Clariant Mining

Non-Sulfide ores

Clariant MINING
2645 Technology Forest Blvd.
The Woodlands, Texas 77381
Tel: +1 281-465-9100
Fax: +1 281-465-9200
www.MINING.clariant.com

This information corresponds to the present state of our knowledge and is intended as a general descrip-
tion of our products and their possible applications. Clariant makes no warranties, express or implied,
as to the information’s accuracy, adequacy, sufficiency or freedom from defect and assumes no liability
in connection with any use of this information. Any user of this product is responsible for determining
the suitability of Clariant’s products for its particular application. * Nothing included in this information
waives any of Clariant’s General Terms and Conditions of Sale, which control unless it agrees otherwise
in writing. Any existing intellectual/industrial property rights must be observed. Due to possible changes
in our products and applicable national and international regulations and laws, the status of our products
could change. Material Safety Data Sheets providing safety precautions, that should be observed when
handling or storing Clariant products, are available upon request and are provided in compliance with
applicable law. You should obtain and review the applicable Material Safety Data Sheet information before
handling any of these products. For additional information, please contact Clariant.® Trademark of
Clariant registered in numerous countries.

* For sales to customers located within the United States and Canada the following applies in addition:
NO EXPRESS OR IMPLIED WARRANTY IS MADE OF THE MERCHANTABILITY, SUITABILITY,

CM-012013
FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE OF ANY PRODUCT OR SERVICE.

© 2012 Clariant International AG, Rothausstrasse 61, 4132 Muttenz, Schweiz

® Product and service marks protected by Clariant
Clariant Mining
Non-Sulfide Ores
Metal/Element clariant Collectors
Ore Type Major Minerals
Values Applications Product Class of Actives
Direct flotation of barite FLOTINOR® FS-100 fatty acids
Ba Barite
Barite If gangue material makes selective flotation of Barite difficult FLOTINOR® FS-2 fatty acids
Clariant Frothers
Applications Product Class of Actives
Flotation of coarse particles FLOTANOL® 7026 fraction of terpene alcohols
For varying or specific conditions (tailor-made frother polypropylene glycol and polypropylene glycol
FLOTANOL® grades
blends) methyl ether
Modifiers
Applications Product Class of Actives
To regulate pH soda Na2CO3
To depress gangue water glass Na2SiO3
For a depressant for fluorspar citric acid C6H8O7
To activate Barite barium chloride BaCl2

Metal/Element Clariant Collectors

Ore Type Major Minerals
Values Applications Product Class of Actives
Smithsonite, Hemimorphite, To enhance performance used in combination with FLOTIGAM® 2835, FLOTIGAM®
Zn alkyl ether di-amine
Calamine Willemite, Hydrozinkite xanthate over just xanthate 2835-2, FLOTIGAM® 2835-2L
Clariant Frothers
Applications Product Class of Actives
FLOTANOL® 7026 fraction of terpene alcohols
Flotation of coarse particles FLOTANOL® M MIBC
MONTANOL® 800 mixture of aliphatic alcohols, ethers and esters
Clariant Additives
Applications Product Class of Actives
Additives to be used as a co-collector with xanthates FLOTIGAM® 2835 alkyl ether di-amine
Modifiers
Applications Product Class of Actives
To regulate pH caustic soda NaOH
For a sulfidizing agent for calamine ("activator") sodium sulfide Na2S
For a dispersant, depressant for gangue material water glass Na2SiO3

Metal/Element clariant Collectors

Ore Type Major Minerals
Values Applications Product Class of Actives
FLOTIGAM® K2C quaternary alkyl amine
Calcite, Ca, Mg Calcite, Magnesite For reverse calcite flotation FLOTINOR® 4815 quaternary alkyl amine formulation
Magnesite FLOTIGAM® ITU, FLOTIGAM® 7079 imidazoline
Clariant Frothers
Applications Product Class of Actives
FLOTANOL® 7026 fraction of terpene alcohols
polypropylene glycol and polypropylene glycol
FLOTANOL® D-25
For flotation of graphite out of calcite methyl ether
MONTANOL® 88 alcohol formulation
MONTANOL® 800 mixture of aliphatic alcohols, ethers and esters
Modifiers
Applications Product Class of Actives
Modifier not typically used

