Group 1 Mass & Energy Balance

1 day 24 hrs
1 ton 1000 kg
Molecular weight of components

2-butanol CH3CH(OH)CH2CH3 0.0741
Methyl ethyl ketone CH3C(O)CH2CH3 0.0721
Hydrogen H2 0.0020
Water H2O 0.0180
Basis 9.24 ton/hr
Number of days of operation 350 days

Yearly Production 71000 ton/yr
Production flow rate 8.4523809524 ton/hr
Yield of MEK 91.9542064684 %
Yield of Hydrogen 2.5837120921 %
Composition of feed butanol is 99.5 wt%
P-101 Buta
In
Stream 1
Temperature (K) 300.15
Molar
flow Mole
rate fraction
(kmol/hr)
CH3CH(OH)CH2CH3 124.01 0.98
CH3C(O)CH2CH3
H2
H2O 2.56 0.02
Total 126.57 1.00
Total mass
flow rate
(ton/hr) 9.24
In
Stream 2
Molar
flow Mole
rate fraction
(kmol/hr)
CH3CH(OH)CH2CH3 124.01 0.98

CH3C(O)CH2CH3
H2
H2O 2.56 0.02
Total 126.57 1.00
Total mass
flow rate
(ton/hr) 9.24
E-102 Shell & Tu
In
Stream 3
Molar
flow Mole
rate fraction
(kmol/hr)
CH3CH(OH)CH2CH3 124.01 0.98

CH3C(O)CH2CH3
H2
H2O 2.56 0.02
Total 126.57 1.00
Total mass
flow rate
(ton/hr) 9.24
Process stream is compressed from 1 bar to 3 bar
C-101 C
In
Stream 4
Molar
flow Mole
rate fraction
(kmol/hr)
CH3CH(OH)CH2CH3 124.01 0.98

CH3C(O)CH2CH3
H2
H2O 2.56 0.02
Total 126.57 1.00
Total mass
flow rate
(ton/hr) 9.24
E-103 Shell & Tu
In
Stream 5
Molar
flow Mole
rate fraction
(kmol/hr)
CH3CH(OH)CH2CH3 124.01 0.98

CH3C(O)CH2CH3
H2
H2O 2.56 0.02
Total 126.57 1.00
Total mass
flow rate
(ton/hr) 9.24
1 CH3CH(OH)CH2CH3 >
Conversion 0.95
R-201 Fixe
In
Stream 6
Molar
flow Mole
rate fraction
(kmol/hr)
CH3CH(OH)CH2CH3 124.01 0.98

CH3C(O)CH2CH3
H2
H2O 2.56 0.02
Total 126.57 1.00
Total mass
flow rate
(ton/hr) 9.24
E-301
In
Stream 8
Molar
flow Mole
rate fraction
(kmol/hr)
CH3CH(OH)CH2CH3 6.20 0.03

CH3C(O)CH2CH3 117.81 0.48
H2 117.81 0.48
H2O 2.56 0.01
Total 244.38 1.00
Total mass
flow rate
(ton/hr) 9.24
100 % separation on hydrogen gas to the top of vessel is assumed. This is due
In
Stream 9
Molar
flow Mole
rate fraction
(kmol/hr)
CH3C(O)CH2CH3 117.81 0.48
H2 117.81 0.48
H2O 2.56 0.01
Total 244.38 1.00
Total mass
flow rate
(ton/hr) 9.24
E-302
In
Stream 11
Molar
flow Mole
rate fraction
(kmol/hr)

CH3C(O)CH2CH3 117.81 0.93
H2 0.00 0.00
H2O 2.56 0.02
Total 126.57 1.00
Total mass
flow rate
(ton/hr) 9.00
Stream 12
Molar
flow Mole
rate fraction
(kmol/hr)

CH3C(O)CH2CH3 117.81 0.93
H2 0.00 0.00
H2O 2.56 0.02
Total 126.57 1.00
Total mass
flow rate
(ton/hr)
E-303 C
In
Stream 13
Molar
flow Mole
rate fraction
(kmol/hr)

CH3C(O)CH2CH3 486.67 1.00
H2 0.00 0.00
H2O 0.00 0.00
Total 487.05 1.00
Total mass
flow rate
(ton/hr) 35.12
Reflux ratio Rm = 2.1011917597
V-302 R
In
Stream 14
Molar
flow Mole
rate fraction
(kmol/hr)

CH3C(O)CH2CH3 486.67 1.00
H2 0.00 0.00
H2O 0.00 0.00
Total 487.05 1.00
Total mass
flow rate
(ton/hr) 35.12
In
Stream 15
Molar
flow
rate Mole
(kmol/hr) fraction
CH3C(O)CH2CH3 486.67 1.00
H2 0.00 0.00
H2O 0.00 0.00
Total 487.05 1.00
Total mass
flow rate
(ton/hr) 35.12
Boil up ratio S= 0.3277356351
In
Stream 18
Molar
flow Mole
rate fraction
(kmol/hr)
CH3C(O)CH2CH3 0.78 0.06
H2 0.00 0.00
H2O 3.40 0.28
Total 12.30 1.00
Total mass
flow rate
(ton/hr) 0.72
ton/kmol 74.12
ton/kmol 72.12
ton/kmol 2.016
ton/kmol 18.02
P-101 Butanol feed pump

In Out
1 2
300.15 300.15
Mass Molar
flow Mass flow Mole
rate fraction rate fraction
(ton/hr) (kmol/hr)
9.19 1.00 124.01 0.98
0.05 0.01 2.56 0.02

9.24 1.00 126.57 1.00
9.24 9.24
E-101 Thermo
Tube
In Out
2 3
300.15 383.15
Mass Molar
flow Mass flow Mole
(ton/hr) (kmol/hr)
9.19 1.00 124.01 0.98
0.05 0.01 2.56 0.02

9.24 1.00 126.57 1.00
9.24 9.24
E-102 Shell & Tube Heat Exchanger

Tube
In Out
3 4
383.15 573.15
Mass Molar
flow Mass flow Mole
(ton/hr) (kmol/hr)
9.19 1.00 124.01 0.98
0.05 0.01 2.56 0.02

9.24 1.00 126.57 1.00
9.24 9.24
bar to 3 bar
C-101 Compressor
In Out
4 5
573.15 638.33
Mass Molar
flow Mass flow Mole
(ton/hr) (kmol/hr)
9.19 1.00 124.01 0.98
0.05 0.01 2.56 0.02

9.24 1.00 126.57 1.00
9.24 9.24

Tube
In Out
5 6
638.33 773.15
Mass Molar
flow Mass flow Mole
(ton/hr) (kmol/hr)
9.19 1.00 124.01 0.98
0.05 0.01 2.56 0.02

9.24 1.00 126.57 1.00
9.24 9.24
1 CH3C(O)CH2CH3 1 H2
R-201 Fixed Bed Reactor

In Out
6 7
773.15 773.15
Mass Molar
flow Mass flow Mole
(ton/hr) (kmol/hr)
9.19 1.00 6.20 0.03

117.81 0.48
117.81 0.48
0.05 0.01 2.56 0.01
9.24 1.00 244.38 1.00
9.24 9.24
E-301 Cooler
Tube
In Out
8 9
506.83 298.15
Mass Molar
flow Mass flow Mole
(ton/hr) (kmol/hr)
0.46 0.05 6.20 0.03

8.49 0.92 117.81 0.48
0.24 0.03 117.81 0.48
0.05 0.01 2.56 0.01
9.24 1.00 244.38 1.00
9.24 9.24
the top of vessel is assumed. This is due to the non-condensable property of hydrogen gas.
V-301 Knock-out drum

