM TOTAL : M51 = M61
 M02 M04
M03

M3 M4 M5
3 4 5

M05

4. Heat Exchanger 8. Kolom Destilasi Fraksionasi

Tempat terjadinya pendinginan (30˚C) Tempat pemurnian
NM TOTAL : M31 = M41 NM TOTAL : M61 = M71 + M72

Tempat terjadinya pencampuran

NM TOTAL : M41 + M03 + M04 + M05 = M51

6. Fermentor

7. Evaporator
Tempat terjadinya evaporasi
NM TOTAL : M51 = M61 + M62
 Kapasitas 1500
Abu 0.05
Tetes 0.95
Komponen
M61 M72 Tetes
6 7 Vinase Abu
sisa air 0.4 Glukose
etanol 1% 0.05 Air
0.6 60% air sisa air 0.4 Etanol
0.95 95% etanol M71 (NH)2SO4
H2SO4
Yeast
8 M82 TOTAL
M01

M11
Air
etanol M81 M12

8518.2968
9564.7625

atau
M01.X01 Abu = M11.X11 Abu + M12.X12 Abu
M01.0,05 = M11.0,01 + (M01-M11) 0,98
M01.0,05 = M11.0,01 + M01.0,98 - M11.0,98
0,93M01 = 0,97M11
M11 1438.1443
0.93 0.97 Hidrolisis
M2(glukosa) = 0,98 x M11
M2(tetes) = 0,02 x M11 tet
M2 (abu) = M11 (abu)

Fermentor
15% dari campuran glukos
0.15
 1438.1443298969 61.855670103
M01 H (entalpi) M01xH01 M11 (F) Enthalpi M11 M11xH11 M12 ( C )
1425 -2311098.0890065 -3293314777 1423.7628866 -2311110.17945 -3290472900 1.2371134
75 -941086.06338606 -70581454.75 14.381443299 -941092.450526 -13534267.72 60.618557
0 0 0
0 0 0
0 0 0
0 0 0
0 0 0
0 0 0
1500 -3252184.1523925 -3363896232 1438.1443299 -3252202.62998 -3304007168 61.85567
Abu 0.05
Tetes 0.95
Abu 0.01 Total air + etanol (feed) - etanol
Tetes 0.99 Total air + etanol (feed)
Abu 0.98
Tetes 0.02

-3252184.152 -6435685.0881
-3363896232 -3381759641.85

Abu Filtrat
M01 x

M01
M01
M01
M01

terkonversi 98% tetes (tetes berubah menjadi glukosa) TETES FILTRAT

glukosa) = 0,98 x M11 tetes M01 x
tetes) = 0,02 x M11 tetes
(abu) = M11 (abu) M01
M01
M01
% dari campuran glukosa menjadi etanol M01
 5 0.01 0.01 0.01
kali glukosa kali GL kali GL kali GL
GL : Air
M2 Enthalpi M2 M2xH2 M3 M4 M02 (air)
28.475257732 -2268328.5264 -64591239.41 28.475258 28.475257732 0
14.381443299 -915153.93176 -13161234.38 14.381443 14.381443299 0
1395.28762887 1395.2876 1395.287628866 0
0 0 0 6976.4381443
0 0 0 0
0 0 0 0
0 0 0 0
0 0 0 0
1438.1443299 -3183482.4581 -77752473.79 1438.1443 1438.1443298969 6976.4381443

xf
ol (feed) - etanol 7115.96690722 xd
8371.7257732 xb

139.52876289

X01 (abu) = M11 x X11 (abu) +

0.05 = M11 0.01

0.05 = M11 0.01
0.05 = M11 0.01 M01
-0.93 = M11 -0.97
M11 = 1438.1443299 Massa Abu Filtrat