Metal/Element clariant Collectors

Ore Type Major Minerals
Values Applications Product Class of Actives
HOSTAPHAT® 7053 alkane phosphonic acid
For a very selective cassiterite collector; add in several
Cassite- Sn Cassiterite FLOTINOR® 3635 alkyl sulphosuccinate
portions to enhance selectivity
rite FLOTINOR® 1682 phosphoric acid ester
Clariant Frothers
Applications Product Class of Actives
FLOTANOL® C 07 polypropylene glycol
FLOTANOL® 7026 fraction of terpene alcohols
Flotation of coarse particles
polypropylene glycol and polypropylene glycol
FLOTANOL® D-25
methyl ether
MONTANOL® 88 alcohol formulation
Flotation of fine particles
MONTANOL® 800 mixture of aliphatic alcohols, ethers and esters
Modifiers
Applications Product Class of Actives
To regulate pH sulfuric acid H2SO4

Metal/Element Collectors
Ore Type Major Minerals
Values Applications Product Class of Actives
C Coal fatty acids, fuel oil, kerosene
Coal Clariant Frothers
Applications Product Class of Actives
MONTANOL® grades mixture of aliphatic alcohol, ethers and esters
Modifiers
Applications Product Class of Actives
Modifier not typically used

Metal/Element clariant Collectors

Ore Type Major Minerals
Values Applications Product Class of Actives
For the flotation of fine grained feldspar to enhance FLOTIGAM® 2835, FLOTIGAM®
alkyl ether di-amine
Feldspar selectivity 2835-2, FLOTIGAM® 2835-2L
For a liquid feldspar collector with very high flash point (> 100 °C) FLOTIGAM® 4343 alkyl di-amine
Al, Si Orthoklase, Albite, Anorthite
FLOTIGAM® 7034 primary amine
Direct flotation FLOTIGAM® DAT alkyl di-amine
FLOTIGAM® EDA alkyl ether amine
Clariant Frothers
Applications Product Class of Actives
Flotation of coarse particles FLOTANOL® 7026 fraction of terpene alcohols
Modifiers
Applications Product Class of Actives
To regulate pH sulfuric acid H2SO4
To activate feldspar hydrofluoric acid or sodium fluoride HF or NaF

Metal/Element clariant Collectors

Ore Type Major Minerals
Values Applications Product Class of Actives
To be used with other anionic collectors to enhance FLOTINOR® FS-2,
fatty acids
Fluorite performance depending on the application FLOTINOR® FS-100
(Fluor- F Fluorite Collectors recommended for use in combination with FLOTINOR® SM 15, FLOTINOR® V 2711 phosphoric acid esters
spar) Flotinor® FS-types FLOTINOR® 2818 modified sodium carboxylate
Direct flotation FLOTIGAM® 5806 fatty acid formulation
Clariant Frothers
Applications Product Class of Actives
Flotation of coarse particles FLOTANOL® C 07, FLOTANOL® D-25 polypropylene glycol
Flotation of fine particles MONTANOL® 800 mixture of aliphatic alcohols, ethers and esters
For very selective fluorite flotation, use frother in
FLOTANOL® D 14 polypropylene glycol methyl ether
combination with FLOTINOR® 2818
Modifiers
Applications Product Class of Actives
To regulate pH soda Na2CO3
For a dispersant, depressant for gangue material water glass Na2SiO3
For a depressant for gangue material quebracho tannin -

Metal/Element clariant Collectors

Ore Type Major Minerals
Values Applications Product Class of Actives
For biotite flotation. Combining with FLOTINOR® FS-
FLOTINOR® SM 15 phosphoric acid ester
Glass types can be beneficial
Sand Collector recommended for use in combination with
FLOTINOR® 3635 sulphosuccinic acid ester
FLOTINOR® FS-types or/and FLOTINOR® SM 15
Depending on the case of application, these collectors in
FLOTINOR® FS-2,
combination with FLOTINOR® 3635 or/and FLOTINOR® fatty acids
Si, Al, K, Na, Ca, Quartz, Feldspar, Heavy Metal FLOTINOR® FS-100
SM 15 can be beneficial
Fe, Ti Oxides, Mica
FLOTIGAM® EDA, FLOTIGAM®
For muscovite flotation EDA C, FLOTIGAM® EDA 3, alkyl ether amine
FLOTIGAM® EDA 3C
For the flotation of fine grained feldspar to enhance FLOTIGAM® 2835, FLOTIGAM®
alkyl ether di-amine
selectivity 2835-2, FLOTIGAM® 2835-2L
For a liquid feldspar collector with very high flash point (> 100 °C) FLOTIGAM® 4343 alkyl di-amine
Clariant Frothers
Applications Product Class of Actives
FLOTANOL® 7026 fraction of terpene alcohols
Flotation of coarse particles polypropylene glycol and plypropylene glycol
FLOTANOL® D-25
methyl ether
Modifiers
Applications Product Class of Actives
To regulate pH sulfuric acid H2SO4