In
9 10
298.00 298.00
Mass Molar
flow Mass flow Mole
(ton/hr) (kmol/hr)
0.46 0.05 0.00 0.00
8.49 0.92 0.00 0.00
0.24 0.03 117.81 1.00
0.05 0.01 0.00 0.00
9.24 1.00 117.81 1.00
9.24
E-302 Heater
Tube
In Out
11 12
298.00 397.88
Mass Molar
flow Mass flow Mole
(ton/hr) (kmol/hr)
0.46 0.05 6.20 0.05

8.49 0.94 117.81 0.93
0.00 0.00 0.00 0.00
0.05 0.01 2.56 0.02
9.00 1.00 126.57 1.00
9.00 9.00
In
12 16
397.88 390.74
Mass Molar
flow Mass flow Mole
(ton/hr) (kmol/hr)
0.46 0.05 0.29 0.00

8.49 0.94 369.45 1.00
0.00 0.00 0.00 0.00
0.05 0.01 0.00 0.00
9.00 1.00 369.74 1.00
35.84
E-303 Condenser
In Out
13 14
390.74 390.74
Mass Molar
flow Mass flow Mole
(ton/hr) (kmol/hr)
0.03 0.00 0.39 0.00

35.09 1.00 486.67 1.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
35.12 1.00 487.05 1.00
35.12 35.12
R= 3.1517876396
V-302 Reflux drum

In Out
14 15
390.74 390.74
Mass Molar
flow Mass flow Mole
(ton/hr) (kmol/hr)
0.03 0.00 0.39 0.00

35.09 1.00 486.67 1.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
35.12 1.00 487.05 1.00
35.12 35.12
Splitting point
In
15 16
390.74 390.74
Mass Molar
flow flow
rate Mass rate Mole
(ton/hr) fraction (kmol/hr) fraction
0.03 0.00 0.29 0.00
35.09 1.00 369.45 1.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
35.12 1.00 369.74 1.00
35.12
E-304 Kettle reboiler

In
18 19
405.03 405.03
Mass Molar
flow Mass flow Mole
(ton/hr) (kmol/hr)
0.60 0.84 2.00 0.66
0.06 0.08 0.19 0.06
0.00 0.00 0.00 0.00
0.06 0.09 0.84 0.28
0.72 1.00 3.03 1.00
0.72
Goal Seek
By changing this value
Goal Seek to this value
Interested parameter
Fixed value
Out
2
300.15
Mass
flow Mass
rate fraction
(ton/hr)
9.19 1.00
0.05 0.01
9.24 1.00
9.24
E-101 Thermosyphon vaporizer

Out In
3 7
383.15 773.15
Mass Molar
flow Mass flow Mole
(ton/hr) (kmol/hr)
9.19 1.00 6.20 0.03

117.81 0.48
117.81 0.48
0.05 0.01 2.56 0.01
9.24 1.00 244.38 1.00
9.24 9.24
Out
4
573.15
Mass
flow Mass
rate fraction
(ton/hr)
9.19 1.00
0.05 0.01
9.24 1.00
9.24
Out
5
638.33
Mass
flow Mass
rate fraction
(ton/hr)
9.19 1.00
0.05 0.01
9.24 1.00
9.24
Out
6
773.15
Mass
flow Mass
rate fraction
(ton/hr)
9.19 1.00
0.05 0.01
9.24 1.00
9.24
Out
7
773.15
Mass
flow Mass
rate fraction
(ton/hr)
0.46 0.05
8.49 0.92
0.24 0.03
0.05 0.01
9.24 1.00
9.24
Out
9
298.15
Mass
flow Mass
rate fraction
(ton/hr)
0.46 0.05
8.49 0.92
0.24 0.03
0.05 0.01
9.24 1.00
9.24
rum
Out
10 11
298.00 298.00
Mass Molar
flow Mass flow Mole
(ton/hr) (kmol/hr)
0.00 0.00 6.20 0.05
0.00 0.00 117.81 0.93
0.24 1.00 0.00 0.00
0.00 0.00 2.56 0.02
0.24 1.00 126.57 1.00
9.24
Out
12
397.88
Mass
flow Mass
rate fraction
(ton/hr)
0.46 0.05
8.49 0.94
0.00 0.00
0.05 0.01
9.00 1.00
9.00
T-301 Distillation column

In
16 19
390.74 405.03
Mass Molar
flow Mass flow Mole
(ton/hr) (kmol/hr)
0.02 0.00 2.00 0.66

26.64 1.00 0.19 0.06
0.00 0.00 0.00 0.00
0.00 0.00 0.84 0.28
26.66 1.00 3.03 1.00
35.84
Out
14
390.74
Mass
flow Mass
rate fraction
(ton/hr)
0.03 0.00
35.09 1.00
0.00 0.00
0.00 0.00
35.12 1.00
35.12
Out
15
390.74
Mass
flow Mass
rate fraction
(ton/hr)
0.03 0.00
35.09 1.00
0.00 0.00
0.00 0.00
35.12 1.00
35.12
Out
16 17
390.74 390.74
Mass Molar
flow flow
rate Mass rate Mole
(ton/hr) fraction (kmol/hr) fraction
0.02 0.00 0.09 0.00
26.64 1.00 117.22 1.00
0.00 0.00 0.00 0.00
0.00 0.00 0.00 0.00
26.66 1.00 117.31 1.00
35.12
ler
Out
19 20
405.03 405.03
Mass Molar
flow Mass flow Mole
(ton/hr) (kmol/hr)
0.15 0.84 6.11 0.66
0.01 0.08 0.59 0.06
0.00 0.00 0.00 0.00
0.02 0.09 2.56 0.28
0.18 1.00 9.26 1.00
0.72
Shell
In Out
7 8
773.15 506.83
Mass Molar
flow Mass flow Mole
(ton/hr) (kmol/hr)
0.46 0.05 6.20 0.03

8.49 0.92 117.81 0.48
0.24 0.03 117.81 0.48
0.05 0.01 2.56 0.01
9.24 1.00 244.38 1.00
9.24 9.24
11
298.00
Mass
flow Mass
rate fraction
(ton/hr)
0.46 0.05
8.49 0.94
0.00 0.00
0.05 0.01
9.00 1.00
lumn
19 13
405.03 390.74
Mass Molar
flow Mass flow Mole
(ton/hr) (kmol/hr)
0.15 0.84 0.39 0.00

0.01 0.08 486.67 1.00
0.00 0.00 0.00 0.00
0.02 0.09 0.00 0.00
0.18 1.00 487.05 1.00
17
390.74
Mass
flow
rate Mass
(ton/hr) fraction
0.01 0.00
8.45 1.00
0.00 0.00
0.00 0.00
8.46 1.00
20
405.03
Mass
flow Mass
rate fraction
(ton/hr)
0.45 0.84
0.04 0.08
0.00 0.00
0.05 0.09
0.54 1.00
Out
8
506.83
Mass
flow Mass
rate fraction
(ton/hr)
0.46 0.05
8.49 0.92
0.24 0.03
0.05 0.01
9.24 1.00
9.24
Out
13 18
390.74 405.03
Mass Molar
flow Mass flow Mole
(ton/hr) (kmol/hr)
0.03 0.00 8.11 0.66

35.09 1.00 0.78 0.06
0.00 0.00 0.00 0.00
0.00 0.00 3.40 0.28
35.12 1.00 12.30 1.00
35.84
18
405.03
Mass
flow Mass
rate fraction
(ton/hr)
0.60 0.84
0.06 0.08
0.00 0.00
0.06 0.09
0.72 1.00
1.01325 bar 760 mm Hg
1 atm 760 mm Hg
1 atm 101325 Pa
Temperature 75 C
348 K
Pressure 3 bar
2250.1850481125 mm Hg
Assumption 1. Sharp split: Component heavier than HK will end up completely in the bottom
2. The key components (LK and HK) are distributed at distillate and bottom
At distillate Recovery of LK 0.995