X01 (tetes) = M11 x X11 (tetes) +

0.95 = M11 0.99

0.95 = M11 0.99
0.95 = M11 0.99 M01
0.93 = M11 0.97
M11 = 1438.1443299 Massa Tetes Filtrat
M03 (Nh2SO4M04 (H2SOM05 (yeastM5 M6 M71 M72 M81 M82
0 0 0 28.475258 28.475258 0 28.475258 0 0
0 0 0 14.381443 14.381443 0 14.381443 0 0
0 0 0 1395.2876 1185.9945 0 1185.9945 0 0
0 0 0 6976.4381 6976.4381 4185.8629 2790.5753 60.594818 4125.2681
0 0 0 0 1255.7589 1192.9709 62.787943 1151.3015 41.669374
13.95287629 0 0 13.952876 13.952876 0 13.952876 0 0
0 13.952876 0 13.952876 13.952876 0 13.952876 0 0
0 0 13.952876 13.952876 13.952876 0 13.952876 0 0
13.95287629 13.952876 13.952876 8456.4411 9502.9068 5378.8338 4124.073 1211.8964 4166.9374
dxb d0,01 1139.1826
0.221789883 X71 0.2217899 dxd d0,95
0.95 M81 0.94 D 1211.8964
0.01 0
B 4166.9374
5378.8338 53.788338
1139.1826 air 5% 60.594818 1151.3015
1211.8964 air 99% 4125.2681 41.669374

M12 x X12 (abu)

M12 0.98
(M01-M11) 0.98
0.98 - 0.98 M11

= 14.381443

M12 x X12 (tetes)

M12 0.02
(M01-M11) 0.02
0.02 0.02 M11

= 1423.7629
fxf 1192.9709 dxd 1151.3015
fxb 53.788338

1211.8964 0.95
4166.9374 0.01
Komponen M01 Enthalpi M01 M01xH01 M11 (F)
Tetes 1425 -2311098.08900647
Abu 75 -941086.063386057
Glukose 0 0
Air 0 0
Etanol 0 0
(NH)2SO4 0 0
H2SO4 0 0
Yeast 0 0
TOTAL
P (bar) 1.5
T°C 28
Enthalpi M11 M12 ( C ) Enthalpi M12 M2 M3 M4
-2311110.179453 -2268328.52636
-941092.4505263 -915153.931763
0
0 0 0 0
0 0 0 0
0 0 0 0
0 0 0 0
0 0 0 0

1 1.2
28 120
M02 (air) M03 (Nh2SO4M04 (H2SOM05 (yeastM5 M6 M71 M72
0 0 0 0 0
0 0 0 0 0
0 0 0 0 0
0 0 0
0 0 0 0 0
0 0 0 0
0 0 0 0
0 0 0 0
M81 M82
0 0
0 0
0 0

0 0
0 0
0 0
 Mole Fraction of ethanol in % w/w %V/v
Temperature (°C)
Liquid (x) Vapor (y) Liquid Vapour Liquid
78.15 0.8943 0.8493 95.6 95.6 97.2
78.41 0.7472 0.7815 88.4 89.3 92.1
78.74 0.6783 0.7385 84.2 87.8 88.9
79.3 0.5732 0.6841 77.4 84.7 83.3
80.7 0.3965 0.6172 62.7 80.1 70.2
82.3 0.2608 0.558 47.4 76.3 55.2
84.1 0.1661 0.5087 33.7 72.6 40.5
86.7 0.0966 0.4375 21.5 66.5 27.5
89 0.0721 0.3891 16.6 61.9 20.4
95.5 0.019 0.17 4.7 34.4 5.9
100 0 0 0 0 0

M81 76.0263114438
M82 97.6033297494
%V/v
Vapour 100
97.2 - 468.617583442x^5 +- 1069.6624908587x^4
f(x) = 2061.2783379159x^6 6166.7721701986x^5 -+ 805.5937139216x^3
7276.392166835x^4 +- 223.4906649826x^2
4312.3543609655x^3- +45.9435047524x + 99.9976219384
1360.744671911x^2 - 231.1532409036x + 99.7829988806
R² = 0.9998615628
0.9994353595
92.8 95
91.2
87.2
90
85.6
82.4
85
Axis Title

Liq (x)
79.2
Polynomial (Liq (x))
77.8 Vapour
80
67.6 Polynomial (Vapour)
41.2
75
0

