Cisse sea ini ii Time Allowed: 1% hours eee Mac eoury Same as Chapter 1 “CHAPTER 12: Atoms eee a Secnon A 1. What is meant by the term stationary orbits in hydrogen atom? 2. The total energy of an electron in its groundistate is 13.6 eV. Give the significance of the negative value of energy. 3. What is the value of ionisation tential fc i for a hydrogen atom? po ‘4. Represent graphically the variation of number of alpha Particles scattered versus the angle of scattering in Geiger and Marsden experiment. 5. Give one reason which led Bohr to promulgate quantisation condition in hydrogen atom. 6. Using Bohr’s postulates of the atomic model, derive the expression for the radius of the nth orbit in hydrogen atom. Hence express the radius r, of the second orbit in terms of r,, the radius of the frst orbit. 7. Represent the Lyman, Balmer and Paschen spectral series of hydrogen atom by means of a diagram. 8. de-Broglie explained Bohr’s quantisation condition for stationary orbit in terms of matter waves. Use the hypothesis to get the quantisation of angular momentum condition. 9. The radius of the innermost electron orbit of a hydrogen atom is 5.3 x 10°'' m. What are the radii of the n = 2 and n = 3 orbits? 10. Use Rydberg's formula to get the longest wavelengths belonging to Lyman and Brackett series in hydrogen spectrum. (Use R = 1.1 x 107 m”'), Secnon C 11. (@) Using Bohr's model, obtain an expression for the speed of the electron in a hydrogen atom in the n orbit. (b) Calculate the orbital period in each of the first three levels. 12. A 12.5 eV electron beam is used to bombard gaseous hydrogen at room temperature. Upto which energy level the hydrogen atoms would be excited? Calculate the wavelength of the first member of Lyman and first member of Balmer series. 13. (a) Using Bohr’s postulate of quantisation of angular ‘momentum, show how de-Broglie hypothesis of ‘matter waves can be explaind for electron orbits in hydrogen atom, (b) The ground state energy of hydrogen atom is =13.6 eV. What ate the kinetic and potential energies of the electron in this state? 14, The electron, in a hydrogen atom, initially in a state of quantum number n, makes a transition to a state whose excitation energy, with respect to the ground state, is 10.2 eV. If the wavelength, associated with the photon emitted in this transition, is 487.5 mm, find the (i) energy in eV, and (i) value of the quantum umber, n, of the electron in its initial state. 15. (a) The energy levels of a hypothetical hydrogen- like atom are shown in the figure. Find out the transition, from the ones shown in the figure, which will result in the emission of a photon of wavelength 275 nm, (b) Which of these transitions corresponds to the emission of radiation of (i) maximum and Gi) minimum wavelength alae cat) -2ev tty 4-10 Secon D 16. Using Bohr’s postulates, derive the expression for the frequency of radiation emitted when electron in hydrogen atom undergoes transition from higher energy state quantum number (n) to the lower state (n,) When electron in hydrogen atom jumps from energy state n; = 4 to n, = 3, 2, 1, identify the spectral series to which the emission lines belong.