Recovery of HK 0.015
Recovery of HNK 0
Feed
Stream No. 12
Mole flow rate Mass flow rate

Component (kmol/hr) Mole fraction (ton/hr)
CH3CH(OH)CH2CH3 6.200409548 0.0489871532 0.4595972972
CH3C(O)CH2CH3 117.8077814113 0.9307559111 8.4948552281
H2 0 0 0
H2O 2.5639639961 0.0202569356 0.0461906831
Total 126.5721549554 1 9.0006432085
Total mass flow rate (ton/hr) 9.0006432085
Dew point 117.7398577787 C

390.7398577787 K �_𝑖 P=𝑥_𝑖 𝑃_𝑖^𝑠𝑎�
Feed Vapour Pressure

Component (Mole fraction) (mm Hg) Ki = Pisat/P
2-butanol 0.0489871532 1424.0338528361 0.6328518866
Methyl ethyl ketone 0.9307559111 2251.3239723668 1.0005061469
Hydrogen 0 1.203550343E+28 5.34867274E+24
Water 0.0202569356 1377.2713831316 0.6120702759
Vapor pressure of component

C1 C2 C3
2-butanol 152.54 -11111 -19.025
Methyl ethyl ketone 72.698 -6143.6 -7.5779
Water 73.649 -7258.2 -7.3037
Hydrogen 12.9 -94.896 1.1125
Bubble point 132.0257088941 C

405.0257088941 K
Feed Vapour Pressure

Component (Mole fraction) (mmHg) Ki = Pisat/P
2-butanol 0.0489871532 2207.434268399 0.981001216
Water 0.0202569356 2139.0830793344 0.950625408
Hydrogen 0 5.32836417E+29 2.367967103E+26
C1 C2 C3
2-butanol 152.54 -11111 -19.025
Water 73.649 -7258.2 -7.3037
Hydrogen 12.9 -94.896 1.1125
Reflux ratio
Bubble point temperature 132.0257088941 C

405.0257088941 K
Feed, xiF Distillate, yi = xiD Vapour pressure

Component (Mole fraction) (Mole fraction) (mm Hg)
Water 0.0202569356 0 2139.0830793344
2-butanol 0.0489871532 0.0007928118 2207.434268399
Hydrogen 0 0 5.32836417E+29
C1 C2 C3
2-butanol 152.54 -11111 -19.025
Water 73.649 -7258.2 -7.3037
Hydrogen 12.9 -94.896 1.1125
Splitter
Total molar flow rate at S-15 487.0534680097
L 369.7417193622
Inlet
Stream No. 15
(kmol/hr) Mole fraction (ton/hr)
2-butanol 0.3861417558 0.0007928118 0.0286222557
Hydrogen 0 0 0
Water 0 0 0
Total 487.0534680097 1 35.121113017
Boil up ratio
�=(𝑅+𝑞) (𝑥_𝐹−𝑥_𝐷)/(𝑥_𝐵−𝑥_𝐹 )+𝑞−1
xF - xD xB - xF S
2-butanol 0.0481943414 0.6105307126 0.3277356351
Methyl ethyl ketone -0.068451277 -0.8671475891 0.3277356351
Total molar flow rate at S-18 12.2953714503

L' 3.0349651425
Inlet
Stream No. 18
2-butanol 8.1090171383 0.6595178658 0.6010703537
Hydrogen 0 0 0
Water 3.4042663646 0.2768738121 0.061329016
Total 12.2953714503 1 0.7187939797
ll end up completely in the bottom
uted at distillate and bottom
At bottom Recovery of LK 0.005

Recovery of HK 0.985
Recovery of HNK 1
Distillate
17

Mass fraction (kmol/hr) Mole fraction (ton/hr) Mass fraction
0.051062717 0.0930061432 0.0007928118 0.0068939595 0.0008149587
0.9438053516 117.2187425043 0.9992071882 8.452380952 0.9991850413
0 0 0 0 0
0.0051319314 0 0 0 0
1 117.3117486475 1 8.4592749115 1
9.0006432085
Distillate, yi
α = Ki/KHK (Mole fraction) xi = yi/Ki
1 0.0007928118 0.0012527605
1.5809483517 0.9992071882 0.9987016984
8.451697552E+24 0 0
0.9671619677 0 0
0.9999544589
C4 C5 Vapor pressure (Pa) Vapor pressure (mm Hg)
0.000010426 2 189855.565971868 1424.0338528361
5.6476E-06 2 300151.844079029 2251.3239723668
4.1653E-06 2 183621.082757644 1377.2713831316
0.00032915 2 1.6046018221139E+30 1.20355034276492E+028
Bottom, xi
α = Ki/KHK (Mole fraction) yi = Kixi
1 0.6595178658 0.6469878283
1.442463415 0.0636083221 0.0900094882
0.9690359119 0.2768738121 0.2632032806
2.413826879E+26 0 0
1.0002005971

0.000010426 2 294300.364796752 2207.434268399
5.6476E-06 2 424517.509239019 3184.143173172
4.1653E-06 2 285187.622386261 2139.0830793344
0.00032915 2 7.1039013091757E+31 5.32836416972469E+029
1−𝑞=∑▒(𝛼_𝑖 𝑥_𝑖𝑓)/(𝛼_𝑖−𝜃)
Bottom, xi = xiB
Ki = Pisat/P αi = Ki/KHK (Mole fraction) αixiF αixiF/αi-θ
1.4150583641 1.442463415 0.0636083221 1.3425813501 2.8611656115
0.950625408 0.9690359119 0.2768738121 0.0196296981 -4.6908172646
0.981001216 1 0.6595178658 0.0489871532 1.8292862704
2.367967103E+26 2.413826879E+26 0 0 0
-0.0003653826
q 1
1-q 0
θ 0.9732206194

0.000010426 2 294300.364796752 2207.434268399
5.6476E-06 2 424517.509239019 3184.143173172
4.1653E-06 2 285187.622386261 2139.0830793344
0.00032915 2 7.1039013091757E+31 5.32836416972469E+029
𝐹=𝐿+𝐷
𝐿=𝑅𝐷
Outlet
16
Mole flow rate
Mass fraction (kmol/hr) Mole fraction Mass flow rate (ton/hr) Mass fraction
0.0008149587 0.2931356126 0.0007928118 0.0217282962 0.0008149587
0.9991850413 369.4485837496 0.9992071882 26.6401098094 0.9991850413
0 0 0 0 0
0 0 0 0 0
1 369.7417193622 1 26.6618381056 1
35.121113017
𝐹=𝐿^′+𝐵
𝐿^′=�𝐵

Outlet
19
Mole flow rate
Mass fraction (kmol/hr) Mole fraction Mass flow rate (ton/hr) Mass fraction
0.8362206288 2.0016137336 0.6595178658 0.1483670159 0.8362206288
0.0784572654 0.1930490403 0.0636083221 0.0139203339 0.0784572654
0 0 0 0 0
0.0853221058 0.8403023686 0.2768738121 0.0151383329 0.0853221058
1 3.0349651425 1 0.1774256826 1
0.7187939797
Bottom
20