Metal/Element Collectors
Ore Type Major Minerals
Values Applications Product Class of Actives
C Graphite kerosene
Graphite Clariant Frothers
Applications Product Class of Actives
FLOTANOL® 7026 fraction of terpene alcohols
Flotation of coarse particles polypropylene glycol and polypropylene
FLOTANOL® D-25
glycol methyl ether
MONTANOL® 88 alcohol formulation
Flotation of fine particles
MONTANOL® 800 mixture of aliphatic alcohols, ethers and esters
Modifiers
Applications Product Class of Actives
To regulate pH caustic soda NaOH

Metal/Element clariant Collectors

Ore Type Major Minerals
Values Applications Product Class of Actives
Collector to be used in combination with Flotinor® FS-
FLOTINOR® 3635 sulphosuccinic acid ester
Heavy types or/and Flotinor® SM 15 recommended
Metal Depending on the case of application, these collectors in
FLOTINOR® FS-2,
Oxides Fe, Ti Biotite, Ilmenite, Rutile combination with FLOTINOR® 3635 or/and FLOTINOR® fatty acids
FLOTINOR® FS-100
SM 15 can be beneficial
For biotite flotation; combining with FLOTINOR® FS-
FLOTINOR® SM-15 phosphoric acid ester
types can be beneficial
Frothers
Applications Product Class of Actives
Frother not typically used
Modifiers
Applications Product Class of Actives
To regulate pH sulfuric acid H2SO4

Metal/Element clariant Collectors

Ore Type Major Minerals
Values Applications Product Class of Actives
FLOTIGAM® EDA, FLOTIGAM®
alkyl ether amine
Iron Ores For reverse hematite flotation EDA-C
FLOTIGAM® V 5444 alkyl ether mono-amine blend
FLOTIGAM® 5806 fatty acid formulation
Fe Hematite, Magnetite
For direct hematite flotation FLOTINOR® FS-2 fatty acids
FLOTINOR® 1682 phosphoric acid ester
FLOTIGAM® 3135, FLOTIGAM® 2835-2L
For reverse magnetite flotation alkyl ether di-amine
FLOTIGAM® 2835, FLOTIGAM® 2835-2
Clariant Frothers
Applications Product Class of Actives
MONTANOL® 88 alcohol formulation
To support flotation of non quartz silicates
MONTANOL® 800 mixture of aliphatic alcohols, ethers and esters
Modifiers
Applications Product Class of Actives
To regulate pH caustic soda NaOH
For a depressant for hematite caustic corn starch -

Metal/Element clariant Collectors

Ore Type Major Minerals
Values Applications Product Class of Actives
Al, Si Kaolinite Flotation of coarse particles FLOTIGAM® 7034 alkyl amine
Kaolin Frothers
Clay Applications Product Class of Actives
Frother not typically used
Modifiers
Applications Product Class of Actives
To regulate pH sulfuric acid H2SO4
To activate feldspar hydrofluoric acid or sodium fluoride HF or NaF
For a coagulant for kaolinite Alumina sulfate Al2(SO4)3

Metal/Element clariant Collectors

Ore Type Major Minerals
Values Applications Product Class of Actives
FLOTIGAM® EDA, FLOTIGAM®
Phosphate EDA 3, FLOTIGAM® EDA-C, alkyl ether amine
For reverse flotation of coarse silica particles
FLOTIGAM® EDA 3C
FLOTIGAM® V 5444 alkyl ether amine blend
FLOTIGAM® 3135, FLOTIGAM®
For reverse flotation of fine silica particles and high
2835, FLOTIGAM® 2835-2L, alkyl ether di-amine
selectivity is required
FLOTIGAM® 2835-2, FLOTINOR® 5442
P Apatite, Phosphorite
For direct apatite flotation; combination with FLOTINOR® FLOTINOR® FS-2, FLOTINOR® FS-5,
fatty acid
2818 can be beneficial FLOTINOR® FS-100
For reverse phosphorite flotation; usage in combination with FLOTINOR® SM 15,
phosphoric acid ester
FLOTIGAM® 3135, EDA-types and 2835 types recommended FLOTINOR® V 2711
For direct apatite flotation; combination with Flotinor
FLOTINOR® 2818 modified sodium carboxylate
FS-types recommended
Direct apatite flotation FLOTIGAM® 5806 fatty acid formulation
Clariant Frothers
Applications Product Class of Actives
Flotation of fine particles MONTANOL® 800 mixture of aliphatic alcohol, ethers and esters
Clariant additives
Applications Product Class of Actives
A depressant for carbonate minerals FLOTICOR® AD 7013 nonyl phenol polyglycolether

