Reactions of Arenea (A2) Cexemplfied by benzene anch mcthylbengene) ~ Benzene ar : pe 4 reachon - Clretrophilre Subshftion reaction, he halogenction ~ reaction with halogen Celoctophilic subshihation) Ly chien nation Ly bromination , 2. nitration Cebechophiic substAwion ) S. hy olrog enaition : 1. Hake qemetion — substitetion reaction with halogen Cjhering om byoming) raaged > Cla(on Br, ) in CCle conditions : helegen comer (Fe, FeCly on Fa Bry, AICy Ccedtelyst) 3M) at room Te nprnotuore observation > Steatay white Runes (He 1Be ) equedion CoH, HCl, ——> Cotlsce HHS2. Nitration ben rea dents concemtratid) FINO; + concentrated HS, Crdtration mixture) cotvyet conditions: reflux at 50 — 60°C observation + & yellow otl 1s Porinad, Crctroben 32K) sgenon Cok + TINO; ——> G tenn, +H20 a No, o 3. Hydreganction of benzene rea g out Ha 9~ cackedyst Pivahy divided nickel condition 150°C 5 20-200 odin equetion 2 ote + 8H, ——> CoH 2 GC : © CHa Oo ea eu 1 ba, bi fl, bons tne cucloheraneeachons math benrene | Aclogencction ~ reaction with hologen Fi Celechophibe subshhetion, > Chlertnation ) > bromchatton , 2. netrotion Celechophilic subst Ady) 3. hydregenoction 4. onrdhation of, Sie chain 5. reach'ohy Ayprcel of ethane, the athyl side chacn - under goes CH; & Frag vadicol subshiletion , OG \ the oromatie rig ~ Undlor 040 elechophilic snbstitotion Note: elechuphilic substihction - yuiher with prethy(bang rie = roma, Fh methyl peep donates elchons into the bangene nha Wiakeiteg ih more Susceptible fo elechoplelic ctack ~ sebstihchion Fokes place of He 2~ anol +- posrhons on THe bang ene es