(kmol/hr) Mole fraction (ton/hr) Mass fraction
6.1074034047 0.6595178658 0.4527033378 0.8362206288
0.5890389071 0.0636083221 0.0424742761 0.0784572654
0 0 0 0
2.5639639961 0.2768738121 0.0461906831 0.0853221058
9.2604063079 1 0.541368297 1
0006432085
0.0050251256
𝑥_𝑖𝑓)/(𝛼_𝑖−𝜃) 𝑅_𝑚+1=∑▒(𝛼_𝑖 𝑥_𝑖𝐷)/(𝛼_𝑖−𝜃)
αixiD αixiD/αi-θ
1.4413198129 3.0715864506
0 0
0.0007928118 0.0296053091
0 0
3.1011917597
Rm 2.1011917597
R/Rm 1.5
R 3.1517876396
Outlet
17
0.0930061432 0.0007928118 0.0068939595 0.0008149587
117.2187425043 0.9992071882 8.452380952 0.9991850413
0 0 0 0
0 0 0 0
117.3117486475 1 8.4592749115 1
.121113017
Outlet
20
6.1074034047 0.6595178658 0.4527033378 0.8362206288
0.5890389071 0.0636083221 0.0424742761 0.0784572654
0 0 0 0
2.5639639961 0.2768738121 0.0461906831 0.0853221058
9.2604063079 1 0.541368297 1
7187939797
1.01325 bar 760 mm Hg
1 atm 760 mm Hg
1 atm 101325 Pa
1 g/cm3 1000 kg/m3
1 bar 1000000 Pa
Pressure 3 bar
2280 mm Hg
Inlet
Stream No. 9
Molar flow rate Mass flow rate

CH3CH(OH)CH2CH3 6.200409548 0.0253720074 0.4595972972
CH3C(O)CH2CH3 117.8077814113 0.4820681401 8.4948552281
H2 117.8077814113 0.4820681401 0.2374934189
H2O 2.5639639961 0.0104917123 0.0461906831
Total 244.3799363667 1 9.24
Bubble point -245.6691228075 C

27.3308771925 K
C1 C2 C3
CH3CH(OH)CH2CH3 152.54 -11111 -19.025
CH3C(O)CH2CH3 72.698 -6143.6 -7.5779
H2 12.9 -94.896 1.1125
H2O 73.649 -7258.2 -7.3037
Dew point 96.0110577134 C

369.0110577134 K
C1 C2 C3
CH3CH(OH)CH2CH3 152.54 -11111 -19.025
CH3C(O)CH2CH3 72.698 -6143.6 -7.5779
H2 12.9 -94.896 1.1125
H2O 73.649 -7258.2 -7.3037
Flash temperature 25 C
298 K
C1 C2 C3
CH3CH(OH)CH2CH3 152.54 -11111 -19.025
CH3C(O)CH2CH3 72.698 -6143.6 -7.5779
H2 12.9 -94.896 1.1125
H2O 73.649 -7258.2 -7.3037
Radford-Rice equation
kmol/hr
F 244.379936367
∑10_𝑖▒ 〖 (𝑧_𝑖 (𝐾_𝑖−1))/(1+𝑉/𝐹 (𝐾_𝑖−1) )=0 〗
V 1193.01267502
L -948.63273865
zi Ki zi(Ki-1)
CH3CH(OH)CH2CH3 0.0253720074 0.0079763951 -0.0251696302
CH3C(O)CH2CH3 0.4820681401 0.0402243243 -0.4626772749
H2 0.4820681401 2.6803115E+15 1.2920928E+15
H2O 0.0104917123 0.0103368203 -0.0103832614
Liquid density (From Perry's Chemical Engineer's Handbook, 7th Edition, Table 2-30)
C1 C2 C3
CH3CH(OH)CH2CH3 0.966 0.26064 536.05
CH3C(O)CH2CH3 0.93767 0.25035 535.5
H2 5.414 0.34893 33.19
H2O 5.459 0.30542 647.13
4.9669 0.27788 647.13
4.391 0.2487 647.13
Temperature in K, liquid density in kmol/m3

�_𝐿=𝐶1/ 〖𝐶 2 〗 ^[1+(1−𝑇/𝐶3)^𝐶4 ]
Vapor velocity factor

FLV A B C
-17.8432888554 -1.877478 -0.81458 -0.187074
Max vapor velocity
v (m/s) Err:502
Volumetric flow rate of vapor (m3/s) -1481.465321342

Volumetric flow rate of liquid 2.3393803102
Area Err:502
Diameter (m) Err:502
Actual diameter (m) Err:502
Surge time
Vertical flash drum
Surge time (min) 5.5
Liquid volume 771.9955023633

Liquid height Err:502
Vapor volume -488883.5560428

Vapor height Err:502
Total height (m) Err:502

3<𝐿/𝑑<5 𝑉𝑒𝑟�𝑖𝑐𝑎𝑙 𝑓𝑙𝑎𝑠ℎ 𝑑𝑟𝑢𝑚
L/d Err:502
Total height with allowance (m) Err:502

Outlet
10

Mass fraction (kmol/hr) Mole fraction (ton/hr) Mass fraction
0.04975 -0.0628278909 -5.266322164684E-05 -0.0046570357 0.021130434
0.9195420647 -6.2770319405 -0.0052614964 -0.4526227127 2.0536914195
0.0257079353 117.8077814113 0.098748139 0.2374934189 -1.0775822397
0.005 -0.0337698055 -2.830632583483E-05 -0.0006083745 0.0027603863
1 1193.0126750185 0.093405673 -0.2203947041 1
9.19
C4 C5 Vapor pressure (Pa) Vapor pressure (mm Hg) Ki

0.000010426 2 2.300150781285E-138 1.72525496548379E-140 7.56690774E-144
5.6476E-06 2 1.1588120333084E-77 8.69180503641164E-80 3.812195191E-83
0.00032915 2 630280.079513291 4727.49 2.0734602501
4.1653E-06 2 1.4427912697885E-94 1.08218244760847E-96 4.74641424E-100

0.000010426 2 88966.4491084355 667.3032452249 0.2926768619
5.6476E-06 2 167134.206271249 1253.6096399324 0.5498287894
0.00032915 2 6.4812495074087E+27 4.86133691155255E+025 2.13216531E+22
4.1653E-06 2 87199.3204862318 654.0486905456 0.2868634608
0.000010426 2 2424.6246888415 18.1861807404 0.0079763951
5.6476E-06 2 12227.1889858382 91.7114594546 0.0402243243
0.00032915 2 8.1474768538542E+20 6.11111019879516E+018 2.68031149E+15
4.1653E-06 2 3142.1349394455 23.5679501996 0.0103368203
m3/hr
8.314 m3.Pa/K.mol
-5333275.1568 𝑥_𝑖=𝑧_𝑖/(1+𝑉/𝐹 (𝐾_𝑖−1) ) �_𝑖=(𝐾_𝑖 𝑧_𝑖)/(1+𝑉/𝐹 (𝐾_𝑖−1) )
8421.76911669
1+(V/F)(Ki-1) zi (Ki-1)/ (1+(V/F)(Ki-1xi liquid density (kg/m3) yi

-3.8428555642 0.0065497206 -0.0066023838 -0.0053195172 -5.26632216E-05
-3.6854277944 0.1255423524 -0.1308038488 -0.1045961874 -0.0052614964
1.308473E+16 0.098748139 3.6842038434937E-17 0 0.098748139
-3.831332453 0.0027100915 -0.0027383978 -0.0027248493 -2.83063258E-05
0.2335503034 -0.1401446305 -0.112640554 0.093405673
C4 Tmin, K Density at Tmin Tmax, K Density at Tmax

0.2746 158.45 12.57 536.05 3.706
0.29964 186.48 12.663 535.5 3.745
0.2706 13.95 38.487 33.19 15.516
0.081 273.16 55.583 333.15 54.703
0.1874 333.15 403.15
0.2534 403.15 647.13
D E K
-0.014523 -0.001015 Err:502 Err:502
𝑒𝑟�𝑖𝑐𝑎𝑙 𝑓𝑙𝑎𝑠ℎ 𝑑𝑟𝑢𝑚 𝐿/𝑑>5 𝐻𝑜𝑟𝑖𝑧𝑜𝑛�𝑎𝑙 𝑓𝑙𝑎𝑠ℎ 𝑑𝑟𝑢𝑚
Outlet
11