Metal/Element clariant Collectors

Ore Type Major Minerals
Values Applications Product Class of Actives
For very warm brine temperatures (> 40 °C); FLOTIGAM® S alkyl amines
K Sylvite
Potash Flotigam® V 5070 used in particular FLOTIGAM® V 5070 alkyl amines
Clariant Frothers
Applications Product Class of Actives
Flotation of coarse particles FLOTANOL® C 07 polypropylene glycol
For a specialized frother for potash flotation FLOTANOL® F alkyl polyglycol ether
Flotation of coarse particles FLOTANOL® 7026 fraction of terpene alcohols
MONTANOL® 88 alcohol formulation
Flotation of fine particles
MONTANOL® 800 mixture of aliphatic alcohols, ethers and esters
Modifiers
Applications Product Class of Actives
For a depressant for clay guar -

Metal/Element clariant Collectors

Ore Type Major Minerals
Values Applications Product Class of Actives
For a collector where no desliming may be necessary FLOTIGAM® 7033 alkylenetriamine
Nb Pyrochlore
Pyro- Flotation of pyrochlore FLOTIGAM® 7014 alkylenetriamine formulation
chlore Frothers
Applications Product Class of Actives
Frother not typically used
Clariant additives
Applications Product Class of Actives
For flotation of pyrochlore; Especially used in combination FLOTICOR® AD 7031,
fatty acid polyglycol ester
with FLOTIGAM® 7014 FLOTICOR® WA 7032

Metal/Element clariant Collectors

Ore Type Major Minerals
Values Applications Product Class of Actives
Recommended collector to be used in combination with FLOTINOR® FS-2,
fatty acids
Scheelite W FLOTINOR® 2818 FLOTINOR® FS-100
Scheelite
To increase selectivity use in combination with
FLOTINOR® 2818 modified sodium carboxylate
FLOTINOR® FS-types
Clariant Frothers
Applications Product Class of Actives
FLOTANOL® 7026 fraction of terpene alcohols
Flotation of coarse particles polypropylene glycol and polypropylene
FLOTANOL® D-25
glycol methyl ether
MONTANOL® 88 alcohol formulation
Flotation of fine particles
MONTANOL® 800 mixture of aliphatic alcohols, ethers and esters
Modifiers
Applications Product Class of Actives
To regulate pH soda ash Na2CO3
Dispersant and depressant water glass Na2SiO3

Metal/Element clariant Collectors

Ore Type Major Minerals
Values Applications Product Class of Actives
Mg Talc To enhance recovery FLOTIGAM® 7034 alkyl amine
Talc Clariant Frothers
Applications Product Class of Actives
FLOTANOL® 7026 fraction of terpene alcohols
Flotation of coarse particles polypropylene glycol and polypropylene
FLOTANOL® D-25
glycol methyl ether
MONTANOL® 88 alcohol formulation
Flotation of fine particles
MONTANOL® 800 mixture of aliphatic alcohols, ethers and esters
Modifiers
Applications Product Class of Actives
For improving selectivity use to regulate pH sulfuric acid H2SO4

Clariant MINING
Contact your local Clariant representative for a
2645 Technology Forest Blvd.
The Woodlands, Texas 77381 solution that is tailored to meet your specific needs.
Tel: +1 281-465-9100
Fax: +1 281-465-9200

www.MINING.clariant.com
 Clariant Mining
Sulfide ores

Clariant MINING
2645 Technology Forest Blvd.
The Woodlands, Texas 77381
Tel: +1 281-465-9100
Fax: +1 281-465-9200
www.MINING.clariant.com

This information corresponds to the present state of our knowledge and is intended as a general descrip-
tion of our products and their possible applications. Clariant makes no warranties, express or implied,
as to the information’s accuracy, adequacy, sufficiency or freedom from defect and assumes no liability
in connection with any use of this information. Any user of this product is responsible for determining
the suitability of Clariant’s products for its particular application. * Nothing included in this information
waives any of Clariant’s General Terms and Conditions of Sale, which control unless it agrees otherwise
in writing. Any existing intellectual/industrial property rights must be observed. Due to possible changes
in our products and applicable national and international regulations and laws, the status of our products
could change. Material Safety Data Sheets providing safety precautions, that should be observed when
handling or storing Clariant products, are available upon request and are provided in compliance with
applicable law. You should obtain and review the applicable Material Safety Data Sheet information before
handling any of these products. For additional information, please contact Clariant.® Trademark of
Clariant registered in numerous countries.

* For sales to customers located within the United States and Canada the following applies in addition:
NO EXPRESS OR IMPLIED WARRANTY IS MADE OF THE MERCHANTABILITY, SUITABILITY,

CM-012013
FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE OF ANY PRODUCT OR SERVICE.

© 2012 Clariant International AG, Rothausstrasse 61, 4132 Muttenz, Schweiz

® Product and service marks protected by Clariant