70
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Axis Title
Diagonal
X Y Liquid (x) Vapor (y) % w/w
0 0 0.8943 0.8493 Liquid Vapour
1 1 0.7472 0.7815 0.956 0.956
0.6783 0.7385 0.884 0.893
Enriching 0.5732 0.6841 0.842 0.878
X Y 0.3965 0.6172 0.774 0.847
0.95 0.95 0.2608 0.558 0.627 0.801
0 0.2375 0.1661 0.5087 0.474 0.763
0.0966 0.4375 0.337 0.726
R=3 0.0721 0.3891 0.215 0.665
0.019 0.17 0.166 0.619
q line 0 0 0.047 0.344
X Y 0 0
0.22 0.22
0.22 0.8 XD
X Y
Striping 0.95 0
X Y
0.01 0.01
0.22 0.45

Chart Title
1.2

f(x) = 0.75x
- 50.5358469148x^6
+ 0.2375 + 168.2900936663x^5 - 219.753947737x^4 + 143.3898078165x^3 - 49.3
R² = 0.998776272
1

0.8

0.6

0.4 f(x) = 2.0952380952x - 0.010952381

0.2
0.4 f(x) = 2.0952380952x - 0.010952381

0.2

0
0 0.2 0.4 0.6
 Stage tray X Y
1 1 0.95 0.95
2 0.9463045 0.95
2 3 0.9463045 0.9472284
4 0.9414703 0.9472284
3 5 0.9414703 0.9436027
6 0.9347683 0.9436027
4 7 0.9347683 0.9385762
8 0.9270011 0.9385762
5 9 0.9270011 0.9327508
10 0.9185364 0.9327508
6 11 0.9185364 0.9264023
12 0.909777 0.9264023
7 13 0.909777 0.9198328
14 0.9010303 0.9198328
8 15 0.9010303 0.9132727
16 0.8924775 0.9132727
9 17 0.8924775 0.9068581
18 0.8854921 0.9068581
10 19 0.8854921 0.9016191
20 0.8782276 0.9016191
11 21 0.8782276 0.8961707
22 0.8706728 0.8961707
12 23 0.8706728 0.8905046
24 0.862695 0.8905046
13 25 0.862695 0.8845212
26 0.8545194 0.8845212
Chart Title 14 27 0.8545194 0.8783896
28 0.8473039 0.8783896
15 29 0.8473039 0.8729779
30 0.8385378 0.8729779
16 31 0.8385378 0.8664033
32 0.8282 0.8664033
4 + 143.3898078165x^3 - 49.3345066502x^2 + 8.8930315158x + 0.0068455678
17 33 0.8282 0.85865
34 0.8150671 0.85865
18 35 0.8150671 0.8488003
36 0.7979 0.8488003
19 37 0.7979 0.835925
38 0.7682886 0.835925
20 39 0.7682886 0.8137165
40 0.6833759 0.8137165
21 41 0.6833759 0.7500319
42 0.4283909 0.7500319
 22 43 0.4283909 0.5587932
44 0.1147112 0.5587932
23 45 0.1147112 0.2293428
46 0.0294991 0.2293428
0.6 0.8 1 1.2 24 47 0.0294991 0.0508066
48 0.0050352 0.0508066
25 49
50
51
52
53
54
Y Hitung Y Hitung - Y

0.9506545 0.0006545223

0.9479739 0.0007455174

0.9439371 0.0003344342

0.9388675 0.0002912673

0.9329641 0.0002132962

0.9265482 0.0001459317

0.9199332 0.0001004555

0.9133525 7.9764227E-05

0.9079495 0.0010913661

0.9023467 0.000727548

0.8965767 0.000405981

0.8905867 8.2066651E-05

0.8845963 7.5101506E-05

0.8794613 0.0010717421

0.873444 0.0004660668

0.866696 0.0002926757

0.8587183 6.8344092E-05

0.8493597 0.0005594387

0.8361171 0.0001921099

0.8147618 0.0010453686

0.7503035 0.0002715929
0.5593613 0.0005680755

0.2297227 0.0003799041

0.0503454 -0.000461155