6.2632374389 -0.0066023838 0.4642543329 0.0493274514
124.0848133519 -0.1308038488 8.9474779408 0.9506777903
-3.4949563818E-14 3.684203843494E-17 -7.04562237E-17 -7.4860388E-18
2.5977338016 -0.0027383978 -4.93331674E-05 -5.24169457E-06
-948.6327386518 -0.1401446305 9.4116829406 1
9.19
zi=xi (mole fraction) yi=xiKi

0.0253720074 1.91987639075E-145
0.4820681401 1.837737845765E-83
0.4820681401 0.9995491264
0.0104917123 4.97980129329E-102
0.9995491264
zi=yi (mole fraction) xi=yi/Ki

0.0253720074 0.0866894882
0.4820681401 0.876760456
0.4820681401 2.260932289845E-23
0.0104917123 0.0365738889
1.0000238331
+𝑉/𝐹 (𝐾_𝑖−1) )
pure vapor density (k vapor density (kg/m3)

0.0897536378 -4.72671572295E-06
0.0873126109 -0.000459395
0.0024410269 0.0002410469
0.0218141067 -6.17477212447E-07
-0.0002236923
Density (kmol/m3) Density (kg/m3)

10.8696199894 0.8056964512
11.0895347728 0.7996415119
0 0
55.2336176688 0.9950524017
1 MJ 1000000 J
Heat of vaporization of components (From Perry's Chemical Engineers' Handbook, 7th Edition, Table 2-193 )
C1 x 10-7 C2 C3 C4
Sec-butanol 7.256 0.4774 0 0

Methyl ethyl ketone 4.622 0.355 0 0
Hydrogen 0.1013 0.698 -1.817 1.447
Water 5.2053 0.3199 -0.212 0.25795
Temperature are in K; heat of vaporization in J/kmol. Tr is the reduced temperature, T/Tc.

∆𝐻_𝑣=𝐶1 × (1−𝑇_𝑟 )^(𝐶2+𝐶3×𝑇_𝑟+𝐶4×𝑇_𝑟×𝑇_𝑟 )
Heat capacities of components (From Perry's Chemical Engineers' Handbook, 7th Edition, Table 2-196 & Table 2-19
Heat of formation of components (From Perry's Chemical Engineers' Handbook, 7th Edition, Table 2-196 for gas; E
LIQUID PHASE
C1 C2 C3 C4
Sec-butanol 206700 -1020.4 3.2900 0

Methyl ethyl ketone 132300 200.87 -0.9597 0.0019533
Hydrogen (eqn. 2) 66.653 6765.9 -123.63 478.27
Water 276370 -2090.1 8.125 -0.014116
Temperature are in K; liquid heat capacities are in J/kmol.K.

Heat capacity for H2 gas = 6.62 + 0.00081T, (T = K; 0°C = 273.1K), cal/deg mol, at T ranging (273 – 2500)K.
Eqn. 1, heat capacity = C1 + C2 x T + C3 x T2 + C4 x T3 + C5 x T4
Eqn. 2, heat capacity = C12/t + C2 – (2 x C1 x C3)t – (C1 x C4)t2 – (C32/3)t3 – (C3 x C4/2)t4 – (C42/5)t5. t = (1-Tr)
Steam table (From Elementary Principles of Chemical Processes, 3rd Edition, Table B.7)
P (bar) 1
Tsat (°C) 99.6
T (°C) 150 200 250 300

Specific enthalpy, Ĥ (kJ/kg) 2776 2875 2975 3074
Reference temperature 298.15 K
P-101 Butanol fee

In
Stream 1
Pressure (bar) 1
Molar flow Heat of Heat of

Mole formation, Hf vaporization, Hv
rate
(kmol/hr) fraction
(J/kmol) (J/kmol)
CH3CH(OH)CH2CH3 124.01 0.98

CH3C(O)CH2CH3
H2
H2O 2.56 0.02
Total 126.57 1.00
Stream enthalpy (MJ/hr) -48.97
Heat duty (MJ/hr)
Power requirement (kW)
In
Stream 2
Pressure (bar) 1.05

rate fraction
(kmol/hr) (J/kmol) (J/kmol)
CH3CH(OH)CH2CH3 124.01 0.98

CH3C(O)CH2CH3
H2
H2O 2.56 0.02
Total 126.57 1.00
Heat duty (MJ/hr)
In
Stream 3
Pressure (bar) 1.05

rate fraction
CH3CH(OH)CH2CH3 124.01 0.98

CH3C(O)CH2CH3
H2
H2O 2.56 0.02
Total 126.57 1.00
Heat duty (MJ/hr)
C-101 Compre
Stream 4
Pressure (bar) 1.05
Molar Heat of Heat of
flow Mole formation, Hf vaporization, Hv
rate fraction
CH3CH(OH)CH2CH3 124.01 0.98

CH3C(O)CH2CH3
H2
H2O 2.56 0.02
Total 126.57 1.00
Heat duty (MJ/hr)
In
Stream 5
Pressure (bar) 3

rate fraction
CH3CH(OH)CH2CH3 124.01 0.98

CH3C(O)CH2CH3
H2
H2O 2.56 0.02
Total 126.57 1.00
Heat duty (MJ/hr)
In
Stream 6
Pressure (bar) 3

rate fraction
CH3CH(OH)CH2CH3 124.01 0.98 -292900000.00

CH3C(O)CH2CH3
H2
H2O 2.56 0.02 -241814000.00
Total 126.57 1.00
Heat duty (MJ/hr)
In
Stream 8
Pressure (bar) 3
rate fraction

CH3C(O)CH2CH3 117.81 0.48
H2 117.81 0.48
H2O 2.56 0.01
Total 244.38 1.00
Heat duty (MJ/hr)
In
Stream 9
Pressure (bar) 3

rate fraction

CH3C(O)CH2CH3 117.81 0.48
H2 117.81 0.48
H2O 2.56 0.01
Total 244.38 1.00
Stream enthalpy (MJ/hr) 3.52
Heat duty (MJ/hr)
In
Stream 11
Pressure (bar) 3

rate fraction

CH3C(O)CH2CH3 117.81 0.93
H2 0.00 0.00
H2O 2.56 0.02
Total 126.57 1.00
Stream enthalpy (MJ/hr) 3.01
Heat duty (MJ/hr)
Stream 12
Pressure (bar) 3

rate fraction

CH3C(O)CH2CH3 117.81 0.93
H2 0.00 0.00
H2O 2.56 0.02
Total 126.57 1.00
Stream enthalpy (MJ/hr)
Heat duty (MJ/hr)
In
Stream 13
Pressure (bar) 3

rate fraction

CH3C(O)CH2CH3 486.67 1.00
H2 0.00 0.00
H2O #VALUE! 0.00
Total 487.05 1.00
Heat duty (MJ/hr)
V-302 Reflux dr
In
Stream 14
Pressure (bar) 3

rate fraction

CH3C(O)CH2CH3 486.67 1.00
H2 0.00 0.00
H2O 0.00 0.00
Total 487.05 1.00
Heat duty (MJ/hr)
In
Stream 15
Pressure (bar) 3

rate fraction

CH3C(O)CH2CH3 486.67 1.00
H2 0.00 0.00
H2O 0.00 0.00
Total 487.05 1.00
Heat duty (MJ/hr)
In
Stream 18
Pressure (bar) 3

rate fraction

CH3C(O)CH2CH3 0.78 0.06
H2 0.00 0.00
H2O 3.40 0.28
Total 12.30 1.00
Heat duty (MJ/hr)
k, 7th Edition, Table 2-193 )
ΔHv at Tmin
Tmin, K Tmax, K ΔHv at Tmax
x 10-7
158.45 6.1383 536.05 0
186.48 3.9704 535.5 0
13.95 0.0913 33.19 0
273.16 4.4733 647.13 0
erature, T/Tc.
Edition, Table 2-196 & Table 2-198)

7th Edition, Table 2-196 for gas; Elementary Principles of Chemical Processes, 3rd Edition, Table B.1)
IDEAL GAS STATE Heat of formation

Gas
C5 C1 C2 C3 C4 C5 (J/kmol x 10E-
7)
0 82020 252200 1601 158640 -704.15 -29.29
0 78400 210320 1548.8 118550 693 -23.9
0 27620 9560 2466 3760 567.6 0
9.3701E-06 33360 26790 2610.5 8900 1169 -24.1814
l, at T ranging (273 – 2500)K.
3 x C4/2)t4 – (C42/5)t5. t = (1-Tr) and Tr is the reduced temperature, T/Tc.
𝐶_� ∆𝑇=𝐶1(𝑇−𝑇𝑟𝑒𝑓)+𝐶2×𝐶3[coth 〖 (𝐶3/𝑇)−coth(𝐶3/𝑇𝑟𝑒𝑓)] −𝐶4×𝐶5 [tanh(𝐶5/𝑇)−tanh(𝐶5/𝑇𝑟𝑒𝑓)] 〗
n, Table B.7)
350 400 450 500 550 600

3176 3278 3382 3468 3596 3705
P-101 Butanol feed pump

Out
2
300.15
1.05
Specific Energy flow, Molar flow Heat of Heat of Specific

enthalpy, ΔĤ ΔḢ rate enthalpy, ΔĤ
(J/kmol) (MJ/hr) (kmol/hr) fraction (J/kmol)
(J/kmol) (J/kmol)
-391745.83 -48.58 124.01 0.98 391745.83
-150737.21 -0.39 2.56 0.02 150737.21

-542483.03 -48.97 126.57 1.00 542483.03
48.97
0.00
5.72E+01
E-101 Thermosyphon vaporizer

Tube
Out
3
383.15
1.05

fraction
(J/kmol) (MJ/hr) (kmol/hr) (J/kmol) (J/kmol) (J/kmol)
-391745.83 -48.58 124.01 0.98 40920438.82 10696623.38
-150737.21 -0.39 2.56 0.02 40329289.90 2874061.51

-542483.03 -48.97 126.57 1.00 13570684.88
6511.71
6560.68
-
Tube
Out
4
573.15
1.05

fraction
-10696623.38 -1326.47 124.01 0.98 41239798.94
-2874061.51 -7.37 2.56 0.02 9527530.74

-13570684.88 -1333.84 126.57 1.00 50767329.68
4 5138.50
3804.66
-
C-101 Compressor
5
638.33
3

fraction
-41239798.94 -5114.07 124.01 0.98 53467272.55
-9527530.74 -24.43 2.56 0.02 11900165.02

-5.08E+07 -5138.50 126.57 1.00 65367437.57
0 6660.89
1522.39
422.89

Tube
Out
6
773.15
3

fraction
-53467272.55 -6630.38 124.01 0.98 81132030.75
-11900165.02 -30.51 2.56 0.02 15846880.73

-65367437.57 -6660.89 126.57 1.00 96978911.48
9 10101.67
3440.78
-
R-201 Fixed Bed Reactor
Out
7
773.15
3

fraction
-81132030.75 -46383.04 6.20 0.03 -292900000.00 81132030.75

117.81 0.48 -239000000.00 71191601.03
117.81 0.48 0.00 13905967.67
-16965847.37 -663.50 2.56 0.01 -241814000.00 16965847.37
-98097878.13 -47046.54 244.38 1.00 183195446.83
4 -20020.45
27026.08
-
E-301 Cooler
Tube
Out
9
298.15
3
fraction
-29657701.99 -183.89 6.20 0.03 0.00

-26245867.74 -3091.97 117.81 0.48 0.00
-6084565.34 -716.81 117.81 0.48 0.00
-7162503.32 -18.36 2.56 0.01 0.00
-69150638.40 -4011.03 244.38 1.00 0.00
3 0.00
-4011.03
-
V-301 Knock-out drum

Out
10
298.00
3

fraction
29228.48 0.18
23795.49 2.80
4316.70 0.51 117.81 1.00 -4316.70
11307.81 0.03
68648.48 3.52 117.81 1.00 -4316.70
-3.52
0.00
-
E-302 Heater
Tube
Out
12
397.88
3

fraction
29228.48 0.18 6.20 0.05 37984290.17 12755912.96

23795.49 2.80 117.81 0.93 829835.31 11406130.85
11307.81 0.03 2.56 0.02 39590470.79 3377405.75

64331.78 3.01 126.57 1.00 78404596.26 27539449.56
1866.27
1869.28
-
In
16
390.74
3

fraction
-25210533.06 -156.32 0.29 0.00 -22954135.87

-16874625.09 -1987.96 369.45 1.00 -15574265.34
0.00 0.00
-7547375.77 -19.35 0.00 0.00
-49632533.91 -2163.63 369.74 1.00 -38528401.21
-7957.24
E-303 Condenser
Tube
Out
14
390.74
3

fraction
-11750279.32 -4.54 0.39 0.00 -38909418.44 22954135.87

-7263574.15 -3534.94 486.67 1.00 -29050306.77 15574265.34
0.00 0.00
-19013853.47 -3539.48 487.05 1.00 38528401.21
8 -6564.51
-10103.99
-
V-302 Reflux drum

Out
15
390.74
3

fraction
-22954135.87 -8.86 0.39 0.00 22954135.87

-15574265.34 -7579.49 486.67 1.00 15574265.34
0.00 0.00
-38528401.21 -7588.35 487.05 1.00 38528401.21
5 7588.35
0.00
-
Splitting point
Out
16
390.74
3

fraction
-22954135.87 -8.86 0.29 0.00 22954135.87

-15574265.34 -7579.49 369.45 1.00 15574265.34
0.00 0.00
0.00 0.00
-38528401.21 -7588.35 369.74 1.00 38528401.21
5 7588.3
0.00
-
Tube
Out
19
405.03
3

fraction
-27548445.51 -223.39 2.00 0.66 37033812.37 13774964.63

-18193602.97 -14.23 0.19 0.06 817918.58 12306340.03
-8096164.40 -27.56 0.84 0.28 39215878.07 3622103.70

-53838212.89 -265.18 3.03 1.00 29703408.36
319.20
54.01
Heat of formation
Liquid (kJ/mol)
0
0
-285.84
(𝐶5/𝑇)−tanh(𝐶5/𝑇𝑟𝑒𝑓)] 〗
Energy flow, ΔḢ
(MJ/hr)
48.58
0.39
48.97
hermosyphon vaporizer
Shell
In
7
773.15
3
Heat of Heat of
Energy flow, ΔḢ Molar flow Specific enthalpy, Energy flow,
rate ΔĤ ΔḢ
(MJ/hr) fraction
(kmol/hr) (J/kmol) (J/kmol) (J/kmol) (MJ/hr)
6400.94 6.20 0.03 -81132030.75 -503.05

117.81 0.48 -71191601.03 -8386.92
117.81 0.48 -13905967.67 -1638.23
110.77 2.56 0.01 -16965847.37 -43.50
6511.71 244.38 1.00 -183195446.83 -10571.71
-10571.71
-6560.68
-
ll & Tube Heat Exchanger
Shell
In
Superheated steam
873.15
1
Heat of Heat of
Energy flow, ΔḢ Molar flow Mass flow Specific enthalpy, Energy flow,
rate rate formation, Hf vaporization, Hv ΔĤ ΔḢ
(MJ/hr) (kmol/hr) (ton/hr) (J/kmol) (J/kmol) (J/kmol) (MJ/hr)
5114.07
24.43 495.01 8.92 66690000.00 33012.36

5138.50 495.01 8.92 66690000.00 33012.36
33012.36
-3804.66
-
Energy flow, ΔḢ
(MJ/hr)
6630.38
30.51
6660.89
ll & Tube Heat Exchanger

Shell
In
Superheated steam
873.15
1
Heat of Heat of
10061.04
40.63 447.67 8.06 66690000.00 29854.98

10101.67 447.67 8.06 66690000.00 29854.98
29854.98
-3440.78
-
1 Fixed Bed Reactor

Shell
In
Superheated steam
873.15
1
Heat of Heat of
-1313.05
-19769.14
1638.23
-576.50 3516.27 63.35 66690000.00 234500.32
-20020.45 3516.27 63.35 66690000.00 234500.32
234500.32
-27026.08
-
E-301 Cooler
Shell
In
Cold Water
303.15
1
Heat of Heat of
0.00
0.00
0.00
0.00 2130.83 38.39 -376738.05 -802.76
0.00 2130.83 38.39 -376738.05 -802.76
-802.76
4011.03
-
Out
11
298.00
3
Heat of Heat of
rate ΔĤ ΔḢ
(MJ/hr) fraction
6.20 0.05 -29228.48 -0.18

117.81 0.93 -23795.49 -2.80
-0.51
2.56 0.02 -11307.81 -0.03
-0.51 126.57 1.00 -64331.78 -3.01
-3.52
E-302 Heater
Shell
In
Superheated steam
623.15
1
Heat of Heat of
314.61
1441.49
110.17 516.66 9.31 57168000.00 29536.54

1866.27 516.66 9.31 57168000.00 29536.54
29536.54
-1869.28
-
T-301 Distillation column
19
405.03
3
Heat of Heat of
rate ΔĤ ΔḢ
(MJ/hr) fraction
-6.73 2.00 0.66 -13774964.63 -27.57

-5753.89 0.19 0.06 -12306340.03 -2.38
0.00 0.00
0.84 0.28 -3622103.70 -3.04
-5760.62 3.03 1.00 -29703408.36 -32.99
-2145.28
-
E-303 Condenser
Shell
In
Cold Water
303.15
1
Heat of Heat of
-6.16
-6558.35
0.04 0.0006 166800.97 5908.42

-6564.51 0.04 0.0006 166800.97 5908.42
5908.42
10103.99
-
Energy flow, ΔḢ
(MJ/hr)
8.86
7579.49
7588.35
Out
17
390.74
3
Heat of Heat of
rate ΔĤ ΔḢ
(MJ/hr) fraction
6.73 0.09 0.00 22954135.87 2.13

5753.89 117.22 1.00 15574265.34 1825.60
0.00 0.00
0.00 0.00
5760.62 117.31 1.00 0.00 38528401.21 1827.73
7588.35

Out
20
405.03
3
Heat of Heat of
rate ΔĤ ΔḢ
(MJ/hr) fraction
101.70 6.11 0.91 27548445.51 168.25

2.53 0.59 0.09 18193602.97 10.72
36.00 -8096164.40 0.00

140.23 6.70 1.00 37645884.09 178.97
319.20
-
Shell
Out
8
506.83
3
Molar flow Heat of Heat of Specific Energy flow,

Mole formation, Hf vaporization, Hv enthalpy, ΔĤ
rate ΔḢ
fraction
6.20 0.03 29657701.99 183.89

117.81 0.48 26245867.74 3091.97
117.81 0.48 6084565.34 716.81
2.56 0.01 7162503.32 18.36
244.38 1.00 69150638.40 4011.03
4011.03
-6560.68 1.9947E-07
Shell
Out
Superheated steam
673.15
1
Molar flow Mass flow Heat of Heat of Specific Energy flow,

rate rate formation, Hf vaporization, Hv enthalpy, ΔĤ ΔḢ
(kmol/hr) (ton/hr) (J/kmol) (J/kmol) (J/kmol) (MJ/hr)
495.01 8.92 59004000.00 29207.70

495.01 8.92 59004000.00 29207.70
29207.70 -3804.6632
-3804.66 0
Shell
Out
Superheated steam
673.15
1

447.67 8.06 59004000.00 26414.20

447.67 8.06 59004000.00 26414.20
26414.20 -3440.7759
-3440.78 0
Shell
Out
Superheated steam
673.15
1

3516.27 63.35 59004000.00 207474.24

3516.27 63.35 59004000.00 207474.24
207474.24
-27026.08 0.00
Shell
Out
Cold Water
318.15
2130.83 38.39 1505645.33 3208.27

2130.83 38.39 1505645.33 3208.27
3208.27 4011.03089
4011.03 0
Shell
Out
Superheated steam
523.15
1

516.66 9.31 53550000.00 27667.26
516.66 9.31 53550000.00 27667.26
27667.26 -1869.2837
-1869.28 0
Out
13
390.74
3
Molar flow Heat of Heat of Specific Energy flow, Molar flow

Mole formation, Hf vaporization, Hv enthalpy, ΔĤ Mole
rate ΔḢ rate
fraction fraction
(kmol/hr) (J/kmol) (J/kmol) (J/kmol) (MJ/hr) (kmol/hr)
0.39 0.00 38909418.44 11750279.32 19.56 8.11 0.66

486.67 1.00 840614.78 10516663.71 5527.22 0.78 0.06
0.00 0.00 0.00 0.00
0.00 0.00 3.40 0.28
487.05 1.00 22266943.02 5546.78 12.30 1.00
5811.96
Shell
Out
Cold Water
304.15
1

0.04 0.0006 452047.42 16012.41

0.04 0.0006 452047.42 16012.41
16012.41 10103.9915
10103.99 0
Shell
In
Superheated Steam Sup
523.15
1
Molar flow Mass flow Heat of Heat of Specific Energy flow, Molar flow Mass flow
rate rate formation, Hf vaporization, Hv enthalpy, ΔĤ ΔḢ rate rate
(kmol/hr) (ton/hr) (J/kmol) (J/kmol) (J/kmol) (MJ/hr) (kmol/hr) (ton/hr)
15.08 0.27 53550000.00 807.51 15.08 0.27

15.08 0.27 53550000.00 807.51 15.08 0.27
807.51
-54.01
18
405.03
3
Heat of Heat of Specific Energy flow,

formation, Hf vaporization, Hv enthalpy, ΔĤ ΔḢ
(J/kmol) (J/kmol) (J/kmol) (MJ/hr)
27548445.51 223.39
18193602.97 14.23
8096164.40 27.56
53838212.89 265.18
Out
Superheated Steam
423.15
1
Heat of Heat of Specific Energy flow,

formation, Hf vaporization, Hv enthalpy, ΔĤ ΔḢ
(J/kmol) (J/kmol) (J/kmol) (MJ/hr)
49968000.00 753.49
49968000.00 753.49
753.49 -54.0149
5.68E-14
1 day 24 hrs
Number of operation days 350 d/yr
Superheated steam
Temperature of
superheated steam Temperature
Unit Code (K) range on process
In Out stream (K)
0 (Isothermal
Fixed-Bed reactor R-201 873.15 673.15 endothermic
reaction)
Shell & Tube Heat Exchanger E-102 873.15 673.15 190.00
Shell & Tube Heat Exchanger E-103 873.15 673.15 134.82
Heater E-302 623.15 523.15 99.88
Kettle reboiler E-304 523.15 423.15 0 (Phase change)
Total
Cooling water
Temperature of Temperature
Unit Code cooling water(K) range on process
In Out stream (K)
Cooler E-301 303.15 318.15 497.83
Condenser E-303 303.15 304.15 0 (Phase change)
Total
Electricity
Unit Code Power requirement (kW)
Butanol Feed Pump P-101 5.72E+01

Compressor C-101 4.23E+02
Total 4.80E+02
�_𝐿=𝐶1/ 〖𝐶 2 〗 ^[1+(1−𝑇/𝐶3)^𝐶4 ]
Liquid density (From Perry's Chemical Engineer's Handbook, 7th Edition, Table 2-30)
C1 C2 C3 C4 Tmin, K
CH3CH(OH)CH2CH3 0.966 0.2606 536.05 0.2746 158.45
H2O 5.459 0.3054 647.13 0.081 273.16
hi
Required flow rate
Heat duty, Q
MJ/hr MJ/yr kmol/hr kmol/yr ton/hr ton/yr
27026.08 227019097.32 3516.27 29536702.748 63.35 532113.742
3804.66 31959170.90 495.01 4158101.86 8.92 74909.62

3440.78 28902517.18 447.67 3760410.77 8.06 67745.08
1869.28 15701982.82 516.66 4339962.08 9.31 78185.89
54.01 453725.36 15.08 126668.16 0.27 2281.97
36194.82 304036493.59 4990.70 41921845.63 89.91 755236.30
Required flow rate

Heat duty, Q
MJ/hr MJ/yr kmol/hr kmol/yr ton/hr ton/yr
4011.03 33692659.4973 2130.83 17898935.956 38.39 322455.417
10103.99 84873528.9112 0.0354 297.54455457 0.0006 5.36036632
14115.02 118566188.408 2130.86 17899233.5 38.39 322460.777
Power requirement
(kWh/year)
480550.88
3552243.87
4032794.75
Density at Tmin Tmax, K Density at TmDensity (kmol Density (ton Actual density
12.57 536.05 3.706 10.840558157 0.80354228 0.78726498
55.583 333.15 54.703 55.202453877 0.99449098 0.02014534
0.80741032
ctual density
C-101 Compressor
Pressure in (bar) 1.05

Pressure out (bar) 3
Heat capacities of components (Average)
IDEAL GAS STATE
C1 C2 C3 C4 C5
Mole fraction
Sec-butanol 0.98 82020 252200 1601 158640 -704.15
Methyl ethyl ketone 0.00 78400 210320 1548.8 118550 693
Hydrogen 0.00 27620 9560 2466 3760 567.6
Water 0.02 33360 26790 2610.5 8900 1169
Average 81034.298 247633.88 1621.4494 155606.73 -666.2057
𝑇_𝑜𝑢�/𝑇_𝑖𝑛 =(𝑃_𝑜𝑢�/𝑃_𝑖𝑛 )^((𝛾−1)/𝛾)

Gas constant, R 8.314 J/mol.K
8314 J/kmol.K
Temperature in (K) 573.15 573.15 573.15 573.15

Temperature out (K) 602.09805 638.33146 638.33138
Cp average (J/kmol.K) 177140.589171 81034.298 81034.384 81034.384
gamma 1.0492457974 1.1143285 1.1143283 1.1143283
𝛾=𝐶_�/(𝐶_�−𝑅)
Cp average (J/kmolK) ɣ
177140.589170943 1.0492458
1 day 24 hrs
Number of days of operation 350 days

Yearly production for MEK 71000 ton/yr
Production flow rate for MEK 8.45 ton/hr
2-Butanol flow rate for production 9.24 ton/hr
Yield of MEK (%) 91.9542064684 %
Yield of Hydrogen (%) 2.5837120921 %
Mass Flow Rate (ton/yr)

Conversion (%) Reactant Products
2-Butanol MEK
10 77600.35 7473.48
20 77600.35 14946.96
30 77600.35 22421.28
40 77600.35 29894.76
50 77600.35 37368.24
60 77600.35 44841.72
70 77600.35 52316.04
80 77600.35 59789.52
90 77600.35 67263.00
95 77600.35 71000.16
97.5 77600.35 72868.32
99.5 77600.35 74363.52
100 77600.35 74736.48
Component Price (RM/tonne)
2-Butanol 4558.71
MEK 7045.23
Hydrogen 2901.00
Rate (ton/yr) Cost (RM/yr)

Products
Reactant Products
Hydrogen Gross profit
210.00 353757325.72 53261557.29 -3.00E+08
420.00 353757325.72 106523114.59 -2.47E+08
630.00 353757325.72 159790589.87 -1.94E+08
840.00 353757325.72 213052147.16 -1.41E+08
1050.00 353757325.72 266313704.45 -8.74E+07
1260.00 353757325.72 319575261.75 -3.42E+07
1470.00 353757325.72 372842737.03 1.91E+07
1680.00 353757325.72 426104294.32 7.23E+07
1890.00 353757325.72 479365851.62 1.26E+08
1995.00 353757325.72 505999589.26 1.52E+08
2047.08 353757325.72 519312280.66 1.66E+08
2089.08 353757325.72 529968142.92 1.76E+08
2100.00 353757325.72 532627408.91 1.79E+08

Group 1 Mass &amp; Energy Balance

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Group 1 Mass &amp; Energy Balance

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1 day 24 hrs

Molecular weight of components

Basis 9.24 ton/hr

Number of days of operation 350 days

Composition of feed butanol is 99.5 wt%

CH3CH(OH)CH2CH3 124.01 0.98

E-102 Shell & Tu

CH3CH(OH)CH2CH3 124.01 0.98

Process stream is compressed from 1 bar to 3 bar

CH3CH(OH)CH2CH3 124.01 0.98

E-103 Shell & Tu

CH3CH(OH)CH2CH3 124.01 0.98

CH3CH(OH)CH2CH3 124.01 0.98

CH3CH(OH)CH2CH3 6.20 0.03

CH3CH(OH)CH2CH3 6.20 0.05

CH3CH(OH)CH2CH3 6.20 0.05

CH3CH(OH)CH2CH3 0.39 0.00

Reflux ratio Rm = 2.1011917597

CH3CH(OH)CH2CH3 0.39 0.00

Boil up ratio S= 0.3277356351

P-101 Butanol feed pump

0.05 0.01 2.56 0.02

9.19 1.00 124.01 0.98

0.05 0.01 2.56 0.02

E-102 Shell & Tube Heat Exchanger

9.19 1.00 124.01 0.98

0.05 0.01 2.56 0.02

9.19 1.00 124.01 0.98

0.05 0.01 2.56 0.02

E-103 Shell & Tube Heat Exchanger

9.19 1.00 124.01 0.98

0.05 0.01 2.56 0.02

R-201 Fixed Bed Reactor

9.19 1.00 6.20 0.03

0.46 0.05 6.20 0.03

V-301 Knock-out drum

0.46 0.05 6.20 0.05

0.46 0.05 0.29 0.00

0.03 0.00 0.39 0.00

V-302 Reflux drum

0.03 0.00 0.39 0.00

E-304 Kettle reboiler

E-101 Thermosyphon vaporizer

9.19 1.00 6.20 0.03

T-301 Distillation column

0.02 0.00 2.00 0.66

0.46 0.05 6.20 0.03

0.15 0.84 0.39 0.00

0.03 0.00 8.11 0.66

At distillate Recovery of LK 0.995

Mole flow rate Mass flow rate

Dew point 117.7398577787 C

Feed Vapour Pressure

Vapor pressure of component

Bubble point 132.0257088941 C

Feed Vapour Pressure

Vapor pressure of component

Bubble point temperature 132.0257088941 C

Feed, xiF Distillate, yi = xiD Vapour pressure

�=(𝑅+𝑞) (𝑥_𝐹−𝑥_𝐷)/(𝑥_𝐵−𝑥_𝐹 )+𝑞−1

Total molar flow rate at S-18 12.2953714503

At bottom Recovery of LK 0.005

Mole flow rate Mass flow rate

Group 1 Mass & Energy Balance

Group 1 Mass & Energy Balance